CN107354014A - A kind of detergent for improving chemical fibre anti-uv-ray - Google Patents

A kind of detergent for improving chemical fibre anti-uv-ray Download PDF

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Publication number
CN107354014A
CN107354014A CN201710506318.0A CN201710506318A CN107354014A CN 107354014 A CN107354014 A CN 107354014A CN 201710506318 A CN201710506318 A CN 201710506318A CN 107354014 A CN107354014 A CN 107354014A
Authority
CN
China
Prior art keywords
parts
detergent
chemical fibre
ray
quaternary ammonium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710506318.0A
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Chinese (zh)
Inventor
刘惠峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Datang Chemical Fiber Factory
Original Assignee
Taicang Datang Chemical Fiber Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taicang Datang Chemical Fiber Factory filed Critical Taicang Datang Chemical Fiber Factory
Priority to CN201710506318.0A priority Critical patent/CN107354014A/en
Publication of CN107354014A publication Critical patent/CN107354014A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/65Mixtures of anionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/1213Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • C11D3/42Brightening agents ; Blueing agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A kind of detergent for improving chemical fibre anti-uv-ray, it is characterised in that the detergent includes the component of following mass fraction:Nano-TiO2:11 17 parts;Ester based quaternary ammonium salt:22 40 parts;Lauryl sodium sulfate:14 28 parts;Carboxymethyl cellulose:39 parts;Sodium lactate:12 20 parts;Sodium tripolyphosphate:22 45 parts;Fluorescent whitening agent:0.2 2 parts;Essence:0.1 2 parts;Ethanol:4 13 parts;Water:24 46 parts.It is an object of the invention to provide a kind of detergent for improving chemical fibre anti-uv-ray, cationic surfactant ester based quaternary ammonium salt and anionic are added in detergent, forms imitated vesicle structure, UV resistant agent nano-TiO2It is wrapped in inside vesica, nano-TiO is gradually outwards discharged in washing process2, chemical & blended fabric is kept uvioresistant effect, protect the human-body safety of wearer.

Description

A kind of detergent for improving chemical fibre anti-uv-ray
Technical field
The present invention relates to a kind of detergent for improving chemical fibre anti-uv-ray.
Background technology
Research shows that the irradiation of appropriate ultraviolet is advantageous to health, but excessive ultraviolet can cause one to human body A little infringements, the textile with anti-uv-ray can protect the health of human body.Ultra-violet absorber makes a kind of light stabilizer, The ultraviolet part in light can be absorbed, and itself does not change.Most uvioresistant fabrics are all in the market It is that UV resistant agent is added during final finishing, repeatedly can gradually loses uvioresistant effect after washing during its shortcoming.
The content of the invention
To solve above-mentioned problem, washing for chemical fibre anti-uv-ray is improved it is an object of the invention to provide a kind of Agent is washed, cationic surfactant ester based quaternary ammonium salt and anion surfactant dodecyl sulphate are added in detergent Sodium, form imitated vesicle structure, UV resistant agent nano-TiO2It is wrapped in inside vesica, nanometer is gradually outwards discharged in washing process TiO2, chemical & blended fabric is kept uvioresistant effect, protect the human-body safety of wearer.
To reach above-mentioned purpose, the technical scheme is that:
A kind of detergent for improving chemical fibre anti-uv-ray, it is characterised in that the detergent includes following mass fraction Component:Nano-TiO2:11-17 parts;Ester based quaternary ammonium salt:22-40 parts;Lauryl sodium sulfate:14-28 parts;Carboxymethyl cellulose: 3-9 parts;Sodium lactate:12-20 parts;Sodium tripolyphosphate:22-45 parts;Fluorescent whitening agent:0.2-2 parts;Essence:0.1-2 parts;Ethanol: 4-13 parts;Water:24-46 parts.
Further, the detergent includes the component of following mass fraction:Nano-TiO2:11-14 parts;Ester group quaternary ammonium Salt:22-34 parts;Lauryl sodium sulfate:19-28 parts;Carboxymethyl cellulose:5-9 parts;Sodium lactate:15-20 parts;Tripolyphosphate Sodium:25-40 parts;Fluorescent whitening agent:0.2-1 parts;Essence:0.1-1 parts;Ethanol:5-8 parts;Water:30-40 parts.
Further, the detergent includes the component of following mass fraction:Nano-TiO2:13 parts;Ester based quaternary ammonium salt:30 Part;Lauryl sodium sulfate:24 parts;Carboxymethyl cellulose:7 parts;Sodium lactate:16 parts;Sodium tripolyphosphate:32 parts;Fluorescent brightening Agent:0.5 part;Essence:0.2 part;Ethanol:6 parts;Water:36 parts.
Further, the ester based quaternary ammonium salt is acid amides ester based quaternary ammonium salt or triethanolamine-type ester based quaternary ammonium salt or urgent two Any of ethanol amine type Biester quarternary ammoniumsalt.
Further, the fluorescent whitening agent is Stilbene-based or Disulfo-type fluorescent whitening agents.
Further, the essence is lemon extract or any of flavoring rose essence or flavoring apple essence.
Further, the detergent is light yellow clear liquid.
The beneficial effects of the present invention are:
A kind of detergent for improving chemical fibre anti-uv-ray provided by the invention, adds cation surface activating in detergent Agent ester based quaternary ammonium salt and anionic, form imitated vesicle structure, UV resistant agent nano-TiO2 It is wrapped in inside vesica, nano-TiO is gradually outwards discharged in washing process2, chemical & blended fabric is kept uvioresistant effect, protect Protect the human-body safety of wearer.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention Scope.
Embodiment one:
A kind of detergent for improving chemical fibre anti-uv-ray, include the component of following mass fraction:Nano-TiO2:11 parts;Ester Based quaternary ammonium salt:22 parts;Lauryl sodium sulfate:14 parts;Carboxymethyl cellulose:9 parts;Sodium lactate:12 parts;Sodium tripolyphosphate:45 Part;Fluorescent whitening agent:0.2 part;Essence:2 parts;Ethanol:13 parts;Water:24 parts.
Embodiment two:
A kind of detergent for improving chemical fibre anti-uv-ray, include the component of following mass fraction:Nano-TiO2:17 parts;Ester Based quaternary ammonium salt:40 parts;Lauryl sodium sulfate:28 parts;Carboxymethyl cellulose:3 parts;Sodium lactate:20 parts;Sodium tripolyphosphate:22 Part;Fluorescent whitening agent:2 parts;Essence:0.1 part;Ethanol:4 parts;Water:46 parts.
Embodiment three:
A kind of detergent for improving chemical fibre anti-uv-ray, include the component of following mass fraction:Nano-TiO2:13 parts;Ester Based quaternary ammonium salt:30 parts;Lauryl sodium sulfate:24 parts;Carboxymethyl cellulose:7 parts;Sodium lactate:16 parts;Sodium tripolyphosphate:32 Part;Fluorescent whitening agent:0.5 part;Essence:0.2 part;Ethanol:6 parts;Water:36 parts.
A kind of detergent for improving chemical fibre anti-uv-ray provided by the invention, adds cationic surface in detergent Activating agent ester based quaternary ammonium salt and anionic, form imitated vesicle structure, UV resistant agent nanometer TiO2It is wrapped in inside vesica, nano-TiO is gradually outwards discharged in washing process2, chemical & blended fabric is kept uvioresistant effect Fruit, protect the human-body safety of wearer.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention In sharp claimed range.

Claims (7)

1. a kind of detergent for improving chemical fibre anti-uv-ray, it is characterised in that the detergent includes following mass fraction Component:Nano-TiO2:11-17 parts;Ester based quaternary ammonium salt:22-40 parts;Lauryl sodium sulfate:14-28 parts;Carboxymethyl cellulose Element:3-9 parts;Sodium lactate:12-20 parts;Sodium tripolyphosphate:22-45 parts;Fluorescent whitening agent:0.2-2 parts;Essence:0.1-2 parts;Second Alcohol:4-13 parts;Water:24-46 parts.
2. the detergent according to claim 1 for improving chemical fibre anti-uv-ray, it is characterised in that the detergent bag Include the component of following mass fraction:Nano-TiO2:11-14 parts;Ester based quaternary ammonium salt:22-34 parts;Lauryl sodium sulfate:19-28 Part;Carboxymethyl cellulose:5-9 parts;Sodium lactate:15-20 parts;Sodium tripolyphosphate:25-40 parts;Fluorescent whitening agent:0.2-1 parts;It is fragrant Essence:0.1-1 parts;Ethanol:5-8 parts;Water:30-40 parts.
3. the detergent according to claim 1 for improving chemical fibre anti-uv-ray, it is characterised in that the detergent bag Include the component of following mass fraction:Nano-TiO2:13 parts;Ester based quaternary ammonium salt:30 parts;Lauryl sodium sulfate:24 parts;Carboxymethyl Cellulose:7 parts;Sodium lactate:16 parts;Sodium tripolyphosphate:32 parts;Fluorescent whitening agent:0.5 part;Essence:0.2 part;Ethanol:6 parts; Water:36 parts.
4. the detergent of the raising chemical fibre anti-uv-ray according to claim 1 or 2 or 3, it is characterised in that the ester Based quaternary ammonium salt is in acid amides ester based quaternary ammonium salt or triethanolamine-type ester based quaternary ammonium salt or urgent diethanol amine type Biester quarternary ammoniumsalt It is any.
5. the detergent of the raising chemical fibre anti-uv-ray according to claim 1 or 2 or 3, it is characterised in that described glimmering Optical brightener is Stilbene-based or Disulfo-type fluorescent whitening agents.
6. the detergent of the raising chemical fibre anti-uv-ray according to claim 1 or 2 or 3, it is characterised in that the perfume (or spice) Essence is lemon extract or any of flavoring rose essence or flavoring apple essence.
7. the detergent of the raising chemical fibre anti-uv-ray according to claim 1 or 2 or 3, it is characterised in that described to wash It is light yellow clear liquid to wash agent.
CN201710506318.0A 2017-06-28 2017-06-28 A kind of detergent for improving chemical fibre anti-uv-ray Pending CN107354014A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710506318.0A CN107354014A (en) 2017-06-28 2017-06-28 A kind of detergent for improving chemical fibre anti-uv-ray

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Application Number Priority Date Filing Date Title
CN201710506318.0A CN107354014A (en) 2017-06-28 2017-06-28 A kind of detergent for improving chemical fibre anti-uv-ray

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CN107354014A true CN107354014A (en) 2017-11-17

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112877149A (en) * 2021-02-05 2021-06-01 杭州诗茵服饰有限公司 Cleaning agent suitable for white jean fabric and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1633531A (en) * 2002-02-18 2005-06-29 西巴特殊化学品控股有限公司 Process for improving the sun protection factor of cellulosic fibre material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1633531A (en) * 2002-02-18 2005-06-29 西巴特殊化学品控股有限公司 Process for improving the sun protection factor of cellulosic fibre material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨俊玲: "纳米TiO2在织物后整理中的应用", 《纺织学报》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112877149A (en) * 2021-02-05 2021-06-01 杭州诗茵服饰有限公司 Cleaning agent suitable for white jean fabric and preparation method thereof

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Application publication date: 20171117