CN107353699A - One kind paint class modified calcium carbonate - Google Patents
One kind paint class modified calcium carbonate Download PDFInfo
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- CN107353699A CN107353699A CN201710641972.2A CN201710641972A CN107353699A CN 107353699 A CN107353699 A CN 107353699A CN 201710641972 A CN201710641972 A CN 201710641972A CN 107353699 A CN107353699 A CN 107353699A
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- calcium carbonate
- modified calcium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
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- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses one kind to paint class modified calcium carbonate, in units of parts by weight, including following raw material：182 205 parts of calcium carbonate fragment, 4.5 6.4 parts of grinding aid, 3.6 6 parts of trihydroxy ethylamine oleate soap, 0.4 0.8 parts of praseodynium aluminium, 0.2 0.3 parts of vanadic anhydride, 0.6 1 parts of diethylenetriamine pentacarboxylic acid sodium, 0.2 0.4 parts of conditioning agent, 0.5 0.7 parts of coupling agent, 1.5 2.8 parts of phthalic acid two (2 ethyl hexyl) ester, 0.4 0.7 parts of modified polyacrylate, 0.3 0.5 parts of hexenyl bis-stearamides, 2 (2' hydroxyls 3', bis- tertiary phenyl of 5') 0.3 0.5 parts of 5 chlorination BTA, 0.2 0.4 parts of polyacrylamide, 0.4 0.8 parts of stabilizer.Present invention paint class is high with modified calcium carbonate activation rate, and oil factor is low and compatibility with high molecular polymer is good.
Description
【Technical field】
The invention belongs to modified calcium carbonate preparing technical field, and in particular to one kind paint class modified calcium carbonate.
【Background technology】
Calcium carbonate is a kind of conventional inorganic filler, because source is wide, cheap etc., be widely used in plastics, rubber, coating,
The fields such as stone slab, paint.But calcium carbonate surface is hydrophilic and oleophobic, specific surface energy is high, easily reunites between particle, with high molecular polymerization
The compatibility of thing is very poor.Therefore, when being filled into high molecular polymer, it is necessary to calcium carbonate surface is modified, makes its table
Face oleophilic drainage, enhancing and the compatibility of high molecular polymer, improve the dispersiveness in high molecular polymer, improve performance.
【The content of the invention】
The technical problem to be solved in the present invention is to provide one kind to paint class modified calcium carbonate, to solve existing calcium carbonate table
Face is hydrophilic and oleophobic, specific surface energy is high, easily reunites between particle, with the compatibility of high molecular polymer it is very poor the problems such as.
In order to solve the above technical problems, the present invention uses following technical scheme：
One kind paint class modified calcium carbonate, in units of parts by weight, including following raw material：Calcium carbonate fragment 182-
205 parts, grinding aid 4.5-6.4 parts, trihydroxy ethylamine oleate soap 3.6-6 parts, praseodynium aluminium 0.4-0.8 parts, vanadic anhydride
0.2-0.3 parts, diethylenetriamine pentacarboxylic acid sodium 0.6-1 parts, conditioning agent 0.2-0.4 parts, coupling agent 0.5-0.7 parts, O-phthalic
Sour two (2- ethyl hexyls) ester 1.5-2.8 parts, modified polyacrylate 0.4-0.7 parts, hexenyl bis-stearamides 0.3-0.5 parts,
2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorination BTA 0.3-0.5 parts, polyacrylamide 0.2-0.4 parts, stabilizer
0.4-0.8 parts.
Further, described paint class modified calcium carbonate, in units of parts by weight, including following raw material：Calcium carbonate
Fragment 196-205 parts, grinding aid 5.5-6.4 parts, trihydroxy ethylamine oleate soap 5-6 parts, praseodynium aluminium 0.6-0.8 parts, five
V 2 O 0.2-0.3 parts, diethylenetriamine pentacarboxylic acid sodium 0.8-1 parts, conditioning agent 0.3-0.4 parts, coupling agent 0.6-0.7 parts,
(2- ethyl hexyls) the ester 2.2-2.8 of phthalic acid two parts, modified polyacrylate 0.6-0.7 parts, hexenyl bis-stearamides
0.4-0.5 parts, 2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorination BTA 0.4-0.5 parts, polyacrylamide 0.3-
0.4 part, stabilizer 0.6-0.8 parts.
Further, described paint class modified calcium carbonate, in units of parts by weight, including following raw material：Calcium carbonate
196 parts of fragment, 5.5 parts of grinding aid, 5 parts of trihydroxy ethylamine oleate soap, 0.6 part of praseodynium aluminium, 0.2 part of vanadic anhydride,
0.8 part of diethylenetriamine pentacarboxylic acid sodium, 0.3 part of conditioning agent, 0.6 part of coupling agent, phthalic acid two (2- ethyl hexyls) ester 2.2
Part, 0.6 part of modified polyacrylate, 0.4 part of hexenyl bis-stearamides, 2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorine
Change 0.4 part of BTA, 0.3 part of polyacrylamide, 0.6 part of stabilizer.
Further, described paint class modified calcium carbonate, the grinding aid, including following raw material：Lignin sulfonic acid
Potassium, polyalcohol amine, zinc stearate.
Further, described paint class modified calcium carbonate, the grinding aid, in units of parts by weight, including it is following
Raw material：Lignin sulfonic acid potassium 9-15 parts, polyalcohol amine 5-9 parts, zinc stearate 3-6 parts.
Further, described paint class modified calcium carbonate, the grinding aid, in units of parts by weight, including it is following
Raw material：Lignin sulfonic acid potassium 12-15 parts, polyalcohol amine 7-9 parts, zinc stearate 5-6 parts.
Further, described paint class modified calcium carbonate, the grinding aid, in units of parts by weight, including it is following
Raw material：12 parts of lignin sulfonic acid potassium, 7 parts of polyalcohol amine, 5 parts of zinc stearate.
Further, described paint class modified calcium carbonate, the conditioning agent are esters of acrylic acid conditioning agent.
Further, described paint class modified calcium carbonate, the coupling agent are trimethylolpropane tris (3- ethylene imines
Base propionic ester).
Further, described paint class modified calcium carbonate, the stabilizer are calcium soap stabilizer.
The invention has the advantages that：
(1) from embodiment 1-3 and the data of comparative example 5, the activation rate of modified calcium carbonate is high, oil factor it is low and
It is good with the compatibility of high molecular polymer；
(2) from embodiment 3 and comparative example 1-4 data, trihydroxy ethylamine oleate soap, praseodynium aluminium, five oxidations
Two vanadium serve synergy in calcium carbonate modified, improve activation rate height and contact angle, it is low to reduce oil factor；This may
It is that surface modifier trihydroxy ethylamine oleate soap is used in calcium carbonate surface modifying, in conjunction with accelerator praseodynium aluminium and urges
Agent vanadic anhydride, it is low to significantly improve modified calcium carbonate activation rate height, contact angle, oil factor, improves and high score
The compatibility of sub- polymer；
(3) from the data of comparative example 2, paint class is with being not added with surface modifier three in modified calcium carbonate preparing raw material
Monoethanolamine oleate soap is to calcium carbonate surface modifying, relatively other two components of activation rate height, contact angle, oil factor of calcium carbonate
(praseodynium aluminium, vanadic anhydride) change is minimum, illustrates that trihydroxy ethylamine oleate soap serves in whole modified technique
Vital effect.
【Embodiment】
For ease of more fully understanding the present invention, it is illustrated by following instance, these examples belong to the protection of the present invention
Scope, but do not limit the scope of the invention.
In embodiment, the paint class modified calcium carbonate, in units of parts by weight, including following raw material：Calcium carbonate
Fragment 182-205 parts, grinding aid 4.5-6.4 parts, trihydroxy ethylamine oleate soap 3.6-6 parts, praseodynium aluminium 0.4-0.8 parts,
Vanadic anhydride 0.2-0.3 parts, diethylenetriamine pentacarboxylic acid sodium 0.6-1 parts, conditioning agent 0.2-0.4 parts, coupling agent 0.5-0.7
Part, (2- ethyl hexyls) the ester 1.5-2.8 of phthalic acid two parts, modified polyacrylate 0.4-0.7 parts, hexenyl bis-stearamides
0.3-0.5 parts, 2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorination BTA 0.3-0.5 parts, polyacrylamide 0.2-
0.4 part, stabilizer 0.4-0.8 parts；
The grinding aid, in units of parts by weight, including following raw material：Lignin sulfonic acid potassium 9-15 parts, polyalcohol amine 5-9
Part, zinc stearate 3-6 parts；
The preparation method of the paint class modified calcium carbonate, comprises the following steps：
S1：Impurity thing is removed after choosing the cleaning such as the marble shipped from yard of material, lime stone, building stones dry removing
Surface moisture is removed, then building stones are crushed with disintegrating machine, calcium carbonate fragment is made；
S2：Calcium carbonate fragment made from step S1 is delivered into vertical mill synchronization addition grinding aid and ground, is made
Calcium carbonate microlith powder；
S3：Calcium carbonate microlith powder made from step S2 is classified with grader, the calcium carbonate of 1200-1500 mesh is made
Powder；
S4：Calcium carbonate powder made from step S3 is added in high-speed mixer, adds trihydroxy ethylamine oleate soap, three
Aluminium acetylacetonate, vanadic anhydride, are warming up to 56-65 DEG C, with 1100-1300r/min speed high-speed stirred 35-40min, system
Obtain mixture a；
S5：Diethylenetriamine pentacarboxylic acid sodium, esters of acrylic acid conditioning agent, three will be added in mixture a made from step S4
Hydroxymethyl-propane three (3- aziridinyls propionic ester), phthalic acid two (2- ethyl hexyls) ester, modified polyacrylate, hexenyl
Bis-stearamides, it is 68-75 DEG C to control temperature, and with 1000-1200r/min speed high-speed stirred 30-36min, mixing is made
Thing b；
S6：2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorinations benzo three will be added in mixture b made from step S5
Azoles, polyacrylamide, calcium soap stabilizer, it is 45-50 DEG C to control temperature, with 800-1000r/min speed high-speed stirred 26-
32min, mixture c is made, gained mixture c is crushed, cross the sieve of 1200-1500 mesh, and done at being 45-50 DEG C in temperature
It is dry to water content≤0.5%, paint class modified calcium carbonate is made.
Below by more specific embodiment, the present invention will be described.
Embodiment 1
One kind paint class modified calcium carbonate, in units of parts by weight, including following raw material：196 parts of calcium carbonate fragment,
5.5 parts of grinding aid, 5 parts of trihydroxy ethylamine oleate soap, 0.6 part of praseodynium aluminium, 0.2 part of vanadic anhydride, diethylenetriamine five
0.8 part of carboxylic acid sodium, 0.3 part of conditioning agent, 0.6 part of coupling agent, 2.2 parts of phthalic acid two (2- ethyl hexyls) ester, modified polypropene
0.6 part of acid esters, 0.4 part of hexenyl bis-stearamides, 2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorinations BTA 0.4
Part, 0.3 part of polyacrylamide, 0.6 part of stabilizer；
The grinding aid, in units of parts by weight, including following raw material：12 parts of lignin sulfonic acid potassium, 7 parts of polyalcohol amine,
5 parts of zinc stearate；
The preparation method of the paint class modified calcium carbonate, comprises the following steps：
S1：Impurity thing is removed after choosing the cleaning such as the marble shipped from yard of material, lime stone, building stones dry removing
Surface moisture is removed, then building stones are crushed with disintegrating machine, calcium carbonate fragment is made；
S2：Calcium carbonate fragment made from step S1 is delivered into vertical mill synchronization addition grinding aid and ground, is made
Calcium carbonate microlith powder；
S3：Calcium carbonate microlith powder made from step S2 is classified with grader, the calcium carbonate powder of 1300 mesh is made；
S4：Calcium carbonate powder made from step S3 is added in high-speed mixer, adds trihydroxy ethylamine oleate soap, three
Aluminium acetylacetonate, vanadic anhydride, 60 DEG C are warming up to, with 1200r/min speed high-speed stirred 38min, mixture a is made；
S5：Diethylenetriamine pentacarboxylic acid sodium, esters of acrylic acid conditioning agent, three will be added in mixture a made from step S4
Hydroxymethyl-propane three (3- aziridinyls propionic ester), phthalic acid two (2- ethyl hexyls) ester, modified polyacrylate, hexenyl
Bis-stearamides, it is 72 DEG C to control temperature, and with 1100r/min speed high-speed stirred 34min, mixture b is made；
S6：2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorinations benzo three will be added in mixture b made from step S5
Azoles, polyacrylamide, calcium soap stabilizer, it is 48 DEG C to control temperature, with 900r/min speed high-speed stirred 28min, is made mixed
Compound c, gained mixture c is crushed, cross the sieve of 1300 mesh, and it is 0.5% to be dried at being 48 DEG C in temperature to water content, system
Class modified calcium carbonate must be painted.
Embodiment 2
One kind paint class modified calcium carbonate, in units of parts by weight, including following raw material：185 parts of calcium carbonate fragment,
4.6 parts of grinding aid, 3.8 parts of trihydroxy ethylamine oleate soap, 0.4 part of praseodynium aluminium, 0.2 part of vanadic anhydride, diethylenetriamine
0.6 part of pentacarboxylic acid sodium, 0.2 part of conditioning agent, 0.5 part of coupling agent, 1.6 parts of phthalic acid two (2- ethyl hexyls) ester, modified poly- third
0.4 part of olefin(e) acid ester, 0.3 part of hexenyl bis-stearamides, 2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorination BTAs
0.3 part, 0.2 part of polyacrylamide, 0.4 part of stabilizer；
The grinding aid, in units of parts by weight, including following raw material：It is 9 parts of lignin sulfonic acid potassium, 5 parts of polyalcohol amine, hard
3 parts of resin acid zinc；
The preparation method of the paint class modified calcium carbonate, comprises the following steps：
S1：Impurity thing is removed after choosing the cleaning such as the marble shipped from yard of material, lime stone, building stones dry removing
Surface moisture is removed, then building stones are crushed with disintegrating machine, calcium carbonate fragment is made；
S2：Calcium carbonate fragment made from step S1 is delivered into vertical mill synchronization addition grinding aid and ground, is made
Calcium carbonate microlith powder；
S3：Calcium carbonate microlith powder made from step S2 is classified with grader, the calcium carbonate powder of 1200 mesh is made；
S4：Calcium carbonate powder made from step S3 is added in high-speed mixer, adds trihydroxy ethylamine oleate soap, three
Aluminium acetylacetonate, vanadic anhydride, 56 DEG C are warming up to, with 1100r/min speed high-speed stirred 40min, mixture a is made；
S5：Diethylenetriamine pentacarboxylic acid sodium, esters of acrylic acid conditioning agent, three will be added in mixture a made from step S4
Hydroxymethyl-propane three (3- aziridinyls propionic ester), phthalic acid two (2- ethyl hexyls) ester, modified polyacrylate, hexenyl
Bis-stearamides, it is 68 DEG C to control temperature, and with 1000r/min speed high-speed stirred 36min, mixture b is made；
S6：2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorinations benzo three will be added in mixture b made from step S5
Azoles, polyacrylamide, calcium soap stabilizer, it is 45 DEG C to control temperature, with 800r/min speed high-speed stirred 32min, is made mixed
Compound c, gained mixture c is crushed, cross the sieve of 1200 mesh, and it is 0.4% to be dried at being 45 DEG C in temperature to water content, system
Class modified calcium carbonate must be painted.
Embodiment 3
One kind paint class modified calcium carbonate, in units of parts by weight, including following raw material：200 parts of calcium carbonate fragment,
6.2 parts of grinding aid, 6 parts of trihydroxy ethylamine oleate soap, 0.8 part of praseodynium aluminium, 0.3 part of vanadic anhydride, diethylenetriamine five
1 part of carboxylic acid sodium, 0.4 part of conditioning agent, 0.7 part of coupling agent, 2.8 parts of phthalic acid two (2- ethyl hexyls) ester, modified polyacrylic acid
0.7 part of ester, 0.5 part of hexenyl bis-stearamides, 2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) 0.5 part of -5- chlorinations BTA,
0.4 part of polyacrylamide, 0.8 part of stabilizer；
The grinding aid, in units of parts by weight, including following raw material：15 parts of lignin sulfonic acid potassium, 9 parts of polyalcohol amine,
6 parts of zinc stearate；
The preparation method of the paint class modified calcium carbonate, comprises the following steps：
S1：Impurity thing is removed after choosing the cleaning such as the marble shipped from yard of material, lime stone, building stones dry removing
Surface moisture is removed, then building stones are crushed with disintegrating machine, calcium carbonate fragment is made；
S2：Calcium carbonate fragment made from step S1 is delivered into vertical mill synchronization addition grinding aid and ground, is made
Calcium carbonate microlith powder；
S3：Calcium carbonate microlith powder made from step S2 is classified with grader, the calcium carbonate powder of 1500 mesh is made；
S4：Calcium carbonate powder made from step S3 is added in high-speed mixer, adds trihydroxy ethylamine oleate soap, three
Aluminium acetylacetonate, vanadic anhydride, 65 DEG C are warming up to, with 1300r/min speed high-speed stirred 40min, mixture a is made；
S5：Diethylenetriamine pentacarboxylic acid sodium, esters of acrylic acid conditioning agent, three will be added in mixture a made from step S4
Hydroxymethyl-propane three (3- aziridinyls propionic ester), phthalic acid two (2- ethyl hexyls) ester, modified polyacrylate, hexenyl
Bis-stearamides, it is 75 DEG C to control temperature, and with 1200r/min speed high-speed stirred 30min, mixture b is made；
S6：2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorinations benzo three will be added in mixture b made from step S5
Azoles, polyacrylamide, calcium soap stabilizer, it is 50 DEG C to control temperature, with 1000r/min speed high-speed stirred 26min, is made mixed
Compound c, gained mixture c is crushed, cross the sieve of 1500 mesh, and it is 0.3% to be dried at being 50 DEG C in temperature to water content, system
Class modified calcium carbonate must be painted.
Comparative example 1
It is essentially identical with the preparation technology of embodiment 3, have only the difference is that preparing the raw material of paint class modified calcium carbonate
In lack trihydroxy ethylamine oleate soap, praseodynium aluminium, vanadic anhydride.
Comparative example 2
It is essentially identical with the preparation technology of embodiment 3, have only the difference is that preparing the raw material of paint class modified calcium carbonate
In lack trihydroxy ethylamine oleate soap.
Comparative example 3
It is essentially identical with the preparation technology of embodiment 3, have only the difference is that preparing the raw material of paint class modified calcium carbonate
In lack praseodynium aluminium.
Comparative example 4
It is essentially identical with the preparation technology of embodiment 3, have only the difference is that preparing the raw material of paint class modified calcium carbonate
In lack vanadic anhydride.
Comparative example 5
It is the unmodified calcium carbonate of 1500 mesh same as Example 3 that class, which is painted, with modified calcium carbonate.
It is see the table below by the paint class that embodiment 1-3 and comparative example 1-5 are prepared with modified calcium carbonate product index result.
| Experimental project | Oil factor (g/100g) | Contact angle (°) | Activation rate (%) |
| Embodiment 1 | 17.02 | 146.3 | 98.73 |
| Embodiment 2 | 18.62 | 138.7 | 93.42 |
| Embodiment 3 | 15.14 | 151.2 | 99.61 |
| Comparative example 1 | 36.64 | 94.6 | 65.17 |
| Comparative example 2 | 25.74 | 123.1 | 86.32 |
| Comparative example 3 | 22.16 | 134.6. | 89.41 |
| Comparative example 4 | 17.48 | 142.8 | 91.54 |
| Comparative example 5 | 39.01 | 0 | 0 |
As seen from the above table：(1) from embodiment 1-3 and the data of comparative example 5, the activation rate of modified calcium carbonate
Height, oil factor is low and compatibility with high molecular polymer is good；
(2) from embodiment 3 and comparative example 1-4 data, trihydroxy ethylamine oleate soap, praseodynium aluminium, five oxidations
Two vanadium serve synergy in calcium carbonate modified, improve activation rate height and contact angle, it is low to reduce oil factor；This may
It is that surface modifier trihydroxy ethylamine oleate soap is used in calcium carbonate surface modifying, in conjunction with accelerator praseodynium aluminium and urges
Agent vanadic anhydride, it is low to significantly improve modified calcium carbonate activation rate height, contact angle, oil factor, improves and high score
The compatibility of sub- polymer；
(3) from the data of comparative example 2, paint class is with being not added with surface modifier three in modified calcium carbonate preparing raw material
Monoethanolamine oleate soap is to calcium carbonate surface modifying, relatively other two components of activation rate height, contact angle, oil factor of calcium carbonate
(praseodynium aluminium, vanadic anhydride) change is minimum, illustrates that trihydroxy ethylamine oleate soap serves in whole modified technique
Vital effect.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (10)
1. one kind paint class modified calcium carbonate, it is characterised in that in units of parts by weight, including following raw material：Calcium carbonate is broken
Mince 182-205 parts, grinding aid 4.5-6.4 parts, trihydroxy ethylamine oleate soap 3.6-6 parts, praseodynium aluminium 0.4-0.8 parts, five
V 2 O 0.2-0.3 parts, diethylenetriamine pentacarboxylic acid sodium 0.6-1 parts, conditioning agent 0.2-0.4 parts, coupling agent 0.5-0.7 parts,
(2- ethyl hexyls) the ester 1.5-2.8 of phthalic acid two parts, modified polyacrylate 0.4-0.7 parts, hexenyl bis-stearamides
0.3-0.5 parts, 2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorination BTA 0.3-0.5 parts, polyacrylamide 0.2-
0.4 part, stabilizer 0.4-0.8 parts.
2. paint class modified calcium carbonate according to claim 1, it is characterised in that in units of parts by weight, including with
Lower raw material：Calcium carbonate fragment 196-205 parts, grinding aid 5.5-6.4 parts, trihydroxy ethylamine oleate soap 5-6 parts, praseodynium aluminium
0.6-0.8 parts, vanadic anhydride 0.2-0.3 parts, diethylenetriamine pentacarboxylic acid sodium 0.8-1 parts, conditioning agent 0.3-0.4 parts, coupling
Agent 0.6-0.7 parts, (2- ethyl hexyls) the ester 2.2-2.8 of phthalic acid two parts, modified polyacrylate 0.6-0.7 parts, hexenyl
Bis-stearamides 0.4-0.5 parts, 2- (bis- tertiary phenyl of 2'- hydroxyls -3', 5'-) -5- chlorination BTA 0.4-0.5 parts, polypropylene
Acid amides 0.3-0.4 parts, stabilizer 0.6-0.8 parts.
3. paint class modified calcium carbonate according to claim 2, it is characterised in that in units of parts by weight, including with
Lower raw material：196 parts of calcium carbonate fragment, 5.5 parts of grinding aid, 5 parts of trihydroxy ethylamine oleate soap, 0.6 part of praseodynium aluminium, five oxygen
Change 0.2 part of two vanadium, 0.8 part of diethylenetriamine pentacarboxylic acid sodium, 0.3 part of conditioning agent, 0.6 part of coupling agent, (the 2- second of phthalic acid two
Base oneself) 2.2 parts of ester, 0.6 part of modified polyacrylate, 0.4 part of hexenyl bis-stearamides, the 2- (uncles of 2'- hydroxyls -3', 5'- bis-
Phenyl) 0.4 part of -5- chlorinations BTA, 0.3 part of polyacrylamide, 0.6 part of stabilizer.
4. paint class modified calcium carbonate according to claim 1, it is characterised in that the grinding aid, including following original
Material：Lignin sulfonic acid potassium, polyalcohol amine, zinc stearate.
5. it is according to claim 4 paint class modified calcium carbonate, it is characterised in that the grinding aid, using parts by weight as
Unit, including following raw material：Lignin sulfonic acid potassium 9-15 parts, polyalcohol amine 5-9 parts, zinc stearate 3-6 parts.
6. it is according to claim 5 paint class modified calcium carbonate, it is characterised in that the grinding aid, using parts by weight as
Unit, including following raw material：Lignin sulfonic acid potassium 12-15 parts, polyalcohol amine 7-9 parts, zinc stearate 5-6 parts.
7. it is according to claim 6 paint class modified calcium carbonate, it is characterised in that the grinding aid, using parts by weight as
Unit, including following raw material：12 parts of lignin sulfonic acid potassium, 7 parts of polyalcohol amine, 5 parts of zinc stearate.
8. paint class modified calcium carbonate according to claim 1, it is characterised in that the conditioning agent is esters of acrylic acid
Conditioning agent.
9. paint class modified calcium carbonate according to claim 1, it is characterised in that the coupling agent is trihydroxy methyl third
Alkane three (3- aziridinyls propionic ester).
10. paint class modified calcium carbonate according to claim 1, it is characterised in that the stabilizer is stable for calcium soap
Agent.
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| CN201710641972.2A CN107353699A (en) | 2017-07-31 | 2017-07-31 | One kind paint class modified calcium carbonate |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135342A (en) * | 2018-09-28 | 2019-01-04 | 贺州钟山县双文碳酸钙新材料有限公司 | Paint-emulsion paint modified calcium carbonate |
| CN109135344A (en) * | 2018-09-28 | 2019-01-04 | 贺州钟山县双文碳酸钙新材料有限公司 | Paint the surface treatment compound modifier of anti-aging calcium carbonate and its application |
| CN111004560A (en) * | 2019-12-24 | 2020-04-14 | 青海民族大学 | Coating for protecting ancient buildings |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597763A (en) * | 2004-08-18 | 2005-03-23 | 上海氯碱化工股份有限公司 | Composite of full filled unplasticizing polyvinyl chloride/calcium carbonate and preparation process thereof |
-
2017
- 2017-07-31 CN CN201710641972.2A patent/CN107353699A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597763A (en) * | 2004-08-18 | 2005-03-23 | 上海氯碱化工股份有限公司 | Composite of full filled unplasticizing polyvinyl chloride/calcium carbonate and preparation process thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135342A (en) * | 2018-09-28 | 2019-01-04 | 贺州钟山县双文碳酸钙新材料有限公司 | Paint-emulsion paint modified calcium carbonate |
| CN109135344A (en) * | 2018-09-28 | 2019-01-04 | 贺州钟山县双文碳酸钙新材料有限公司 | Paint the surface treatment compound modifier of anti-aging calcium carbonate and its application |
| CN111004560A (en) * | 2019-12-24 | 2020-04-14 | 青海民族大学 | Coating for protecting ancient buildings |
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