CN107326259A - A kind of alloy material with noctilucent function - Google Patents

A kind of alloy material with noctilucent function Download PDF

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Publication number
CN107326259A
CN107326259A CN201710382376.7A CN201710382376A CN107326259A CN 107326259 A CN107326259 A CN 107326259A CN 201710382376 A CN201710382376 A CN 201710382376A CN 107326259 A CN107326259 A CN 107326259A
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CN
China
Prior art keywords
alloy material
noctilucent function
coating agent
parts
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710382376.7A
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Chinese (zh)
Inventor
张斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Auri Special Steel Co Ltd
Original Assignee
Jiangsu Auri Special Steel Co Ltd
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Filing date
Publication date
Application filed by Jiangsu Auri Special Steel Co Ltd filed Critical Jiangsu Auri Special Steel Co Ltd
Priority to CN201710382376.7A priority Critical patent/CN107326259A/en
Publication of CN107326259A publication Critical patent/CN107326259A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7783Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals one of which being europium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides

Abstract

The invention discloses a kind of alloy material with noctilucent function, described alloy material includes following element:Iron, carbon, barium, yttrium, europium, terbium, cerium, phosphorus, its each composition quality, which is matched, is:88~92 parts of iron, 0.2~0.3 part of carbon, 0.3~0.5 part of yttrium, 0.2~0.3 part of europium, 0.2~0.5 part of terbium, 0.2~0.5 part of cerium, phosphorus 0.1~0.2%;Also include 1~2 part of 1~2 part of stabilizer and coating agent.Alloy material provided by the present invention has fluorescence, it can apply to the wheel hub of the vehicles, the fluorescence that can be sent at night by it causes the attention of pedestrian, increase the security of night traffic, in addition the alloy material of the present invention with noctilucent function does not have radioactive substance, safe to the human body.

Description

A kind of alloy material with noctilucent function
Technical field
The invention belongs to technical field of metal material, it is related to a kind of alloy material with noctilucent function.
Background technology
Hard alloy [is the one kind being made up of the hard compounds and binding metal of refractory metal of powder metallurgical technique Alloy material.A series of premium properties such as hard alloy has high, wear-resisting hardness, intensity and toughness is preferable, heat-resisting, corrosion-resistant, Particularly its high rigidity and wearability, is also held essentially constant at a temperature of 500 DEG C, still has very high at 1000 DEG C Hardness.Hard alloy is widely used as cutter material, and such as lathe tool, milling cutter, planing tool, drill bit, boring cutter for cutting cast iron, have Non-ferrous metal, plastics, chemical fibre, graphite, glass, stone material and common iron, may also be used for cutting heat resisting steel, stainless steel, potassium steel, The difficult to machine materials such as tool steel.
Hard alloy has very high hardness, intensity, wearability and corrosion resistance, " industrial tooth " is described as, for making Cutting element, cutter, cobalt tool and wear-resisting spare part are made, is widely used in military project, space flight and aviation, machining, metallurgy, petroleum drilling The fields such as well, mine instrument, telecommunications, building, with the development of downstream industry, the hard alloy market demand is continued to increase. And following new- and high-tech weaponry and equipment manufacture, the progress of advanced science technology and the fast development of nuclear power source, will be carried energetically Height is to high technology content and the demand of the hart metal product of high-quality stability.
Fluorescent material be with metal (zinc, chromium) sulfide or rare earth oxide and trace active agent through calcining form. Colourless or shallow white, is under ultraviolet light (200~400nm) irradiation, according to metal in pigment and activator species, content not Together, the visible ray (400~800nm) of a variety of colors is showed.
With the progress of science and technology, research of the people to fluorescence is more and more, and the application of fluorescent material is increasingly Extensively.Fluorescent material in addition to as dyestuff, also organic pigment, Optical Bleaching Agent, photooxidant, coating, chemistry and biochemical analysis, The fields such as solar energy trap, anti-fake mark, pharmaceutical indications and laser have obtained wider application.
The content of the invention
Goal of the invention:For weak point of the prior art, the invention provides a kind of alloy with noctilucent function Material.Visible ray can be sent at night.
Technical scheme:A kind of alloy material with noctilucent function, described alloy material includes following element:Iron, carbon, Barium, yttrium, europium, terbium, cerium, phosphorus, its each composition quality, which is matched, is:88~92 parts of iron, 0.2~0.3 part of carbon, 0.3~0.5 part of yttrium, europium 0.2~0.3 part, 0.2~0.5 part of terbium, 0.2~0.5 part of cerium, phosphorus 0.1~0.2%;Also include 1~2 part of stabilizer and coating agent 1 ~2 parts.
Described feature steel also contain 1~4 part of nano silicon.
It is molded using conventional metallurgical method metallurgy, it is characterised in that be made according to the formula as described in claim 1~2 Steel, after after steel shaping, being its one layer of coating agent of outside coating, that is, obtain the alloy material with noctilucent function.
Further study, be both to be surface-treated again in the outer surface of the steel.Specifically, the present invention is also carried The preparation method of the steel is supplied.For the present invention, according to above-mentioned formula, it is molded using conventional metallurgical method metallurgy. After after steel shaping, being its outside coating coating agent, described coating agent coats one layer, that is, obtains the conjunction with noctilucent function Golden material.
Further, after coating coating agent, irradiated 20~30 minutes with ultraviolet, its effect is more preferable.
Specifically, the coating agent described in described coating agent is the metallic solution of baric and the mixture of halide.It is preferred that Described coating agent is the mixture of barium sulfate solution and Ethidum Eremide.Further preferably described coating agent constituent content is sulphur Sour 10 parts of barium solution, 7 parts of Ethidum Eremide.
Beneficial effect:Alloy material provided by the present invention has fluorescence, can apply to the wheel hub of the vehicles, The fluorescence that can be sent at night by it causes the attention of pedestrian, increases the security of night traffic, of the present invention in addition The alloy material with noctilucent function there is no radioactive substance, it is safe to the human body.
Embodiment:
Embodiment 1
Alloy material with noctilucent function turns into:88 parts of iron, 0.2 part of carbon, 0.3 part of yttrium, 0.2 part of europium, 0.2 part of terbium, 0.2 part of cerium, 0.1 part of phosphorus.
According to aforementioned proportion, raw material proportioning, mixing, just refining, refining are carried out using conventional method.One layer is coated after shaping Coating agent.The formula of the coating agent is 10 parts of barium sulfate solution, 7 parts of Ethidum Eremide.
Embodiment 2
Alloy material with noctilucent function turns into:92 parts of iron, 0.3 part of carbon, 0.5 part of yttrium, 0.3 part of europium, 0.5 part of terbium, 0.5 part of cerium, 0.2 part of phosphorus.
According to aforementioned proportion, raw material proportioning, mixing, just refining, refining are carried out using conventional method.One layer is coated after shaping Coating agent.The formula of the coating agent is 10 parts of barium sulfate solution, 7 parts of Ethidum Eremide.
Embodiment 3
Alloy material with noctilucent function turns into:92 parts of iron, 0.2 part of carbon, 0.5 part of yttrium, 0.2 part of europium, 0.2 part of terbium, 0.5 part of cerium, 0.1 part of phosphorus.
According to aforementioned proportion, raw material proportioning, mixing, just refining, refining are carried out using conventional method.One layer is coated after shaping Coating agent.The formula of the coating agent is 10 parts of barium sulfate solution, 7 parts of Ethidum Eremide.
Embodiment 4
Alloy material with noctilucent function turns into:88 parts of iron, 0.2 part of carbon, 0.5 part of yttrium, 0.2 part of europium, 0.2 part of terbium, 0.2 part of cerium, 0.2 part of phosphorus.
According to aforementioned proportion, raw material proportioning, mixing, just refining, refining are carried out using conventional method.One layer is coated after shaping Coating agent.The formula of the coating agent is 10 parts of barium sulfate solution, 7 parts of Ethidum Eremide.
Embodiment 5
Alloy material with noctilucent function turns into:88 parts of iron, 0.3 part of carbon, 0.3 part of yttrium, 0.3 part of europium, 0.2 part of terbium, 0.5 part of cerium, 0.1 part of phosphorus.
According to aforementioned proportion, raw material proportioning, mixing, just refining, refining are carried out using conventional method.One layer is coated after shaping Coating agent.The formula of the coating agent is 10 parts of barium sulfate solution, 7 parts of Ethidum Eremide.

Claims (7)

1. a kind of alloy material with noctilucent function, it is characterised in that described alloy material includes following element:Iron, carbon, Barium, yttrium, europium, terbium, cerium, phosphorus, its each composition quality, which is matched, is:88~92 parts of iron, 0.2~0.3 part of carbon, 0.3~0.5 part of yttrium, europium 0.2~0.3 part, 0.2~0.5 part of terbium, 0.2~0.5 part of cerium, 0.1~0.2 part of phosphorus;Also include 1~2 part of stabilizer and coating agent 1 ~2 parts.
2. the alloy material according to claim 1 with noctilucent function, it is characterised in that described stabilizer is nanometer Silica.
3. the alloy material with noctilucent function described in claim 1~2, is molded, it is special using conventional metallurgical method metallurgy Levy and be steel are made according to the formula as described in claim 1~2, after steel are molded, be its outside one layer of coating Coating agent, that is, obtain the alloy material with noctilucent function.
4. the preparation method of the alloy material with noctilucent function described in claim 1, it is characterised in that in coating coating agent Afterwards, irradiated 20~30 minutes with ultraviolet.
5. the preparation method of the alloy material with noctilucent function described in claim 1, it is characterised in that described coating agent The mixture of metallic solution and halide for baric.
6. the preparation method of the alloy material with noctilucent function described in claim 1, it is characterised in that described coating agent For barium sulfate solution and the mixture of Ethidum Eremide.
7. the preparation method of the alloy material with noctilucent function described in claim 1, it is characterised in that described coating agent Constituent content is 10 parts of barium sulfate solution, 7 parts of Ethidum Eremide.
CN201710382376.7A 2017-05-26 2017-05-26 A kind of alloy material with noctilucent function Pending CN107326259A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710382376.7A CN107326259A (en) 2017-05-26 2017-05-26 A kind of alloy material with noctilucent function

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710382376.7A CN107326259A (en) 2017-05-26 2017-05-26 A kind of alloy material with noctilucent function

Publications (1)

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CN107326259A true CN107326259A (en) 2017-11-07

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102703077A (en) * 2012-06-11 2012-10-03 中国科学院福建物质结构研究所 Fluorescent powder, and preparation method and application thereof
CN103158297A (en) * 2013-04-07 2013-06-19 合肥美的荣事达电冰箱有限公司 Fluorescent metal plate and manufacturing process thereof
CN103710563A (en) * 2013-12-25 2014-04-09 北海鑫利坤金属材料科技开发有限公司 Silver alloy material with fluorescent effect
CN105462210A (en) * 2014-09-05 2016-04-06 青岛颐世保塑料有限公司 Reinforced and brightened alloy material
CN105951002A (en) * 2016-05-25 2016-09-21 江苏金基特钢有限公司 Preparation method of corrosion-resistance stainless steel wire easy to mold

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102703077A (en) * 2012-06-11 2012-10-03 中国科学院福建物质结构研究所 Fluorescent powder, and preparation method and application thereof
CN103158297A (en) * 2013-04-07 2013-06-19 合肥美的荣事达电冰箱有限公司 Fluorescent metal plate and manufacturing process thereof
CN103710563A (en) * 2013-12-25 2014-04-09 北海鑫利坤金属材料科技开发有限公司 Silver alloy material with fluorescent effect
CN105462210A (en) * 2014-09-05 2016-04-06 青岛颐世保塑料有限公司 Reinforced and brightened alloy material
CN105951002A (en) * 2016-05-25 2016-09-21 江苏金基特钢有限公司 Preparation method of corrosion-resistance stainless steel wire easy to mold

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Application publication date: 20171107