CN107340264A - Cleaning machine - Google Patents

Cleaning machine Download PDF

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Publication number
CN107340264A
CN107340264A CN201710196426.2A CN201710196426A CN107340264A CN 107340264 A CN107340264 A CN 107340264A CN 201710196426 A CN201710196426 A CN 201710196426A CN 107340264 A CN107340264 A CN 107340264A
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CN
China
Prior art keywords
light source
detection
ultraviolet
line receiver
control
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710196426.2A
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Chinese (zh)
Other versions
CN107340264B (en
Inventor
陈建华
王行飞
茅忠群
诸永定
刘戈
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Fotile Kitchen Ware Co Ltd
Original Assignee
Ningbo Fotile Kitchen Ware Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Ningbo Fotile Kitchen Ware Co Ltd filed Critical Ningbo Fotile Kitchen Ware Co Ltd
Priority to CN201710196426.2A priority Critical patent/CN107340264B/en
Publication of CN107340264A publication Critical patent/CN107340264A/en
Application granted granted Critical
Publication of CN107340264B publication Critical patent/CN107340264B/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/33Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using ultraviolet light
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01Arrangements or apparatus for facilitating the optical investigation
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/33Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using ultraviolet light
    • G01N2021/335Vacuum UV

Abstract

The present invention relates to a kind of cleaning machine, including the cleaning chamber with water inlet and delivery port, it is characterised in that:The water inlet or/and water outlet of the cleaning chamber are provided with the organic matter detection sensor for being used for detecting the Organic substance in water content for entering cleaning chamber or/and outflow cleaning chamber.Compared with prior art, the advantage of the invention is that:The organic matter detection sensor for being used for detecting the Organic substance in water content for entering cleaning chamber or/and outflow cleaning chamber is provided with by water inlet or/and water outlet that chamber is cleaned in cleaning machine, so that cleaning function detection enters the Organic substance in water content of cleaning chamber or/and outflow cleaning chamber;And then the Organic substance in water content for entering cleaning chamber or/and outflow cleaning chamber detected can be utilized, Mobile state adjustment is entered to the mode of washing of wash.

Description

Cleaning machine
Technical field
The present invention relates to a kind of cleaning machine, more particularly to a kind of cleaning that can detect content of organics in water inlet or water outlet Machine.
Background technology
The mode of washing of existing cleaning machine is all pre-set in controller, i.e., is previously provided with washing in controller Program, it is unified to be washed according to pre-set washing procedure regardless of the quality of water quality in use environment.Then differently Area's water quality difference is larger, and some regional water qualities are poor, and the water hardness is higher, and the organic components contained are more, other area Water quality is relatively preferable, and existing cleaning machine can not adjust mode of washing according to the water quality situation in washing cavities is entered.It is also, clear Washing machine can not adjust mode of washing in washing process according to by the content of organics in delivery port.
The detection of content of organics at present mainly relies on spectrophotometer, and its operation principle is:By being 254 to wavelength The trap of the ultraviolet of nanometer to characterize the total content of organic matter indirectly, after the ultraviolet that wavelength is 254 nanometers passes through water, water In organic matter can absorb the ultraviolet of part, and the concentration of organic matter is bigger, and the intensity of ultraviolet radiation absorption is also bigger, therefore purple The trap of outside line correspond to the content of organic matter.Different organic matters has different absorptions strong for different wave length ultraviolet Degree, by scanning the absorption intensity of different wave length ultraviolet, can substantially analyze the content of different type organics in water outlet.It is and total The measurement of content, i.e., the overall target of different content of organics, is mainly reflected on the ultraviolet of 254 nano wave lengths.But it is divided Photometer is an instrument in itself, and price is very expensive, and volume is also very huge, most importantly the use for ordinary person Also certain obstacle.
The content of the invention
The technical problems to be solved by the invention are to provide one kind for above-mentioned prior art to enter cleaning chamber or/and outflow Clean the cleaning machine of the Organic substance in water content of chamber.
Technical scheme is used by the present invention solves above-mentioned technical problem:A kind of cleaning machine, including with water inlet and The cleaning chamber of delivery port, it is characterised in that:The water inlet of the cleaning chamber or/and water outlet or/and cleaning intracavitary are provided with For detecting the organic matter detection sensor for the Organic substance in water content for entering cleaning chamber or/and outflow cleaning chamber.
As an improvement, the organic matter detection sensor, including the light source of ultraviolet can be sent, and coordinate with the light source The detection components that can detect Organic substance in water content, the detection components include
The detection pipe that can be penetrated by the ultraviolet that the light source is sent, water can pass through the detection pipe;
The ultraviolet line receiver of detection group, sent from the light source for detecting and penetrate the ultraviolet after the detection pipe Intensity;
Circuit board, the ultraviolet line receiver of detection group are connected with circuit board, and the circuit board is used for according to detection group ultraviolet The uitraviolet intensity that receiver receives is calculated by Organic substance in water content in detection pipe.
The light source that ultraviolet can be sent typically uses uviol lamp, and uviol lamp is with the extension of usage time, its purple sent Outer line strength can produce certain decay, in order to improve the accuracy of detection, as an improvement, present invention additionally comprises control component, The control component includes the ultraviolet line receiver of control group for the intensity that can detect the ultraviolet directly sent from the light source, right Also be connected according to ultraviolet line receiver is organized with circuit board, circuit board according to the uitraviolet intensity of the ultraviolet line receiver reception of detection group with And the ultraviolet line receiver of the control group uitraviolet intensity that receives is calculated by Organic substance in water content in detection pipe.
In said structure, what the ultraviolet line receiver of control group received is the ultraviolet directly sent from the light source, control Another structure of component is that control component includes:
The control tube that can be penetrated by the ultraviolet that the light source is sent, control tube inner vacuum or set air or set it is pure Water;
The ultraviolet line receiver of control group, sent from the light source for detecting and penetrate the ultraviolet after the control tube Intensity;
The ultraviolet line receiver of control group is also connected with circuit board, the purple that circuit board receives according to the ultraviolet line receiver of detection group The uitraviolet intensity that the outer ultraviolet line receiver of line strength and control group receives is contained to calculate by Organic substance in water in detection pipe Amount.
The control component can be arranged on the homonymy of light source with detection components, can also be symmetricly set on the two-phase of light source Offside, not homonymy can also be located at outside light source and form the angle of not 180 degrees between two lines after light source line respectively.
Improve again, organic matter detection sensor provided by the invention, in addition to housing, detection components are arranged in housing: It is arranged in the housing provided with light source accommodating cavity or the light source accommodating hole for allowing light source to pass through, the light source in light source accommodating cavity Or it is located in light source accommodating hole;It is additionally provided with the housing and connects with light source accommodating cavity or the light source accommodating hole for allowing light source to pass through Logical detection pipe accommodating cavity, detection pipe are arranged in detection pipe accommodating cavity;The ultraviolet line receiver of detection group is arranged on housing It is interior and relative with detection pipe.
It is arranged with isolation shading protective case outside the light source, light source is arranged the light that housing is arranged on after isolation shading protective case In the accommodating cavity of source or it is located in light source accommodating hole;Detection light loophole is provided with isolation shading protective case;The light source is sent Ultraviolet reach the ultraviolet line receiver of detection group by penetrating the detection pipe after detection light loophole again.Isolate shading The promising isolation light source of effect of protective case, prevent the ultraviolet that light source is sent from causing housing aging to irradiation.By being hidden in isolation Light protective case opens up detection light loophole, can make light launch angle between light source and the ultraviolet line receiver of detection group compared with It is small, so as to reduce light in transmit process due to the uncertainty of detection data caused by refraction and reflection.
Improve again, the water supply connector connected respectively with detection pipe both ends and water out adapter are connected with the housing.
Improve again, the position that the water supply connector and water out adapter are connected with detection pipe both ends is provided with sealing ring.
Improve again, the circuit board is fixed on housing, and the detection light connected with detection pipe accommodating cavity is provided with housing and is led to Road, the ultraviolet line receiver of detection group are located at after being fixed on circuit board in detection optical channel.
Improve again, control component is also disposed in housing, wherein a kind of preferably scheme of control component is:
The control group ultraviolet that control component includes the intensity that can detect the ultraviolet directly sent from the light source connects Device is received, the ultraviolet line receiver of control group is also connected with circuit board, and circuit board receives ultraviolet according to the ultraviolet line receiver of detection group Uitraviolet intensity that line strength and the ultraviolet line receiver of control group receive is calculated by Organic substance in water content in detection pipe;
It is provided with the isolation shading protective case and the housing is arranged on to irradiation loophole, the ultraviolet line receiver of control group It is interior and relative with to irradiation loophole, so that the ultraviolet that the light source is sent passes through to directly arrival pair after irradiation loophole According to the ultraviolet line receiver of group.By being opened up in isolation shading protective case to irradiation loophole, light source can be made ultraviolet with control group Light launch angle between line receiver is smaller, so as to reduce light in transmit process due to inspection caused by refraction and reflection Survey the uncertainty of data.
Control component and the detection components are arranged on the homonymy of light source, the detection light loophole and described saturating to irradiation Unthreaded hole is positioned at isolation shading protective case the same side;It is provided with the housing and is connected with to irradiation loophole and face is led to irradiation Road, the ultraviolet line receiver of control group are arranged in control optical channel.
The control component is symmetricly set on the two opposite sides of light source accommodating cavity, the detection light loophole with detection components Isolation shading protective case two opposite sides are symmetricly set on to irradiation loophole with described;Be provided with housing with to irradiation loophole just To the ultraviolet line receiver mounting hole of control group, the ultraviolet line receiver of control group is arranged on the installation of the control group ultraviolet line receiver In hole.
Control component and the detection components be located at light source accommodating cavity not homonymy outside, the detection light loophole and described right Irradiation loophole is arranged on the isolation same circumference diverse location of shading protective case, and with isolating the same circle center of shading protective case Into the angle of not 180 degrees between point line, it is provided with the housing and compares optical channel with to the connection of irradiation loophole and face, The ultraviolet line receiver of control group is arranged in control optical channel.
Another preferable scheme of control component is that the control component includes:
The control tube that can be penetrated by the ultraviolet that the light source is sent, control tube inner vacuum or set air or set it is pure Water;
The ultraviolet line receiver of control group, sent from the light source for detecting and penetrate the ultraviolet after the control tube Intensity;
The ultraviolet line receiver of control group is also connected with circuit board, the purple that circuit board receives according to the ultraviolet line receiver of detection group The uitraviolet intensity that the outer ultraviolet line receiver of line strength and control group receives is contained to calculate by Organic substance in water in detection pipe Amount.
It can be provided with insulation blocking set to irradiation loophole, the ultraviolet that the light source is sent passes through to irradiation printing opacity The control tube arrival ultraviolet line receiver of control group is being penetrated behind hole.
Now, the control component can be arranged on the homonymy of light source, the detection light loophole and institute with detection components State to irradiation loophole positioned at isolation shading protective case the same side;It is provided with the housing and irradiation loophole is connected with described Control tube accommodating cavity, control tube are arranged in control tube accommodating cavity;The ultraviolet line receiver of control group is arranged in housing simultaneously It is relative with control tube, so that the ultraviolet that the light source is sent to penetrating the control tube after irradiation loophole again by reaching The ultraviolet line receiver of control group.
The control component can also be symmetricly set on the two opposite sides of light source accommodating cavity, the detection light with detection components Loophole and described be symmetricly set on to irradiation loophole isolate shading protective case two opposite sides;It is provided with housing and is compareed with described The control tube accommodating cavity of light loophole connection, control tube are arranged in control tube accommodating cavity;The ultraviolet line receiver of control group It is interior and relative with control tube to be arranged on housing, so that the ultraviolet that the light source is sent passes through to being penetrated again after irradiation loophole The control tube reaches the ultraviolet line receiver of control group.
Control component and the detection components may be located on outside light source accommodating cavity not homonymy, the detection light loophole and It is described that the isolation same circumference diverse location of shading protective case is arranged on to irradiation loophole, and with isolating the same circle of shading protective case Housed between all central point lines into the angle of not 180 degrees, interior be provided with of housing with the control tube connected to irradiation loophole Chamber, control tube are arranged in control tube accommodating cavity;The ultraviolet line receiver of control group be arranged in housing and with control tube phase It is right, so that the ultraviolet that the light source is sent to penetrating the control tube after irradiation loophole again by reaching the control group Ultraviolet line receiver.
Do not opened up specially to irradiation loophole, when being only provided with detection light loophole, the housing when insulation blocking is put It is interior be provided with detection light loophole face and the light lead passage that connect, middle part and the vertically disposed light splitting passage of light lead passage, and For the ultraviolet in light lead passage to be evenly spread to the spectroscope of light splitting passage both sides, the detection pipe accommodating cavity is arranged on It is divided passage side;Control tube accommodating cavity is provided with positioned at light splitting passage opposite side in the housing, control tube is arranged on control tube In accommodating cavity;The ultraviolet line receiver of control group is arranged in housing and relative with control tube, so that the light source is sent Ultraviolet reached by penetrating the control tube again after spectroscope enters light splitting passage after detection light loophole, light lead passage The ultraviolet line receiver of control group.
The light lead vias inner walls are provided with the first insulation blocking sleeve.
The light splitting vias inner walls are provided with the second insulation blocking sleeve.
Organic matter sensor in the present invention also includes and temperature of the light source contacts for detecting the light-source temperature Sensor.
Cleaning machine in the present invention, in addition to the wash for being cleaned to cleaning chamber, and washed for controlling The controller of the mode of washing of component, the organic matter detection sensor are connected with the controller, and controller is according to organic quality testing Survey sensor detection enter cleaning chamber or/and the Organic substance in water content of outflow cleaning chamber adjusts the washing side of wash Formula.
Compared with prior art, the advantage of the invention is that:By cleaning the water inlet of chamber in cleaning machine or/and going out At the mouth of a river or/and cleaning intracavitary is provided with and is used to detect having into the Organic substance in water content of cleaning chamber or/and outflow cleaning chamber Machine analyte detection sensor, so that cleaning function detection enters the Organic substance in water content of cleaning chamber or/and outflow cleaning chamber; And then the Organic substance in water content for entering cleaning chamber or/and outflow cleaning chamber detected can be utilized, wash is washed The mode of washing enters Mobile state adjustment.
Brief description of the drawings
Fig. 1 is the functional block diagram of cleaning machine in the embodiment of the present invention;
Fig. 2 is the dimensional structure diagram of the first structure of organic matter detection sensor in the embodiment of the present invention;
Fig. 3 is the three-dimensional cutaway view of the first structure of organic matter detection sensor in the embodiment of the present invention;
Fig. 4 is the three-dimensional exploded view of the first structure of organic matter detection sensor in the embodiment of the present invention;
Fig. 5 is the three-dimensional exploded view at another visual angle of the first structure of organic matter detection sensor in the embodiment of the present invention;
Fig. 6 is the dimensional structure diagram of second of structure of organic matter detection sensor in the embodiment of the present invention;
Fig. 7 is the sectional view of second of structure of organic matter detection sensor in the embodiment of the present invention;
Fig. 8 is the sectional view of the third structure of organic matter detection sensor in the embodiment of the present invention;
Fig. 9 is the sectional view of the 5th kind of structure of organic matter detection sensor in the embodiment of the present invention;
Figure 10 is the sectional view of the 6th kind of structure of organic matter detection sensor in the embodiment of the present invention;
Figure 11 is the dimensional structure diagram of the 7th kind of structure of organic matter detection sensor in the embodiment of the present invention;
Figure 12 is the three-dimensional cutaway view of the 7th kind of structure of organic matter detection sensor in the embodiment of the present invention;
Figure 13 is the dimensional structure diagram of the 8th kind of structure of organic matter detection sensor in the embodiment of the present invention;
Figure 14 is the three-dimensional cutaway view of the 8th kind of structure of organic matter detection sensor in the embodiment of the present invention;
Figure 15 is the three-dimensional cutaway view of the tenth kind of structure of organic matter detection sensor in the embodiment of the present invention.
Embodiment
The present invention is described in further detail below in conjunction with accompanying drawing embodiment.
Cleaning machine as shown in Figure 1, including the cleaning chamber 101 with water inlet 102 and delivery port 103, for cleaning The wash 105 that chamber 101 is cleaned, and the controller 106 of the mode of washing for controlling wash, the cleaning chamber At 101 water inlet 102 or/and at delivery port 103 or cleaning intracavitary is provided with to be used to detect and enters cleaning chamber or/and outflow cleaning The organic matter detection sensor 104 of the Organic substance in water content of chamber or/and cleaning intracavitary;Organic matter detection sensor 104 is with being somebody's turn to do Controller 106 connects, and controller 106 enters cleaning chamber or/and outflow cleaning chamber according to organic matter detection sensor detection 104 Organic substance in water content adjust the mode of washing of wash 105.
The structure of organic matter detection sensor 104 can be with a variety of, separately below to the knot of organic matter detection sensor 104 Structure is described in detail.
The first structure of organic matter detection sensor:
Organic matter detection sensor as shown in Figure 2-5, it includes the light source 1 that can send ultraviolet, and with the light source 1 detection components that can detect Organic substance in water content coordinated, and for detection components are matching used compares component.
Wherein, the detection components include
The detection pipe 2 that can be penetrated by the ultraviolet that the light source 1 is sent, water can pass through the detection pipe 2;
The ultraviolet line receiver 3 of detection group, send and penetrate ultraviolet after the detection pipe 2 from the light source 1 for detecting The intensity of line;
Control component includes:
The control tube 6 that can be penetrated by the ultraviolet that the light source 1 is sent, the inner vacuum of control tube 6 or sets air or setting Pure water;
The ultraviolet line receiver 5 of control group, send and penetrate ultraviolet after the control tube 6 from the light source 1 for detecting The intensity of line;
The ultraviolet line receiver 3 of above-mentioned detection group and the ultraviolet line receiver 5 of control group are connected with circuit board 4, circuit board 4 The uitraviolet intensity that the uitraviolet intensity and the ultraviolet line receiver 5 of control group received according to the ultraviolet line receiver 3 of detection group receives To calculate by Organic substance in water content in detection pipe 2.
In this structure, organic matter detection sensor includes the housing 7 assembled by the first housing 7a and the second housing 7b, Housing 7 is provided with the light source accommodating hole for allowing light source to pass through in middle part, and light source 1 is located in light source accommodating hole;In first housing 7a The detection pipe accommodating cavity connected with light source accommodating hole is additionally provided with, detection pipe 2 is arranged in detection pipe accommodating cavity;The detection group is purple Outer line receiver is arranged in the first housing 7a and relative with detection pipe 2.It is provided with second housing 7b and is connected with light source accommodating hole Control tube accommodating cavity, control tube 6 is arranged in control tube accommodating cavity;The ultraviolet line receiver 5 of control group is arranged on the second housing It is in 7b and relative with control tube 6.
Isolation shading protective case 8 is arranged with outside light source 1, light source 1 is located in housing 7 after being arranged isolation shading protective case 8 In light source accommodating hole;Detection light loophole 81 is provided with isolation shading protective case 8;The ultraviolet that the light source 1 is sent passes through inspection The detection pipe 2 is penetrated after light-metering loophole 81 again and reaches the ultraviolet line receiver 3 of the detection group.Isolate on shading protective case 8 Also it is provided with to irradiation loophole 82;The ultraviolet that the light source 1 is sent passes through to penetrating the control again after irradiation loophole 82 Pipe 6 reaches the ultraviolet line receiver 5 of the control group.
The water supply connector 71 connected respectively with the both ends of detection pipe 2 and water out adapter 72, water inlet are connected with first housing 7a The position that joint 71 and water out adapter 72 are connected with the both ends of detection pipe 2 is provided with sealing ring 73.
Circuit board 4 can be fixed on the first housing 7a, can also be fixed on the second housing 7b, in the present embodiment, electricity Road plate 4 is fixed on the first housing 7a, and the ultraviolet line receiver 5 of control group is arranged on side plate, and side plate is fixed on the second housing 7b On, the output end of the ultraviolet line receiver 5 of control group is connected by wire with circuit board 4.
The detection optical channel 74 connected with detection pipe accommodating cavity is provided with first housing 7a, the detection group ultraviolet receives Device 3 is fixed to be located in detection optical channel 74 afterwards on the circuit board 4;Pair connected with control tube accommodating cavity is provided with second housing 7b Irradiation passage 75, the ultraviolet line receiver 5 of control group are located at after being fixed on side plate in control optical channel 75.
In this example, the control component is symmetricly set on the two opposite sides of light source accommodating hole with detection components, i.e.,:Control Component is symmetrical arranged with detection components;The detection light loophole 81 and described be symmetricly set on to irradiation loophole 82 isolate screening The two opposite sides of light protective case 8;The benefit so set is that the ultraviolet that the ultraviolet of detection group intake absorbs with control group comes from In 1 same circumferential position of light source, therefore the original light intensity difference very little of the ultraviolet of both intakes;Shortcoming is:But if Light source, which installs rear position, radial deflection, then the detection data that can cause to compare component and detection components acquisition occur larger Deviation.
The detection method of organic matter detection sensor in this structure, it comprises the following steps:
Step (1), control tube 6 vacuumized, or keep being full of air in control tube 6, or poured in control tube 6 pure Water, the light source 1 is opened, circuit board 4 records the uitraviolet intensity value that the ultraviolet line receiver 5 of this control group receives, and will The uitraviolet intensity value is designated as the first uitraviolet intensity reference point;
Step (2), prepare the control water sample that known to N parts content of organics and content differs, keep the light source 1 to open Open, this N part control water sample is then passed sequentially through into the control tube 6 respectively, circuit board 4 records N parts control water sample and flowed through successively The uitraviolet intensity value that the ultraviolet line receiver 5 of control group receives during control tube 6, and N part uitraviolet intensities value of acquisition is divided Be not designated as the second uitraviolet intensity reference point, the 3rd uitraviolet intensity reference point ... N+1 uitraviolet intensity reference points, its Middle N is the natural number more than or equal to 3;
Step (3), the N part uitraviolet intensity reference points obtained according to step (2), obtain organic matter in a control water sample The table of comparisons between content and uitraviolet intensity reference point;
Step (4), keep the light source 1 to open, control tube 6 is vacuumized, or keep being full of air in control tube 6, or Pure water is poured in control tube 6;Water to be measured is flowed through into the detection pipe 2, circuit board 4 records the reception of this detection group ultraviolet The uitraviolet intensity value that device 3 receives, and the uitraviolet intensity value is designated as uitraviolet intensity detected value, while record control group The uitraviolet intensity value that ultraviolet line receiver 5 receives, the uitraviolet intensity value is designated as interim uitraviolet intensity reference point, will Interim uitraviolet intensity reference point divided by the first uitraviolet intensity reference point, obtain intensity of light source attenuation ratio, and ultraviolet is strong Degree detected value is multiplied by intensity of light source attenuation ratio, obtains uitraviolet intensity lookup value, then using the uitraviolet intensity lookup value, The table of comparisons obtained by query steps 3, obtain the content of organics in now water to be measured.
In above-mentioned detection method, main disturbing factor is the change of light source, and the change of light source is mainly due to temperature Degree, as the usage time of light source pushes away length, the temperature of light source can gradually rise;Because in the characteristic of uviol lamp, ultraviolet it is strong Degree can become strong with uprising for temperature, in order to further improve the precision of detection, also include connecing with the light source 1 in housing 7 Touch the temperature sensor 11 for detecting the temperature of light source 1;In the step (1) and step (2), the light source 1 is kept Open, then detect the temperature of light source 1 in real time by the temperature sensor 11, recording light source (1) is more under different temperatures value Individual first uitraviolet intensity reference point and multiple second uitraviolet intensity reference points, multiple 3rd uitraviolet intensity references Value ... multiple N+1 uitraviolet intensity reference points;Then the step (3) obtains content of organics in a control water sample The table of comparisons between reference point is forced with ultraviolet of the light source under different temperatures value;Finally in step (4), institute is equally kept Light source (1) unlatching is stated, and detects the temperature of light source (1) in real time by the temperature sensor (11), according to current light source (1) Temperature value and present ultraviolet intensity detection value, pass through the content of organics that obtains in now water to be measured of tabling look-up.
Second of structure of organic matter sensor:
Organic matter detection sensor as shown in Figure 6 and Figure 7, it includes the light source 1 that can send ultraviolet, and with the light The detection components that can detect Organic substance in water content that source 1 coordinates, the detection components include
The detection pipe 2 that can be penetrated by the ultraviolet that the light source 1 is sent, water can pass through the detection pipe 2;
The ultraviolet line receiver 3 of detection group, send and penetrate ultraviolet after the detection pipe 2 from the light source 1 for detecting The intensity of line;
The ultraviolet line receiver 3 of detection group is connected with circuit board 4, and circuit board 4 receives according to the ultraviolet line receiver 3 of detection group Uitraviolet intensity calculates by Organic substance in water content in detection pipe 2.
In this structure, organic matter detection sensor is identical with embodiment one, including by the first housing 7a and the second housing 7b The housing 7 assembled, housing 7 are provided with the light source accommodating hole for allowing light source to pass through in middle part, and light source 1 is located in light source accommodating hole It is interior;The detection pipe accommodating cavity connected with light source accommodating hole is additionally provided with first housing 7a, detection pipe 2 is arranged on detection pipe accommodating cavity It is interior;The ultraviolet line receiver of detection group is arranged in the first housing 7a and relative with detection pipe 2.
Isolation shading protective case 8 is arranged with outside light source 1, light source 1 is located in housing 7 after being arranged isolation shading protective case 8 In light source accommodating hole;Detection light loophole 81 is provided with isolation shading protective case 8;The ultraviolet that the light source 1 is sent passes through inspection The detection pipe 2 is penetrated after light-metering loophole 81 again and reaches the ultraviolet line receiver 3 of the detection group.
The water supply connector 71 connected respectively with the both ends of detection pipe 2 and water out adapter 72 are connected with first housing 7a.
Circuit board 4 can be fixed on the first housing 7a, can also be fixed on the second housing 7b, in the present embodiment, electricity Road plate 4 is fixed on the first housing 7a.
The detection method of organic matter detection sensor in this structure comprises the following steps:
Step (1), detection pipe 2 vacuumized, or keep being full of air in detection pipe 2, or poured in detection pipe 2 pure Water, the light source 1 being then turned on, circuit board 4 records the uitraviolet intensity value that the ultraviolet line receiver 3 of this detection group receives, And the uitraviolet intensity value is designated as the first uitraviolet intensity reference point;
Step (2), prepare the control water sample that known to N parts content of organics and content differs, keep the light source 1 to open Open, this N part control water sample is then passed sequentially through into the detection pipe 2 respectively, circuit board 4 records N parts control water sample and flowed through successively The uitraviolet intensity value that the ultraviolet line receiver 3 of detection group receives during detection pipe 2, and N part uitraviolet intensities value of acquisition is divided Be not designated as the second uitraviolet intensity reference point, the 3rd uitraviolet intensity reference point ... N+1 uitraviolet intensity reference points, its Middle N is the natural number more than or equal to 3;
Step (3), the N+1 part uitraviolet intensity reference points obtained according to step (1) and step (2), obtain a control The table of comparisons in water sample between content of organics and uitraviolet intensity reference point;
Step (4), keep the light source 1 to open, water to be measured is flowed through into the detection pipe 2, the record of circuit board 4 this time detects The uitraviolet intensity value that the ultraviolet line receiver 3 of group receives, and the uitraviolet intensity value is designated as uitraviolet intensity detected value, so The table of comparisons obtained afterwards by query steps (3), obtain the content of organics in now water to be measured.
The third structure of organic matter sensor:
Unlike the first structure, the control component is arranged on the homonymy of light source 1, the detection with detection components Light loophole 81 and it is described to irradiation loophole 82 positioned at the same side of isolation shading protective case 8, its internal structure is referring to Fig. 8 institutes Show.
In this configuration, it is when radial deflection occurs for uviol lamp position to compare the benefit of component and detection components in the same side When, detection components and the uitraviolet intensity deviation that control component absorbs are less;Its shortcoming is:Because uviol lamp is axially distinct The luminous intensity in position may have certain deviation, so, in the embodiment, it is desirable to uviol lamp light intensity in the axial direction Need uniformity good.
The detection method of organic matter detection sensor in this structure is identical with the first structure.
4th kind of structure of organic matter sensor:
Unlike the first structure, the control component is located at outside light source accommodating cavity not homonymy, institute with detection components State detection light loophole 81 and described be arranged on to irradiation loophole 82 isolate 8 same excircle diverse location of shading protective case, And with isolating between the same circle center's point line of shading protective case 8 into the angle of not 180 degrees, the angle in the present embodiment is 60 Degree.
The detection method of organic matter detection sensor in this structure is identical with the first structure.
5th kind of structure of organic matter sensor
Unlike the first structure, control component only includes the ultraviolet line receiver 5 of control group, is not provided with compareing Pipe, the ultraviolet line receiver 5 of control group are set directly in control optical channel 75, and its internal structure is shown in Figure 9.The light source 1 ultraviolet sent along control optical channel 75 to irradiation loophole 82 by directly reaching the ultraviolet line receiver 5 of control group.
The detection method of organic matter detection sensor in this structure, it comprises the following steps:
Step (1), open the light source 1, circuit board 4 record the ultraviolet line receiver 5 of this control group receive it is ultraviolet Line strength value, and the uitraviolet intensity value is designated as the first uitraviolet intensity reference point;
Step (2), prepare the control water sample that known to N parts content of organics and content differs, keep the light source 1 to open Open, this N part control water sample is then passed sequentially through into the detection pipe 2 respectively, circuit board 4 records N parts control water sample and flowed through successively The uitraviolet intensity value that the ultraviolet line receiver 3 of detection group receives during detection pipe 2, and N part uitraviolet intensities value of acquisition is divided Be not designated as the second uitraviolet intensity reference point, the 3rd uitraviolet intensity reference point ... N+1 uitraviolet intensity reference points, its Middle N is the natural number more than or equal to 3;
Step (3), the N part uitraviolet intensity reference points obtained according to step (2), obtain organic matter in a control water sample The table of comparisons between content and uitraviolet intensity reference point;
Step (4), keep the light source 1 to open, water to be measured is flowed through into the detection pipe 2, the record of circuit board 4 this time detects The uitraviolet intensity value that the ultraviolet line receiver 3 of group receives, and the uitraviolet intensity value is designated as uitraviolet intensity detected value, together The uitraviolet intensity value that the ultraviolet line receiver 5 of Shi Jilu control groups receives, the uitraviolet intensity value is designated as interim ultraviolet Intensity reference point, by interim uitraviolet intensity reference point divided by the first uitraviolet intensity reference point, obtain intensity of light source attenuation ratio Example, uitraviolet intensity detected value is multiplied by intensity of light source attenuation ratio, obtains uitraviolet intensity lookup value, it is then ultraviolet using this Line strength lookup value, the table of comparisons obtained by query steps (3), obtain the content of organics in now water to be measured.
6th kind of structure of organic matter sensor:
Unlike the 5th kind of structure, compare component and detection components are arranged on the homonymy of light source, housing configuration Then identical with embodiment two, internal structure is shown in Figure 10.
The detection method of organic matter detection sensor in this structure is identical with the 5th kind of structure.
7th kind of structure of organic matter sensor:
Unlike the 5th kind of structure, housing 7 is single piece, and control component is located at outside light source accommodating cavity with detection components Not homonymy, the detection light loophole 81 and described be arranged on to irradiation loophole 82 isolate 8 same excircle of shading protective case Diverse location, and with isolating between the same circle center's point line of shading protective case 8 into the angle of not 180 degrees, in the present embodiment Angle be 60 degree, housing contour structures are shown in Figure 12 referring to Figure 11, housing interior structure.
The detection method of organic matter detection sensor in this structure is identical with the 5th kind of structure.
8th kind of structure of organic matter sensor:
Unlike the first structure, a detection light loophole 81 is only provided with isolation shading protective case 8, and it is described Be provided with housing 7 with the face of detection light loophole 81 and the light lead passage 76 that connects, middle part and light lead passage 76 are vertically disposed Passage 77 is divided, and for the ultraviolet in light lead passage 76 to be evenly spread to the spectroscope 78 of light splitting passage 77 both sides, point Light microscopic 78 is prism;The detection pipe accommodating cavity is arranged on light splitting passage 77 side;Positioned at light splitting passage 77 in the housing 7 Opposite side is provided with control tube accommodating cavity, and control tube 6 is arranged in control tube accommodating cavity;The ultraviolet line receiver 5 of control group is set Put in housing 7 and with control tube 6 relatively, so that the ultraviolet that the light source 1 is sent passes through detection light loophole 81, light lead The control tube 2 is penetrated again after spectroscope 78 enters light splitting passage 77 after passage 76 reaches the ultraviolet line receiver of the control group 5.The inwall of light lead passage 76 is provided with the first insulation blocking sleeve 9, and the light splitting inwall of passage 77 is provided with the second insulation blocking sleeve 10, referring to figure 13rd, shown in 14.
In this structure, ultraviolet is divided by spectroscope 78, ensures the original light intensity phase of ultraviolet of detection combination control group Together.
9th kind of structure of organic matter sensor:
Unlike the 8th kind of structure, control component only sets the ultraviolet line receiver 5 of control group, is compareed without setting Pipe.
Tenth kind of structure of organic matter sensor:
Unlike the 5th kind of structure, light source accommodating cavity is provided with housing 7, light source 1 is that small-sized uviol lamp or LED are purple Outer lamp, light source 1 is integrally provided in light source accommodating cavity, shown in Figure 15.

Claims (24)

1. a kind of cleaning machine, including the cleaning chamber (101) with water inlet (102) and delivery port (103), it is characterised in that:Institute State to be provided with water inlet (102) place or/and delivery port (103) place or/and cleaning chamber (101) of cleaning chamber (101) and be used to detect Into cleaning chamber or/and outflow cleaning chamber or/and the organic matter detection sensor for the Organic substance in water content for cleaning intracavitary (104)。
2. cleaning machine according to claim 1, it is characterised in that:The organic matter detection sensor includes:
The light source (1) of ultraviolet, and the detection group that can detect Organic substance in water content coordinated with the light source (1) can be sent Part, the detection components include
The detection pipe (2) that the ultraviolet that can be sent by the light source (1) penetrates, into cleaning chamber or/and the water of outflow cleaning chamber The detection pipe (2) can be passed through;
The ultraviolet line receiver of detection group (3), sent from the light source (1) for detecting and penetrate the purple after the detection pipe (2) The intensity of outside line;
Circuit board (4), the ultraviolet line receiver of detection group (3) are connected with circuit board (4), and the circuit board (4) is used for according to detection The uitraviolet intensity that the ultraviolet line receiver (3) of group receives, which calculates, passes through the interior Organic substance in water content of detection pipe (2).
3. cleaning machine according to claim 2, it is characterised in that:The organic matter detection sensor also includes control group Part, the control group ultraviolet that the control component includes the intensity that can detect the ultraviolet directly sent from the light source (1) connect Device (5) is received, the ultraviolet line receiver of control group (5) is also connected with circuit board (4), and circuit board (4) receives according to detection group ultraviolet The uitraviolet intensity that the uitraviolet intensity and the ultraviolet line receiver of control group (5) that device (3) receives receive passes through detection to calculate Manage (2) interior Organic substance in water content.
4. cleaning machine according to claim 2, it is characterised in that:The organic matter detection sensor also includes control component The control component includes:
The control tube (6) that the ultraviolet that can be sent by the light source (1) penetrates, control tube (6) inner vacuum or sets air or sets Put pure water;
The ultraviolet line receiver of control group (5), sent from the light source (1) for detecting and penetrate the purple after the control tube (6) The intensity of outside line;
The ultraviolet line receiver of control group (5) is also connected with circuit board (4), and circuit board (4) is according to the ultraviolet line receiver of detection group (3) Uitraviolet intensity that the ultraviolet line receiver of uitraviolet intensity and control group (5) of reception receives is calculated by detection pipe (2) Interior Organic substance in water content.
5. the cleaning machine according to claim 3 or 4, it is characterised in that:The control component is arranged on light with detection components The homonymy in source (1), or be symmetricly set on the two opposite sides of light source (1), or homonymy and do not connect respectively with light source outside positioned at light source (1) The angle of not 180 degrees is formed after line between two lines.
6. cleaning machine according to claim 2, it is characterised in that:The organic matter detection sensor also includes housing (7), In the housing (7) light source appearance is arranged on provided with light source accommodating cavity or the light source accommodating hole for allowing light source to pass through, the light source (1) Put intracavitary or be located in light source accommodating hole;It is additionally provided with what is connected with light source accommodating cavity or light source accommodating hole in the housing (7) Detection pipe accommodating cavity, detection pipe (2) are arranged in detection pipe accommodating cavity;The ultraviolet line receiver of detection group (3) is arranged on shell It is in body (7) and relative with detection pipe (2).
7. cleaning machine according to claim 6, it is characterised in that:Isolation shading protective case is arranged with outside the light source (1) (8), light source (1) is arranged after isolation shading protective case (8) to be arranged in the light source accommodating cavity of housing (7) or be located in light source and housed In hole;Detection light loophole (81) is provided with isolation shading protective case (8);The ultraviolet that the light source (1) sends passes through detection The detection pipe (2) is penetrated after light loophole (81) again and reaches the ultraviolet line receiver of detection group (3).
8. cleaning machine according to claim 6, it is characterised in that:Be connected with the housing (7) respectively with detection pipe (2) The water supply connector (71) and water out adapter (72) that both ends are connected.
9. cleaning machine according to claim 8, it is characterised in that:The water supply connector (71) and water out adapter (72) and inspection The position of test tube (2) both ends connection is provided with sealing ring (73).
10. cleaning machine according to claim 6, it is characterised in that:The circuit board (4) is fixed on housing (7), housing (7) the detection optical channel (74) connected with detection pipe accommodating cavity is provided with, the ultraviolet line receiver of detection group (3) is fixed on electricity After on road plate (4) in detection optical channel (74).
11. according to the cleaning machine described in claim 7 or 8 or 9 or 10, it is characterised in that:The organic matter detection sensor is also Including compareing component, the control component includes the control for the intensity that can detect the ultraviolet directly sent from the light source (1) The ultraviolet line receiver (5) of group, the ultraviolet line receiver of control group (5) are also connected with circuit board (4), and circuit board (4) is according to detection group Uitraviolet intensity that the uitraviolet intensity and the ultraviolet line receiver of control group (5) that ultraviolet line receiver (3) receives receive is counted Calculation passes through the interior Organic substance in water content of detection pipe (2);
It is provided with the isolation shading protective case (8) and institute is arranged on to irradiation loophole (82), the ultraviolet line receiver of control group (5) State in housing (7) and with to irradiation loophole (82) relatively so that the ultraviolet that the light source (1) is sent pass through it is saturating to irradiation Unthreaded hole (82) directly reaches the ultraviolet line receiver of control group (5) afterwards.
12. cleaning machine according to claim 11, it is characterised in that:The control component is arranged on light source with detection components (1) homonymy, the detection light loophole (81) and it is described to irradiation loophole (82) positioned at isolation shading protective case (8) it is same Side;It is provided with the housing (7) and compares optical channel (75) with to irradiation loophole (82) connection and face, the control group is purple Outer line receiver (5) is arranged in control optical channel (75).
13. cleaning machine according to claim 11, it is characterised in that:The control component is symmetricly set on detection components The two opposite sides of light source accommodating cavity, the detection light loophole (81) and described are symmetricly set on isolation to irradiation loophole (82) Shading protective case (8) two opposite sides;It is provided with housing (7) and the ultraviolet line receiver of control group to irradiation loophole (82) face Mounting hole, the ultraviolet line receiver of control group (5) are arranged in the ultraviolet line receiver mounting hole of the control group.
14. cleaning machine according to claim 11, it is characterised in that:The control component is located at light source appearance with detection components Putting chamber, homonymy, the detection light loophole (81) and described be arranged on to irradiation loophole (82) do not isolate shading protective case outside (8) same circumference diverse location, and with isolating between the same circle center's point line of shading protective case (8) into the folder of not 180 degrees Angle, it is provided with the housing (7) and compares optical channel (75) with to irradiation loophole (82) connection and face, the control group is purple Outer line receiver (5) is arranged in control optical channel (75).
15. according to the cleaning machine described in claim 7 or 8 or 9 or 10, it is characterised in that:The organic matter detection sensor is also Including compareing component, the control component includes:
The control tube (6) that the ultraviolet that can be sent by the light source (1) penetrates, control tube (6) inner vacuum or sets air or sets Put pure water;
The ultraviolet line receiver of control group (5), sent from the light source (1) for detecting and penetrate the purple after the control tube (6) The intensity of outside line;
The ultraviolet line receiver of control group (5) is also connected with circuit board (4), and circuit board (4) is according to the ultraviolet line receiver of detection group (3) Uitraviolet intensity that the ultraviolet line receiver of uitraviolet intensity and control group (5) of reception receives is calculated by detection pipe (2) Interior Organic substance in water content.
16. cleaning machine according to claim 15, it is characterised in that:It is provided with the insulation blocking sleeve (8) saturating to irradiation Unthreaded hole (82), the ultraviolet that the light source (1) sends pass through to penetrating the control tube (6) arrival after irradiation loophole (82) The ultraviolet line receiver of control group (5).
17. cleaning machine according to claim 16, it is characterised in that:The control component is arranged on light source with detection components (1) homonymy, the detection light loophole (81) and it is described to irradiation loophole (82) positioned at isolation shading protective case (8) it is same Side;It is provided with the housing (7) and is arranged on the control tube accommodating cavity connected to irradiation loophole (82), control tube (6) In control tube accommodating cavity;The ultraviolet line receiver of control group (5) is arranged in housing (7) and with control tube (6) relatively, so that Pass through the ultraviolet that the light source (1) is sent described right to penetrating the control tube (6) arrival after irradiation loophole (82) again According to the ultraviolet line receiver (5) of group.
18. cleaning machine according to claim 16, it is characterised in that:The control component is symmetricly set on detection components The two opposite sides of light source accommodating cavity, the detection light loophole (81) and described are symmetricly set on isolation to irradiation loophole (82) Shading protective case (8) two opposite sides;Be provided with housing (7) with the control tube accommodating cavity connected to irradiation loophole (82), Control tube (6) is arranged in control tube accommodating cavity;The ultraviolet line receiver of control group (5) be arranged in housing (7) and with it is right (6) are looked after relatively, so that the ultraviolet that the light source (1) is sent passes through to penetrating the control again after irradiation loophole (82) Manage (6) and reach the ultraviolet line receiver of control group (5).
19. cleaning machine according to claim 16, it is characterised in that:The control component is located at light source appearance with detection components Putting chamber, homonymy, the detection light loophole (81) and described be arranged on to irradiation loophole (82) do not isolate shading protective case outside (8) same circumference diverse location, and with isolating between the same circle center's point line of shading protective case (8) into the folder of not 180 degrees Angle, interior be provided with of housing (7) are arranged on control with the control tube accommodating cavity connected to irradiation loophole (82), control tube (6) Tube capacity puts intracavitary;The ultraviolet line receiver of control group (5) is arranged in housing (7) and with control tube (6) relatively, so that institute The ultraviolet that light source (1) is sent is stated to pass through to penetrating the control tube (6) the arrival control group after irradiation loophole (82) again Ultraviolet line receiver (5).
20. cleaning machine according to claim 15, it is characterised in that:It is provided with and detection light loophole in the housing (7) (81) face and the light lead passage (76) connected, middle part and the vertically disposed light splitting passage (77) of light lead passage (76), and be used for Ultraviolet in light lead passage (76) is evenly spread to the spectroscope (78) of light splitting passage (77) both sides, the detection pipe houses Chamber is arranged on light splitting passage (77) side;Control tube accommodating cavity is provided with positioned at light splitting passage (77) opposite side in the housing (7), Control tube (6) is arranged in control tube accommodating cavity;The ultraviolet line receiver of control group (5) be arranged in housing (7) and with it is right (6) are looked after relatively, so that after the ultraviolet that sends of the light source (1) is by detection light loophole (81), light lead passage (76) The control tube (6) is penetrated again after spectroscope (78) enters light splitting passage (77) reaches the ultraviolet line receiver of control group (5)。
21. cleaning machine according to claim 20, it is characterised in that:Light lead passage (76) inwall is provided with the first isolation Protective case (9).
22. cleaning machine according to claim 20, it is characterised in that:Described light splitting passage (77) inwall is provided with the second isolation Protective case (10).
23. according to the cleaning machine described in Claims 2 or 3 or 4 or 6 or 7 or 8 or 9 or 10, it is characterised in that:Also include and institute State light source (1) and contact the temperature sensor (11) for being used for detecting the light source (1) temperature.
24. cleaning machine according to claim 1, it is characterised in that:Also include being used for clean cleaning chamber (101) Wash (105), and the controller (106) of the mode of washing for controlling wash, the organic matter detection sensor (104) it is connected with the controller (106), controller (106) detects entering for (104) according to organic matter detection sensor and cleans chamber Or/and outflow cleaning chamber or/and clean the Organic substance in water content of intracavitary and adjust the mode of washing of wash (105).
CN201710196426.2A 2017-03-29 2017-03-29 Cleaning machine Active CN107340264B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102042963A (en) * 2010-10-14 2011-05-04 长春理工大学 Online detector for detecting total organic carbon (TOC) in sewage with ultraviolet spectrometry method
CN102145967A (en) * 2011-05-11 2011-08-10 中山市泰帝科技有限公司 Device and method for processing restaurant wastewater
CN202869961U (en) * 2012-08-21 2013-04-10 杭州希玛诺光电技术有限公司 Mobile reference light path device for water quality analysis meter
CN103130389A (en) * 2013-03-04 2013-06-05 同济大学 Method for removing endocrine disrupter in sludge by combining ultraviolet rays and hydrogen peroxide
CN105084620A (en) * 2015-08-13 2015-11-25 青岛双瑞海洋环境工程股份有限公司 Domestic sewage treatment technology and system
CN105155202A (en) * 2015-06-30 2015-12-16 无锡小天鹅股份有限公司 Washing machine control method and washing machine

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102042963A (en) * 2010-10-14 2011-05-04 长春理工大学 Online detector for detecting total organic carbon (TOC) in sewage with ultraviolet spectrometry method
CN102145967A (en) * 2011-05-11 2011-08-10 中山市泰帝科技有限公司 Device and method for processing restaurant wastewater
CN202869961U (en) * 2012-08-21 2013-04-10 杭州希玛诺光电技术有限公司 Mobile reference light path device for water quality analysis meter
CN103130389A (en) * 2013-03-04 2013-06-05 同济大学 Method for removing endocrine disrupter in sludge by combining ultraviolet rays and hydrogen peroxide
CN105155202A (en) * 2015-06-30 2015-12-16 无锡小天鹅股份有限公司 Washing machine control method and washing machine
CN105084620A (en) * 2015-08-13 2015-11-25 青岛双瑞海洋环境工程股份有限公司 Domestic sewage treatment technology and system

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