CN107326465A - A kind of processing method for improving fishing net polyamide monofilament wearability - Google Patents

A kind of processing method for improving fishing net polyamide monofilament wearability Download PDF

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Publication number
CN107326465A
CN107326465A CN201710426670.3A CN201710426670A CN107326465A CN 107326465 A CN107326465 A CN 107326465A CN 201710426670 A CN201710426670 A CN 201710426670A CN 107326465 A CN107326465 A CN 107326465A
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polyamide monofilament
wearability
fishing net
processing method
monofilament
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向泽柱
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Chaohu Tianyu Fishing Tackle Co Ltd
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Chaohu Tianyu Fishing Tackle Co Ltd
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246Esters of unsaturated carboxylic acids
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/415Amides of aromatic carboxylic acids; Acylated aromatic amines
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    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
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    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/05Cellulose or derivatives thereof
    • D06M15/09Cellulose ethers
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    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
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    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
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    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35Abrasion, pilling or fibrillation resistance

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  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Plasma & Fusion (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Artificial Filaments (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention belongs to the preparing technical field of fishing polyamide monofilament, and in particular to a kind of processing method of raising fishing net polyamide monofilament wearability, including counter extensioin silk raw material selected, match after plated film under vacuum.The present invention has advantages below compared with prior art:By carrying out scientific matching to polyamide monofilament raw material in the present invention, uniformly adhere to one layer of hybrid films on its surface again, while made fishing net fouling resistance is improved, improve the wearability of polyamide monofilament, wearability will not be soaked due to long-time in water or service wear is serious, the bending strength and service life of polyamide monofilament are also increased simultaneously, add the scope of application of polyamide monofilament.

Description

A kind of processing method for improving fishing net polyamide monofilament wearability
Technical field
The invention belongs to the preparing technical field of fishing polyamide monofilament, and in particular to one kind improves fishing net polyamide list The processing method of silk wearability.
Background technology
Synthetic fibers are the main bodys of fishing materials, not only substitute fishing natural fiber, and valency substantially in fishery Lattice are generally below traditional fishing natural fiber such as cotton, silk, and the progress that fishing is obtained with synthetic fibers in science and technology is used also above fishing Natural fiber, wherein polyamide monofilament employ a variety of methods to improve its wearability, but have that pliability is poor, do not meet fishing Required with monofilament, or the problems such as technology hardly possible, high expensive, also have and dried after polyamide spinning, using its water imbibition, passed through Gold adsorbs aqueous finish, using shallow Surface absorption with covering finish reduction and the coefficient of friction of other materials, improves anti-wear performance, Because polyamide fishing monofilament yarn works in water for a long time when in use, aqueous finish causes wear time short quickly by aquation, resistance to The problems such as effect is poor is ground, therefore, the wearability for how improving polyamide monofilament should be studied.
The content of the invention
The purpose of the present invention be for it is existing the problem of there is provided it is a kind of raising fishing net polyamide monofilament wearability plus Work method.
The present invention is achieved by the following technical solutions:A kind of processing side for improving fishing net polyamide monofilament wearability Method, including herein below:
(1)By weight, 78-84 parts of polyamide, metallocene catalyzed polyolefin 4-7 that molecular weight is 3.5-4.2 ten thousand are taken Part, 0.6-0.9 parts of active nanoparticles, 8-12 parts of ultra-high molecular weight polyethylene, the 2.6-3.4 parts of mixing of PE grafted maleic anhydrides are equal Dried after even to water content less than 0.1%, melt spinning, then drafting silk is obtained through high power heat-traction;
(2)It is 1.6 × 10 in vacuum-2Pa-3.5×10-2Under conditions of Pa, add the lead using laser photolysis, caesium mixing and steam The mixed weight ratio of gas, lead and caesium is 3-5:1, handle 10-15 minutes, obtain high abrasion polyamide monofilament.
As further improvement of these options, the metallocene catalyzed polyolefin is ENGAGETMPolyolefin elastomer, AFFINITYTMGA polyolefin elastomers or INFUSETMAny one in polyolefin block polymer.
As further improvement of these options, the active nanoparticles are by stearic acid modified nano-calcium carbonate Calcium.
As further improvement of these options, the condition of the stearic acid modified nano-calcium carbonate is:Mass concentration Calcium carbonate for 12% and the stearic acid equivalent to its weight 2.8%, in the bar that temperature is 90 DEG C, mixing speed is 3000 turns/min Reacted 40 minutes under part, drying temperature is 96 DEG C, obtain the modified nano calcium carbonate that activation index is 0.95.
As further improvement of these options, the ultra-high molecular weight polyethylene molecular weight is 200-300 ten thousand.
As further improvement of these options, the spinning temperature is 280 DEG C, and spinning speed is 26m/min, drawing-off Multiple is 8.5 times.
As further improvement of these options, the lead, the effect of caesium mixed vapour add drafting silk diameter 0.006-0.012mm。
The present invention has advantages below compared with prior art:Matched somebody with somebody in the present invention by carrying out science to polyamide monofilament raw material Than, then in one layer of hybrid films of the uniform attachment in its surface, while made fishing net fouling resistance is improved, improve polyamide monofilament Wearability, wearability will not be soaked due to long-time in water or service wear is serious, while also increasing polyamide monofilament Bending strength and service life, add the scope of application of polyamide monofilament.
Embodiment
Embodiment 1
A kind of processing method for improving fishing net polyamide monofilament wearability, including herein below:
(1)By weight, 80 parts of polyamide, INFUSE that molecular weight is 3.5-4.2 ten thousand are takenTMPolyolefin block polymerize 5 parts of thing, 0.8 part of active nanoparticles, molecular weight are 200-300 ten thousand 10 parts of ultra-high molecular weight polyethylene, PE grafted maleics Dried after 3.2 parts of acid anhydride is well mixed to water content and be less than 0.1%, melt spinning, spinning temperature is 280 DEG C, and spinning speed is 26m/ Min, then drafting silk is obtained through high power heat-traction, drafting multiple is 8.5 times;
Wherein, the active nanoparticles are stearic acid modified nano-calcium carbonate, the bar of the stearic acid modified nano-calcium carbonate Part is:Mass concentration for 12% calcium carbonate and the stearic acid equivalent to its weight 2.8%, temperature be 90 DEG C, mixing speed be Reacted 40 minutes under conditions of 3000 turns/min, drying temperature is 96 DEG C, obtain the modified nano-meter caco 3 that activation index is 0.95 Calcium;
(2)It is 2.5 × 10 in vacuum-2Under conditions of Pa, lead, the caesium mixed vapour using laser photolysis are added, lead and caesium Mixed weight ratio is 4:1, handle 10-15 minutes, obtain high abrasion polyamide monofilament.
Embodiment 2
A kind of processing method for improving fishing net polyamide monofilament wearability, including herein below:
(1)By weight, 78 parts of polyamide, ENGAGE that molecular weight is 3.5-4.2 ten thousand are takenTMPolyolefin elastomer 7 Part, 12 parts of ultra-high molecular weight polyethylene, the PE grafted maleic anhydrides that 0.6 part of active nanoparticles, molecular weight are 200-300 ten thousand 2.6 parts it is well mixed after dry to water content and be less than 0.1%, melt spinning, spinning temperature is 280 DEG C, and spinning speed is 26m/ Min, then drafting silk is obtained through high power heat-traction, drafting multiple is 8.5 times;
Wherein, the active nanoparticles are stearic acid modified nano-calcium carbonate, the bar of the stearic acid modified nano-calcium carbonate Part is:Mass concentration for 12% calcium carbonate and the stearic acid equivalent to its weight 2.8%, temperature be 90 DEG C, mixing speed be Reacted 40 minutes under conditions of 3000 turns/min, drying temperature is 96 DEG C, obtain the modified nano-meter caco 3 that activation index is 0.95 Calcium;
(2)It is 1.8 × 10 in vacuum-2Under conditions of Pa, lead, the caesium mixed vapour using laser photolysis are added, lead and caesium Mixed weight ratio is 5:1, handle 10-15 minutes, obtain high abrasion polyamide monofilament.
Embodiment 3
A kind of processing method for improving fishing net polyamide monofilament wearability, including herein below:
(1 )By weight, 84 parts of polyamide, AFFINITY that molecular weight is 3.5-4.2 ten thousand are takenTMGA polyolefin elastics 4 parts of body, 0.6 part of active nanoparticles, molecular weight are 200-300 ten thousand 8 parts of ultra-high molecular weight polyethylene, PE grafted maleic anhydrides 3.4 parts it is well mixed after dry to water content and be less than 0.1%, melt spinning, spinning temperature is 280 DEG C, and spinning speed is 26m/ Min, then drafting silk is obtained through high power heat-traction, drafting multiple is 8.5 times;
Wherein, the active nanoparticles are stearic acid modified nano-calcium carbonate, the bar of the stearic acid modified nano-calcium carbonate Part is:Mass concentration for 12% calcium carbonate and the stearic acid equivalent to its weight 2.8%, temperature be 90 DEG C, mixing speed be Reacted 40 minutes under conditions of 3000 turns/min, drying temperature is 96 DEG C, obtain the modified nano-meter caco 3 that activation index is 0.95 Calcium;
(2)It is 3.5 × 10 in vacuum-2Under conditions of Pa, lead, the caesium mixed vapour using laser photolysis are added, lead and caesium Mixed weight ratio is 3:1, handle 10-15 minutes, obtain high abrasion polyamide monofilament.
Control group 1 is set, is that embodiment 1 removes step(2)Operation;Control group 2 is set, is that Dare fishing is pacified by Chaohu The polyamide monofilament provided is provided;
Experiment 1 is set, a diameter of 0.05mm of gained drafting silk in embodiment 1-3, gained polyamide monofilament it is a diameter of 0.06mm;The a diameter of 0.06mm of polyamide monofilament of control group 1 and control group 2, each group is tested through wear resistant instrument, and detection each group is comprehensive Physical property is closed, and is single wire fracture strength 20% in pre-tension, remaining 50% number of ultimate strength of abrasion is counted, obtained Data below:
Table 1
Experiment 2 is set, a diameter of 0.59mm of gained drafting silk in embodiment 1-3, gained polyamide monofilament it is a diameter of 0.6mm;The a diameter of 0.6mm of polyamide monofilament of control group 1 and control group 2, each group is tested through wear resistant instrument, and detection each group is integrated Physical property, and be single wire fracture strength 20% in pre-tension, remaining 50% number of ultimate strength of abrasion is counted, obtain with Lower data:
Table 2
Can be seen that control group 1 compared to existing product physical property by data in Tables 1 and 2 has certain raising, by true Processing of the empty plated film to polyamide monofilament, makes its anti-wear performance be significantly improved, and expands the scope of application of polyamide monofilament.

Claims (7)

1. a kind of processing method for improving fishing net polyamide monofilament wearability, it is characterised in that including herein below:
(1)By weight, 78-84 parts of polyamide, metallocene catalyzed polyolefin 4-7 that molecular weight is 3.5-4.2 ten thousand are taken Part, 0.6-0.9 parts of active nanoparticles, 8-12 parts of ultra-high molecular weight polyethylene, the 2.6-3.4 parts of mixing of PE grafted maleic anhydrides are equal Dried after even to water content less than 0.1%, melt spinning, then drafting silk is obtained through high power heat-traction;
(2)It is 1.6 × 10 in vacuum-2Pa-3.5×10-2Under conditions of Pa, add the lead using laser photolysis, caesium mixing and steam The mixed weight ratio of gas, lead and caesium is 3-5:1, handle 10-15 minutes, obtain high abrasion polyamide monofilament.
2. a kind of processing method for improving fishing net polyamide monofilament wearability as claimed in claim 1, it is characterised in that described Metallocene catalyzed polyolefin is ENGAGETMPolyolefin elastomer, AFFINITYTMGA polyolefin elastomers or INFUSETMPolyolefin Any one in block polymer.
3. a kind of processing method for improving fishing net polyamide monofilament wearability as claimed in claim 1, it is characterised in that described Active nanoparticles are by stearic acid modified nano-calcium carbonate.
4. a kind of processing method for improving fishing net polyamide monofilament wearability as claimed in claim 3, it is characterised in that described The condition of stearic acid modified nano-calcium carbonate is:Calcium carbonate of the mass concentration for 12% and the stearic acid equivalent to its weight 2.8%, Temperature be 90 DEG C, mixing speed be to react 40 minutes under conditions of 3000 turns/min, drying temperature is 96 DEG C, obtains activation and refers to Number is 0.95 modified nano calcium carbonate.
5. a kind of processing method for improving fishing net polyamide monofilament wearability as claimed in claim 1, it is characterised in that described Ultra-high molecular weight polyethylene molecular weight is 200-300 ten thousand.
6. a kind of processing method for improving fishing net polyamide monofilament wearability as claimed in claim 1, it is characterised in that described Spinning temperature is 280 DEG C, and spinning speed is 26m/min, and drafting multiple is 8.5 times.
7. a kind of processing method for improving fishing net polyamide monofilament wearability as claimed in claim 1, it is characterised in that described Lead, the effect of caesium mixed vapour make drafting silk diameter add 0.006-0.012mm.
CN201710426670.3A 2017-06-08 2017-06-08 A kind of processing method for improving fishing net polyamide monofilament wearability Pending CN107326465A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111394881A (en) * 2020-04-15 2020-07-10 巢湖市翔宇渔具有限公司 Preparation method of silica gel reinforced anti-aging fishing net

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CN1687507A (en) * 2005-04-12 2005-10-26 夏芝林 Method for preparing silver metallized organic fiber and textile
CN103147283A (en) * 2013-03-19 2013-06-12 中国水产科学研究院东海水产研究所 Preparation method of copper-plated polyethylene monofilament for fisheries
CN103147157A (en) * 2013-03-19 2013-06-12 中国水产科学研究院东海水产研究所 Preparation method of fishery polyamide wear-resistant monofilament
CN104831527A (en) * 2015-03-31 2015-08-12 嘉兴中科奥度新材料有限公司 Technology for total-cladding composite ion plating of surface of aramid fiber or laid fabric with nanometals, and product thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1687507A (en) * 2005-04-12 2005-10-26 夏芝林 Method for preparing silver metallized organic fiber and textile
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