CN107353707B - Preparation method of heat-resistant ink composition - Google Patents
Preparation method of heat-resistant ink composition Download PDFInfo
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- CN107353707B CN107353707B CN201710717359.4A CN201710717359A CN107353707B CN 107353707 B CN107353707 B CN 107353707B CN 201710717359 A CN201710717359 A CN 201710717359A CN 107353707 B CN107353707 B CN 107353707B
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- epoxy acrylate
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- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 12
- OEQSRBSQZBBOHN-UHFFFAOYSA-N BC(C(C(C)(C)C1=C2C(CCCCCCCC)(CCCCCCCC)C3=C1C(C)(C)CC=C3)=O)C2=O Chemical compound BC(C(C(C)(C)C1=C2C(CCCCCCCC)(CCCCCCCC)C3=C1C(C)(C)CC=C3)=O)C2=O OEQSRBSQZBBOHN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000004040 coloring Methods 0.000 claims abstract description 7
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 6
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 6
- 239000003085 diluting agent Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- -1 3-propyl Chemical group 0.000 claims abstract description 3
- RRXYBJYIUHTJTO-UHFFFAOYSA-N europium;1,10-phenanthroline Chemical compound [Eu].C1=CN=C2C3=NC=CC=C3C=CC2=C1 RRXYBJYIUHTJTO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 6
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 6
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 claims description 6
- PTNWZQNRTQEQTC-UHFFFAOYSA-N [Eu+3].N1=CC=CC2=CC=C3C=CC=NC3=C12.C(C1=CC=CC=C1)(=O)CC(C1=CC=CC=C1)=O Chemical compound [Eu+3].N1=CC=CC2=CC=C3C=CC=NC3=C12.C(C1=CC=CC=C1)(=O)CC(C1=CC=CC=C1)=O PTNWZQNRTQEQTC-UHFFFAOYSA-N 0.000 claims description 5
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 2
- 239000001023 inorganic pigment Substances 0.000 claims description 2
- 239000012860 organic pigment Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 description 35
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000013065 commercial product Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- MXVMODFDROLTFD-UHFFFAOYSA-N 2-[2-[2-(2-butoxyethoxy)ethoxy]ethoxy]ethanol Chemical compound CCCCOCCOCCOCCOCCO MXVMODFDROLTFD-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- LNBHUCHAFZUEGJ-UHFFFAOYSA-N europium(3+) Chemical compound [Eu+3] LNBHUCHAFZUEGJ-UHFFFAOYSA-N 0.000 description 1
- ADHNFLCTOCFIFV-UHFFFAOYSA-N europium(3+) 1,10-phenanthroline Chemical compound [Eu+3].c1cnc2c(c1)ccc1cccnc21 ADHNFLCTOCFIFV-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A preparation method of a heat-resistant ink composition comprises the steps of putting epoxy acrylate into a reaction kettle, adding a dispersing agent, a coloring pigment, an adhesion promoter, an active diluent, 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctyl fluorene, (1, 3-diphenyl-1, 3-propyl diketo) (1, 10-phenanthroline) europium (III), stirring for 30-80min, uniformly mixing, adding a defoaming agent, and stirring at the rotating speed of 100rpm for 10-30min to obtain an ink composition product.
Description
Technical Field
The invention relates to a preparation method of an ink composition, in particular to a preparation method of a heat-resistant ink composition.
Background
Ink is an important material for printing, and nowadays the United states is the biggest ink producing country and consuming country in the world, the second time in Japan, the third time in Germany and the fourth time in China. With the rapid development of national economy, the prosperity of printing and packaging industry drives the rapid growth of ink manufacturing industry, so that China rapidly grows up to be one of the world ink manufacturing big countries in the last ten years, and the ink industrial scale in China is continuously and rapidly increased at a speed of more than 10%. The rapid development of the packaging industry in China in nearly ten years enables the ink industry in China to be greatly expanded. In 2004, printing factories mainly used offset printing ink, but the printing factories extended the coexistence of solvent ink, water-based ink, UV ink, silk-screen ink and offset printing ink, so that the printing ink market was huge and promising.
CN107001832A discloses a method for preparing an ink, comprising: (a)0.5 to 5 parts of a self-dispersing pigment; (b)1 to 10 parts of a styrene acrylic latex binder and/or a styrene butadiene latex binder; (c)0 to 5 parts of a glycol selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol or triethylene glycol; (d)1 to 10 parts of 2-pyrrolidone; (e)1 to 15 parts of glycerol; (f)0.1 to 3 parts of an acetylenic surfactant; (g)0.001 to 5 parts of an antimicrobial agent; (h)0 to 10 parts of a viscosity modifier; and (i) water in an amount balanced to 100 parts. The invention also provides an ink jet printing process, a print substrate, an ink container for an ink jet printer, and an ink jet printer having a recirculating printhead.
CN102002279B discloses an ink composition containing a metallic pigment. The ink composition comprises an organic solvent, a metal pigment and a resin, wherein the organic solvent comprises 60 mass% or more of diethylene glycol diethyl ether, 24 to 37 mass% of gamma-butyrolactone and/or tetraethylene glycol dimethyl ether, and more than 1 mass% and less than 5 mass% of tetraethylene glycol monobutyl ether, relative to the total amount of the ink composition, and the 50% average particle diameter of the metal pigment, as measured by a light scattering method and converted into a sphere, is 0.8 to 1.2 [ mu ] m.
With the improvement of economic level and technological level, the requirements of the consumer market on ink products are more comprehensive, the existing ink product preparation methods mainly focus on the environmental protection property, durability and adhesion property of ink, and the existing ink products are deficient in light resistance and heat resistance, so that the development of a light-resistant, heat-resistant and non-discoloring ink product is necessary.
Disclosure of Invention
The purpose of the invention is: provided is a method for preparing a heat-resistant ink composition, which is characterized by comprising the following steps:
putting epoxy acrylate into a reaction kettle, adding a dispersing agent, a coloring pigment, an adhesion promoter, an active diluent, 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctyl fluorene, (1, 3-diphenyl-1, 3-propyl diketo) (1, 10-phenanthroline) europium (III), stirring for 30-80min, uniformly mixing, grinding, adding a defoaming agent, and stirring at the rotating speed of 100rpm for 10-30min to obtain the ink composition product.
The dispersing agent is a hyper-dispersing agent Solsperse-27000, and the mass amount of the dispersing agent is 0.2-2% of that of the epoxy acrylate.
The coloring pigment can be applied to a plurality of organic pigments and inorganic pigments, such as pigment carbon black, titanium dioxide and other stable coloring pigments with low reaction activity. The mass consumption of the epoxy acrylate is 1-20 percent of that of the epoxy acrylate.
The adhesion promoter is V-glycidyl ether propyl trimethoxy silane. The mass consumption of the epoxy acrylate is 0.3-2 percent of that of the epoxy acrylate.
The active diluent is propylene oxide phenyl ether and polypropylene glycol diglycidyl ether. The mass consumption of the epoxy acrylate is 5-40 percent of that of the epoxy acrylate.
The mass amount of the 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctyl fluorene is 0.01-0.1 percent of the epoxy acrylate.
The mass amount of the (1, 3-diphenyl-1, 3-propanedione) (1, 10-phenanthroline) europium (III) is 0.01-0.1% of that of the epoxy acrylate.
The defoaming agent is organic modified siloxane defoaming emulsion. The mass consumption of the epoxy acrylate is 0.05-0.2 percent of that of the epoxy acrylate.
The epoxy acrylate is a commercial product, such as a product produced by Jinjinle chemical Co., Ltd, Hunan; the hyper-dispersant Solsperse-27000 is a commercially available product, such as the product produced by Shanghai Tager Polymer technology, Inc.; v-glycidyl ether propyl trimethoxy silane is a commercial product, such as a product produced by Suzhou Spi New Material Co., Ltd; the propylene oxide phenyl ether is a commercially available product, such as a product produced by Shandong Xiaoye chemical Co., Ltd; the polypropylene glycol diglycidyl ether is a commercial product, such as a product produced by Wuhan Daohan Co-creation science and technology Limited; the organic modified siloxane defoaming emulsion is a product sold in the market, such as a product produced by Zhengzhou Zhenlei chemical product Limited; 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctyl fluorene is a commercially available product, such as a product produced by Zhengzhou alpha chemical industry Co., Ltd; (1, 3-diphenyl-1, 3-propanedione) (1, 10-phenanthroline) europium (III) is a commercially available product, such as that produced by Zhengbei Jingyunpang Biotech Co., Ltd.
The product of the invention has the following beneficial effects:
according to the preparation method of the heat-resistant ink composition, the raw materials of the ink composition product have good stability, and on the premise of ensuring good wear resistance and adhesiveness of the ink product, the light resistance and heat resistance of the ink product are better, so that the requirement of no color change under illumination and at higher temperature can be met.
Detailed Description
The following examples are intended to further illustrate the present invention and are not intended to limit the scope of the invention.
Example 1
100Kg of epoxy acrylate, 1.1Kg of a hyper-dispersant Solsperse-27000, 10Kg of high-color carbon black, 1.1Kg of V-glycidyl ether propyl trimethoxy silane, 22.5Kg of propylene oxide phenyl ether, 0.05Kg of 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctylfluorene, and 0.05Kg of (1, 3-diphenyl-1, 3-propanedione) (1, 10-phenanthroline) europium (III) are added into a reaction kettle, stirred at the rotating speed of 120rpm for 55min, ground to less than 12 μm, then 0.1Kg of an organic modified siloxane defoaming emulsion is added, and stirred at the rotating speed of 100rpm for 15min, thus obtaining the ink composition product. Product number M-1.
Example 2
100Kg of epoxy acrylate, 0.2Kg of a hyper-dispersant Solsperse-27000, 1Kg of high-color carbon black, 0.3Kg of V-glycidyl ether propyl trimethoxy silane, 5Kg of propylene oxide phenyl ether, 0.01Kg of 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctylfluorene, and 0.01Kg of (1, 3-diphenyl-1, 3-propanedione) (1, 10-phenanthroline) europium (III) are added into a reaction kettle, stirred at the rotating speed of 120rpm for 30min, ground to less than 12 μm, then 0.05Kg of an organic modified siloxane defoaming emulsion is added, and stirred at the rotating speed of 100rpm for 10min, thus obtaining the ink composition product. Product number M-2.
Example 3
100Kg of epoxy acrylate, 2Kg of hyper-dispersant Solsperse-27000, 20Kg of high color carbon black, 2Kg of V-glycidyl ether propyl trimethoxy silane, 40Kg of propylene oxide phenyl ether, 0.1Kg of 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctyl fluorene and 0.1Kg of (1, 3-diphenyl-1, 3-propanedione) (1, 10-orthophenanthroline) europium (III) are added into a reaction kettle, stirred for 80min at the rotating speed of 120rpm, ground to less than 12 mu m, then 0.2Kg of organic modified siloxane defoaming emulsion is added, and stirred for 30min at the rotating speed of 100rpm, thus obtaining the ink composition product. Product number M-3.
Comparative example 1
The same procedure as in example 1 was repeated except that V-glycidoxypropyltrimethoxysilane was not added. Product number M-4.
Comparative example 2
No hyperdispersant Solsperse-27000 was added, and the other conditions were the same as in example 1. Product number M-5.
Comparative example 3
The same procedure as in example 1 was repeated except that 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctylfluorene was not added. Product number M-6.
Comparative example 4
The same procedure as in example 1 was repeated except that europium (III) (1, 10-phenanthroline) was not added to the reaction mixture (1, 3-diphenyl-1, 3-propanedione group). Product number M-7.
Example 4
The viscosity of the ink products of examples 1-3 and comparative examples 1-4 was examined, the ink products produced by different processes were printed on two ABS synthetic resin plates, the thickness of the ink film was 10 μm, the plates were kept at 70 ℃ for 15min, the plates were taken out and left to stand at room temperature, the adhesion thereof was examined according to GB/T9286-1998 standard (grade 0-5, grade 0 adhesion being the best, grade 5 being the worst), and the other ABS plate with the ink film attached thereto was placed at 85 ℃ for 120 hours, and the degree of discoloration and the presence of cracks in the paint were observed. See table 1.
Table 1: viscosity, adhesion, and light and heat resistance of the ink mixture.
| Product numbering | Viscosity/cps | Grade of adhesion | Degree of color change | Crack(s) |
| M-1 | 1180 | Level 0 | No color change | Is free of |
| M-2 | 1294 | Level 0 | No color change | Is free of |
| M-3 | 1085 | Level 0 | No color change | Is free of |
| M-4 | 1145 | Grade 3 | No color change | Much more |
| M-5 | 1238 | Stage 2 | Has color change | Much more |
| M-6 | 1187 | Level 1 | Has color change | Small amount of |
| M-7 | 1169 | Level 1 | Has color change | Small amount of |
Claims (5)
1. A method for preparing a light-resistant ink composition is characterized by comprising the following steps: putting epoxy acrylate into a reaction kettle, adding a dispersing agent, a coloring pigment, an adhesion promoter, an active diluent, 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctyl fluorene, (1, 3-diphenyl-1, 3-propyl diketo) (1, 10-phenanthroline) europium (III), stirring at the rotating speed of 120rpm for 30-80min, uniformly mixing, grinding to less than 12 mu m, adding a defoaming agent, and stirring at the rotating speed of 100rpm for 10-30min to obtain an ink composition product;
the mass amount of the 2, 7-bis (4,4,5, 5-tetramethyl-1, 3-dioxo-2-boryl) -9, 9-dioctyl fluorene is 0.01-0.1 percent of the epoxy acrylate; the adhesion promoter is gamma-glycidyl ether propyl trimethoxy silane, and the mass amount of the adhesion promoter is 0.3-2% of that of the epoxy acrylate; the mass amount of the (1, 3-diphenyl-1, 3-propanedione) (1, 10-phenanthroline) europium (III) is 0.01-0.1% of that of the epoxy acrylate.
2. A method of making a light-fast ink composition as defined in claim 1, wherein: the dispersing agent is a hyper-dispersing agent Solsperse-27000, and the mass amount of the dispersing agent is 0.2-2% of that of the epoxy acrylate.
3. A method of making a light-fast ink composition as defined in claim 1, wherein: the active diluent is epoxypropane phenyl ether and polypropylene glycol diglycidyl ether, and the mass amount of the active diluent is 5-40% of that of the epoxyacrylate.
4. A method of making a light-fast ink composition as defined in claim 1, wherein: the defoaming agent is organic modified siloxane defoaming emulsion, and the mass amount of the defoaming agent is 0.05-0.2% of epoxy acrylate.
5. A method of making a light-fast ink composition as defined in claim 1, wherein: the coloring pigment is prepared from various organic pigments and inorganic pigments, and the mass usage amount of the coloring pigment is 1-20% of that of epoxy acrylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710717359.4A CN107353707B (en) | 2017-08-21 | 2017-08-21 | Preparation method of heat-resistant ink composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710717359.4A CN107353707B (en) | 2017-08-21 | 2017-08-21 | Preparation method of heat-resistant ink composition |
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| Publication Number | Publication Date |
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| CN107353707A CN107353707A (en) | 2017-11-17 |
| CN107353707B true CN107353707B (en) | 2020-12-18 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104962130A (en) * | 2015-07-04 | 2015-10-07 | 佛山市南方包装有限公司 | Heat-resistant yellow-stain-resistant epoxy acrylate low polymer and preparation method of UV (ultraviolet) ink |
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2017
- 2017-08-21 CN CN201710717359.4A patent/CN107353707B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104962130A (en) * | 2015-07-04 | 2015-10-07 | 佛山市南方包装有限公司 | Heat-resistant yellow-stain-resistant epoxy acrylate low polymer and preparation method of UV (ultraviolet) ink |
Non-Patent Citations (1)
| Title |
|---|
| 铕(Ⅲ ) -丙烯酸酯共聚物的合成及其光性能研究;程原;《华北工学院学报》;20050228;第26卷(第1期);第31-34页 * |
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