CN107346808A - A kind of automobile starting/stopping system lithium ion battery - Google Patents

A kind of automobile starting/stopping system lithium ion battery Download PDF

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Publication number
CN107346808A
CN107346808A CN201710597797.1A CN201710597797A CN107346808A CN 107346808 A CN107346808 A CN 107346808A CN 201710597797 A CN201710597797 A CN 201710597797A CN 107346808 A CN107346808 A CN 107346808A
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CN
China
Prior art keywords
explosion
proof cap
curved slab
lithium ion
failure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710597797.1A
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Chinese (zh)
Inventor
吴晓潭
王枭烽
杨东兴
杨永
刘丹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG XINGHAI ENERGY TECHNOLOGY Co Ltd
Original Assignee
ZHEJIANG XINGHAI ENERGY TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG XINGHAI ENERGY TECHNOLOGY Co Ltd filed Critical ZHEJIANG XINGHAI ENERGY TECHNOLOGY Co Ltd
Priority to CN201710597797.1A priority Critical patent/CN107346808A/en
Publication of CN107346808A publication Critical patent/CN107346808A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/364Composites as mixtures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/147Lids or covers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • H01M50/574Devices or arrangements for the interruption of current
    • H01M50/578Devices or arrangements for the interruption of current in response to pressure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2200/00Safety devices for primary or secondary batteries
    • H01M2200/20Pressure-sensitive devices
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Secondary Cells (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The invention discloses a kind of automobile starting/stopping system lithium ion battery, including explosion-proof cap, failure of current device, shell and battery core, the shell coats whole battery core, and the upper end varus of shell compresses the outer rim upper end of explosion-proof cap, the failure of current device is welded by curved slab and surface plate, the outer rim upper surface of the curved slab is bonded with the outer rim lower surface of explosion-proof cap, and the outer edge of curved slab and the outer edge full weld of explosion-proof cap connect, the lower end weldering of the surface plate and curved slab connects, the upper end of surface plate and battery core connects, the battery core is by positive pole, barrier film, the structure that negative pole helically coiling forms, described negative pole is to be coated on copper foil to form by the negative material formed by soft carbon and carbonaceous mesophase spherules compounding.The present invention reduces internal resistance by the way of laser full weld, improves the fast charging and discharging ability of battery core, and soft carbon and carbonaceous mesophase spherules compounding form during negative material uses, and have quick charge capability and low temperature charging ability concurrently.

Description

A kind of automobile opens-stop system lithium ion battery
【Technical field】
The present invention relates to the technical field of lithium ion battery, more particularly to a kind of automobile opens-stop system lithium ion battery.
【Background technology】
As Chinese Government is persistently encouraged energy-saving and environment-friendly automobile, low oil consumption saves vehicle, will turn into domestic motor market Main flow.Meanwhile regulation requires oil consumption increasingly severeer, in order to reach these requirements, various power-saving technologies are progressively employed Promote, such as turbocharging, in-cylinder direct-jet, hybrid power, start stop system.
Start stop system, when vehicle is in halted state (non-parked state), engine is (and unconventional by break-off Idling is kept), while pause, in-engine lubricating oil can continuous running, engine interior is kept lubrication;Made when unclamping After dynamic pedal, engine will be again started up, now,, also will not be right even if frequently stopping and starting to walk because lubricating oil circulates always Engine interior causes to wear evidence.Relevant report, being capable of fuel-economizing 4%~5% equipped with start stop system automobile.And lithium ion battery Capacity is big, impulsive discharge ability is strong, the most suitable for start and stop power supply.
But there are two big key issues in lithium-ion-power cell as automobile start and stop power supply:1) lithium-ion-power cell exists Discharge and recharge problem under low temperature environment:Internal resistance increases lithium-ion-power cell at low ambient temperatures, active volume and multiplying power discharging Performance is significantly reduced, and easily causes startup ability to decline and can not normally start vehicle;2) the serious is low temperature charging performance, I.e. the charging of lithium-ion-power cell low temperature is also easy to produce analysis lithium phenomenon, sets off an explosion.And traditional lithium ion battery is using spot welding Mode (refers to Fig. 1), generally only 4 each pads, and internal resistance is big, have impact on the fast charging and discharging ability of battery core, therefore, it is necessary to It is proposed that a kind of automobile opens-stop system lithium ion battery, solution conventional ion battery fast charging and discharging ability is poor, low temperature fills The problem of electric bad low temperature.
【The content of the invention】
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of automobile opens-stop system lithium ion Battery, it aims to solve the problem that the positive terminal sub-assembly internal resistance of conventional ion battery in the prior art is higher, fast charging and discharging ability compared with Difference, the technical problem of the bad low temperature of low temperature charging.
To achieve the above object, the present invention proposes a kind of automobile and opens-stop system lithium ion battery, including Explosion-proof cap The upper end connection of cap, failure of current device, shell and battery core, described failure of current device and battery core, described explosion-proof cap Located at the top of failure of current device, and explosion-proof cap connects with the weldering of failure of current device, and described shell coats whole battery core, and And the upper end varus of shell compresses the outer rim upper end of explosion-proof cap, described failure of current device is welded by curved slab and surface plate Form, the center section of described curved slab is in spherical crown planar to lower recess, and the center section of described explosion-proof cap is convex It is in cap-like structure to go out, and the outer rim upper surface of described curved slab is bonded with the outer rim lower surface of explosion-proof cap, and curved slab is outer The outer edge full weld of edge and explosion-proof cap connects, and the lower end weldering of described surface plate and curved slab connects, under described surface plate End face and the upper surface of battery core connect, and described battery core is the structure formed by positive pole, barrier film, negative pole helically coiling, described Negative pole be by being uniformly coated on copper foil and being formed by soft carbon and the negative material that forms of carbonaceous mesophase spherules compounding.
Preferably, the external diameter for the curved slab stated is identical with the external diameter of explosion-proof cap, and curved slab is bonded with explosion-proof cap Afterwards, a circle laser spot welding is carried out along the outer of curved slab and explosion-proof cap junction by laser-beam welding machine, realizes curved slab It is connected with explosion-proof cap full weld.
Preferably, outer ring equidistantly distributed of the described explosion-proof cap in convex part has some steam vents.
Preferably, described failure of current device also includes connection ring, described connection ring is welded under curved slab End face, opening's edge offers stopper slot in the lower end of described connection ring, and described surface plate is inlaid in described stopper slot, and The center of surface plate offers through hole, and described through hole interior edge is welded by the lower surface of laser-beam welding machine and curved slab to be connected.
Preferably, described failure of current device is made up of aluminium flake.
Preferably, being provided with a circle shoulder in the upper inside wall of described shell, the internal diameter of described shoulder, which is less than, to be prevented Quick-fried block and the external diameter of failure of current device, the lower surface outer rim of described failure of current device prop up shoulder upper surface.
Preferably, described barrier film is set between a positive electrode and a negative electrode.
Preferably, the compound proportion of soft carbon and carbonaceous mesophase spherules is 1 in described negative material:(2~5).
Beneficial effects of the present invention:Compared with prior art, a kind of automobile provided by the invention opens-stop system lithium ion Battery, rational in infrastructure, by the way of laser full weld, conducting energy between the two is greatly improved with failure of current device in explosion-proof cap Power, more solder joint can increase the contact area of explosion-proof cap and failure of current device, and traditional spot welding, pole are replaced with full weld The big contact internal resistance for reducing battery core, by actual measurement, internal resistance is reduced to 0.08mOhm by original 0.12mOhm averages, improved The fast charging and discharging ability of battery core, meanwhile, connected by the full weld of a circle, greatly improve the shock resistance of battery core, help More preferable stability is kept in battery core;Soft carbon and carbonaceous mesophase spherules compounding form during negative material uses, and can have concurrently quick Charging ability and low temperature charging ability, circulating battery ability are obviously improved, and support more than 10C fast charges, cycle life 800 It is secondary to keep 80%.
The feature and advantage of the present invention will be described in detail by embodiment combination accompanying drawing.
【Brief description of the drawings】
Fig. 1 is that a kind of automobile of the embodiment of the present invention opens the-schematic diagram of stop system lithium ion battery;
Fig. 2 is that a kind of automobile of the embodiment of the present invention opens-half cut-away view of stop system lithium ion battery;
Fig. 3 is that a kind of automobile of the embodiment of the present invention opens the-top view of stop system lithium ion battery.
In figure:1- explosion-proof caps, 2 failure of current devices, 21- curved slabs, 22- surface plates, 23- connection rings, 24- are spacing Groove, 25- through holes, 3- shells, 31- shoulders, 4- battery cores.
【Embodiment】
To make the object, technical solutions and advantages of the present invention of greater clarity, below by drawings and Examples, to this Invention is further elaborated.However, it should be understood that the specific embodiments described herein are merely illustrative of the present invention, The scope being not intended to limit the invention.In addition, in the following description, the description to known features and technology is eliminated, to keep away Exempt from unnecessarily to obscure idea of the invention.
Refering to Fig. 3, the embodiment of the present invention provides a kind of automobile and opens-stop system lithium ion battery, including explosion-proof cap 1, Failure of current device 2, shell 3 and battery core 4, described failure of current device 2 are connected with the upper end of battery core 4, described Explosion-proof cap Cap 1 is located at the top of failure of current device 2, and explosion-proof cap 1 connects with the weldering of failure of current device 2, and described shell 3 coats entirely Battery core 4, and the upper end varus of shell 3 compresses the outer rim upper end of explosion-proof cap 1, and described failure of current device 2 is by curved slab 21 and surface plate 22 be welded, the center section of described curved slab 21 to lower recess be in spherical crown planar, described Explosion-proof cap It is in cap-like structure that the center section of cap 1 is protruding upward, the outer rim upper surface of described curved slab 21 with the outer rim of explosion-proof cap 1 End face is bonded, and the outer edge of curved slab 21 is connected with the outer edge full weld of explosion-proof cap 1, described surface plate 22 and curved slab 21 lower end weldering connects, and the described lower surface of surface plate 22 is connected with the upper surface of battery core 4, and described battery core 4 is by positive pole, isolation The structure that film, negative pole helically coiling form, described negative pole are the negative poles by being formed by soft carbon and carbonaceous mesophase spherules compounding Material is uniformly coated on copper foil and formed.
Further, the external diameter for the curved slab 21 stated is identical with the external diameter of explosion-proof cap 1, and curved slab 21 and Explosion-proof cap After cap 1 is bonded, a circle laser spot welding is carried out along the outer of curved slab 21 and the junction of explosion-proof cap 1 by laser-beam welding machine, Realize that curved slab 21 is connected with the full weld of explosion-proof cap 1.
Conventional positive terminal sub-assembly is generally linked together aluminium flake and cover plate by way of spot welding, because technique limits System, generally only 4 solder joints squeezed into from top to bottom, as shown in figure 1, internal resistance height be present in the sub-assembly that this mode is formed, and it is interior In the case that resistance is higher, the charge/discharge rates of battery are relatively low;In addition, pass through W=I2R understands that caused Joule heat is more, influences The security of battery, service life, operating efficiency and customer experience.And the automobile start-stop time with millisecond meter, internal resistance is wanted Ask very high, the present invention uses brand-new technique, and a circle laser spots are carried out in explosion-proof cap 1 and the junction of failure of current device 2 Weldering, so as to which ducting capacity between the two be greatly improved, more solder joint can increase explosion-proof cap 1 and failure of current device 2 Contact area, reduce the contact internal resistance of battery core.Sub-assembly shows through actual measurement:Internal resistance is reduced to by original 0.12mOhm averages 0.08mOhm, sub-assembly internal resistance more than 30% is directly reduced, improve the charge/discharge rates of battery, meanwhile, more solder joints Contribute to battery core to keep more preferable antivibration kinetic force, improve the stability of battery core.
In embodiments of the present invention, a circle shoulder 31, described shoulder 31 are provided with the upper inside wall of described shell 3 Internal diameter be less than the external diameter of explosion-proof cap 1 and failure of current device 2, the lower surface outer rim of described failure of current device 2 props up The upper surface of shoulder 31, and shell 3 is arranged to the conical surface at the outer wall of shoulder 31, plays a part of to strengthen support shoulder 31, contributes to Improve the structural strength of shoulder 31.
Further, outer ring equidistantly distributed of the described explosion-proof cap 1 in convex part has some steam vents 11, when When inside battery produces gas, it will be discharged in time from steam vent 11.
Further, described failure of current device 2 also includes connection ring 23, and described connection ring 23 is welded on curved slab 21 lower surface, opening's edge offers stopper slot 24 in the lower end of described connection ring 23, and described surface plate 22 is inlaid in described Stopper slot 24 in, and the center of surface plate 22 offers through hole 25, the described interior edge of through hole 25 pass through laser-beam welding machine with it is bent The lower surface weldering of panel 21 connects, and described failure of current device 2 is made up of aluminium flake.
Further, described barrier film is set between a positive electrode and a negative electrode, and soft carbon is with described negative material Between phase carbosphere compound proportion be 1:(2~5).
Traditional lithium ion battery negative material uses Delanium, is not suitable for low temperature discharge and recharge.Soft carbon is easy graphitization Carbon, can graphited amorphous carbon at a high temperature of referring to more than 2500 DEG C.The crystallinity of soft carbon is that degree of graphitization is low, crystal grain chi Very little small, interplanar distance is larger, is advantageous to notable expansion of the insertion of lithium without causing structure;Compatibility with electrolyte simultaneously Good, charge and discharge platform is higher.Had a clear superiority compared to common graphite at most 6-8C charge rate, soft carbon in terms of fast charge. However, soft carbon is there is also such as efficiency is low first, compacted density is low, and due to the presence of loose structure, easily absorb water oxygen uptake. Therefore, the present invention by into carbonaceous mesophase spherules mixing portion soft carbon be used as negative material, quick charge capability can be had concurrently With low temperature charging ability, more than 10C fast charges, 800 holdings 80% of cycle life are supported.It is now electrochemical at quick charge initial stage It is smaller to learn polarization, thus carbonaceous mesophase spherules can bear large current charge;Latter stage of charging is arrived, LiCx compounds are gradual Converted from second order compound L iC12 to single order compound L iC6, polarization sharply increases, and the soft carbon now with larger interlamellar spacing connects Power.Through experiment test, added in carbonaceous mesophase spherules after a certain proportion of soft carbon, circulating battery ability has obtained significantly carrying Rise, 10C charge and discharge cycles are promoted to 800 times by adulterating first 500 times, and it is bad to solve the charging of conventional lithium ion battery low temperature Problem.
A kind of automobile of the present invention opens-stop system lithium ion battery, rational in infrastructure, explosion-proof cap 1 and failure of current device 2 By the way of laser full weld, ducting capacity between the two is greatly improved, more solder joint can increase explosion-proof cap 1 and electric current The contact area of shearing device 2, traditional spot welding is replaced with full weld, greatly reduces the contact internal resistance of battery core, by surveying, Internal resistance is reduced to 0.08mOhm by original 0.12mOhm averages, improves the fast charging and discharging ability of battery core, meanwhile, pass through one The full weld connection of circle, greatly improves the shock resistance of battery core, contributes to battery core to keep more preferable stability;Negative material is adopted Formed with middle soft carbon and carbonaceous mesophase spherules compounding, quick charge capability and low temperature charging ability, circulating battery energy can be had concurrently Power is obviously improved, and supports more than 10C fast charges, 800 holdings 80% of cycle life.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention Any modification, equivalent substitution or improvement made within refreshing and principle etc., should be included in the scope of the protection.

Claims (8)

1. a kind of automobile opens-stop system lithium ion battery, including explosion-proof cap (1), failure of current device (2), shell (3) and Battery core (4), described failure of current device (2) are connected with the upper end of battery core (4), and described explosion-proof cap (1) is cut located at electric current The top of disconnected device (2), and explosion-proof cap (1) connects with failure of current device (2) weldering, described shell (3) coats whole battery core (4), and the upper end varus of shell (3) compresses the outer rim upper end of explosion-proof cap (1), it is characterised in that:Described failure of current Device (2) is welded by curved slab (21) and surface plate (22), and the center section of described curved slab (21) is in lower recess Spherical crown planar, it is in cap-like structure that the center section of described explosion-proof cap (1) is protruding upward, the outer rim of described curved slab (21) Upper surface is bonded with the outer rim lower surface of explosion-proof cap (1), and the outer edge of the outer edge of curved slab (21) and explosion-proof cap (1) Full weld connects, and the lower end weldering of described surface plate (22) and curved slab (21) connects, described surface plate (22) lower surface and battery core (4) upper surface connection, described battery core (4) is the structure formed by positive pole, barrier film, negative pole helically coiling, and described is negative Pole is to be uniformly coated on copper foil to form by the negative material formed by soft carbon and carbonaceous mesophase spherules compounding.
2. a kind of automobile as claimed in claim 1 opens-stop system lithium ion battery, it is characterised in that:Described curved slab (21) after external diameter is identical with the external diameter of explosion-proof cap (1), and curved slab (21) is bonded with explosion-proof cap (1), Laser Welding is passed through Pick and carry out a circle laser spot welding along the outer of curved slab (21) and explosion-proof cap (1) junction, realize curved slab (21) with Explosion-proof cap (1) full weld connects.
3. a kind of automobile as claimed in claim 1 opens-stop system lithium ion battery, it is characterised in that:Described Explosion-proof cap Outer ring equidistantly distributed of the cap (1) in convex part has some steam vents (11).
4. a kind of automobile as claimed in claim 1 opens-stop system lithium ion battery, it is characterised in that:Described electric current is cut Disconnected device (2) also includes connection ring (23), and described connection ring (23) is welded on the lower surface of curved slab (21), described connection Opening's edge offers stopper slot (24) in the lower end of ring (23), and described surface plate (22) is inlaid in described stopper slot (24), And the center of surface plate (22) offers through hole (25), described through hole (25) interior edge passes through laser-beam welding machine and curved slab (21) Lower surface weldering connect.
5. a kind of automobile as described in any one of claim 1 and 4 opens-stop system lithium ion battery, it is characterised in that:Institute The failure of current device (2) stated is made up of aluminium flake.
6. a kind of automobile as claimed in claim 1 opens-stop system lithium ion battery, it is characterised in that:Described shell (3) Upper inside wall on be provided with a circle shoulder (31), the internal diameter of described shoulder (31) is less than explosion-proof cap (1) and failure of current The external diameter of device (2), the lower surface outer rim of described failure of current device (2) prop up shoulder (31) upper surface.
7. a kind of automobile as claimed in claim 1 opens-stop system lithium ion battery, it is characterised in that:Described positive pole and Pass through barrier film interval between negative pole.
8. a kind of automobile as claimed in claim 1 opens-stop system lithium ion battery, it is characterised in that:Described negative pole material The compound proportion of soft carbon and carbonaceous mesophase spherules is 1 in material:(2~5).
CN201710597797.1A 2017-07-20 2017-07-20 A kind of automobile starting/stopping system lithium ion battery Pending CN107346808A (en)

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CN201710597797.1A CN107346808A (en) 2017-07-20 2017-07-20 A kind of automobile starting/stopping system lithium ion battery

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Application Number Priority Date Filing Date Title
CN201710597797.1A CN107346808A (en) 2017-07-20 2017-07-20 A kind of automobile starting/stopping system lithium ion battery

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111727516A (en) * 2018-02-16 2020-09-29 Fdk株式会社 Sealing body and battery

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US20020048700A1 (en) * 2000-10-23 2002-04-25 Materials And Systems Research, Inc. Internally manifolded, planar solid oxide fuel cell (SOFC) stack with an inexpensive interconnect
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CN103066250A (en) * 2011-10-18 2013-04-24 上海德朗能动力电池有限公司 Lithium ion battery negative electrode with double-layer active substance structure and lithium ion battery with the same
CN103236505A (en) * 2013-04-28 2013-08-07 泰兴市振兴电子有限公司 Power type lithium ion battery nut cap and welding process thereof
CN103346327A (en) * 2013-07-19 2013-10-09 天津力神电池股份有限公司 Lithium-ion battery negative material and lithium-ion power battery
CN104795527A (en) * 2014-01-21 2015-07-22 微宏动力系统(湖州)有限公司 Battery module

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1019974A1 (en) * 1997-09-05 2000-07-19 Ceramic Fuel Cells Limited Electrical conductivity in a fuel cell assembly
US20020048700A1 (en) * 2000-10-23 2002-04-25 Materials And Systems Research, Inc. Internally manifolded, planar solid oxide fuel cell (SOFC) stack with an inexpensive interconnect
JP2006040640A (en) * 2004-07-23 2006-02-09 Toyota Central Res & Dev Lab Inc Positive electrode active material, its manufacturing method and lithium secondary battery
CN102195040A (en) * 2010-03-13 2011-09-21 东莞新能源科技有限公司 Lithium ion battery
CN102005549A (en) * 2010-10-27 2011-04-06 杨学新 Explosion-proof combined cap of high-power battery
CN103066250A (en) * 2011-10-18 2013-04-24 上海德朗能动力电池有限公司 Lithium ion battery negative electrode with double-layer active substance structure and lithium ion battery with the same
CN103236505A (en) * 2013-04-28 2013-08-07 泰兴市振兴电子有限公司 Power type lithium ion battery nut cap and welding process thereof
CN103346327A (en) * 2013-07-19 2013-10-09 天津力神电池股份有限公司 Lithium-ion battery negative material and lithium-ion power battery
CN104795527A (en) * 2014-01-21 2015-07-22 微宏动力系统(湖州)有限公司 Battery module

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111727516A (en) * 2018-02-16 2020-09-29 Fdk株式会社 Sealing body and battery
CN111727516B (en) * 2018-02-16 2023-12-05 Fdk株式会社 Sealing body and battery

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