CN107325722A - A kind of aqueous basement membrane of multiple-effect and preparation method thereof - Google Patents

A kind of aqueous basement membrane of multiple-effect and preparation method thereof Download PDF

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Publication number
CN107325722A
CN107325722A CN201710478235.5A CN201710478235A CN107325722A CN 107325722 A CN107325722 A CN 107325722A CN 201710478235 A CN201710478235 A CN 201710478235A CN 107325722 A CN107325722 A CN 107325722A
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CN
China
Prior art keywords
aqueous
basement membrane
effect
parts
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710478235.5A
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Chinese (zh)
Inventor
陈向新
崔晶晶
胡中源
郑毅
赵娟
崔佳慧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Industry and Trade Group Co Ltd
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Publication date
Application filed by Hebei Chenyang Industry and Trade Group Co Ltd filed Critical Hebei Chenyang Industry and Trade Group Co Ltd
Priority to CN201710478235.5A priority Critical patent/CN107325722A/en
Publication of CN107325722A publication Critical patent/CN107325722A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D187/00Coating compositions based on unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plant Pathology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses aqueous basement membrane of a kind of multiple-effect and preparation method thereof, the aqueous basement membrane of a kind of multiple-effect of the invention, including following components by weight:150 240 parts of deionized water, 720 800 parts of water-based emulsion, 25 parts of defoamer, 10 15 parts of coalescents, 24 parts of pH adjusting agent, 58 parts of thickener, 68 parts of mould inhibitor, 13 parts of bactericide.The water-based emulsion is anionic emulsion of the styrene-acrylic emulsion through epoxy resin modification copolymerization, and by vacuumize process, particle diameter is less than 30nm, 3 DEG C of MFT.Bio-toxicity of the present invention is low, and adhesive force is strong, and drying time is short, with good consolidation effect, Saline alkali tolerance energy, antimycotic antiseptic effect and environmental-protecting performance.

Description

A kind of aqueous basement membrane of multiple-effect and preparation method thereof
Technical field
The present invention relates to paint field technical field, more particularly to a kind of aqueous basement membrane of multiple-effect and preparation method thereof.
Background technology
The features such as wallpaper has novel design, short construction period, facilitates easy-to-use as a kind of emerging ornament materials, it is more next The accreditation of people is more received, one layer of basement membrane of brush is needed before wallpaper, putty layer, the use longevity of isolation alkalescence extension wallpaper is reinforced Life.
Basement membrane quality on the market is uneven at present and single effect, and part basement membrane even reaches bonding using glue Effect, therefore, basement membrane is sold in room can not generally meet good consolidation effect, alkaline resistance properties, antimycotic antiseptic and excellent ring Guaranteed cost.
The content of the invention
To solve the above problems, it is an object of the invention to provide be to overcome the shortcoming of prior art to have there is provided one kind There are the aqueous basement membrane of excellent consolidation effect, alkaline resistance properties, the multiple-effect of antimycotic antiseptic performance and excellent environmental-protecting performance and its system Preparation Method.
To realize above-mentioned technical purpose, the technical solution adopted by the present invention is as follows:A kind of aqueous basement membrane of multiple-effect of the present invention, It is characterized in that including following components by weight:
Further, the water-based emulsion is anionic emulsion of the styrene-acrylic emulsion through epoxy resin modification copolymerization, warp Vacuumize process is crossed, particle diameter is less than 30nm, and MFT is not higher than 3 DEG C.
Further, the defoamer is any one in polysiloxane-polyether copolymer type of latex type or mineral oils.
Further, the coalescents are propane diols list grease.
Further, the pH adjusting agent is 2-amino-2-methyl-1-propanol.
Further, the thickener is solvent-free class polyurethane thickener.
Further, the mould inhibitor is benzimidazole methyl carbamate and N '-(3,4- dichlorophenyl)-N, N- diformazans Base urea is compounded, and compound proportion is 1:1.5.
Further, the bactericide is silver ion disinfectant.
The preparation method of the aqueous basement membrane of multiple-effect of the present invention, comprises the following steps:
(1) the accurate each component weighed in claim 1, add in a reservoir deionized water, water-based emulsion, defoamer, Coalescents, pH adjusting agent, mould inhibitor and bactericide, mixing time are 3-5min;
(2) viscosity is adjusted to 4 glasss of viscosity 30-50s are applied with thickener, the aqueous basement membrane of multiple-effect is made.
Beneficial effect:Bio-toxicity of the present invention is low, and adhesive force is strong, and drying time is short, with good consolidation effect, salt tolerant Alkaline energy, antimycotic antiseptic effect and environmental-protecting performance, greatly improve the service life of wallpaper and the safety coefficient of basement membrane.
Compared with prior art, the invention has the advantages that:
(1) excellent environmental-protecting performance, the present invention is screened by strict material, from higher boiling coalescents, causes this The environmental-protecting performance of invention is heightened significantly.
(2) from unique water-based emulsion, anionic emulsion of the styrene-acrylic emulsion through epoxy resin modification copolymerization passes through Vacuumize process, particle diameter is less than 30nm, 3 DEG C of MFT;Processed emulsion can be good at penetrating into greasy Sublayer, there is good reinforcement effect to putty layer, improves the cohesive force of wallpaper and putty layer.
Embodiment
The present invention is further illustrated by the following examples.It should be understood that these embodiments are the explainations of the present invention And citing, the scope of the present invention is not limited in any form.
Embodiment 1
A kind of aqueous basement membrane of multiple-effect of the present invention, including following components by weight:
The water-based emulsion is anionic emulsion of the styrene-acrylic emulsion through epoxy resin modification copolymerization, by vacuumizing place Reason, particle diameter is less than 30nm, 3 DEG C of MFT.
The defoamer is polysiloxane-polyether copolymer type of latex type.
The coalescents are propane diols list grease.
The pH adjusting agent is 2-amino-2-methyl-1-propanol.
The thickener is solvent-free class polyurethane thickener.
The mould inhibitor is benzimidazole methyl carbamate and N '-(3,4- dichlorophenyl)-N, and N- dimethyl ureas are compounded, Compound proportion is 1:1.5.
The bactericide is silver ion disinfectant.
The preparation method of the aqueous basement membrane of multiple-effect of the present invention, comprises the following steps:
(1) each component is accurately weighed, deionized water, water-based emulsion, defoamer, coalescents, pH are added in a reservoir and is adjusted Agent, mould inhibitor and bactericide are saved, mixing time is 5min;
(2) viscosity is adjusted to 50s (applying 4 glasss), the obtained aqueous basement membrane of multiple-effect with thickener.
Embodiment 2
The difference of embodiment 2 and embodiment 1 is:A kind of aqueous basement membrane of multiple-effect of the present invention, including by weight Following components:
The water-based emulsion is anionic emulsion of the styrene-acrylic emulsion through epoxy resin modification copolymerization, by vacuumizing place Reason, particle diameter is less than 30nm, 3 DEG C of MFT.
The defoamer is polysiloxane-polyether copolymer type of latex type.
The coalescents are propane diols list grease.
The pH adjusting agent is 2-amino-2-methyl-1-propanol.
The thickener is solvent-free class polyurethane thickener.
The mould inhibitor is benzimidazole methyl carbamate and N '-(3,4- dichlorophenyl)-N, N- dimethyl ureas compounding.
The bactericide is silver ion disinfectant.
The preparation method of the aqueous basement membrane of multiple-effect of the present invention, comprises the following steps:
(1) it is accurate weigh in each component, add in a reservoir deionized water, water-based emulsion, defoamer, coalescents, PH adjusting agent, mould inhibitor and bactericide, mixing time are 3min;
(2) viscosity is adjusted to 40s (applying 4 glasss), the obtained aqueous basement membrane of multiple-effect with thickener.
Embodiment 3
The difference of embodiment 3 and embodiment 1 is:A kind of aqueous basement membrane of multiple-effect of the present invention, including by weight Following components:
The water-based emulsion is anionic emulsion of the styrene-acrylic emulsion through epoxy resin modification copolymerization, by vacuumizing place Reason, particle diameter is less than 30nm, 3 DEG C of MFT.
The defoamer is mineral oils.
The coalescents are propane diols list grease.
The pH adjusting agent is 2-amino-2-methyl-1-propanol.
The thickener is solvent-free class polyurethane thickener.
The mould inhibitor is benzimidazole methyl carbamate and N '-(3,4- dichlorophenyl)-N, N- dimethyl ureas compounding.
The bactericide is silver ion disinfectant.
The preparation method of the aqueous basement membrane of multiple-effect of the present invention, comprises the following steps:
(1) each component is accurately weighed, deionized water, water-based emulsion, defoamer, coalescents, pH are added in a reservoir and is adjusted Agent, mould inhibitor and bactericide are saved, mixing time is 4min;
(2) viscosity is adjusted to 30s (applying 4 glasss), the obtained aqueous basement membrane of multiple-effect with thickener.
Experiment 1
In addition, the present invention can be detected for the aqueous basement membrane progressive of multiple-effect made by above-described embodiment, the items measured Technical indicator is shown in Table 1:
Table 1
It can be seen from Table 1 that, the present invention has excellent adhesive force, efficient antifungi and bacterium performance and excellent Environmental-protecting performance, be it is a for wallpaper paste the aqueous basement membrane of multiple-effect.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, the present invention Claimed scope is by appended claims, specification and its equivalent thereof.

Claims (9)

1. a kind of aqueous basement membrane of multiple-effect, it is characterised in that including following components by weight:
2. the aqueous basement membrane of multiple-effect according to claim 1, it is characterised in that:The water-based emulsion is styrene-acrylic emulsion through epoxy The anionic emulsion of resin modified copolymerization, by vacuumize process, particle diameter is less than 30nm, and MFT is not higher than 3 ℃。
3. the aqueous basement membrane of multiple-effect according to claim 1, it is characterised in that:The defoamer is common for polysiloxane-polyether Any one in copolymer emulsion class or mineral oils.
4. the aqueous basement membrane of multiple-effect according to claim 1, it is characterised in that:The coalescents are propane diols list grease.
5. the aqueous basement membrane of multiple-effect according to claim 1, it is characterised in that:The pH adjusting agent be 2- amino-2-methyls- 1- propyl alcohol.
6. the aqueous basement membrane of multiple-effect according to claim 1, it is characterised in that:The thickener is solvent-free class polyurethane Thick dose.
7. the aqueous basement membrane of multiple-effect according to claim 1, it is characterised in that:The mould inhibitor is benzimidazole carbamic acid Methyl esters and N '-(3,4- dichlorophenyl)-N, N- dimethyl ureas compounding, compound proportion is 1:1.5.
8. the aqueous basement membrane of multiple-effect according to claim 1, it is characterised in that:The bactericide is silver ion disinfectant.
9. the preparation method of the aqueous basement membrane of multiple-effect described in claim any one of 1-8, it is characterised in that comprise the following steps:
(1) the accurate each component weighed in claim 1, adds deionized water, water-based emulsion, defoamer, film forming in a reservoir Auxiliary agent, pH adjusting agent, mould inhibitor and bactericide, mixing time are 3-5min;
(2) viscosity is adjusted to 4 glasss of viscosity 30-50s are applied with thickener, the aqueous basement membrane of multiple-effect is made.
CN201710478235.5A 2017-06-21 2017-06-21 A kind of aqueous basement membrane of multiple-effect and preparation method thereof Pending CN107325722A (en)

Priority Applications (1)

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CN201710478235.5A CN107325722A (en) 2017-06-21 2017-06-21 A kind of aqueous basement membrane of multiple-effect and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710478235.5A CN107325722A (en) 2017-06-21 2017-06-21 A kind of aqueous basement membrane of multiple-effect and preparation method thereof

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CN107325722A true CN107325722A (en) 2017-11-07

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109943120A (en) * 2019-03-18 2019-06-28 浙江吴越人家新材料股份有限公司 A kind of wall paper basement membrane and its preparation process
CN111363419A (en) * 2020-05-08 2020-07-03 北京硅宝纳米活性硅材料有限公司 Multifunctional air purification emulsion paint

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105295635A (en) * 2015-11-30 2016-02-03 桂林市和鑫防水装饰材料有限公司 Epoxy-modified styrene-acrylate emulsion paint and preparation method thereof
CN105623461A (en) * 2014-11-04 2016-06-01 江苏冠军涂料科技集团有限公司 Waterborne epoxy decorative finish board waterproof coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105623461A (en) * 2014-11-04 2016-06-01 江苏冠军涂料科技集团有限公司 Waterborne epoxy decorative finish board waterproof coating
CN105295635A (en) * 2015-11-30 2016-02-03 桂林市和鑫防水装饰材料有限公司 Epoxy-modified styrene-acrylate emulsion paint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109943120A (en) * 2019-03-18 2019-06-28 浙江吴越人家新材料股份有限公司 A kind of wall paper basement membrane and its preparation process
CN111363419A (en) * 2020-05-08 2020-07-03 北京硅宝纳米活性硅材料有限公司 Multifunctional air purification emulsion paint

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Application publication date: 20171107

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