CN107352946A - A kind of epithermal energy silicon wafer porcelain energy-saving coatings and preparation method and application - Google Patents

A kind of epithermal energy silicon wafer porcelain energy-saving coatings and preparation method and application Download PDF

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CN107352946A
CN107352946A CN201710553565.6A CN201710553565A CN107352946A CN 107352946 A CN107352946 A CN 107352946A CN 201710553565 A CN201710553565 A CN 201710553565A CN 107352946 A CN107352946 A CN 107352946A
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heat energy
energy
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oxide
flux
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CN107352946B (en
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曹云
崔廷余
刘女姣
阳秀娟
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • C04B2111/00525—Coating or impregnation materials for metallic surfaces

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Abstract

The invention discloses a kind of epithermal energy silicon wafer porcelain energy-saving coatings and preparation method and application, the coating includes filler 60~70%, base-material 30~40%；The filler includes the black material of heat energy, No. 1 heat energy flux and No. 2 crystallite heat energy flux, and in the filler, the black material of heat energy, No. 1 heat energy flux and No. 2 crystallite heat energy flux mass ratioes are 5~7：3~5：90~110.Also disclose a kind of black cobalt material and the black material of heat energy comprising black cobalt material.The present invention provides a kind of epithermal energy silicon wafer porcelain energy-saving coatings, is aided in using the black cobalt material of specific heat energy, and plurality of raw materials, plays the effect of energy-conservation.

Description

A kind of epithermal energy silicon wafer porcelain energy-saving coatings and preparation method and application
Technical field
The invention belongs to paint field, is related to a kind of epithermal energy silicon wafer porcelain energy-saving coatings and preparation method and application.
Background technology
Reasonable employment heating energy source and the saving energy, it is important step and the measure of national energy-saving consumption reduction, according to domestic and international The present situation of energy-conserving product, a variety of energy-conserving products save energy consumptions 3~8% or so, do not adapt to the energy-saving country and state much Border demand.This research group after the research of technique more than 3 years, energy-saving material, heat energy, electromagnetism, microwave HEATING INFRARED technology, Ultraviolet, spectrum electric energy etc. are a series of technically to be studied, is tackled key problems, being improved through the experiments of thousands of times and tackling key problem, is successfully manufactured TCL201 type epithermal energy silicon wafer porcelain energy-saving coatings are gone out.
The content of the invention
Purpose to be solved by this invention is to be directed to problem above, there is provided a kind of epithermal energy silicon wafer porcelain energy-saving coatings, is adopted Aided in the black cobalt material of specific heat energy, and plurality of raw materials, play the effect of energy-conservation.
To realize object above, the technical solution adopted in the present invention is：A kind of black cobalt material of heat energy, a kind of include black cobalt material The black material of heat energy and a kind of epithermal energy silicon wafer porcelain energy-saving coatings comprising the black material of heat energy and preparation method and application.
A kind of black cobalt material of heat energy, by weight percentage, including：Cobalt carbonate 75~85%, yittrium oxide 0.8~1.2%, oxidation Aluminium 2~3%, bismuth oxide 1~2%, niobium oxide 0.5~1%, stainless steel powder 2~3%, black wood charcoal silicon 8~10%.
A kind of black material of heat energy, by weight percentage, including the black cobalt material 50~55% of heat energy, molybdenum oxide 8~9%, nickel oxide 2 ~3%, the titanium new material 10~11% of tetragonal zirconia polycrystal 12~14%, 890, chrome green 1~2%, rare earth 3~8%, oxygen Change cerium 1~2%, silicon nitride 2~3%.
Preferably, the 890 titanium new material is by titanium dioxide, yittrium oxide, niobium oxide, oxydone, nickel oxide, No. 1 heat energy Agent reaction is made.
A kind of epithermal energy silicon wafer porcelain energy-saving coatings, by weight percentage, including filler 60~70%, base-material 30~ 40%；The filler includes the black material of heat energy, No. 1 heat energy flux and No. 2 crystallite heat energy flux, in the filler, the black material of heat energy, No. 1 Heat energy flux and No. 2 crystallite heat energy flux mass ratioes are 5~7：3~5：90~110.
Preferably, No. 1 heat energy flux includes：Lithium carbonate, sodium hydroxide, zinc oxide, boron are done, aluminum oxide, silica, and two Titanium oxide, sodium tripolyphosphate, ice crystal, sodium carbonate；Its mass ratio is 3~4:4~5:2~3:17~18:1~2:15~16:4 ~5:3~4:4~5:1~2.
Preferably, by weight percentage, No. 2 crystallite heat energy flux include：Diboron trioxide 10~14%, silica 70~75%, potassium carbonate 7~9%, ice crystal 5~7%, chrome green 1~1.5%.
Preferably, the base-material is that silicon wafer gas melts heat-resistant adhesive, and the silicon wafer gas, which melts heat-resistant adhesive, to be included：Solid silicon is cut into slices, Gu Body potassium silicate, powder magnesium chloride, magnesium hydroxide；Its mass ratio is 50~60:25~30:80~90:60~70.
A kind of epithermal energy silicon wafer porcelain energy-saving coatings preparation method, comprises the following steps：
A.1 prepared by number heat energy flux
1）Raw material co-precipitation is handled：First by lithium carbonate, zinc oxide, aluminum oxide, silica, titanium dioxide, it is co-precipitated Processing, ball milling or is ground to 1000-1250 mesh superfines；
2）Batch mixing stirs：The high blunt or superfine type boron of selection is dry, sodium hydroxide, sodium tripolyphosphate, ice crystal, powdered sodium carbonate, then The complete lithium carbonate of precipitation process, zinc oxide etc. are placed in electric smelter and carry out batch mixing together, ball milling or to be ground to 900-1100 mesh ultra-fine Powder, No. 1 heat energy flux is made；
B.2 prepared by number crystallite heat energy flux
1）Raw material co-precipitation is handled：First by silica, potassium carbonate, chrome green, co-precipitation processing is carried out, is milled to 1000-1250 mesh superfines；
2）Batch mixing stirs：Choose high blunt or superfine type diboron trioxide, ice crystal powder, then the complete titanium dioxide of precipitation process together Silicon, potassium carbonate etc. are placed in electric smelter and carry out batch mixing, ball milling or are ground to 900-1100 mesh superfines, and No. 2 crystallite heat energy are made Flux；
C. prepared by the black cobalt material of heat energy
1）Raw material disposal of stability：By cobalt carbonate, yittrium oxide, aluminum oxide, bismuth oxide, niobium oxide, black wood charcoal silicon is in 900-1000 DEG C high-temperature calcination disposal of stability, obtains frit；
2）Raw material co-precipitation is handled：Frit carries out co-precipitation processing after crushing, grinding, and obtains required raw material through drying It is dry, it is milled to 1000-1250 mesh superfines；
3）Batch mixing：Stainless steel powder is chosen, is screened to 600-800 mesh, then the complete cobalt carbonate of precipitation process together, yittrium oxide, oxidation Aluminium, bismuth oxide, niobium oxide, black wood charcoal silicon carry out batch mixing, and black cobalt material is made；
D. prepared by the black material of heat energy
Raw material co-precipitation is handled：By black cobalt material, molybdenum oxide, nickel oxide, tetragonal zirconia polycrystal, 890 titanium new materials, three oxygen Change two chromium, rare earth, cerium oxide, silicon nitride, carry out co-precipitation processing, obtain required raw material drying, be milled to 1000-1250 Mesh superfines, batch mixing, the black material of heat energy is made；
E. prepared by base-material
Solid silicon is cut into slices, solid silicic acid potassium, powder magnesium chloride, magnesium hydroxide, silicon is made through 350-400 DEG C of vapor (steam) temperature reaction Brilliant gas melts heat-resistant adhesive, that is, base-material is made；
F. prepared by filler
No. 1 heat energy flux, No. 2 crystallite heat energy flux and the black material batch mixing stirring of heat energy are taken, filler is made；
G. prepared by energy-saving coatings
Filler is mixed with base-material, after stirring 35-40 minutes, is then ground to more than 1200 mesh, vibrates air pressure filtration, inspection Test, metal bucket packs, storage.
Preferably, No. 1 heat energy flux and No. 2 crystallite heat energy flux preparation process, electric smelter heats up in batch mixing stirring Curve is：Normal temperature protects Warm 15 minutes to 300 DEG C of 30 minutes heating-up times；300 to 500 DEG C of 45 minutes heating-up times, it is incubated 20 points Clock；500 to 750 spend the heating-up time 50 minutes, are incubated 15 minutes；750 to 950 DEG C of 55 minutes heating-up times, it is incubated 15 minutes； 950 to 1150 DEG C of 60 minutes heating-up times, it is incubated, crystalline phase automatic discharging function complete to raw material reaction, normal and continuous operation；
A kind of application of epithermal energy silicon wafer porcelain energy-saving coatings, the coating temperature in use are 100-1050 DEG C.
A kind of application of epithermal energy silicon wafer porcelain energy-saving coatings, the coating are applied to boiler, heating furnace, foundry furnace, ceramics Sintering furnace, heat-treatment furnace, on oven, power plant boiler monowall tube or wall with refractory lining, refracto, Gas-making Furnace, Crude Oil Transportation heat Stove, household electrical appliance pot and stove apparatus, power plant's water-cooling wall, Industrial Stoves inwall, solar energy tube wall, stainless steel heater, military project, boat My god, smelting, the industry such as chemical industry.
Preferably, stainless steel powder, density are：7.55g/cm3。
Preferably, electric smelter is that double systems connect platinum crucibles or silica crucible, is communicated in an electric smelter provided with two Crucible, wherein the first crucible is raw material pyroreaction section；Second crucible is the complete liquid phase section of pyroreaction.Raw material is first In crucible then pyroreaction flows into the second crucible to liquid melts.
890 titanium new material used in the present invention, by weight, by titanium dioxide：Yittrium oxide：Niobium oxide：Oxydone：Oxidation Nickel：No. 1 heat energy flux=60-80:1-3:1-2:5-9:3-5:6-10, interact reaction under 800-1050 DEG C of high temperature, carries out Mix 30 minutes, sieve 900-1250 mesh, obtains 890 titanium new materials；890 DEG C of the 890 titanium new material softening point, it is therefore named 890 titanium new materials, there is heating speed-raising, aid in infra-red radiation power, improvement raw material is stable and low temperature uses, and it is fine and close to improve coating Degree, energy low absorption encourage the emissivity of infrared ray and wavelength.
Beneficial effects of the present invention：
1st, coating products of the present invention be widely used in boiler, heating furnace, ceramic sintering furnace, heat-treatment furnace, for oven, power plant boiler On monowall tube or wall with refractory lining, refracto, Gas-making Furnace, Crude Oil Transportation heating furnace, household electrical appliance pot and stove apparatus, military project, space flight, smelting, The industries such as chemical industry.The present invention is reachable to the use synthesis energy saving rate of industrial furnace, household electrical appliance, natural gas, oil, electric power, coal It is high energy-consuming enterprises to energy consumption more than 22% is saved, military project and household electric appliances are energy-saving with great economic benefit and society Benefit.
2nd, the present invention uses coprecipitation, can remove the impurity in raw material, improve the accuracy of product；The present invention adopts With disposal of stability, prevent paint coatings from ftractureing, improve the fractional energy savings and ageing resistance of product, make coating more stable, prevent Come off.
3rd, the present invention use No. 1 and No. 2 two kinds of flux, coating using when be adapted to the boiler of different temperatures, add Hot stove etc., two kinds of flux dissolve each other, but do not react between each other.
4th, the present invention does high temperature adhesive using specific base-material, can play good effect at high temperature, while No. 2 molten Agent can also play the effect of auxiliary bonding.
5th, the present invention uses the black cobalt material of specific heat energy, and No. 1 heat energy flux, No. 2 crystallite heat energy flux and silicon wafer gas melt The plurality of raw materials such as heat-resistant adhesive aid in, and play and save heat-resisting effect.
6th, coating of the present invention paints coating in inwalls such as boilers and metal covering sprays（Brush）After construction, fine and close integration knot is formed Structure, in high Warm（800-1200℃）In the presence of, coating progressively produces infrared ray and circulated with reflection, and temperature rapid increase is infrared Linear light energy, the increase of photovoltaic electric energy, current potential movement, blackness rise, due to the electric heating resistance in coating metal face and penetrating for infrared ray The expansion of power and infrared waves is had an effect, and mutually excites one infrared field of unified electromagnetism of composition, produces induction field, infrared ray, micro- The magnetic line of force interacts, and improves the programming rate of boiler, improves boiler temperature, reduces electricity consumption, with coal, the time with gas, plays The effect of energy-conservation.
Embodiment
In order that those skilled in the art more fully understand technical scheme, the present invention is retouched in detail below State, the description of this part is only exemplary and explanatory, there should not be any restriction effect to protection scope of the present invention.
In order that those skilled in the art more fully understand technical scheme, the present invention is retouched in detail below State, the description of this part is only exemplary and explanatory, there should not be any restriction effect to protection scope of the present invention.
It is specific embodiment below
Embodiment 1
A kind of black cobalt material of heat energy, by weight percentage, including：Cobalt carbonate 85%, yittrium oxide 1%, aluminum oxide 2%, bismuth oxide 1%, Niobium oxide 1%, stainless steel powder 2%, black wood charcoal silicon 8%.
One kind includes the black material of heat energy, by weight percentage, including the black cobalt material 50% of heat energy, molybdenum oxide 9%, nickel oxide 3%, Tetragonal zirconia polycrystal 14%, 890 titanium new materials 11%, chrome green 2%, rare earth 6%, cerium oxide 2%, silicon nitride 3%.
The 890 titanium new material, by weight, by titanium dioxide：Yittrium oxide：Niobium oxide：Oxydone：Nickel oxide：No. 1 Heat energy flux=60:1:1:5:3:6, interact reaction under 800 DEG C of high temperature, mix 30 minutes, and sieve 900 mesh, Obtain 890 titanium new materials；
A kind of epithermal energy silicon wafer porcelain energy-saving coatings, by weight percentage, including filler 60%, base-material 40%；The filler bag Include the black material of heat energy, No. 1 heat energy flux and No. 2 crystallite heat energy flux, in the filler, the black material of heat energy, No. 1 heat energy flux and No. 2 Crystallite heat energy flux mass ratio is 5：3：90.
No. 1 heat energy flux includes：Lithium carbonate, sodium hydroxide, zinc oxide, boron are done, aluminum oxide, silica, titanium dioxide, Sodium tripolyphosphate, ice crystal, sodium carbonate；Its mass ratio is 3:4:2:17:1:15:4:3:4:1.
By weight percentage, No. 2 crystallite heat energy flux include：Diboron trioxide 10%, silica 75%, potassium carbonate 9%, ice crystal 5%, chrome green 1%.
The base-material is that silicon wafer gas melts heat-resistant adhesive, and the silicon wafer gas, which melts heat-resistant adhesive, to be included：Solid silicon is cut into slices, solid silicic acid Potassium, powder magnesium chloride, magnesium hydroxide；Its mass ratio is 50:25:80:60.
A kind of epithermal energy silicon wafer porcelain energy-saving coatings preparation method, comprises the following steps：
A.1 prepared by number heat energy flux
1）Raw material co-precipitation is handled：First lithium carbonate, zinc oxide, aluminum oxide, silica, titanium dioxide, respectively individual event are ground Mill or ball milling, 5-7 hours then are soaked with pure water, discard upper strata floating debris, gained middle level is raw material, bottom needed for product Layered material is dried again, and co-precipitation, drying and processing, required raw material drying, are milled to 1000-1250 mesh superfine powders repeatedly End；
2）Batch mixing stirs：The high blunt or superfine type boron of selection is dry, sodium hydroxide, sodium tripolyphosphate, ice crystal, powdered sodium carbonate, then The complete lithium carbonate of precipitation process, zinc oxide etc. are placed in electric smelter and carry out batch mixing together, stirring, set heating curve and charging speed Degree, charging rate are 10-12 kilograms per hour, 1150 ± 15 DEG C of maximum temperature, and liquid material placement distance is in electric smelter crucible 0.8-0.9 rice, depth of water 0.8-0.9 rice is emitted into, is heated to liquid via electric smelter, reaction is eutectic under high temperature, flows into 8- Quenching 1.5-2.5 hours in 13 DEG C or so of recirculated cooling water, then drying, ball milling or to be ground to 900-1100 mesh ultra-fine Powder, No. 1 heat energy flux is made；
B.2 prepared by number crystallite heat energy flux
1）Raw material co-precipitation is handled：First by silica, potassium carbonate, chrome green, individual event grinding or ball milling are distinguished, then 5-7 hours are soaked with pure water, discard upper strata floating debris, gained middle level is that raw material, underlying material needed for product are dried again Dry, co-precipitation, drying and processing, required raw material drying, are milled to 1000-1250 mesh superfines repeatedly；
2）Batch mixing stirs：Choose high blunt or superfine type diboron trioxide, ice crystal powder, then the complete titanium dioxide of precipitation process together Silicon, potassium carbonate etc. are placed in electric smelter and carry out batch mixing, stirring, set heating curve and charging rate, charging rate is per hour 10-12 kilograms, 1150 ± 15 DEG C of maximum temperature, it is 0.8-0.9 rice that liquid material, which places distance, in electric smelter crucible, is emitted into the depth of water 0.8-0.9 rice, liquid is heated to via electric smelter, reaction is eutectic under high temperature, with 8-13 DEG C or so follow of wire type inflow Quenching 1.5-2.5 hours in ring cooling water, then drying, ball milling or be ground to 900-1100 mesh superfines, be made 2 Number crystallite heat energy flux；
C. prepared by the black cobalt material of heat energy
1）Raw material disposal of stability：Cobalt carbonate, yittrium oxide, aluminum oxide, bismuth oxide, niobium oxide, the difference individual event of black wood charcoal silicon are existed 900-1000 DEG C of high-temperature calcination disposal of stability, obtains frit；
2）Raw material co-precipitation is handled：Frit soaks 5-7 hours after crushing, grinding, with pure water, and it is miscellaneous to discard upper strata floating Thing, gained middle level are that raw material, underlying material needed for product are dried again, repeatedly co-precipitation, drying and processing, required raw material warp Drying, is milled to 1000-1250 mesh superfines,；
3）Batch mixing：Stainless steel powder is chosen, is screened to 600-800 mesh, then the complete cobalt carbonate of precipitation process together, yittrium oxide, oxidation Aluminium, bismuth oxide, niobium oxide, black wood charcoal silicon carry out batch mixing, stirring, black cobalt material are made；
D. prepared by the black material of heat energy
Raw material co-precipitation is handled：By black cobalt material, molybdenum oxide, nickel oxide, tetragonal zirconia polycrystal, 890 titanium new materials, three oxygen Change two chromium, rare earth, cerium oxide, silicon nitride, individual event grinding or ball milling, then soak 5-7 hours with pure water, discard upper strata respectively Debris is floated, gained middle level is that raw material, underlying material needed for product are dried again, repeatedly co-precipitation, drying and processing, required original Material drying, in proportion through 950 DEG C of heat treatments, 1000-1250 mesh superfines is milled to, batch mixing, is stirred, heat is made Can black material；
E. prepared by base-material
Solid silicon is cut into slices, solid silicic acid potassium, powder magnesium chloride, magnesium hydroxide, silicon is made through 350-400 DEG C of vapor (steam) temperature reaction Brilliant gas melts heat-resistant adhesive, that is, base-material is made；
F. prepared by filler
No. 1 heat energy flux, No. 2 crystallite heat energy flux and the black material batch mixing stirring of heat energy are taken, filler is made；
G. prepared by energy-saving coatings
Filler is mixed with base-material, after stirring 35-40 minutes, is then ground to more than 1200 mesh, vibrates air pressure filtration, inspection Test, metal bucket packs, storage.
No. 1 heat energy flux and No. 2 crystallite heat energy flux preparation process, electric smelter heating curve is in batch mixing stirring： Normal temperature protects Warm 15 minutes to 300 DEG C of 30 minutes heating-up times；300 to 500 DEG C of 45 minutes heating-up times, it is incubated 20 minutes；500 To 750 degree of 50 minutes heating-up times, 15 minutes are incubated；750 to 950 DEG C of 55 minutes heating-up times, it is incubated 15 minutes；950 to 1150 DEG C of 60 minutes heating-up times, it is incubated, crystalline phase automatic discharging function complete to raw material reaction, normal and continuous operation；
Embodiment 2
A kind of black cobalt material of heat energy, by weight percentage, including：Cobalt carbonate 85%, yittrium oxide 0.8%, aluminum oxide 2.2%, bismuth oxide 1.5%, niobium oxide 0.5%, stainless steel powder 2%, black wood charcoal silicon 8%.
One kind includes the black material of heat energy, by weight percentage, including the black cobalt material 55% of heat energy, molybdenum oxide 8%, nickel oxide 2%, Tetragonal zirconia polycrystal 12%, 890 titanium new materials 11%, chrome green 2%, rare earth 6%, cerium oxide 2%, silicon nitride 2%.
The 890 titanium new material, by weight, by titanium dioxide：Yittrium oxide：Niobium oxide：Oxydone：Nickel oxide：No. 1 Heat energy flux=80: 3: 2: 9: 5:10, interact reaction under 1050 DEG C of high temperature, mix 30 minutes, mistake 1250 mesh are sieved, obtain 890 titanium new materials；
A kind of epithermal energy silicon wafer porcelain energy-saving coatings, by weight percentage, including filler 70%, base-material 30%；The filler bag Include the black material of heat energy, No. 1 heat energy flux and No. 2 crystallite heat energy flux, in the filler, the black material of heat energy, No. 1 heat energy flux and No. 2 Crystallite heat energy flux mass ratio is 7： 5： 110.
No. 1 heat energy flux includes：Lithium carbonate, sodium hydroxide, zinc oxide, boron are done, aluminum oxide, silica, titanium dioxide, Sodium tripolyphosphate, ice crystal, sodium carbonate；Its mass ratio is 4: 5: 3: 18: 2: 16:5: 4: 5: 2.
By weight percentage, No. 2 crystallite heat energy flux include：Diboron trioxide 14%, silica 70%, potassium carbonate 8%, ice crystal 7%, chrome green 1%.
The base-material is that silicon wafer gas melts heat-resistant adhesive, and the silicon wafer gas, which melts heat-resistant adhesive, to be included：Solid silicon is cut into slices, solid silicic acid Potassium, powder magnesium chloride, magnesium hydroxide；Its mass ratio is 60: 30: 90: 70.
The epithermal energy silicon wafer porcelain energy-saving coatings preparation method of embodiment 2, preparation method in reference implementation example 1, by embodiment 1 In raw material and percentage by weight and mass ratio be substituted in embodiment 2 corresponding raw material and dosage.
Embodiment 3
A kind of black cobalt material of heat energy, by weight percentage, including：Cobalt carbonate 80%, yittrium oxide 1.2%, aluminum oxide 2.8%, bismuth oxide 2%, niobium oxide 1%, stainless steel powder 3%, black wood charcoal silicon 10%.
One kind includes the black material of heat energy, by weight percentage, including the black cobalt material 52% of heat energy, molybdenum oxide 8.5%, nickel oxide 2.5%, tetragonal zirconia polycrystal 13%, 890 titanium new materials 11%, chrome green 2%, rare earth 6%, cerium oxide 2%, silicon nitride 3%。
The 890 titanium new material, by weight, by titanium dioxide：Yittrium oxide：Niobium oxide：Oxydone：Nickel oxide：No. 1 Heat energy flux=70:2:1.5:7:4:8, interact reaction under 900 DEG C of high temperature, mix 30 minutes, sieving 1000 Mesh, obtain 890 titanium new materials；
A kind of epithermal energy silicon wafer porcelain energy-saving coatings, by weight percentage, including filler 65%, base-material 35%；The filler bag Include the black material of heat energy, No. 1 heat energy flux and No. 2 crystallite heat energy flux, in the filler, the black material of heat energy, No. 1 heat energy flux and No. 2 Crystallite heat energy flux mass ratio is 6：4：100.
No. 1 heat energy flux includes：Lithium carbonate, sodium hydroxide, zinc oxide, boron are done, aluminum oxide, silica, titanium dioxide, Sodium tripolyphosphate, ice crystal, sodium carbonate；Its mass ratio is 3.5:4.5:2.5:17.5:1.5:15.5:4.5:3.5:4.5:1.5.
By weight percentage, No. 2 crystallite heat energy flux include：Diboron trioxide 12%, silica 72%, potassium carbonate 9%, ice crystal 6%, chrome green 1%.
The base-material is that silicon wafer gas melts heat-resistant adhesive, and the silicon wafer gas, which melts heat-resistant adhesive, to be included：Solid silicon is cut into slices, solid silicic acid Potassium, powder magnesium chloride, magnesium hydroxide；Its mass ratio is 55:28:85:65.
The epithermal energy silicon wafer porcelain energy-saving coatings preparation method of embodiment 3, preparation method in reference implementation example 1, by embodiment 1 In raw material and percentage by weight and mass ratio be substituted in embodiment 3 corresponding raw material and dosage.
Coating products characteristic of the present invention is：The product involves the high heat energy of low absorption using a variety of high heat energy, infrared ray, electromagnetism Material, composite modified, crosslinking technology principle, disposal of stability, according to infrared technique and electromagnetic energy, spectrum, blackness principle point Analysis, being formed through chemical technology Seiko configuration, the product heat conductivility is good, infrared heat radiation and antiradiation spectral emissivity, Normal direction hair rate superior performance entirely, heat are shaken stable performance, are firmly bonded, energy-saving effect is notable, and every power-saving technology index has reached Or reach more than 20% more than national and foreign standards requirement, integrated energy efficiency, it is that each row industry household electrical appliances, military project, energy-conservation subtract at present Row, the last word of optimal control.
Coating products energy-saving principle of the present invention：The product coating is heated, electromagnetic radiation, and infrared ray has extremely strong penetrate Power, the rapid thermally equivalent of heating object can be made, effectively shorten the heat time, blackness brings up to more than 0.85 from 0.45 or so, stove Body, inner surface of pot body radiation are jumped with quadruplicate numerical value, and in the presence of temperature, coating forms the porcelain body of compact structure System, coating heat transfer coefficient far below body of heater in itself, substantially reduce scattering and disappearing for burning capacity, carry the heating object thermal efficiency Height, reach the purpose for saving the energy.
Coating technology index of the present invention is as shown in table 1 below：
1 coating technology index of the present invention of table
Project Technical indicator
Heat resistance Coating heat resisting temperature is 100-1050 DEG C；
Infra-red electromagnetic emissivity ≥92%（Relatively）
Infra-red electromagnetic wavelength 3.2-9.5um
Compression strength Through 350 DEG C of heat treatments, compression strength 2000g/cm2
Thermal conductivity factor Degree during≤0.35 kilocalorie/meter（860℃）
Normal direction total emissivity ≥0.93
Adhesive force Adhesive force one-level, bears 2000g/cm2Impact after it is flawless
Vibrostability Coating is through cold cycling, flawless, no peeling
Proportion ≥1.92±0.5%（g/cm3）
Blackness 0.46→0.92
Spectral emissivity ≥0.925
Infra-red electromagnetic reflectivity ≥89%
Energy-saving effect 22-30%
It should be noted that herein, term " comprising ", "comprising" or its any other variant are intended to nonexcludability Include so that process, method, article or equipment including a series of elements not only include those key elements, but also Including the other element being not expressly set out, or also include for this process, method, article or equipment intrinsic want Element.
Specific case used herein is set forth to the principle and embodiment of the present invention, the explanation of above example It is only intended to help the method and its core concept for understanding the present invention.Described above is only the preferred embodiment of the present invention, should When pointing out due to the finiteness of literal expression, and unlimited concrete structure objectively be present, for the common skill of the art For art personnel, under the premise without departing from the principles of the invention, some improvement, retouching or change can also be made, can also incited somebody to action Above-mentioned technical characteristic is combined by rights；These improve retouching, change or combination, or not improved by utility model Design and technical scheme directly apply to other occasions, be regarded as protection scope of the present invention.

Claims (10)

  1. A kind of 1. black cobalt material of heat energy, it is characterised in that by weight percentage, including：Cobalt carbonate 75~85%, yittrium oxide 0.8~ 1.2%, aluminum oxide 2~3%, bismuth oxide 1~2%, niobium oxide 0.5~1%, stainless steel powder 2~3%, black wood charcoal silicon 8~10%.
  2. A kind of 2. black material of heat energy of the black cobalt material of the heat energy comprising claim 1, it is characterised in that by weight percentage, including The black cobalt material 50~55% of heat energy, molybdenum oxide 8~9%, nickel oxide 2~3%, the titanium new material of tetragonal zirconia polycrystal 12~14%, 890 10~11%, chrome green 1~2%, rare earth 3~8%, cerium oxide 1~2%, silicon nitride 2~3%.
  3. 3. the epithermal energy silicon wafer porcelain energy-saving coatings of a kind of black material of the heat energy comprising claim 2, it is characterised in that by weight hundred Divide than meter, including filler 60~70%, base-material 30~40%；The filler includes the black material of heat energy, No. 1 heat energy flux and No. 2 crystallites Heat energy flux, in the filler, the black material of heat energy, No. 1 heat energy flux and No. 2 crystallite heat energy flux mass ratioes are 5~7：3~5：90 ~110.
  4. A kind of 4. epithermal energy silicon wafer porcelain energy-saving coatings according to claim 3, it is characterised in that No. 1 heat energy flux bag Include：Lithium carbonate, sodium hydroxide, zinc oxide, boron are done, aluminum oxide, silica, titanium dioxide, sodium tripolyphosphate, ice crystal, carbon Sour sodium；Its mass ratio is 3~4:4~5:2~3:17~18:1~2:15~16:4~5:3~4:4~5:1~2.
  5. 5. a kind of epithermal energy silicon wafer porcelain energy-saving coatings according to claim 3, it is characterised in that by weight percentage Meter, No. 2 crystallite heat energy flux include：Diboron trioxide 10~14%, silica 70~75%, potassium carbonate 7~9%, ice crystal 5 ~7%, chrome green 1~1.5%.
  6. 6. a kind of epithermal energy silicon wafer porcelain energy-saving coatings according to claim 3, it is characterised in that the base-material is silicon wafer Gas melts heat-resistant adhesive, and the silicon wafer gas, which melts heat-resistant adhesive, to be included：Solid silicon is cut into slices, solid silicic acid potassium, powder magnesium chloride, magnesium hydroxide； Its mass ratio is 50~60:25~30:80~90:60~70.
  7. 7. any one epithermal energy silicon wafer porcelain energy-saving coatings preparation method as described in claim 3-6, it is characterised in that bag Include following steps：
    A.1 prepared by number heat energy flux
    1）Raw material co-precipitation is handled：First by lithium carbonate, zinc oxide, aluminum oxide, silica, titanium dioxide, it is co-precipitated Processing, ball milling or is ground to 1000-1250 mesh superfines；
    2）Batch mixing stirs：The high blunt or superfine type boron of selection is dry, sodium hydroxide, sodium tripolyphosphate, ice crystal, powdered sodium carbonate, then The complete lithium carbonate of precipitation process, zinc oxide etc. are placed in electric smelter and carry out batch mixing together, ball milling or to be ground to 900-1100 mesh ultra-fine Powder, No. 1 heat energy flux is made；
    B.2 prepared by number crystallite heat energy flux
    1）Raw material co-precipitation is handled：First by silica, potassium carbonate, chrome green, co-precipitation processing is carried out, is milled to 1000-1250 mesh superfines；
    2）Batch mixing stirs：Choose high blunt or superfine type diboron trioxide, ice crystal powder, then the complete titanium dioxide of precipitation process together Silicon, potassium carbonate etc. are placed in electric smelter and carry out batch mixing, ball milling or are ground to 900-1100 mesh superfines, and No. 2 crystallite heat energy are made Flux；
    C. prepared by the black cobalt material of heat energy
    1）Raw material disposal of stability：By cobalt carbonate, yittrium oxide, aluminum oxide, bismuth oxide, niobium oxide, black wood charcoal silicon is in 900-1000 DEG C high-temperature calcination disposal of stability, obtains frit；
    2）Raw material co-precipitation is handled：Frit carries out co-precipitation processing after crushing, grinding, and obtains required raw material through drying It is dry, it is milled to 1000-1250 mesh superfines；
    3）Batch mixing：Stainless steel powder is chosen, is screened to 600-800 mesh, then the complete cobalt carbonate of precipitation process together, yittrium oxide, oxidation Aluminium, bismuth oxide, niobium oxide, black wood charcoal silicon carry out batch mixing, and black cobalt material is made；
    D. prepared by the black material of heat energy
    Raw material co-precipitation is handled：By black cobalt material, molybdenum oxide, nickel oxide, tetragonal zirconia polycrystal, 890 titanium new materials, three oxygen Change two chromium, rare earth, cerium oxide, silicon nitride, carry out co-precipitation processing, obtain required raw material drying, be milled to 1000-1250 Mesh superfines, batch mixing, the black material of heat energy is made；
    E. prepared by base-material
    Solid silicon is cut into slices, solid silicic acid potassium, powder magnesium chloride, magnesium hydroxide, silicon is made through 350-400 DEG C of vapor (steam) temperature reaction Brilliant gas melts heat-resistant adhesive, that is, base-material is made；
    F. prepared by filler
    No. 1 heat energy flux, No. 2 crystallite heat energy flux and the black material batch mixing stirring of heat energy are taken, filler is made；
    G. prepared by energy-saving coatings
    Filler is mixed with base-material, after stirring 35-40 minutes, is then ground to more than 1200 mesh, vibrates air pressure filtration, inspection Test, metal bucket packs, storage.
  8. 8. a kind of epithermal energy silicon wafer porcelain energy-saving coatings preparation method according to claim 7, it is characterised in that described 1 Number heat energy flux and No. 2 crystallite heat energy flux preparation process, electric smelter heating curve is in batch mixing stirring：Normal temperature is risen to 300 DEG C The warm 30 minutes time, protect Warm 15 minutes；300 to 500 DEG C of 45 minutes heating-up times, it is incubated 20 minutes；During 500 to 750 degree heating Between 50 minutes, be incubated 15 minutes；750 to 950 DEG C of 55 minutes heating-up times, it is incubated 15 minutes；950 to 1150 DEG C of heating-up times 60 minutes, it is incubated, crystalline phase automatic discharging function complete to raw material reaction, normal and continuous operation.
  9. 9. the application of any one epithermal energy silicon wafer porcelain energy-saving coatings as described in claim 3-6, it is characterised in that the painting It is 100-1050 DEG C to expect temperature in use.
  10. 10. the application of any one epithermal energy silicon wafer porcelain energy-saving coatings as described in claim 3-6, it is characterised in that should Coating be applied to boiler, heating furnace, foundry furnace, ceramic sintering furnace, heat-treatment furnace, for oven, power plant boiler fin panel casing Pipe or wall with refractory lining, refracto on, Gas-making Furnace, Crude Oil Transportation heating furnace, household electrical appliance pot and stove apparatus, power plant's water-cooling wall, Industrial Stoves inwall, Solar energy tube wall, stainless steel heater, military project, space flight, smelting, chemical industry.
CN201710553565.6A 2017-07-08 2017-07-08 A kind of epithermal energy silicon wafer porcelain energy-saving coatings and the preparation method and application thereof Active CN107352946B (en)

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CN112723892A (en) * 2021-01-07 2021-04-30 林萍华 Preparation method of ceramic material with excellent thermal conductivity and ceramic material
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