CN107338356B - A kind of shaft cooler furnace a tail wind recycling technique - Google Patents

A kind of shaft cooler furnace a tail wind recycling technique Download PDF

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Publication number
CN107338356B
CN107338356B CN201710533023.2A CN201710533023A CN107338356B CN 107338356 B CN107338356 B CN 107338356B CN 201710533023 A CN201710533023 A CN 201710533023A CN 107338356 B CN107338356 B CN 107338356B
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shaft cooler
temperature
pelletizing
air
furnace
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CN107338356A (en
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林平平
陈继双
宋国平
张展飞
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Chenzhou Tin Tao Environmental Technology Co Ltd
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Chenzhou Tin Tao Environmental Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/26Cooling of roasted, sintered, or agglomerated ores
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/02Roasting processes
    • C22B1/08Chloridising roasting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00Obtaining noble metals

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention belongs to tail gas recycle fields, specifically disclose a kind of shaft cooler furnace a tail wind recycling technique.The technique are as follows: be packed into high temperature iron pelletizing from the top of shaft cooler, heat exchange is carried out during reverse flow in shaft cooler through cold air and high temperature iron pelletizing, make the temperature of high temperature iron pelletizing be reduced to 100 DEG C hereinafter, there is a small amount of metal chloride to volatilize in pelletizing cooling procedure simultaneously;Temperature is increased to 400 DEG C or so after cold air passes through heat exchange, becomes hot-air;Hot-air a part is discharged from the hole in the middle part of shaft cooler, sends to subsequent handling;Another part is discharged from the hole on shaft cooler top, and rotary kiln is returned after valuable metal chloride therein is recycled in cyclone dust collection and recycles thermal energy therein.The present invention is recycled furnace a tail wind, on the one hand recycles heat therein, the call of response national energy-saving consumption reduction;On the other hand precious metal chloride therein is recycled, improves metal recovery rate.

Description

A kind of shaft cooler furnace a tail wind recycling technique
Technical field
Production the present invention relates to metallurgical technology field, after being related to the group of iron ball made of pyrite cinder high-temperature roasting chlorinated gold extracting A kind of method that product are cooling, valuable metal chloride and waste heat recycle, and in particular to shaft cooler furnace a tail wind recycling work Skill.
Background technique
Pyrite cinder is with addition of a certain amount of calcium chloride solution, through profit mill, pelletizing, into rotary kiln in carry out high-temp chlorination roasting It burns, 1100~1250 DEG C of maturing temperature, the valuable metal reaction in pelletizing generates chloride-sublimation, while pelletizing is consolidated, and is become At high intensity roast ball, into shaft cooler in cooled down.
Cold air is blasted in shaft cooler by centrifugal blower and is contacted with high temperature pelletizing (temperature > 800 DEG C), and hot friendship is carried out Cooling pelletizing is changed, pelletizing temperature is down to 80 DEG C or so.Air after heat exchange goes out from the furnace last row of shaft cooler, temperature Degree is increased to 400 DEG C or so, while may still have a small amount of metal chloride to volatilize in pelletizing cooling procedure, returns to furnace a tail wind It receives and utilizes, on the one hand recycle heat therein, the call of response national energy-saving consumption reduction;On the other hand your gold therein can be recycled Belong to chloride, improves metal recovery rate.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of shaft cooler furnace a tail winds to recycle technique, the technique It is recycled including the recuperation of heat of furnace a tail wind and metal chloride, has on the one hand recycled the heat in furnace a tail wind, reached energy-saving mesh , the precious metal chloride in another aspect recovery furnace a tail wind improves metal recovery rate.
In order to solve the above technical problems, the technical solution adopted by the present invention is that: the shaft cooler furnace a tail wind recycling benefit With technique, specifically includes the following steps:
It (1) is 800~1200 DEG C by the temperature after high-temperature roasting, average particle size is the high temperature iron pelletizing of 12~18mm, from The top of shaft cooler is packed into, and opens up the hole of 570~630mm of diameter on the middle part of shaft cooler and top;
(2) cold air is passed through from the lower part of shaft cooler, the high temperature iron pelletizing and cold air are in shaft cooler Interior reverse flow, the temperature to the high temperature iron pelletizing be reduced to 100 DEG C hereinafter, cooled iron ball group from shaft cooler Lower part discharge, while thering is a small amount of metal chloride to evaporate into cold air in pelletizing cooling procedure;The cold air pass through with After high temperature iron pelletizing heat exchange, temperature is increased to 300~450 DEG C, becomes hot-air;
(3) above-mentioned hot-air a part is discharged from the hole in the middle part of shaft cooler, sends to subsequent handling use;Another portion Divide and be discharged from the hole on shaft cooler top, is added after valuable metal chloride therein is recycled in cyclone dust collection, then through high temperature Rotary kiln is returned after pressure fan recycles thermal energy therein.
Preferably, above-mentioned shaft cooler furnace a tail wind recycles technique, in step (2), the temperature of the high temperature iron pelletizing Degree is reduced to 50~90 DEG C.
Wherein, above-mentioned shaft cooler furnace a tail wind recycles technique, in step (3), the high-temperature blower and rotary kiln The pipeline enclosure of connection is equipped with air quantity and adjusts flowmeter.
Wherein, above-mentioned shaft cooler furnace a tail wind recycles technique, and in step (3), the hot-air is from high-temperature pressurizing After being come out in blower, and coal gas and First air, after burning in burner noz(zle), into rotary kiln.
Wherein, above-mentioned shaft cooler furnace a tail wind recycles technique, and in step (3), the subsequent handling is that ore pulp soaks Heating process or calcium chloride heat enrichment process out.
Compared with prior art, the beneficial effects of the present invention are: present invention is generally directed to iron ball groups made of pyrite cinder Product cooling, valuable metal chloride and waste heat recycling after high-temperature roasting chlorinated gold extracting provide a kind of new technique, the work Skill will carry out the cold air of heat exchange with high temperature iron pelletizing, i.e., final furnace a tail wind (i.e. hot-air) is handled: a part Heat enters subsequent handling, and a part of heat enters rotary kiln and recycles, and reaches mesh that is energy-saving, reducing production cost 's.Meanwhile the precious metal chloride in the technology utilization cyclone dust collection recovery furnace a tail wind (i.e. hot-air), not only increase metal The rate of recovery, and avoid precious metal chloride and pollute the environment.
Detailed description of the invention
Fig. 1 is the flow diagram that shaft cooler furnace a tail wind of the present invention recycles technique.
Specific embodiment
The present invention provides a kind of shaft cooler furnace a tail wind recycle technique, the technique specifically includes the following steps:
It (1) is 800~1200 DEG C by the temperature after high-temperature roasting, average particle size is the high temperature iron pelletizing of 12~18mm, from The top of shaft cooler is packed into;And the hole of 570~630mm of diameter is opened up on the middle part of shaft cooler and top;
(2) cold air is passed through from the lower part of shaft cooler, the high temperature iron pelletizing and cold air are in shaft cooler Interior reverse flow, the temperature to the high temperature iron pelletizing be reduced to 100 DEG C hereinafter, cooled iron ball group from shaft cooler Lower part discharge, while thering is a small amount of metal chloride to evaporate into cold air in pelletizing cooling procedure;The cold air pass through with After high temperature iron pelletizing heat exchange, temperature is increased to 300~450 DEG C, becomes hot-air;
(3) above-mentioned hot-air a part is discharged from the hole in the middle part of shaft cooler, sends to subsequent handling recycling;Separately A part is discharged from the hole on shaft cooler top, after valuable metal chloride therein is recycled in cyclone dust collection, then through height Warm booster fan after burning in burner noz(zle), returns to rotary kiln and recycles thermal energy therein with coal gas and First air.
Preferably, above-mentioned shaft cooler furnace a tail wind recycles technique, in step (2), the temperature of the high temperature iron pelletizing Degree is reduced to 50~90 DEG C.
Wherein, above-mentioned shaft cooler furnace a tail wind recycles technique, in step (3), the high-temperature pressurizing blower with return The pipeline enclosure of rotary kiln connection installs an air quantity and adjusts flowmeter, for controlling the air quantity for returning to rotary kiln and using, to guarantee back Turn kiln temperature to stablize.
Wherein, above-mentioned shaft cooler furnace a tail wind recycles technique, and in step (3), the subsequent handling can be to appoint The process that meaning needs to heat (i.e. supply heat), such as ore pulp leaches heating process, calcium chloride heats enrichment process.
Below in conjunction with specific embodiment, the present invention will be further explained, but is not intended to limit the present invention Protection scope.
Embodiment 1
Shaft cooler furnace a tail wind recycle technique, the technique specifically includes the following steps:
It (1) is 1100 DEG C by the temperature after high-temperature roasting, average particle size is the high temperature iron pelletizing of 13mm, from shaft cooler Top be packed into;And the hole of diameter 580mm is opened up on the middle part of shaft cooler and top;
(2) cold air is passed through by centrifugal blower from the lower part of shaft cooler, the high temperature iron pelletizing and cold air The reverse flow in shaft cooler, the temperature to the high temperature iron pelletizing are reduced to 80 DEG C, and cooled iron ball is rolled into a ball from vertical The lower part of cooler is discharged, while having a small amount of metal chloride to evaporate into cold air in pelletizing cooling procedure;The cold sky Gas passes through with after high temperature iron pelletizing heat exchange, and temperature is increased to 400 DEG C, becomes hot-air;
(3) above-mentioned hot-air a part is discharged from the hole in the middle part of shaft cooler, sends to calcium chloride CONCENTRATION PLANT to chlorine Change calcium and is evaporated concentration;Another part is discharged from the hole on shaft cooler top, gathers dust recycling wherein through cyclone separator Valuable metal chloride after, then through two high-temperature pressurizing blowers, returned after burning in burner noz(zle) with coal gas and First air Huis rotary kiln recycles thermal energy therein;The pipeline enclosure that the high-temperature pressurizing blower is connect with rotary kiln installs an air quantity and adjusts stream Meter, for controlling the air quantity for returning to rotary kiln and using, to guarantee that rotary kiln temperature is stablized.
Embodiment 2
Shaft cooler furnace a tail wind recycle technique, the technique specifically includes the following steps:
It (1) is 1000 DEG C by the temperature after high-temperature roasting, average particle size is the high temperature iron pelletizing of 16mm, from shaft cooler Top be packed into;And the hole of diameter 580mm is opened up on the middle part of shaft cooler and top;
(2) cold air is passed through by centrifugal blower from the lower part of shaft cooler, the high temperature iron pelletizing and cold air The reverse flow in shaft cooler, the temperature to the high temperature iron pelletizing are reduced to 90 DEG C, and cooled iron ball is rolled into a ball from vertical The lower part of cooler is discharged, while having a small amount of metal chloride to evaporate into cold air in pelletizing cooling procedure;The cold sky Gas passes through with after high temperature iron pelletizing heat exchange, and temperature is increased to 410 DEG C, obtains hot-air;
(3) above-mentioned hot-air a part is discharged from the hole in the middle part of shaft cooler, sends to ore pulp and leaches heating process;Separately A part is discharged from the hole on shaft cooler top, after cyclone separator gathers dust and recycles valuable metal chloride therein, It after burning in burner noz(zle), returns to rotary kiln with coal gas and First air through two high-temperature pressurizing blowers again and recycles heat therein Energy;The pipeline enclosure that the high-temperature pressurizing blower is connect with rotary kiln installs an air quantity and adjusts flowmeter, returns back for controlling The air quantity that rotary kiln uses, to guarantee that rotary kiln temperature is stablized.
Embodiment 3
Shaft cooler furnace a tail wind recycle technique, the technique specifically includes the following steps:
It (1) is 1000 DEG C by the temperature after high-temperature roasting, average particle size is the high temperature iron pelletizing of 16mm, from shaft cooler Top be packed into;And the hole of diameter 630mm is opened up on the middle part of shaft cooler and top;
(2) cold air is passed through by centrifugal blower from the lower part of shaft cooler, the high temperature iron pelletizing and cold air The reverse flow in shaft cooler, the temperature to the high temperature iron pelletizing are reduced to 50 DEG C, and cooled iron ball is rolled into a ball from vertical The lower part of cooler is discharged, while having a small amount of metal chloride to evaporate into cold air in pelletizing cooling procedure;The cold sky Gas passes through with after high temperature iron pelletizing heat exchange, and temperature is increased to 450 DEG C, becomes hot-air;
(3) above-mentioned hot-air a part is discharged from the hole in the middle part of shaft cooler, sends to ore pulp and leaches heating process;Separately A part is discharged from the hole on shaft cooler top, after cyclone separator gathers dust and recycles valuable metal chloride therein, It after burning in burner noz(zle), returns to rotary kiln with coal gas and First air through two high-temperature pressurizing blowers again and recycles heat therein Energy;The pipeline enclosure that the high-temperature pressurizing blower is connect with rotary kiln installs an air quantity and adjusts flowmeter, returns back for controlling The air quantity that rotary kiln uses, to guarantee that rotary kiln temperature is stablized.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art, is not being taken off Under the premise of from structure of the invention, various modifications and improvements can be made, these should also be as being considered as protection scope of the present invention, These all will not influence the practicability of effect and this patent that the present invention is implemented.

Claims (2)

1. shaft cooler furnace a tail wind recycle technique, which is characterized in that the technique specifically includes the following steps:
It (1) is 1000 DEG C by the temperature after high-temperature roasting, average particle size is iron ball group made of the high-temperature sulfuric acid slag of 16mm, from The top of shaft cooler is packed into, and opens up the hole of diameter 630mm on the middle part of shaft cooler and top;
(2) cold air is passed through from the lower part of shaft cooler, the high temperature iron pelletizing and cold air are inverse in shaft cooler To flowing, the temperature to the high temperature iron pelletizing is reduced to 50 DEG C, and cooled iron ball group is discharged from the lower part of shaft cooler, There is a small amount of metal chloride to evaporate into cold air in pelletizing cooling procedure simultaneously;The cold air passes through and high temperature iron pelletizing After heat exchange, temperature is increased to 450 DEG C, becomes hot-air;
(3) above-mentioned hot-air a part is discharged from the hole in the middle part of shaft cooler, sends to subsequent handling use;Another part from It is discharged in the hole on shaft cooler top, after valuable metal chloride therein is recycled in cyclone dust collection, then through high-temperature pressurizing wind After machine, with coal gas and First air, rotary kiln is returned after burning in burner noz(zle) and recycles thermal energy therein;The high-temperature pressurizing wind The pipeline enclosure that machine is connect with rotary kiln is equipped with air quantity and adjusts flowmeter.
2. shaft cooler furnace a tail wind according to claim 1 recycles technique, which is characterized in that in step (3), institute Stating subsequent handling is that ore pulp leaches heating process or calcium chloride heats enrichment process.
CN201710533023.2A 2017-07-03 2017-07-03 A kind of shaft cooler furnace a tail wind recycling technique Active CN107338356B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108866327A (en) * 2018-05-31 2018-11-23 江苏东九重工股份有限公司 A kind of high temperature pelletizing cooling means and its device

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85103266A (en) * 1984-08-24 1986-10-22 Skf钢铁工程公司 The method and apparatus of cooling pellets
CN102242254A (en) * 2011-06-29 2011-11-16 中南大学 High sulfide pyrite pellet reinforced roasting consolidation technology
CN102534188A (en) * 2012-01-20 2012-07-04 个旧市富祥工贸有限责任公司 Method for producing iron pellet with sulfur acid residue containing large contents of impurities and enriching valuable metal
CN104846194A (en) * 2015-03-16 2015-08-19 北京矿冶研究总院 Cooling method of chloridized roasted pellets

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85103266A (en) * 1984-08-24 1986-10-22 Skf钢铁工程公司 The method and apparatus of cooling pellets
CN102242254A (en) * 2011-06-29 2011-11-16 中南大学 High sulfide pyrite pellet reinforced roasting consolidation technology
CN102534188A (en) * 2012-01-20 2012-07-04 个旧市富祥工贸有限责任公司 Method for producing iron pellet with sulfur acid residue containing large contents of impurities and enriching valuable metal
CN104846194A (en) * 2015-03-16 2015-08-19 北京矿冶研究总院 Cooling method of chloridized roasted pellets

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