CN107352839A - A kind of gunite concrete liquid alkali-free chlorine-free accelerator and preparation method thereof - Google Patents
A kind of gunite concrete liquid alkali-free chlorine-free accelerator and preparation method thereof Download PDFInfo
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- CN107352839A CN107352839A CN201710733893.4A CN201710733893A CN107352839A CN 107352839 A CN107352839 A CN 107352839A CN 201710733893 A CN201710733893 A CN 201710733893A CN 107352839 A CN107352839 A CN 107352839A
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- component
- free
- liquid alkali
- free chlorine
- accelerator
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/10—Accelerators; Activators
- C04B2103/12—Set accelerators
Abstract
The invention discloses a kind of gunite concrete liquid alkali-free chlorine-free accelerator and preparation method thereof.A kind of gunite concrete provided by the invention liquid alkali-free chlorine-free accelerator includes the solidifying component of rush, stable component, concrete enhancing component, pH and adjusts component.Alkali-free chlorine-free liquid accelerating agent non-corrosiveness and penetrating odor provided by the invention, it is in stable condition, adaptability is good.According to JC477 2005 experiment condition, alkali-free chlorine-free liquid accelerating agent provided by the invention is certified products when parameter is 5 7%.
Description
Technical field
The present invention relates to a kind of concrete additive, and in particular to a kind of gunite concrete liquid alkali-free chlorine-free accelerator
And preparation method thereof.
Background technology
In the prior art, gunite concrete is broadly divided into two kinds of aqua and pulvis with accelerator, and wherein aqua includes again
Alkali accelerator and alkali-free quick-coagulant, substantial amounts of sodium ion due to having in alkali accelerator be present and easily occur after alkali-aggregate reaction causes
Phase intensity declines the phenomenon for even ftractureing, coming off；So alkali-free liquid accelerating agent just becomes optimal selection.And current nothing
There is the present situation that production process is cumbersome, production cost is high in alkali liquid accelerating agent, greatly constrain alkali-free liquid accelerating agent in work
Popularization in journey, also rarely have businessman to produce and sell such accelerator.Common alkali-free liquid accelerating agent generally uses work on the market
The polyaluminium sulfate of industry level is as main functional component.
The content of the invention
It is an object of the invention to provide the good gunite concrete liquid alkali-free chlorine-free accelerator of a kind of environmental protection, rapid hardening effect
And preparation method thereof.
The present invention is achieved by the following technical solution：
A kind of gunite concrete includes following parts by weight of component with liquid alkali-free chlorine-free accelerator：Promote solidifying component, stable group
Divide, concrete enhancing component, pH regulation components.
It is further preferred that above-mentioned gunite concrete, with liquid alkali-free chlorine-free accelerator, the solidifying component of rush is sulfuric acid
Aluminium and/or aluminum fluoride；The stable component is citric acid, urea, triisopropanolamine, glycine, lactic acid, the mixture of sucrose；
Concrete enhancing component is in magnesium sulfate, magnesium fluosilicate, sodium metasilicate, calcium formate, calcium oxalate, calcium nitrate, hydroxylmethyl cellulose
One or more of mixing in element；The pH regulations component is one or more of mixing in phosphoric acid, sulfuric acid, trifluoroacetic acid.
Further, for above-mentioned gunite concrete with liquid alkali-free chlorine-free accelerator, the stable component is citric acid, urine
Element, triisopropanolamine, glycine, lactic acid, sucrose are according to mass ratio (1-6)：(1-6)：(1-6)：(1-6)：(1-6)：(1-6) is mixed
Close and prepare.
Alkali-free chlorine-free liquid accelerating agent preparation technology is comparatively simple, it is thus only necessary to which casings in twice, once heating can be complete
Into all operations, the production enforcement difficulty of enterprise is greatly reduced.Secondly, this accelerator selects the raw material of relative low price,
Have that stability is strong, hydrotropy is good using citric acid, urea as main complexing stable elements while be also that concrete is early strong
Agent, the solubility of aluminum sulfate in the solution can be greatly promoted and be enough to substitute polyaluminium sulfate while improve early strength；Three is different
Propanolamine can postpone the holding time of accelerator as auxiliary stabilizer, while can also improve early stage as concrete early strength agent
Intensity.Magnesium sulfate, sodium metasilicate and the miscible dissolution velocity that can significantly improve aluminum sulfate of aluminum sulfate, are that this technique is so simply closed
Key, make stable system with stablizing component generation complex reaction when aluminum sulfate quickly dissolves.
Further, for above-mentioned gunite concrete with liquid alkali-free chlorine-free accelerator, the solidifying component of rush presses following quality
Proportioning composition：The mass ratio of aluminum sulfate and aluminum fluoride is (1-5)：(1-5).
Further, above-mentioned gunite concrete is with liquid alkali-free chlorine-free accelerator, and the concrete enhancing component is by such as
Lower quality proportioning composition：In magnesium sulfate, magnesium fluosilicate, sodium metasilicate, the matter of calcium formate, calcium oxalate, calcium nitrate, hydroxymethyl cellulose
It is (10-14) to measure ratio：(7-10)：(1-2)：(1-2)：(1-2)：(1-3)：(1-2).
Further, above-mentioned gunite concrete with liquid alkali-free chlorine-free accelerator, by following quality matched somebody with somebody by the pH regulations
Than composition：Phosphoric acid, sulfuric acid, the mass ratio of trifluoroacetic acid are (1-5)：(1-5)：(1-5).
Above-mentioned gunite concrete includes step with the preparation method of liquid alkali-free chlorine-free accelerator：
S1. water is added in a kettle, is kept stirring for, and pre-heating temperature elevation is to 80 DEG C
S2. solidifying component, stable component, concrete enhancing component will load weighted in advance be promoted after temperature reaches design temperature
It is added in reactor, reacts 1.5 hours in the lump；
S3. pH regulations component is added dropwise after reaction terminates to adjust pH value to 2, naturally cools to room temperature and produces product.
The present invention has the advantages that：Alkali-free chlorine-free liquid accelerating agent non-corrosiveness provided by the invention and excitant
Smell, it is in stable condition, adaptability is good.According to JC477-2005 experiment condition, alkali-free chlorine-free liquid rapid hardening provided by the invention
Agent is certified products when parameter is 5-7%.
Embodiment
With reference to specific embodiment, the present invention will be further described.The embodiment is only being preferable to carry out for the present invention
Example, is not intended to limit the invention, for those skilled in the art, the present invention can have various changes and change
Change.Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., should be included in the present invention
Protection domain within.In each embodiment parts by weight are referred both to without signified component number in the case of specified otherwise.
Embodiment 1
Water is added in a kettle, and it is 150r/min that mixer, which sets rotating speed, and pre-heating temperature elevation is to 80 DEG C；
Load weighted 45% rush component, 25% stable component, 30% coagulation will be coagulated after temperature reaches design temperature in advance
Soil enhancing component is added in reactor in the lump, is reacted 1.5 hours；
It by aluminum sulfate and aluminum fluoride is 1 in mass ratio to promote solidifying component：5 prepare；Stable component is by citric acid, urea, three
Isopropanolamine, glycine, lactic acid, sucrose are according to mass ratio 2：3：5：2：6：1 mixed preparing；Concrete strengthens component by sulfuric acid
In magnesium, magnesium fluosilicate, sodium metasilicate, the mass ratio of calcium formate, calcium oxalate, calcium nitrate, hydroxymethyl cellulose be 10：10：1：2：
1.5：3：1 prepares；
Reaction is added dropwise pH regulations component and adjusts pH value to 2 after terminating；PH adjusts component by phosphoric acid, sulfuric acid, trifluoroacetic acid
Mass ratio be 1：5：1 prepares；
Room temperature is naturally cooled to, to improve stability.
Embodiment 2
Water is added in a kettle, and it is 150r/min that mixer, which sets rotating speed, and pre-heating temperature elevation is to 80 DEG C；
Load weighted 50% rush component, 25% stable component, 25% coagulation will be coagulated after temperature reaches design temperature in advance
Soil enhancing component is added in reactor in the lump, is reacted 1.5 hours；
It by aluminum sulfate and aluminum fluoride is 1 in mass ratio to promote solidifying component：5 prepare；Stable component is by citric acid, urea, three
Isopropanolamine, glycine, lactic acid, sucrose are according to mass ratio 5：2：6：3：1：5 mixed preparings；Concrete strengthens component by sulfuric acid
In magnesium, magnesium fluosilicate, sodium metasilicate, the mass ratio of calcium formate, calcium oxalate, calcium nitrate, hydroxymethyl cellulose be 14：7：2：1：2：1：
2 prepare；
Reaction is added dropwise pH regulations component and adjusts pH value to 2 after terminating；PH adjusts component by phosphoric acid, sulfuric acid, trifluoroacetic acid
Mass ratio be 5：2：3 prepare；
Room temperature is naturally cooled to, to improve stability.
Embodiment 3
Water is added in a kettle, and it is 150r/min that mixer, which sets rotating speed, and pre-heating temperature elevation is to 80 DEG C；
Load weighted 55% rush component, 25% stable component, 20% coagulation will be coagulated after temperature reaches design temperature in advance
Soil enhancing component is added in reactor in the lump, is reacted 1.5 hours；
It by aluminum sulfate and aluminum fluoride is 1 in mass ratio to promote solidifying component：5 prepare；Stable component is by citric acid, urea, three
Isopropanolamine, glycine, lactic acid, sucrose are according to mass ratio 3：5：1：6：2：1 mixed preparing；Concrete strengthens component by sulfuric acid
In magnesium, magnesium fluosilicate, sodium metasilicate, the mass ratio of calcium formate, calcium oxalate, calcium nitrate, hydroxymethyl cellulose be 12：8：2：2：2：1：
2 prepare；
Reaction is added dropwise pH regulations component and adjusts pH value to 2 after terminating；PH adjusts component by phosphoric acid, sulfuric acid, trifluoroacetic acid
Mass ratio be 5：1：4 prepare；
Room temperature is naturally cooled to, to improve stability.
Table 1 takes the commercial like product intensity of setting time, 1 day and 28 days intensity compared with this product is when parameter is 6%：
| Presetting period | Final setting time | 1 day intensity/MPa | 28 days intensity/MPa | |
| Blank | 180min | 240min | 54.90 | |
| Embodiment 1 | 8min60s | 12min20s | 10 | 44.86 |
| Embodiment 2 | 4min43s | 9min53s | 8 | 45.90 |
| Embodiment 3 | 4min25 | 8mn23 | 6 | 42.79 |
| Outer company's sample | 4min39s | 9min10s | 7 | 42.62 |
The Example 2 of table 2 carries out setting time experiment with different cement respectively
| Presetting period | Final setting time | |
| Reference cement | 4min50s | 9min36s |
| International trade cement | 4min05s | 9min00s |
| South Sea cement | 4min10s | 8min35s |
Claims (7)
1. a kind of gunite concrete liquid alkali-free chlorine-free accelerator, it is characterised in that including following parts by weight of component：
40-60 parts promote solidifying component, the stable component of 30-40 parts, 20-30 parts concrete enhancing component, 5-10 parts pH regulation components.
2. gunite concrete according to claim 1 liquid alkali-free chlorine-free accelerator, it is characterised in that
The solidifying component of rush is aluminum sulfate and/or aluminum fluoride；
The stable component is citric acid, urea, triisopropanolamine, glycine, lactic acid, the mixture of sucrose；
Concrete enhancing component is in magnesium sulfate, magnesium fluosilicate, sodium metasilicate, calcium formate, calcium oxalate, calcium nitrate, methylol
One or more of mixing in cellulose；
The pH regulations component is one or more of mixing in phosphoric acid, sulfuric acid, trifluoroacetic acid.
3. gunite concrete according to claim 2 liquid alkali-free chlorine-free accelerator, it is characterised in that
The stable component is citric acid, urea, triisopropanolamine, glycine, lactic acid, sucrose according to mass ratio (1-6)：(1-
6)：(1-6)：(1-6)：(1-6)：(1-6) mixed preparing.
4. gunite concrete according to claim 1 liquid alkali-free chlorine-free accelerator, it is characterised in that
It is described to promote solidifying component by following quality proportioning composition：
The mass ratio of aluminum sulfate and aluminum fluoride is (1-5)：(1-5).
5. gunite concrete according to claim 2 liquid alkali-free chlorine-free accelerator, it is characterised in that
The concrete enhancing component is formed by following quality proportioning：
In magnesium sulfate, magnesium fluosilicate, sodium metasilicate, the mass ratio of calcium formate, calcium oxalate, calcium nitrate, hydroxymethyl cellulose be (10-
14)：(7-10)：(1-2)：(1-2)：(1-2)：(1-3)：(1-2).
6. gunite concrete according to claim 2 liquid alkali-free chlorine-free accelerator, it is characterised in that
The pH regulations are formed by following quality proportioning：
Phosphoric acid, sulfuric acid, the mass ratio of trifluoroacetic acid are (1-5)：(1-5)：(1-5).
7. the preparation method of the gunite concrete liquid alkali-free chlorine-free accelerator as described in any one in claim 1 to 6,
It is characterised in that it includes step：
S1. water is added in a kettle, is kept stirring for, and pre-heating temperature elevation is to 80 DEG C；
S2. solidifying component, stable component, concrete enhancing component will load weighted in advance be promoted after temperature reaches design temperature in the lump
It is added in reactor, reacts 1.5 hours；
S3. pH regulations component is added dropwise after reaction terminates to adjust pH value to 2, naturally cools to room temperature and produces product.
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| CN201710733893.4A CN107352839A (en) | 2017-08-24 | 2017-08-24 | A kind of gunite concrete liquid alkali-free chlorine-free accelerator and preparation method thereof |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107954628A (en) * | 2018-01-19 | 2018-04-24 | 江苏苏博特新材料股份有限公司 | A kind of alkali-free chlorine-free sulfate radical-free liquid accelerator |
| CN108249802A (en) * | 2018-01-24 | 2018-07-06 | 武汉优城科技有限公司 | It is a kind of for solubilized stabilizer of high concentration polyaluminum sulfate aluminum solutions and preparation method thereof |
| CN108264257A (en) * | 2018-01-08 | 2018-07-10 | 贵州天威建材科技有限责任公司 | A kind of polymer phosphate aluminium series is without chlorine without sulphur alkali-free liquid setting accelerator and preparation method thereof |
| CN108585593A (en) * | 2018-08-13 | 2018-09-28 | 山西宝路加交通科技有限公司 | A kind of accelerator synthesis technology |
| CN109665736A (en) * | 2018-12-13 | 2019-04-23 | 中铁四局集团有限公司 | A kind of liquid accelerator and preparation method thereof |
| CN110451838A (en) * | 2019-08-05 | 2019-11-15 | 四川铁科新型建材有限公司 | A kind of novel energy-saving environment-friendly alkali-free quick-coagulant and preparation method thereof |
| CN110734242A (en) * | 2019-11-13 | 2020-01-31 | 中国建材检验认证集团厦门宏业有限公司 | sprayed concrete alkali-free liquid accelerator for alpine regions and preparation method thereof |
| CN111003962A (en) * | 2019-11-03 | 2020-04-14 | 湖南加美乐素新材料股份有限公司 | Alkali-free concrete accelerator and processing method thereof |
| CN111153619A (en) * | 2020-01-14 | 2020-05-15 | 攀枝花市吉源科技有限责任公司 | Non-hazardous chemical substance alkali-free accelerator of magnesium aluminum fluoride system and preparation method thereof |
| CN111377651A (en) * | 2018-12-29 | 2020-07-07 | 江苏苏博特新材料股份有限公司 | Low-alkali liquid accelerator containing microbial polysaccharide and preparation method thereof |
| CN111747675A (en) * | 2020-07-23 | 2020-10-09 | 中国科学院过程工程研究所 | Alkali-free accelerator and preparation method and application thereof |
| CN113548832A (en) * | 2021-08-26 | 2021-10-26 | 山东交通学院 | Alkali-free liquid foam concrete conditioning and solidifying agent and preparation method thereof |
| CN113880485A (en) * | 2021-11-02 | 2022-01-04 | 北京建筑大学 | Alkali-free fluorine-free liquid accelerator and preparation and application thereof |
| CN114988744A (en) * | 2022-06-15 | 2022-09-02 | 济南大学 | Concrete shrinkage-reducing reinforcing agent and application thereof |
| CN115636615A (en) * | 2022-11-04 | 2023-01-24 | 中南大学 | Alkali-free chlorine-free fluorine-free early strength type liquid accelerator and preparation method thereof |
| CN115947564A (en) * | 2023-03-11 | 2023-04-11 | 石家庄市长安育才建材有限公司 | High-adhesion low-resilience alkali-free accelerator and preparation method and use method thereof |
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| CN108264257A (en) * | 2018-01-08 | 2018-07-10 | 贵州天威建材科技有限责任公司 | A kind of polymer phosphate aluminium series is without chlorine without sulphur alkali-free liquid setting accelerator and preparation method thereof |
| CN108264257B (en) * | 2018-01-08 | 2020-06-02 | 贵州天威建材科技有限责任公司 | Polymerized aluminum phosphate series chlorine-free sulfur-free liquid alkali-free setting accelerator and preparation method thereof |
| CN107954628A (en) * | 2018-01-19 | 2018-04-24 | 江苏苏博特新材料股份有限公司 | A kind of alkali-free chlorine-free sulfate radical-free liquid accelerator |
| CN107954628B (en) * | 2018-01-19 | 2020-06-26 | 江苏苏博特新材料股份有限公司 | Alkali-free chlorine-free sulfate radical-free liquid accelerator |
| CN108249802B (en) * | 2018-01-24 | 2020-10-02 | 武汉优城科技有限公司 | Solubilization stabilizer for high-concentration polyaluminum sulfate solution and preparation method thereof |
| CN108249802A (en) * | 2018-01-24 | 2018-07-06 | 武汉优城科技有限公司 | It is a kind of for solubilized stabilizer of high concentration polyaluminum sulfate aluminum solutions and preparation method thereof |
| CN108585593A (en) * | 2018-08-13 | 2018-09-28 | 山西宝路加交通科技有限公司 | A kind of accelerator synthesis technology |
| CN109665736A (en) * | 2018-12-13 | 2019-04-23 | 中铁四局集团有限公司 | A kind of liquid accelerator and preparation method thereof |
| CN109665736B (en) * | 2018-12-13 | 2021-09-24 | 中铁四局集团有限公司 | Liquid accelerator and preparation method thereof |
| CN111377651A (en) * | 2018-12-29 | 2020-07-07 | 江苏苏博特新材料股份有限公司 | Low-alkali liquid accelerator containing microbial polysaccharide and preparation method thereof |
| CN110451838A (en) * | 2019-08-05 | 2019-11-15 | 四川铁科新型建材有限公司 | A kind of novel energy-saving environment-friendly alkali-free quick-coagulant and preparation method thereof |
| CN111003962A (en) * | 2019-11-03 | 2020-04-14 | 湖南加美乐素新材料股份有限公司 | Alkali-free concrete accelerator and processing method thereof |
| CN110734242A (en) * | 2019-11-13 | 2020-01-31 | 中国建材检验认证集团厦门宏业有限公司 | sprayed concrete alkali-free liquid accelerator for alpine regions and preparation method thereof |
| CN110734242B (en) * | 2019-11-13 | 2021-08-03 | 中国建材检验认证集团厦门宏业有限公司 | Sprayed concrete alkali-free liquid accelerator for alpine regions and preparation method thereof |
| CN111153619A (en) * | 2020-01-14 | 2020-05-15 | 攀枝花市吉源科技有限责任公司 | Non-hazardous chemical substance alkali-free accelerator of magnesium aluminum fluoride system and preparation method thereof |
| CN111747675A (en) * | 2020-07-23 | 2020-10-09 | 中国科学院过程工程研究所 | Alkali-free accelerator and preparation method and application thereof |
| CN111747675B (en) * | 2020-07-23 | 2022-06-17 | 中国科学院过程工程研究所 | Alkali-free accelerator and preparation method and application thereof |
| CN113548832A (en) * | 2021-08-26 | 2021-10-26 | 山东交通学院 | Alkali-free liquid foam concrete conditioning and solidifying agent and preparation method thereof |
| CN113880485A (en) * | 2021-11-02 | 2022-01-04 | 北京建筑大学 | Alkali-free fluorine-free liquid accelerator and preparation and application thereof |
| CN114988744A (en) * | 2022-06-15 | 2022-09-02 | 济南大学 | Concrete shrinkage-reducing reinforcing agent and application thereof |
| CN115636615A (en) * | 2022-11-04 | 2023-01-24 | 中南大学 | Alkali-free chlorine-free fluorine-free early strength type liquid accelerator and preparation method thereof |
| CN115636615B (en) * | 2022-11-04 | 2023-09-08 | 中南大学 | Alkali-free chlorine-free fluorine-free early-strength liquid accelerator and preparation method thereof |
| CN115947564A (en) * | 2023-03-11 | 2023-04-11 | 石家庄市长安育才建材有限公司 | High-adhesion low-resilience alkali-free accelerator and preparation method and use method thereof |
| CN115947564B (en) * | 2023-03-11 | 2023-08-04 | 石家庄市长安育才建材有限公司 | High-adhesiveness low-resilience alkali-free accelerator, and preparation method and use method thereof |
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Application publication date: 20171117 |