CN107353521A - A kind of anti-aging insulation material - Google Patents
A kind of anti-aging insulation material Download PDFInfo
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- CN107353521A CN107353521A CN201710773962.4A CN201710773962A CN107353521A CN 107353521 A CN107353521 A CN 107353521A CN 201710773962 A CN201710773962 A CN 201710773962A CN 107353521 A CN107353521 A CN 107353521A
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- tiny balloon
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- insulation material
- haloflex
- ammonium salt
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/286—Chlorinated polyethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
- C08J2323/28—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2409/02—Copolymers with acrylonitrile
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
- C08L2205/20—Hollow spheres
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- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The present invention provides a kind of anti-aging insulation material, including body, the body surface are arranged with resistance wet layer；The body is to include following parts by weight component：Nitrile rubber 22 43, haloflex 35 46, aluminium hydroxide 5 19, magnesia are 15 26, chitosan quaternary ammonium salt 12 21, it is low it is floating it is fine without alkaline short glass fiber 4 15, calcium oxide 18 25, talcum powder be 26,22 35 parts of mannitol, 4 15 parts of carbon black, diphenylguanidine PG12 18, tiny balloon 14 32, the low floating fine length without alkaline short glass fiber is 9 15mm, a diameter of 5 11um.Inventive formulation uses aluminium hydroxide, haloflex, chitosan quaternary ammonium salt, mannitol, can not only be fire-retardant as primary raw material, and can prevent smoke, not produce droppings, do not produce toxic gas, it is superior compared to like product environmental-protecting performance on the market, it is pollution-free.
Description
Technical field
The present invention relates to product of rubber and plastic technical field, and in particular to a kind of anti-aging insulation material.
Background technology
Insulation material material mainly has two big application fields, first, the heat-insulation and heat-preservation field of architectural exterior-protecting construction, state's outgoing
Building thermal insulation material dosage up to country accounts for the 75%-80% of insulation material total amount, China's building thermal insulation material dosage proportion
Just increase year by year；Second, the cold and hot equipment of industry, kiln, pipeline, vehicles heat-insulation and heat-preservation.
The production of insulating rubber plastic and application under construction, after century 70, foreign countries have just paid attention to, and make every effort to
The consumption of the energy is greatly reduced, so as to reduce environmental pollution and greenhouse effects.External insulating rubber plastic industry has had
Very long history, in terms of the development of insulating rubber plastic slurry, developed country is to dab multi-functional composite slurry rubber at present
Mould based on insulation material.The more traditional slurry insulating rubber plastic of properties of such slurry insulating rubber plastic significantly improves,
Such as there is relatively low thermal conductivity factor and good safety in utilization and durability.Meanwhile this kind of composite slurry rubber and plastic thermal insulating material
Material has excellent feature again, such as non-freon flame retarded polyurethane-foam composite slurry insulating rubber plastic, Ultralight money
Hydrophobic calcium silicates slurry insulating rubber plastic etc., can meet the requirement of different use conditions.
Heat preservation technology level in China's has improved a lot in recent years, and the production capacity of insulation material constantly expands, kind with
It's too late for foreign countries' difference, but description series is not complete enough, and application technology and external gap are larger, integral heat insulation energy-saving benefit compared with
There is sizable gap in developed country.At home insulating rubber plastic because its cost it is cheap, be widely used in the day of people
Often in life, especially in packaging, field of thermal insulation, have become irreplaceable material.However, in the annual new building in China
In, only 10%-15% can reach the pressure energy conservation standard of country's formulation, it is seen that need in terms of the construction material energy-saving heat preserving in China
Improve.
It is fast with China's real estate, electric power, metallurgy, petroleum gas, petrochemical industry, decorations and environmental protection industry
Speed development, particularly building energy conservation are carried forward vigorously, and adiabatic heat-barrier material is rapidly developed so that the insulation material market demand
Increase very fast, customer requirement continuous development, NEW TYPE OF COMPOSITE stickup insulating rubber plastic future has wide market prospects.
The content of the invention
In view of this, the present invention provides the anti-aging thermal insulating material that a kind of performance of heat-insulating and fire-proof compared with prior art is obviously improved
Material, inventive formulation can not only be hindered using aluminium hydroxide, haloflex, chitosan quaternary ammonium salt, mannitol as primary raw material
Combustion, and smoke can be prevented, droppings is not produced, do not produce toxic gas, it is excellent compared to like product environmental-protecting performance on the market
More, it is pollution-free.
The technical scheme is that：Anti-aging insulation material, including body, it is characterised in that the body surface pair
Claim to be provided with resistance wet layer；The body is to include following parts by weight component：Nitrile rubber 22-43, haloflex 35-46, hydrogen
Aluminum oxide 5-19, magnesia 15-26, chitosan quaternary ammonium salt 12-21, low floating fibre are without alkaline short glass fiber 4-15, oxidation
Calcium 18-25, talcum powder 2-6, mannitol 22-35 parts, carbon black 4-15 parts, diphenylguanidine PG12-18, tiny balloon 14-32, institute
It is 9-15mm, a diameter of 5-11um to state the low floating fine length without alkaline short glass fiber.
In the present invention, the aluminium hydroxide, haloflex, chitosan quaternary ammonium salt, mannitol, low floating fibre are chopped without alkalescence
Glass fibre, tiny balloon synergistic compounding, are remarkably improved the fire resistance of body and the intensity of space structure.The accelerator
DPG can act as from effect property accelerator, and the good dispersion property in rubber makes rubber good mechanical property, suitable for tire,
Adhesive tape etc..
Further, the tiny balloon is polyaniline-graphite alkene tiny balloon, and the tiny balloon includes following weight
Number component：Polyaniline 23-45, graphene 16-28, aqueous polyurethane 9-21, epoxy resin 17-29.
Further, average grain diameter d=70-150um of the tiny balloon.
In the present invention, the tiny balloon of use, the thermal conductivity factor of material of the present invention can be effectively reduced, and then significantly improve
Thermal and insulating performance.Particularly, the tiny balloon can be prepared by this area any prior art.
The beneficial effects of the present invention are：
1st, inventive formulation is using aluminium hydroxide, haloflex, chitosan quaternary ammonium salt, and mannitol is as primary raw material, not only
Can be fire-retardant, and smoke can be prevented, droppings is not produced, do not produce toxic gas.
2nd, NEW TYPE OF COMPOSITE pastes the base material of insulating rubber plastic and uses presulfurization foaming technique, temperature in use at 100 DEG C just
The diphenylguanidine PG of sulphur can be played, sizing material first foams between high temperature 160-175 again after 120-150 DEG C of progress presulfurization of low temperature, so
Gas can be effectively pinned, expanded closed-cell rate is improved and reduces aperture, uniform foam cell, so as to heat insulation effect more preferably.
3rd, this compound stickup insulating rubber plastic, all material is researched and developed by national requirements for environmental protection, including foamed rubber-plastic,
Environment-friendlyglue glue, metal outer.It is superior compared to like product environmental-protecting performance on the market, it is pollution-free.
Embodiment
Embodiment 1
Anti-aging insulation material, including body 1, it is characterised in that the body surface is arranged with resistance wet layer 2；The body
It is to include following parts by weight component：Nitrile rubber 43, haloflex 46, aluminium hydroxide 19, magnesia 26, chitosan season
Ammonium salt 21, low floating fibre are without alkaline short glass fiber 15, calcium oxide 25, talcum powder 6,35 parts of mannitol, 15 parts of carbon black, promotion
Agent DPG18, tiny balloon 32, the low floating fine length without alkaline short glass fiber is 15mm, a diameter of 11um.The present invention
Body can be prepared by any processing method in this area.
Further, the tiny balloon is polyaniline-graphite alkene tiny balloon, and the tiny balloon includes following weight
Number component：Polyaniline 45, graphene 28, aqueous polyurethane 21, epoxy resin 29.
Further, average grain diameter d=150um of the tiny balloon.
In the present invention, the tiny balloon of use, the thermal conductivity factor of material of the present invention can be effectively reduced, and then significantly improve
Thermal and insulating performance.Particularly, the tiny balloon can be prepared by this area any prior art.
The beneficial effects of the present invention are：1st, inventive formulation uses aluminium hydroxide, haloflex, chitosan quaternary ammonium
Salt, mannitol, can not only be fire-retardant as primary raw material, and can prevent smoke, not produce droppings, do not produced poison gas
Body.
2nd, NEW TYPE OF COMPOSITE pastes the base material of insulating rubber plastic and uses presulfurization foaming technique, temperature in use at 100 DEG C just
The diphenylguanidine PG of sulphur can be played, sizing material first foams between high temperature 160-175 again after 120-150 DEG C of progress presulfurization of low temperature, so
Gas can be effectively pinned, expanded closed-cell rate is improved and reduces aperture, uniform foam cell, so as to heat insulation effect more preferably.
3rd, this compound stickup insulating rubber plastic, all material is researched and developed by national requirements for environmental protection, including foamed rubber-plastic,
Environment-friendlyglue glue, metal outer.It is superior compared to like product environmental-protecting performance on the market, it is pollution-free.
Embodiment 2
Anti-aging insulation material, including body 1, it is characterised in that the body surface is arranged with resistance wet layer 2；The body
It is to include following parts by weight component：Nitrile rubber 22, haloflex 35, aluminium hydroxide 5, magnesia 15, chitosan season
Ammonium salt 12, low floating fibre are without alkaline short glass fiber 4, calcium oxide 18, talcum powder 2,22 parts of mannitol, 4 parts of carbon black, accelerator
DPG12, tiny balloon 14, the low floating fine length without alkaline short glass fiber is 9mm, a diameter of 5um.
Further, the tiny balloon is polyaniline-graphite alkene tiny balloon, and the tiny balloon includes following weight
Number component：Polyaniline 23, graphene 16, aqueous polyurethane 9, epoxy resin 17.
Further, average grain diameter d=70um of the tiny balloon.
In the present invention, the tiny balloon of use, the thermal conductivity factor of material of the present invention can be effectively reduced, and then significantly improve
Thermal and insulating performance.Particularly, the tiny balloon can be prepared by this area any prior art.
Embodiment 3
Anti-aging insulation material, including body 1, it is characterised in that the body surface is arranged with resistance wet layer 2；The body
It is to include following parts by weight component：Nitrile rubber 33, haloflex 40, aluminium hydroxide 12, magnesia 20, chitosan season
Ammonium salt 16, low floating fibre are without alkaline short glass fiber 10, calcium oxide 22, talcum powder 4,29 parts of mannitol, 10 parts of carbon black, promotion
Agent DPG15, tiny balloon 23, the low floating fine length without alkaline short glass fiber is 12mm, a diameter of 8um.The present invention
Body can be prepared by any processing method in this area.
Further, the tiny balloon is polyaniline-graphite alkene tiny balloon, and the tiny balloon includes following weight
Number component：Polyaniline 34, graphene 22, aqueous polyurethane 15, epoxy resin 23.
Further, average grain diameter d=110um of the tiny balloon.
In the present invention, the tiny balloon of use, the thermal conductivity factor of material of the present invention can be effectively reduced, and then significantly improve
Thermal and insulating performance.Particularly, the tiny balloon can be prepared by this area any prior art.
The beneficial effects of the present invention are：1st, inventive formulation uses aluminium hydroxide, haloflex, chitosan quaternary ammonium
Salt, mannitol, can not only be fire-retardant as primary raw material, and can prevent smoke, not produce droppings, do not produced poison gas
Body.
2nd, NEW TYPE OF COMPOSITE pastes the base material of insulating rubber plastic and uses presulfurization foaming technique, temperature in use at 100 DEG C just
The diphenylguanidine PG of sulphur can be played, sizing material first foams between high temperature 160-175 again after 120-150 DEG C of progress presulfurization of low temperature, so
Gas can be effectively pinned, expanded closed-cell rate is improved and reduces aperture, uniform foam cell, so as to heat insulation effect more preferably.
3rd, this compound stickup insulating rubber plastic, all material is researched and developed by national requirements for environmental protection, including foamed rubber-plastic,
Environment-friendlyglue glue, metal outer.It is superior compared to like product environmental-protecting performance on the market, it is pollution-free.
Embodiment 4
Anti-aging insulation material, including body 1, it is characterised in that the body surface is arranged with resistance wet layer 2；The body
It is to include following parts by weight component：Nitrile rubber 25, haloflex 36, aluminium hydroxide 7, magnesia 17, chitosan season
Ammonium salt 14, low floating fibre are without alkaline short glass fiber 6, calcium oxide 20, talcum powder 3,24 parts of mannitol, 6 parts of carbon black, accelerator
DPG13, tiny balloon 16, the low floating fine length without alkaline short glass fiber is 11mm, a diameter of 7um.The present invention's
Body can be prepared by any processing method in this area.
Further, the tiny balloon is polyaniline-graphite alkene tiny balloon, and the tiny balloon includes following weight
Number component：Polyaniline 25, graphene 16, aqueous polyurethane 11, epoxy resin 19.
Further, average grain diameter d=76um of the tiny balloon.
In the present invention, the tiny balloon of use, the thermal conductivity factor of material of the present invention can be effectively reduced, and then significantly improve
Thermal and insulating performance.Particularly, the tiny balloon can be prepared by this area any prior art.
The beneficial effects of the present invention are：1st, inventive formulation uses aluminium hydroxide, haloflex, chitosan quaternary ammonium
Salt, mannitol, can not only be fire-retardant as primary raw material, and can prevent smoke, not produce droppings, do not produced poison gas
Body.
2nd, NEW TYPE OF COMPOSITE pastes the base material of insulating rubber plastic and uses presulfurization foaming technique, temperature in use at 100 DEG C just
The diphenylguanidine PG of sulphur can be played, sizing material first foams between high temperature 160-175 again after 120-150 DEG C of progress presulfurization of low temperature, so
Gas can be effectively pinned, expanded closed-cell rate is improved and reduces aperture, uniform foam cell, so as to heat insulation effect more preferably.
3rd, this compound stickup insulating rubber plastic, all material is researched and developed by national requirements for environmental protection, including foamed rubber-plastic,
Environment-friendlyglue glue, metal outer.It is superior compared to like product environmental-protecting performance on the market, it is pollution-free.
Embodiment 5
Anti-aging insulation material, including body 1, it is characterised in that the body surface is arranged with resistance wet layer 2；The body
It is to include following parts by weight component：Nitrile rubber 40, haloflex 43, aluminium hydroxide 16, magnesia 23, chitosan season
Ammonium salt 19, low floating fibre are 33 parts of 5 mannitol, 13 parts of carbon black, promotion without alkaline short glass fiber 13, calcium oxide 23, talcum powder
Agent DPG17, tiny balloon 30, the low floating fine length without alkaline short glass fiber is 13mm, a diameter of 10um.The present invention
Body can be prepared by any processing method in this area.
Further, the tiny balloon is polyaniline-graphite alkene tiny balloon, and the tiny balloon includes following weight
Number component：Polyaniline 43, graphene 26, aqueous polyurethane 17, epoxy resin 26.
Further, average grain diameter d=132um of the tiny balloon.
In the present invention, the tiny balloon of use, the thermal conductivity factor of material of the present invention can be effectively reduced, and then significantly improve
Thermal and insulating performance.Particularly, the tiny balloon can be prepared by this area any prior art.
The beneficial effects of the present invention are：1st, inventive formulation uses aluminium hydroxide, haloflex, chitosan quaternary ammonium
Salt, mannitol, can not only be fire-retardant as primary raw material, and can prevent smoke, not produce droppings, do not produced poison gas
Body.
2nd, NEW TYPE OF COMPOSITE pastes the base material of insulating rubber plastic and uses presulfurization foaming technique, temperature in use at 100 DEG C just
The diphenylguanidine PG of sulphur can be played, sizing material first foams between high temperature 160-175 again after 120-150 DEG C of progress presulfurization of low temperature, so
Gas can be effectively pinned, expanded closed-cell rate is improved and reduces aperture, uniform foam cell, so as to heat insulation effect more preferably.
3rd, this compound stickup insulating rubber plastic, all material is researched and developed by national requirements for environmental protection, including foamed rubber-plastic,
Environment-friendlyglue glue, metal outer.It is superior compared to like product environmental-protecting performance on the market, it is pollution-free.
Comparative example 1
Anti-aging insulation material, including body 1, it is characterised in that the body surface is arranged with resistance wet layer 2；The body
It is to include following parts by weight component：Nitrile rubber 33, haloflex 40, aluminium hydroxide 12, magnesia 20, chitosan season
Ammonium salt 16, low floating fibre are without alkaline short glass fiber 10, calcium oxide 22, talcum powder 4,29 parts of mannitol, 10 parts of carbon black, promotion
Agent DPG15, the low floating fine length without alkaline short glass fiber is 12mm, a diameter of 8um.The body of the present invention can pass through
Any processing method in this area prepares.
The beneficial effects of the present invention are：1st, inventive formulation uses aluminium hydroxide, haloflex, chitosan quaternary ammonium
Salt, mannitol, can not only be fire-retardant as primary raw material, and can prevent smoke, not produce droppings, do not produced poison gas
Body.
2nd, NEW TYPE OF COMPOSITE pastes the base material of insulating rubber plastic and uses presulfurization foaming technique, temperature in use at 100 DEG C just
The diphenylguanidine PG of sulphur can be played, sizing material first foams between high temperature 160-175 again after 120-150 DEG C of progress presulfurization of low temperature, so
Gas can be effectively pinned, expanded closed-cell rate is improved and reduces aperture, uniform foam cell, so as to heat insulation effect more preferably.
3rd, this compound stickup insulating rubber plastic, all material is researched and developed by national requirements for environmental protection, including foamed rubber-plastic,
Environment-friendlyglue glue, metal outer.It is superior compared to like product environmental-protecting performance on the market, it is pollution-free.
Comparative example 2
Anti-aging insulation material, including body 1, it is characterised in that the body surface is arranged with resistance wet layer 2；The body
It is to include following parts by weight component：Nitrile rubber 33, haloflex 40, aluminium hydroxide 12, magnesia 20, chitosan season
Ammonium salt 16, calcium oxide 22, talcum powder 4,29 parts of mannitol, 10 parts of carbon black, diphenylguanidine PG15, tiny balloon 23.
Further, the tiny balloon is polyaniline-graphite alkene tiny balloon, and the tiny balloon includes following weight
Number component：Polyaniline 34, graphene 22, aqueous polyurethane 15, epoxy resin 23.
Further, average grain diameter d=110um of the tiny balloon.
In the present invention, the tiny balloon of use, the thermal conductivity factor of material of the present invention can be effectively reduced, and then significantly improve
Thermal and insulating performance.Particularly, the tiny balloon can be prepared by this area any prior art.
The beneficial effects of the present invention are：1st, inventive formulation uses aluminium hydroxide, haloflex, chitosan quaternary ammonium
Salt, mannitol, can not only be fire-retardant as primary raw material, and can prevent smoke, not produce droppings, do not produced poison gas
Body.
2nd, NEW TYPE OF COMPOSITE pastes the base material of insulating rubber plastic and uses presulfurization foaming technique, temperature in use at 100 DEG C just
The diphenylguanidine PG of sulphur can be played, sizing material first foams between high temperature 160-175 again after 120-150 DEG C of progress presulfurization of low temperature, so
Gas can be effectively pinned, expanded closed-cell rate is improved and reduces aperture, uniform foam cell, so as to heat insulation effect more preferably.
3rd, this compound stickup insulating rubber plastic, all material is researched and developed by national requirements for environmental protection, including foamed rubber-plastic,
Environment-friendlyglue glue, metal outer.It is superior compared to like product environmental-protecting performance on the market, it is pollution-free.
Comparative example 3
Anti-aging insulation material, including body 1, it is characterised in that the body surface is arranged with resistance wet layer 2；The body
It is to include following parts by weight component：Nitrile rubber 33, magnesia 20, chitosan quaternary ammonium salt 16, low floating fibre are chopped without alkalescence
Glass fibre 10, calcium oxide 22, talcum powder 4,29 parts of mannitol, 10 parts of carbon black, diphenylguanidine PG15, tiny balloon 23, it is described
The low floating fine length without alkaline short glass fiber is 12mm, a diameter of 8um.The body of the present invention can add by the way that this area is any
Work method prepares.
Further, the tiny balloon is polyaniline-graphite alkene tiny balloon, and the tiny balloon includes following weight
Number component：Polyaniline 34, graphene 22, aqueous polyurethane 15, epoxy resin 23.
Further, average grain diameter d=110um of the tiny balloon.
In the present invention, the tiny balloon of use, the thermal conductivity factor of material of the present invention can be effectively reduced, and then significantly improve
Thermal and insulating performance.Particularly, the tiny balloon can be prepared by this area any prior art.
The beneficial effects of the present invention are：1st, inventive formulation uses chitosan quaternary ammonium salt, mannitol as primary raw material,
Can not only be fire-retardant, and smoke can be prevented, droppings is not produced, do not produce toxic gas.
2nd, NEW TYPE OF COMPOSITE pastes the base material of insulating rubber plastic and uses presulfurization foaming technique, temperature in use at 100 DEG C just
The diphenylguanidine PG of sulphur can be played, sizing material first foams between high temperature 160-175 again after 120-150 DEG C of progress presulfurization of low temperature, so
Gas can be effectively pinned, expanded closed-cell rate is improved and reduces aperture, uniform foam cell, so as to heat insulation effect more preferably.
3rd, this compound stickup insulating rubber plastic, all material is researched and developed by national requirements for environmental protection, including foamed rubber-plastic,
Environment-friendlyglue glue, metal outer.It is superior compared to like product environmental-protecting performance on the market, it is pollution-free.
Thermal conductivity factor and shock resistance test
Choose embodiment and comparative example carries out thermal conductivity factor and shock resistance test, as a result such as table 1, wherein, thermal conductivity factor is surveyed
It is GB/T10294-2008 to calibrate standard, and shock resistance bioassay standard is GB/T115418-2589.
The fire-resistance thermal insulation board performance evaluation of table 1
| Experimental group | Impact resistance（Sheet metal thickness is 1cm）cm·kg | Thermal conductivity factor W/ (mK) |
| Embodiment 1 | 180 | 0.032 |
| Embodiment 2 | 175 | 0.041 |
| Embodiment 3 | 220 | 0.020 |
| Embodiment 5 | 225 | 0.023 |
| Comparative example 1 | 100 | 1.286 |
| Comparative example 2 | 85 | 1.582 |
| Comparative example 3 | 95 | 1.367 |
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes from the present invention, the present invention can be realized in other specific forms.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask rather than described above limits, it is intended that all changes in the implication and scope of the equivalency of claim will be fallen
Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can be by appointing
One prior art is realized.
Claims (3)
1. anti-aging insulation material, including body, it is characterised in that the body surface is arranged with resistance wet layer；The body
It is to include following parts by weight component：Nitrile rubber 22-43, haloflex 35-46, aluminium hydroxide 5-19, magnesia 15-
26th, chitosan quaternary ammonium salt 12-21, it is low it is floating it is fine without alkaline short glass fiber 4-15, it is calcium oxide 18-25, talcum powder 2-6, sweet
Reveal alcohol 22-35 parts, carbon black 4-15 parts, diphenylguanidine PG12-18, tiny balloon 14-32, the low floating fibre is without alkaline staple glass
The length of fiber is 9-15mm, a diameter of 5-11um.
2. anti-aging insulation material according to claim 1, it is characterised in that the tiny balloon is polyaniline-graphite
Alkene tiny balloon, the tiny balloon include following parts by weight component：Polyaniline 23-45, graphene 16-28, water-based poly- ammonia
Ester 9-21, epoxy resin 17-29.
3. anti-aging insulation material according to claim 1, it is characterised in that the average grain diameter d of the tiny balloon=
70-150um。
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710773962.4A CN107353521A (en) | 2017-08-31 | 2017-08-31 | A kind of anti-aging insulation material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710773962.4A CN107353521A (en) | 2017-08-31 | 2017-08-31 | A kind of anti-aging insulation material |
Publications (1)
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| CN107353521A true CN107353521A (en) | 2017-11-17 |
Family
ID=60290576
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710773962.4A Pending CN107353521A (en) | 2017-08-31 | 2017-08-31 | A kind of anti-aging insulation material |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107522915A (en) * | 2017-11-20 | 2017-12-29 | 惠州优比贝柠科技股份有限公司 | Compound viscose glue insulating rubber plastic |
| CN108485001A (en) * | 2018-01-25 | 2018-09-04 | 江苏海迅铁路器材集团股份有限公司 | A kind of novel rubber plastic thermal insulation material |
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