CN1073478A - Prescription of composite detergent - Google Patents

Prescription of composite detergent Download PDF

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Publication number
CN1073478A
CN1073478A CN 91107555 CN91107555A CN1073478A CN 1073478 A CN1073478 A CN 1073478A CN 91107555 CN91107555 CN 91107555 CN 91107555 A CN91107555 A CN 91107555A CN 1073478 A CN1073478 A CN 1073478A
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CN
China
Prior art keywords
bottle
clean
washing
sodium
water
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Granted
Application number
CN 91107555
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Chinese (zh)
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CN1036074C (en
Inventor
朱兆其
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Shanghai Research Institute of Chemical Industry SRICI
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Shanghai Research Institute of Chemical Industry SRICI
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Priority to CN 91107555 priority Critical patent/CN1036074C/en
Publication of CN1073478A publication Critical patent/CN1073478A/en
Application granted granted Critical
Publication of CN1036074C publication Critical patent/CN1036074C/en
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/16—Phosphates including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/08—Acids

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

A kind of washing composition that contains the plurality of inorganic salt raw material in identical temperature and advance under bottle speed, can improve and reclaim the clean yield of bottle, simultaneously concentration is joined lowly, helps the alkalinity in the discharge of wastewater liquid, thereby has improved environmental protection condition.After using washing composition immersion of the present invention and washing, the clean rate of its bottle can reach more than 99%, the outward appearance of clean bottle is bright and clean bright, hand touches the sexy feel of bottle alkali-free, increase the check work efficiency and be easy to detect not clean as yet bottle, the pH value of clean bottle debris between 7～8, the pH of the waste water that bottle washing machine gives off＜10.Use washing composition of the present invention, one ton of beer of every filling is spent only for using 40% of NaOH.Washing composition of the present invention also can be used for washing other kinds beverage bottle, also can be used as the sanitising agent of glass port, ophthalmic lens.

Description

Prescription of composite detergent
The present invention belongs to contain plurality of inorganic salt raw material combination type washing composition.
In prior art, be applied to Beer Bottle and various types of beverages bottle washing composition, be to make washing composition mostly with liquid or solid NaOH.Qualification rate only reaches 95%, and the outward appearance of clean bottle is more unglazed, and it is strong that hand touches the alkali sense, debris PH＞8 of clean bottle, and waste water PH＞12 of discharging can't reach the phase of the giving requirement to clean bottle.
Report Ma in Malting and Brewing Seirce 2CO 3Or composite detergent, but the qualification rate of wash bottle has only 96%, also has the shortcoming of waste water PH＞11 of debris PH＞8, discharging, so eager needs are developed a kind of new composite detergent.
Each production brew-house all very payes attention to the Beer Bottle clean level both at home and abroad at present, and clean-out system has been proposed new demand.Therefore require to select for use efficient and the suitable washing composition of price substitutes, thereby satisfy every requirement wash bottle.
The objective of the invention is in identical temperature and advance under bottle speed, improve and reclaim the clean yield of bottle, simultaneously concentration is joined lowly, help the alkalinity in the discharge of wastewater liquid, thereby improved environmental protection condition.
The present invention is a kind of composite detergent based on the plurality of inorganic salt raw material, wherein comprises sodium hydroxide, yellow soda ash, tertiary sodium phosphate, tripoly phosphate sodium STPP and water, also is furnished with three kinds of additive A, B and C in washing composition.Additive A is to belong to vitriol and/or silicate and/or metasilicate.The used additive A of the present invention is sodium sulfate and/or water glass and/or Starso.Additive B is complexing agent ethylenediamine tetraacetic acid (EDTA) and/or citric acid.Addition of C is nontoxic non-ionic type defoamer thanomin.The PH of water-detergent solution system that is made up of above-mentioned prescription is between 7～8.
The prescription of SP-N washing composition of the present invention is different with the prescription of other like product, pollutes and the low advantage of cost thereby demonstrate to reduce, and the weight percent of washing composition of the present invention is: sodium hydroxide (NaOH) 1～30, yellow soda ash (Na 2CO 3) 0.1～10, tertiary sodium phosphate (Na 3PO 412H 2O) 1～50, tripoly phosphate sodium STPP (Na 5P 3O 10) 0.1～10, sodium sulfate (Na 2SO 4) 0.1～15, ethylenediamine tetraacetic acid (EDTA) C 2H 4N 2(CH 2COOH) 40.01～10, thanomin (NH 2CH 2CH 2OH) 0.01～1, water (H 2O) be surplus.
Also can replace sodium sulfate with water glass in the above-mentioned prescription, weight percent is: sodium hydroxide (NaOH) 1～30, yellow soda ash (Na 2CO 3) 0.1～10, tertiary sodium phosphate (Na 3PO 412H 2O) 1～50, tripoly phosphate sodium STPP (Na 5P 3O 10) 0.1～10, water glass (Na 2SiO 3) 0.1～15, ethylenediamine tetraacetic acid (EDTA) C 2H 4N 2(CH 2COOH) 40.01～10, thanomin (NH 2CH 2CH 2OH) 0.01～1, water (H 2O) be surplus.
The weight percent of composite detergent of the present invention prescription can also be sodium hydroxide (NaOH) 1～30, yellow soda ash (Na 2CO 3) 0.1～10, tertiary sodium phosphate (Na 3PO 412H 2O) 1～50, tripoly phosphate sodium STPP (Na 5P 3O 10) 0.1～10, sodium sulfate (Na 2SO 4) and/or water glass (Na 2SiO 3) and/or Starso (Na 2SiO 39H 2O) 0.1～15, ethylenediamine tetraacetic acid (EDTA) C 2H 4N 2(CH 2COOH) 4And/or citric acid HO 2CCH 2C(OH) (CO 2H) CH 2CCO 2H0.01～10, thanomin (NH 2CH 2CH 2OH) 0.01～1, water (H 2O) be surplus.
Washing composition of the present invention (SP-N), its form can be liquid or solids.The production technique of composite detergent is will to send in molten Jie's groove after the raw material metering earlier, adds the water through metering simultaneously, is provided with in molten Jie's groove and stirs and heating, and Heating temperature is 50～90 ℃.Then this solution being injected filter filters.Again solution is sent to send out in the vaporizer and evaporate, send into the crystallizer crystallization after being evaporated to finite concentration.That to flow out from crystallizer, that contain certain amount of solid at last material carries out liquid-solid separation, the liquid of gained and add an amount of additive after be liquid washing agent, solid phase adds an amount of additive again and is the solid detergent finished product through mixing after warm air drying.Solid detergent will dilute 50～100 times earlier when using, and best dilution is 65～80 times.
The composite detergent that SP-N type washing composition of the present invention is made up of the material of multiple efficacies, it has functions such as scale removal, chelating, wetting, sterilization, softening, protecting materials, so it has intensive cleaning function and good disinfecting power.
Contain strong scale remover in this washing composition, organic substances such as it can molten Jie wheat leaf, beer alcohol mother and residue thereof porous are again gone in the dirt, make loose dirt become the particle suspension shape.Once flushing, suspended substance promptly disperses to remove away, will not be bonded in the inwall of washing clean bottle again.And this washing composition is the sterilizing agent of no free chlorine.Therefore can guarantee that clean bottle can meet the sterilization requirement.Also contain the high-quality tenderizer in the washing composition, it can make molten Jie of the calcium ions and magnesium ions that contains in the former water, thereby well heater and shower fouling in the bottle washing machine are reduced, and has both improved thermo-efficiency, has also guaranteed the normal running of shower.Also added anticorrosive agent in washing composition, it can guarantee that the apparatus that contacts with washing composition is not corroded, so can prolong the work-ing life of equipment.
Because the selected additive of the present invention has complexation of metal ions and separating metal, prevent to lump, the effect of drying, sterilization, froth breaking, so use the composite detergent of this new prescription, in identical temperature and after advancing immersion under bottle speed, washing Beer Bottle, make the clean rate of bottle all can reach more than 99%, the outward appearance of clean bottle is bright and clean bright, hand touches the sexy feel of bottle alkali-free, has reached every index request of clean bottle.And can increase the check work efficiency and be easy to detect not clean as yet bottle, the residual residual pH value of clean bottle is between 7～8, and the PH of the waste water that bottle washing machine gives off＜10 have been improved environmental protection condition like this.
Use SP-N washing composition of the present invention, one ton of beer of every filling (about 1550 bottles) is spent only for using 40% of NaOH.
Used SP-N composite detergent of the present invention,, also reduced the service fee that beer is caused because of bottle is unclean after sale simultaneously, so also be one of approach that improves brew-house's prestige because the raising of washing rate reduces the rate of washing of returning because of unclean bottle.
Washing composition of the present invention not only can be used to wash Beer Bottle, also can wash saccharification C, I, P, fermentation C, I, P. on beer production line, not only washing effect is good and improved thermo-efficiency.When washing method washing rate when identical with heat, expense can be saved about 30% at least.Also can be used for washing other kinds beverage bottle.Can also be as the clean-out system of glass port, ophthalmic lens.The present invention's water reuse that is used for phosphatic apparatus system preferably.
Most preferred embodiment of the present invention:
Implement 1, the weight percent of composite detergent prescription is: sodium hydroxide 4, yellow soda ash 2, tertiary sodium phosphate 3, tripoly phosphate sodium STPP 0.3, sodium sulfate 1.3, ethylenediamine tetraacetic acid (EDTA) 0.05, thanomin 0.05, water are surplus, with 10000 of this prescription detergent washing Beer Bottles, underproof bottle is 60, qualification rate reaches 99.4%, and the PH of clean bottle debris is about about 7.8.
Example 2, the weight percent of composite detergent prescription is: sodium hydroxide 28, yellow soda ash 4, tertiary sodium phosphate 42, tripoly phosphate sodium STPP 3, sodium sulfate and/or water glass 4, ethylenediamine tetraacetic acid (EDTA) 1, thanomin 1, water are surplus.Diluent with this prescription washing composition washs 10000 of Beer Bottles, and underproof bottle is 70, and qualification rate reaches 99.3%, and the PH of clean bottle debris is about about 7.4.
Example 3, the weight percent of composite detergent prescription is: sodium hydroxide 8, yellow soda ash 1, tertiary sodium phosphate 6, tripoly phosphate sodium STPP 0.5, sodium sulfate and/or Starso 2, ethylenediamine tetraacetic acid (EDTA) and/or citric acid 0.2, thanomin 0.2, water are surplus.With 10000 of this prescription detergent washing Beer Bottles, underproof bottle is 40, and qualification rate reaches 99.6%, and the PH of clean bottle debris is about about 7.1.

Claims (5)

1, a kind of composite detergent based on the plurality of inorganic salt raw material, wherein contain sodium hydroxide, yellow soda ash, tertiary sodium phosphate, tripoly phosphate sodium STPP, water, it is characterized in that: this washing composition also is furnished with three kinds of additive A, B and C, additive A is vitriol and/or silicate and/or metasilicate, additive B is complexing agent ethylenediamine tetraacetic acid (EDTA) and/or citric acid, addition of C is a non-ionic type defoamer thanomin, and PH is between 7～8 in the water-detergent solution system.
2, according to the described composite detergent of claim 1, it is characterized in that: additive A is sodium sulfate and/or water glass and/or Starso.
3, according to claim 1,2 described composite detergents is characterized in that: its weight percent is
Sodium hydroxide (NaOH) 1～30
Yellow soda ash (Na 2CO 3) 0.1～10
Tertiary sodium phosphate (Na 3PO 412H 2O) 1～50
Tripoly phosphate sodium STPP (Na 5P 3O 10) 0.1～10
Sodium sulfate (Na 2SO 4) and/or water glass (Na 2SiO 3)
And/or Starso (Na 2SiO 39H 2O) 0.1～15
Ethylenediamine tetraacetic acid (EDTA) C 2H 4N 2(CH 2COOH) 4
And/or citric acid HO 2CCH 2C(OH) (CO 2H) CH 2CCO 2H
0.01～10
Thanomin (NH 2CH 2CH 2OH) 0.01～1
Water (H 2O) surplus
4, according to the described composite detergent of claim 3, it is characterized in that: its weight percent is
Sodium hydroxide (NaOH) 1～30
Yellow soda ash (Na 2CO 3) 0.1～10
Tertiary sodium phosphate (Na 3PO 412H 2O) 1～50
Tripoly phosphate sodium STPP (Na 5P 3O 10) 0.1～10
Sodium sulfate (Na 2SO 4) 0.1～15
Ethylenediamine tetraacetic acid (EDTA) C 2H 4N 2(CH 2COOH) 40.01～10
Thanomin (NH 2CH 2CH 2OH) 0.01～1
Water (H 2O) surplus
Or
Sodium hydroxide (NaOH) 1～30
Yellow soda ash (Na 2CO 3) 0.1～10
Tertiary sodium phosphate (Na 3PO 412H 2O) 1～50
Tripoly phosphate sodium STPP (Na 5P 3O 10) 0.1～10
Water glass (Na 2SiO 3) 0.1～15
Ethylenediamine tetraacetic acid (EDTA) C 2H 4N 2(CH 2COOH) 40.01～10
Thanomin (NH 2CH 2CH 2OH) 0.01～1
Water (H 2O) surplus
5, according to the described composite detergent of claim 3, it is characterized in that: the form of composite detergent is liquid and solid.
CN 91107555 1991-12-11 1991-12-11 Prescription of composite detergent Expired - Fee Related CN1036074C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 91107555 CN1036074C (en) 1991-12-11 1991-12-11 Prescription of composite detergent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 91107555 CN1036074C (en) 1991-12-11 1991-12-11 Prescription of composite detergent

Publications (2)

Publication Number Publication Date
CN1073478A true CN1073478A (en) 1993-06-23
CN1036074C CN1036074C (en) 1997-10-08

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100431675C (en) * 2006-11-03 2008-11-12 上海印钞厂 Scavenger for ultrafiltering ceramic membrane and its prepn and application
CN100453151C (en) * 2006-06-06 2009-01-21 娄底市裕德科技有限公司 Alkali-base detergent for inorganic ultrafiltering cermic membrane
CN102504982A (en) * 2011-11-08 2012-06-20 镇江方源生物科技有限公司 Mold removing cleaning agent
CN102601072A (en) * 2012-03-09 2012-07-25 王家德 Process for cleaning optical resin lens substrate and forming mould
CN103334112A (en) * 2013-06-18 2013-10-02 辽宁天龙化工有限公司 Oil removal cleaning agent for metal surfaces
CN104031768A (en) * 2014-06-12 2014-09-10 仇彩霞 Culture dish cleaning solution formula and cleaning process thereof
CN105176715A (en) * 2015-09-10 2015-12-23 黑龙江大学 Beer bottle cleaning agent and preparation method thereof
CN107384563A (en) * 2017-07-20 2017-11-24 湖南省鎏源新能源有限责任公司 A kind of type activators of SH 1
CN108485833A (en) * 2018-05-24 2018-09-04 安徽凤阳淮河玻璃有限公司 A kind of glass anti-pollution cleaning solution and preparation method thereof
CN110042018A (en) * 2019-04-14 2019-07-23 广州恒荣电子科技有限公司 A kind of clear slot agent of wiring board welding masking developing
CN110819479A (en) * 2019-12-03 2020-02-21 广州森波化工科技有限公司 Novel cleaning powder
CN111484905A (en) * 2019-12-21 2020-08-04 合肥皖化电泵有限公司 Furnace water pump inner cavity cleaning additive solution and use method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100404657C (en) * 2006-03-15 2008-07-23 江苏久吾高科技股份有限公司 Cleaning agent for ceramic film and its preparation method

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100453151C (en) * 2006-06-06 2009-01-21 娄底市裕德科技有限公司 Alkali-base detergent for inorganic ultrafiltering cermic membrane
CN100431675C (en) * 2006-11-03 2008-11-12 上海印钞厂 Scavenger for ultrafiltering ceramic membrane and its prepn and application
CN102504982A (en) * 2011-11-08 2012-06-20 镇江方源生物科技有限公司 Mold removing cleaning agent
CN102601072A (en) * 2012-03-09 2012-07-25 王家德 Process for cleaning optical resin lens substrate and forming mould
CN103334112B (en) * 2013-06-18 2015-02-18 辽宁天龙化工有限公司 Oil removal cleaning agent for metal surfaces
CN103334112A (en) * 2013-06-18 2013-10-02 辽宁天龙化工有限公司 Oil removal cleaning agent for metal surfaces
CN104031768A (en) * 2014-06-12 2014-09-10 仇彩霞 Culture dish cleaning solution formula and cleaning process thereof
CN105176715A (en) * 2015-09-10 2015-12-23 黑龙江大学 Beer bottle cleaning agent and preparation method thereof
CN105176715B (en) * 2015-09-10 2018-01-23 黑龙江大学 A kind of Detergent power
CN107384563A (en) * 2017-07-20 2017-11-24 湖南省鎏源新能源有限责任公司 A kind of type activators of SH 1
CN108485833A (en) * 2018-05-24 2018-09-04 安徽凤阳淮河玻璃有限公司 A kind of glass anti-pollution cleaning solution and preparation method thereof
CN110042018A (en) * 2019-04-14 2019-07-23 广州恒荣电子科技有限公司 A kind of clear slot agent of wiring board welding masking developing
CN110819479A (en) * 2019-12-03 2020-02-21 广州森波化工科技有限公司 Novel cleaning powder
CN111484905A (en) * 2019-12-21 2020-08-04 合肥皖化电泵有限公司 Furnace water pump inner cavity cleaning additive solution and use method thereof

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