CN107345020A - A kind of door glass thermal isolation film - Google Patents
A kind of door glass thermal isolation film Download PDFInfo
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- CN107345020A CN107345020A CN201710621467.1A CN201710621467A CN107345020A CN 107345020 A CN107345020 A CN 107345020A CN 201710621467 A CN201710621467 A CN 201710621467A CN 107345020 A CN107345020 A CN 107345020A
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- thermal isolation
- isolation film
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08J2423/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08J2423/22—Copolymers of isobutene; butyl rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Joining Of Glass To Other Materials (AREA)
- Securing Of Glass Panes Or The Like (AREA)
Abstract
The invention belongs to protect technical field of membrane, and in particular to a kind of door glass thermal isolation film.The pad pasting is made up of compositions such as polyethylene, low molecule amount polyisobutene, vinyl silicone oil, ethylene-vinyl acetate copolymer, polybutylene terephthalate (PBT), ultra-violet absorber and plasticizer, film forming is extruded by calender, also has one layer of titanium nitride coating using physical vapour deposition (PVD) in film surface.The door glass thermal isolation film has good effect of heat insulation, can reduce the thermogenic action of outdoor solar light and air to indoor environment, it is seen that light transmission rate is preferable, and indoor lighting is not had an impact.The pad pasting is bonded without using chemical glue-line by way of vacuum suction with the glass of window；Easily put up and take off, may be reused.
Description
Technical field
The invention belongs to protect technical field of membrane, and in particular to a kind of door glass thermal isolation film.
Background technology
The window of many families is all windowpane, and these door and window daylighting effects are fine, but effect of heat insulation is poor；Even if having
A little windows use the double glazing with vacuum interlayer, but in hot summer, do not keep out sunlight still to indoor radiation.Wall
Heat-insulation layer heat insulation effect in body is preferable, but the effect of heat insulation of windowpane is poor, and this can increase the refrigerating thermal-insulation expense of family.
All it is the place that can not be stayed for a long time around window during summer, household articles also can be shone hot in many families；Even if
Draw the curtain together and also be difficult to the radiation for keeping out heat, and draw the curtain together daytime and can also influence indoor lighting.
In order to improve the effect of heat insulation of glass, people apply last layer thermal protection layer in glass surface, or put up protection
Film, this solves the heat-insulating problem of glass well.But the stop of these pad pastings or coating to light is also more serious, influences
Indoor lighting, and thermogenic action of the sunlight to indoor environment can be also influenceed in winter；Conventional safety film is posted on glass
It is difficult to peel afterwards.
The content of the invention
For problem above, it is an object of the invention to provide a kind of door glass thermal isolation film, the thermal isolation film has visible
Light transmission rate is high, the advantages of good heat-insulation effect, and easily puts up, also easily peels, may be reused.
A kind of door glass thermal isolation film, it is characterised in that according to mass fraction, the composition of the film is：Polyethylene 25-30
Part, low molecule amount polyisobutene 5-7 parts, vinyl silicone oil 8-14 parts, ethylene-vinyl acetate copolymer 11-15 parts, gather to benzene two
Formic acid butanediol ester 2-4 parts, ultra-violet absorber 2-3 parts, coalescents 2-5 parts, plasticizer 1-2 parts.
Preferably, it is according to mass fraction, the composition of the film：Polyethylene 27-29 parts, low molecule amount polyisobutene 6-7 parts,
Vinyl silicone oil 10-12 parts, ethylene-vinyl acetate copolymer 12-14 parts, polybutylene terephthalate (PBT) 2-3 parts, ultraviolet
Absorbent 2-3 parts, coalescents 3-4 parts, plasticizer 1-2 parts.
It is further preferred that according to mass fraction, the composition of the film is：28 parts of polyethylene, low molecule amount polyisobutene 6
Part, 11 parts of vinyl silicone oil, 13 parts of ethylene-vinyl acetate copolymer, 3 parts of polybutylene terephthalate (PBT), ultraviolet radiation absorption
2.5 parts of agent, 3 parts of coalescents, 1.5 parts of plasticizer.
Wherein, the pad pasting outer layer has also deposited titanium nitride layer.
Preferably, the coalescents are ethylene glycol monobutyl ether, and the plasticizer is phthalic acid ester.
Preferably, the thickness of the film layer is 0.25-0.3mm.
The preparation method of the pad pasting is：According to mass fraction, by polyethylene, low molecule amount polyisobutene, vinyl silicone oil,
Ethylene-vinyl acetate copolymer mixing is sent in mixer, is stirred, is then fed into extruder, then into extruder,
Polybutylene terephthalate (PBT), ultra-violet absorber, plasticizer and coalescents are sequentially added, are squeezed after above raw material is mixed
Go out to be granulated, obtained particle is sent in calender, is suppressed to obtain required pad pasting by roller, pad pasting is then used into physics gas
Phase sedimentation, deposit to obtain one layer of titanium nitride film on the surface of pad pasting, then film layer is dried and wound, obtains required door and window
Glass heat-proof film.
The application method of the thermal isolation film is：Door glass cleaning is clean, one layer of water is uniformly sprayed to glass surface, so
The pad pasting for having cut corresponding size is posted in glass surface afterwards, extrudes the water between film layer and glass with scraper plate, thermal isolation film is just
It is close with glass gluing.
A kind of door glass thermal isolation film provided by the invention, compared with prior art, there is advantages below：
The pad pasting has good effect of heat insulation, can reduce the radiation effects to indoor environment such as ultraviolet, mitigates room
Temperature rise effect of the outer high temperature air to interior.Indoor temperature is reduced, the energy resource consumption of the refrigeration plants such as air conditioner is reduced, saves very much
Can environmental protection.
And the more common pad pasting of visible light transmissivity of the pad pasting is higher, does not interfere with the daylighting of indoor environment, film layer
Ageing resistace is also preferable, under strong ultraviolet radiation, can also keep the service life of long period, in addition, the pad pasting does not make
With glue-line, it is bonded at by way of vacuum suction on glass, puts up and take off being all very easy to, can be easily after terminating in summer
Remove, can also be reused in summer in the coming year.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
Embodiment 1
According to mass fraction, 25 parts of polyethylene, 5 parts of low molecule amount polyisobutene, 8 parts of vinyl silicone oil, ethyl vinyl acetate second
11 parts of alkene copolymer, 2 parts of polybutylene terephthalate (PBT), 2 parts of ultra-violet absorber, 2 parts of ethylene glycol monobutyl ether, O-phthalic
1 part of acid esters.Polyethylene, low molecule amount polyisobutene, vinyl silicone oil, ethylene-vinyl acetate copolymer mixing are sent to mixed
In conjunction machine, it is stirred, is then fed into extruder, then into extruder, sequentially adds polybutylene terephthalate (PBT), purple
Ultraviolet absorbers, phthalic acid ester and ethylene glycol monobutyl ether, extruding pelletization after above raw material is mixed, obtained particle is sent
Enter into calender, suppressed to obtain required pad pasting by roller, the thickness of film layer is 0.25mm.Then pad pasting is used into physical vapor
Sedimentation, deposit to obtain one layer of titanium nitride film on the surface of pad pasting, then film layer is dried and wound, obtain required door and window glass
Glass thermal isolation film.
The application method of the thermal isolation film is：Door glass cleaning is clean, one layer of water is uniformly sprayed to glass surface, so
The pad pasting for having cut corresponding size is posted in glass surface afterwards, extrudes the water between film layer and glass with scraper plate, thermal isolation film is just
It is close with glass gluing.
Embodiment 2
According to mass fraction, 30 parts of polyethylene, 7 parts of low molecule amount polyisobutene, 14 parts of vinyl silicone oil, ethyl vinyl acetate
15 parts of ethylene copolymer, 4 parts of polybutylene terephthalate (PBT), 3 parts of ultra-violet absorber, 5 parts of ethylene glycol monobutyl ether, adjacent benzene two
2 parts of formic acid esters.Polyethylene, low molecule amount polyisobutene, vinyl silicone oil, ethylene-vinyl acetate copolymer are mixed and be sent to
In mixer, be stirred, be then fed into extruder, then into extruder, sequentially add polybutylene terephthalate (PBT),
Ultra-violet absorber, phthalic acid ester and ethylene glycol monobutyl ether, extruding pelletization after above raw material is mixed, the particle that will be obtained
It is sent in calender, is suppressed to obtain required pad pasting by roller, the thickness of film layer is 0.3mm.Then pad pasting is used into physics gas
Phase sedimentation, deposit to obtain one layer of titanium nitride film on the surface of pad pasting, then film layer is dried and wound, obtains required door and window
Glass heat-proof film.
The application method of the thermal isolation film is：Door glass cleaning is clean, one layer of water is uniformly sprayed to glass surface, so
The pad pasting for having cut corresponding size is posted in glass surface afterwards, extrudes the water between film layer and glass with scraper plate, thermal isolation film is just
It is close with glass gluing.
Embodiment 3
According to mass fraction, 27 parts of polyethylene, 6 parts of low molecule amount polyisobutene, 10 parts of vinyl silicone oil, ethyl vinyl acetate
13 parts of ethylene copolymer, 3 parts of polybutylene terephthalate (PBT), 2 parts of ultra-violet absorber, 4 parts of ethylene glycol monobutyl ether, adjacent benzene two
2 parts of formic acid esters.Polyethylene, low molecule amount polyisobutene, vinyl silicone oil, ethylene-vinyl acetate copolymer are mixed and be sent to
In mixer, be stirred, be then fed into extruder, then into extruder, sequentially add polybutylene terephthalate (PBT),
Ultra-violet absorber, phthalic acid ester and ethylene glycol monobutyl ether, extruding pelletization after above raw material is mixed, the particle that will be obtained
It is sent in calender, is suppressed to obtain required pad pasting by roller, the thickness of film layer is 0.27mm.Then pad pasting is used into physics gas
Phase sedimentation, deposit to obtain one layer of titanium nitride film on the surface of pad pasting, then film layer is dried and wound, obtains required door and window
Glass heat-proof film.
The application method of the thermal isolation film is：Door glass cleaning is clean, one layer of water is uniformly sprayed to glass surface, so
The pad pasting for having cut corresponding size is posted in glass surface afterwards, extrudes the water between film layer and glass with scraper plate, thermal isolation film is just
It is close with glass gluing.
Embodiment 4
According to mass fraction, 26 parts of polyethylene, 4 parts of low molecule amount polyisobutene, 12 parts of vinyl silicone oil, ethyl vinyl acetate
12 parts of ethylene copolymer, 3 parts of polybutylene terephthalate (PBT), 2 parts of ultra-violet absorber, 4 parts of ethylene glycol monobutyl ether, adjacent benzene two
1 part of formic acid esters.Polyethylene, low molecule amount polyisobutene, vinyl silicone oil, ethylene-vinyl acetate copolymer are mixed and be sent to
In mixer, be stirred, be then fed into extruder, then into extruder, sequentially add polybutylene terephthalate (PBT),
Ultra-violet absorber, phthalic acid ester and ethylene glycol monobutyl ether, extruding pelletization after above raw material is mixed, the particle that will be obtained
It is sent in calender, is suppressed to obtain required pad pasting by roller, the thickness of film layer is 0.3mm.Then pad pasting is used into physics gas
Phase sedimentation, deposit to obtain one layer of titanium nitride film on the surface of pad pasting, then film layer is dried and wound, obtains required door and window
Glass heat-proof film.
The application method of the thermal isolation film is：Door glass cleaning is clean, one layer of water is uniformly sprayed to glass surface, so
The pad pasting for having cut corresponding size is posted in glass surface afterwards, extrudes the water between film layer and glass with scraper plate, thermal isolation film is just
It is close with glass gluing.
Performance test
A certain fine period of summer is chosen, is contrasted on same balcony different glass window, the same time uses
The window of the embodiment thermal isolation film and the window without using thermal isolation film, the morning 9:00 to afternoon 2:00 point, the rise of temperature in 5h
Amplitude, follow-on test 5d, as the experiment to the pad pasting heat-proof quality, obtain following test result：
Table 1：The performance test results of the present embodiment
| Increasing extent of temperature (DEG C) | Control group | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| 1d | 12 | 6 | 4 | 5 | 5 |
| 2d | 11 | 5 | 5 | 4 | 5 |
| 3d | 10 | 5 | 4 | 5 | 4 |
| 4d | 13 | 6 | 6 | 7 | 6 |
| 5d | 12 | 6 | 5 | 5 | 5 |
Data above shows, the door glass thermal isolation film that the present embodiment provides, really with good heat insulation and preservation effect,
The thermogenic action of outdoor solar light and air to indoor environment can be reduced.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of door glass thermal isolation film, it is characterised in that according to mass fraction, the composition of the film is：Polyethylene 25-30 parts,
Low molecule amount polyisobutene 5-7 parts, vinyl silicone oil 8-14 parts, ethylene-vinyl acetate copolymer 11-15 parts, poly- terephthaldehyde
Sour butanediol ester 2-4 parts, ultra-violet absorber 2-3 parts, coalescents 2-5 parts, plasticizer 1-2 parts.
2. a kind of door glass thermal isolation film according to claim 1, it is characterised in that according to mass fraction, the composition of the film
For：Polyethylene 27-29 parts, low molecule amount polyisobutene 6-7 parts, vinyl silicone oil 10-12 parts, ethylene-vinyl acetate copolymer
12-14 parts, polybutylene terephthalate (PBT) 2-3 parts, ultra-violet absorber 2-3 parts, coalescents 3-4 parts, plasticizer 1-2
Part.
3. a kind of door glass thermal isolation film according to claim 1, it is characterised in that according to mass fraction, the composition of the film
For：28 parts of polyethylene, 6 parts of low molecule amount polyisobutene, 11 parts of vinyl silicone oil, 13 parts of ethylene-vinyl acetate copolymer, poly- pair
3 parts of benzene dicarboxylic acid butanediol ester, 2.5 parts of ultra-violet absorber, 3 parts of coalescents, 1.5 parts of plasticizer.
A kind of 4. door glass thermal isolation film according to claim 1, it is characterised in that：The pad pasting outer layer has also deposited nitridation
Titanium layer.
A kind of 5. door glass thermal isolation film according to claim 1, it is characterised in that：The coalescents are ethylene glycol only son
Ether, the plasticizer are phthalic acid ester.
A kind of 6. door glass thermal isolation film according to claim 1, it is characterised in that：The thickness of the film layer is 0.25-
0.3mm。
A kind of 7. door glass thermal isolation film according to claim 1, it is characterised in that：The preparation method of the pad pasting is：According to
Mass fraction, polyethylene, low molecule amount polyisobutene, vinyl silicone oil, ethylene-vinyl acetate copolymer mixing are sent to mixed
In conjunction machine, it is stirred, is then fed into extruder, then into extruder, sequentially adds polybutylene terephthalate (PBT), purple
Ultraviolet absorbers, plasticizer and coalescents, extruding pelletization after above raw material is mixed, calender is sent to by obtained particle
In, suppressed to obtain required pad pasting by roller, pad pasting is then used into physical vaporous deposition, deposits to obtain one on the surface of pad pasting
Layer titanium nitride film, film layer then dried and wound, and obtains required door glass thermal isolation film.
A kind of 8. door glass thermal isolation film according to claim 1, it is characterised in that：The application method of the thermal isolation film is：
Door glass cleaning is clean, one layer of water is uniformly sprayed to glass surface, is then posted in the pad pasting for having cut corresponding size
Glass surface, the water between film layer and glass is extruded with scraper plate, thermal isolation film is just close with glass gluing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710621467.1A CN107345020A (en) | 2017-07-27 | 2017-07-27 | A kind of door glass thermal isolation film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710621467.1A CN107345020A (en) | 2017-07-27 | 2017-07-27 | A kind of door glass thermal isolation film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107345020A true CN107345020A (en) | 2017-11-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710621467.1A Withdrawn CN107345020A (en) | 2017-07-27 | 2017-07-27 | A kind of door glass thermal isolation film |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107915889A (en) * | 2017-12-21 | 2018-04-17 | 福建泓宝信塑胶科技有限公司 | Intermediate film for laminated glasses and the laminated glass containing it |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483719A (en) * | 2013-08-28 | 2014-01-01 | 杭州正奥科技有限公司 | Repeatedly-adhered heat-insulating film and manufacturing method thereof |
-
2017
- 2017-07-27 CN CN201710621467.1A patent/CN107345020A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483719A (en) * | 2013-08-28 | 2014-01-01 | 杭州正奥科技有限公司 | Repeatedly-adhered heat-insulating film and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 于守武 等著: "《高分子材料改性 原理及技术》", 31 May 2015, 知识产权出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107915889A (en) * | 2017-12-21 | 2018-04-17 | 福建泓宝信塑胶科技有限公司 | Intermediate film for laminated glasses and the laminated glass containing it |
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Application publication date: 20171114 |