CN107325505A - A kind of antistatic textile material added with natural fiber and preparation method thereof - Google Patents
A kind of antistatic textile material added with natural fiber and preparation method thereof Download PDFInfo
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- CN107325505A CN107325505A CN201710531372.0A CN201710531372A CN107325505A CN 107325505 A CN107325505 A CN 107325505A CN 201710531372 A CN201710531372 A CN 201710531372A CN 107325505 A CN107325505 A CN 107325505A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of antistatic textile material added with natural fiber and preparation method thereof, it is made from the following raw materials in parts by weight：17 25 parts of acid fiber by polylactic, 12 22 parts of chitin, 15 25 parts of silk fiber, 12 18 parts of cocoanut fiber, 10 16 parts of soybean fiber, 5 15 parts of milk protein fiber, 8 15 parts of bamboo fiber, 4 10 parts of sisal hemp, 26 parts of polyvinyl butyral resin, 25 parts of PET, 7 12 parts of diglycidyl ether, 69 parts of sucrose stearate, 13 parts of silicone grease ethyl ester, 47 parts of sorbierite, 5 10 parts of sodium alginate, 38 parts of tannic acid, 8 10 parts of methyl valerolactone, 37 parts of stearate, 14 parts of metasilicic acid trimethyl, just own 13 parts of the ester of acetyl citrate three, 35 parts of lutidines, 12 parts of zinc ricinate, 12 parts of barium metaborate, 25 parts of adhesive, 25 parts of dispersant, 14 parts of heat stabilizer.The antistatic textile material added with natural fiber being prepared from, its antistatic property is good, and natural environmental-protective is non-stimulated.Meanwhile, also disclose the preparation method of this antistatic textile material added with natural fiber.
Description
Technical field
The present invention relates to textile material field, be related specifically to a kind of antistatic textile material added with natural fiber and
Its preparation method.
Background technology
Natural fiber is primarily referred to as the fibre composition extracted from natural animal and plant.Natural fiber has good moisture absorption
Gas permeability, reactivity, biocompatibility, biodegradability, no antigen, without cause inflammatory, without deleterious breakdown product, absorption
Property, cohesive, antibiotic property and security etc., so as to be widely used in textile industry.Textile fabric is divided into natural fiber and change
Learn two kinds of fiber.What is obtained from plant belongs to natural fiber, such as flax, cotton yarn, rope made of hemp etc.；What is obtained from animal is also day
Right fiber, such as：Wool and silk.The species of chemical fibre is a lot, such as nylon, staple fibre, glass fibre etc., wherein,
Chemical fibre includes regenerated fiber, synthetic fibers and inorfil.Natural fiber has that higher intensity, cost be low, density is low
The characteristics of, and regularity it is good when, the intensity of yarn is high, uniform, any surface finish, filoplume are few, and therefore, spinning property is good.With section
Continuing to develop for research is learned, the composite being made of natural fiber and high polymer material has been successfully applied to each field.This
Invention make it that not only firm and durable, performance stablize same to the textile material developed using novel technological means and combination of materials
When there is anlistatig characteristic, it is adaptable to many fields.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of antistatic textile material and its system added with natural fiber
Preparation Method, is combined by using specified raw material, coordinates corresponding production technology, and what is obtained is anti-quiet added with natural fiber
Electric textile material, its antistatic property is good, and natural environmental-protective is non-stimulated, disclosure satisfy that the requirement of industry, before preferable application
Scape.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of antistatic textile material added with natural fiber, is made from the following raw materials in parts by weight：Acid fiber by polylactic 17-25
Part, 12-22 parts of chitin, 15-25 parts of silk fiber, 12-18 parts of cocoanut fiber, 10-16 parts of soybean fiber, milk protein are fine
5-15 parts of dimension, 8-15 parts of bamboo fiber, 4-10 parts of sisal hemp, 2-6 parts of polyvinyl butyral resin, PET 2-5
Part, 7-12 parts of diglycidyl ether, 6-9 parts of sucrose stearate, 1-3 parts of silicone grease ethyl ester, 4-7 parts of sorbierite, sodium alginate 5-
10 parts, 3-8 parts of tannic acid, 8-10 parts of methyl valerolactone, 3-7 parts of stearate, 1-4 parts of metasilicic acid trimethyl, acetyl group lemon
Acid is three just own ester 1-3 part, 3-5 parts of lutidines, 1-2 parts of zinc ricinate, 1-2 parts of barium metaborate, 2-5 parts of adhesive, divide
2-5 parts of powder, 1-4 parts of heat stabilizer.
Preferably, adhesive is selected from triphenyl phosphite, 5-sulphosalicylic acid dihydrate, trisodium citrate monocalcium salt and closed
One or more in thing and dibutyl phthalate.
Preferably, described dispersant is selected from taurate, aminoguanidine sulfonate, lignosulfonates and vinyl
One or more in sulfonate.
Preferably, described heat stabilizer be selected from certain herbaceous plants with big flowers acid glycerol three ester, iodine propilolic alcohol butyl mephenesin Carbamate, maleate and
One or more in orange osmanthus acid esters.
The preparation method of the described antistatic textile material added with natural fiber, comprises the following steps：
（1）Each raw material is weighed according to parts by weight；
（2）By acid fiber by polylactic, chitin, silk fiber, cocoanut fiber, soybean fiber, milk protein fiber, bamboo fiber,
Sisal hemp, polyvinyl butyral resin, PET, diglycidyl ether, sucrose stearate, silicone grease ethyl ester, mountain
Pears alcohol, dispersant add reactor, stir and evenly mix, and are heated to 130-160 DEG C, stirring insulation 30 minutes, mixing speed 500-600
Rev/min；
（3）By step（2）In reactant be cooled to room temperature, add sodium alginate, tannic acid, methyl valerolactone, stearate,
The just own ester of metasilicic acid trimethyl, acetyl citrate three, heat stabilizer, are again heated to 110-125 DEG C, stirring insulation 20-30
Minute, 500-600 revs/min of mixing speed；
（4）To step（3）Mixture injection high-temperature vapor, continue be incubated 60 minutes；
（5）By step（4）Mixture and lutidines, zinc ricinate, barium metaborate, adhesive injection reactor in it is high
Homogenizer is pressed, is mixed, mixing speed is 500-600 revs/min, pressure is adjusted to 15-20MPa, the reaction time is 60 points
Clock, reaction temperature is 105 DEG C；
（6）By step（5）In reactant as spinning under inert gas environment, handled by drawing, deaerate drying, be cooled to
Room temperature is got product.
Preferably, the inert gas is argon gas.
Preferably, the spinning speed is 2000-2500m/min.
Preferably, the drying temperature is 60-75 DEG C, drying time 2-3 hours.
Compared with prior art, its advantage is the present invention：
（1）The antistatic textile material added with natural fiber of the present invention, with acid fiber by polylactic, chitin, silk fiber, coconut palm
Subbundle, soybean fiber, milk protein fiber, bamboo fiber, sisal hemp, polyvinyl butyral resin, PET,
Diglycidyl ether, sucrose stearate, silicone grease ethyl ester, sorbierite be main component, by add sodium alginate, tannic acid,
The just own ester of methyl valerolactone, stearate, metasilicic acid trimethyl, acetyl citrate three, lutidines, zinc ricinate,
Barium metaborate, adhesive, heat stabilizer, dispersant, are aided with heating response, uniform stirring, steam activation, pressurized dispersion, drawing
The techniques such as spinning, degassing drying so that the antistatic textile material added with natural fiber being prepared from, its antistatic property
Good, natural environmental-protective is non-stimulated, disclosure satisfy that the requirement of industry, with preferable application prospect.
（2）Antistatic textile material raw material added with natural fiber of the invention is cheap, technique is simple, suitable for extensive
Industrialization is used, practical.
Embodiment
The technical scheme of invention is described in detail with reference to specific embodiment.
Embodiment 1
（1）17 parts of acid fiber by polylactic, 12 parts of chitin, 15 parts of silk fiber, 12 parts of cocoanut fiber, soybean are weighed according to parts by weight
10 parts of fiber, 5 parts of milk protein fiber, 8 parts of bamboo fiber, 4 parts of sisal hemp, 2 parts of polyvinyl butyral resin, poly terephthalic acid second
2 parts of diester, 7 parts of diglycidyl ether, 6 parts of sucrose stearate, 1 part of silicone grease ethyl ester, 4 parts of sorbierite, 5 parts of sodium alginate, list
Peaceful 3 parts of acid, 8 parts of methyl valerolactone, 3 parts of stearate, 1 part of metasilicic acid trimethyl, just own 1 part of the ester of acetyl citrate three, two
3 parts of picoline, 1 part of zinc ricinate, 1 part of barium metaborate, 2 parts of triphenyl phosphite, 2 parts of taurate, certain herbaceous plants with big flowers acid glycerol three
1 part of ester；
（2）By acid fiber by polylactic, chitin, silk fiber, cocoanut fiber, soybean fiber, milk protein fiber, bamboo fiber,
Sisal hemp, polyvinyl butyral resin, PET, diglycidyl ether, sucrose stearate, silicone grease ethyl ester, mountain
Pears alcohol, taurate add reactor, stir and evenly mix, and are heated to 130 DEG C, stirring insulation 30 minutes, 500 revs/min of mixing speed
Clock；
（3）By step（2）In reactant be cooled to room temperature, add sodium alginate, tannic acid, methyl valerolactone, stearate,
The just own ester of metasilicic acid trimethyl, acetyl citrate three, certain herbaceous plants with big flowers acid glycerol three ester, are again heated to 110 DEG C, 20 points of stirring insulation
Clock, 500 revs/min of mixing speed；
（4）To step（3）Mixture injection high-temperature vapor, continue be incubated 60 minutes；
（5）By step（4）Mixture and lutidines, zinc ricinate, barium metaborate, triphenyl phosphite injection reaction
Kettle mesohigh homogenizer, is mixed, and mixing speed is 500 revs/min, and pressure is adjusted to 15MPa, and the reaction time is 60 points
Clock, reaction temperature is 105 DEG C；
（6）By step（5）In reactant as spinning under ar gas environment, handled by drawing, deaerate drying, be cooled to room temperature
Get product, spinning speed is 2000m/min, drying temperature is 60 DEG C, drying time 2 hours.
The performance test results of the obtained antistatic textile material added with natural fiber are as shown in table 1.
Embodiment 2
（1）19 parts of acid fiber by polylactic, 16 parts of chitin, 17 parts of silk fiber, 14 parts of cocoanut fiber, soybean are weighed according to parts by weight
12 parts of fiber, 7 parts of milk protein fiber, 10 parts of bamboo fiber, 6 parts of sisal hemp, 3 parts of polyvinyl butyral resin, poly terephthalic acid
3 parts of second diester, 9 parts of diglycidyl ether, 7 parts of sucrose stearate, 1 part of silicone grease ethyl ester, 5 parts of sorbierite, 7 parts of sodium alginate,
Just own 2 parts of the ester of 4 parts of tannic acid, 9 parts of methyl valerolactone, 4 parts of stearate, 2 parts of metasilicic acid trimethyl, acetyl citrate three,
3 parts of lutidines, 1 part of zinc ricinate, 2 parts of barium metaborate, 3 parts of 5-sulphosalicylic acid dihydrate, aminoguanidine sulfonate
3 parts, 2 parts of iodine propilolic alcohol butyl mephenesin Carbamate；
（2）By acid fiber by polylactic, chitin, silk fiber, cocoanut fiber, soybean fiber, milk protein fiber, bamboo fiber,
Sisal hemp, polyvinyl butyral resin, PET, diglycidyl ether, sucrose stearate, silicone grease ethyl ester, mountain
Pears alcohol, aminoguanidine sulfonate add reactor, stir and evenly mix, and are heated to 140 DEG C, stirring insulation 30 minutes, mixing speed 520
Rev/min；
（3）By step（2）In reactant be cooled to room temperature, add sodium alginate, tannic acid, methyl valerolactone, stearate,
The just own ester of metasilicic acid trimethyl, acetyl citrate three, iodine propilolic alcohol butyl mephenesin Carbamate, are again heated to 115 DEG C, stirring is protected
Temperature 22 minutes, 520 revs/min of mixing speed；
（4）To step（3）Mixture injection high-temperature vapor, continue be incubated 60 minutes；
（5）By step（4）Mixture and lutidines, zinc ricinate, barium metaborate, 5-sulphosalicylic acid dihydrate
Reactor mesohigh homogenizer is injected, is mixed, mixing speed is 520 revs/min, and pressure is adjusted to 16MPa, reaction time
For 60 minutes, reaction temperature was 105 DEG C；
（6）By step（5）In reactant as spinning under ar gas environment, handled by drawing, deaerate drying, be cooled to room temperature
Get product, spinning speed is 2100m/min, drying temperature is 65 DEG C, drying time 2.3 hours.
The performance test results of the obtained antistatic textile material added with natural fiber are as shown in table 1.
Embodiment 3
（1）21 parts of acid fiber by polylactic, 20 parts of chitin, 23 parts of silk fiber, 17 parts of cocoanut fiber, soybean are weighed according to parts by weight
15 parts of fiber, 13 parts of milk protein fiber, 12 parts of bamboo fiber, 8 parts of sisal hemp, 5 parts of polyvinyl butyral resin, poly terephthalic acid
4 parts of second diester, 10 parts of diglycidyl ether, 8 parts of sucrose stearate, 2 parts of silicone grease ethyl ester, 6 parts of sorbierite, 9 parts of sodium alginate,
Just own 2 parts of the ester of 7 parts of tannic acid, 9 parts of methyl valerolactone, 6 parts of stearate, 3 parts of metasilicic acid trimethyl, acetyl citrate three,
4 parts of lutidines, 2 parts of zinc ricinate, 2 parts of barium metaborate, 4 parts of trisodium citrate monocalcium salt compound, lignosulfonates 4
Part, 3 parts of maleate；
（2）By acid fiber by polylactic, chitin, silk fiber, cocoanut fiber, soybean fiber, milk protein fiber, bamboo fiber,
Sisal hemp, polyvinyl butyral resin, PET, diglycidyl ether, sucrose stearate, silicone grease ethyl ester, mountain
Pears alcohol, lignosulfonates add reactor, stir and evenly mix, and are heated to 150 DEG C, stirring insulation 30 minutes, mixing speed 550
Rev/min；
（3）By step（2）In reactant be cooled to room temperature, add sodium alginate, tannic acid, methyl valerolactone, stearate,
The just own ester of metasilicic acid trimethyl, acetyl citrate three, maleate, are again heated to 120 DEG C, stirring insulation 28 minutes is stirred
Mix 550 revs/min of speed；
（4）To step（3）Mixture injection high-temperature vapor, continue be incubated 60 minutes；
（5）By step（4）Mixture and lutidines, zinc ricinate, barium metaborate, trisodium citrate monocalcium salt compound
Reactor mesohigh homogenizer is injected, is mixed, mixing speed is 550 revs/min, and pressure is adjusted to 18MPa, reaction time
For 60 minutes, reaction temperature was 105 DEG C；
（6）By step（5）In reactant as spinning under ar gas environment, handled by drawing, deaerate drying, be cooled to room temperature
Get product, spinning speed is 2300m/min, drying temperature is 70 DEG C, drying time 2.5 hours.
The performance test results of the obtained antistatic textile material added with natural fiber are as shown in table 1.
Embodiment 4
（1）Weigh 25 parts of acid fiber by polylactic according to parts by weight, it is 22 parts of chitin, 25 parts of silk fiber, 18 parts of cocoanut fiber, big
It is 16 parts of beans fiber, 15 parts of milk protein fiber, 15 parts of bamboo fiber, 10 parts of sisal hemp, 6 parts of polyvinyl butyral resin, poly- to benzene two
5 parts of formic acid second diester, 12 parts of diglycidyl ether, 9 parts of sucrose stearate, 3 parts of silicone grease ethyl ester, 7 parts of sorbierite, sodium alginate
10 parts, 8 parts of tannic acid, 10 parts of methyl valerolactone, 7 parts of stearate, 4 parts of metasilicic acid trimethyl, acetyl citrate three just oneself
3 parts of ester, 5 parts of lutidines, 2 parts of zinc ricinate, 2 parts of barium metaborate, 5 parts of dibutyl phthalate, vinyl sulfonic acid
5 parts of salt, 4 parts of orange osmanthus acid esters；
（2）By acid fiber by polylactic, chitin, silk fiber, cocoanut fiber, soybean fiber, milk protein fiber, bamboo fiber,
Sisal hemp, polyvinyl butyral resin, PET, diglycidyl ether, sucrose stearate, silicone grease ethyl ester, mountain
Pears alcohol, vinylsulfonate add reactor, stir and evenly mix, and are heated to 160 DEG C, stirring insulation 30 minutes, mixing speed 600
Rev/min；
（3）By step（2）In reactant be cooled to room temperature, add sodium alginate, tannic acid, methyl valerolactone, stearate,
The just own ester of metasilicic acid trimethyl, acetyl citrate three, orange osmanthus acid esters, are again heated to 125 DEG C, stirring insulation 30 minutes is stirred
Mix 600 revs/min of speed；
（4）To step（3）Mixture injection high-temperature vapor, continue be incubated 60 minutes；
（5）By step（4）Mixture and lutidines, zinc ricinate, barium metaborate, dibutyl phthalate injection
Reactor mesohigh homogenizer, is mixed, and mixing speed is 600 revs/min, and pressure is adjusted to 20MPa, and the reaction time is 60
Minute, reaction temperature is 105 DEG C；
（6）By step（5）In reactant as spinning under ar gas environment, handled by drawing, deaerate drying, be cooled to room temperature
Get product, spinning speed is 2500m/min, drying temperature is 75 DEG C, drying time 3 hours.
The performance test results of the obtained antistatic textile material added with natural fiber are as shown in table 1.
Comparative example 1
（1）17 parts of acid fiber by polylactic, 12 parts of chitin, 15 parts of silk fiber, 12 parts of cocoanut fiber, soybean are weighed according to parts by weight
10 parts of fiber, 8 parts of bamboo fiber, 4 parts of sisal hemp, 2 parts of polyvinyl butyral resin, 2 parts of PET, sucrose are stearic
6 parts of acid esters, 1 part of silicone grease ethyl ester, 4 parts of sorbierite, 5 parts of sodium alginate, 3 parts of tannic acid, 8 parts of methyl valerolactone, stearate 3
Part, just own 1 part of the ester of 1 part of metasilicic acid trimethyl, acetyl citrate three, 3 parts of lutidines, 1 part of zinc ricinate, metaboric acid
1 part of barium, 2 parts of triphenyl phosphite, 2 parts of taurate, 1 part of certain herbaceous plants with big flowers acid glycerol three ester；
（2）By acid fiber by polylactic, chitin, silk fiber, cocoanut fiber, soybean fiber, bamboo fiber, sisal hemp, polyvinyl alcohol
Butyral, PET, sucrose stearate, silicone grease ethyl ester, sorbierite, taurate add reactor, stir
Mixing is mixed, 130 DEG C, stirring insulation 30 minutes, 500 revs/min of mixing speed are heated to；
（3）By step（2）In reactant be cooled to room temperature, add sodium alginate, tannic acid, methyl valerolactone, stearate,
The just own ester of metasilicic acid trimethyl, acetyl citrate three, certain herbaceous plants with big flowers acid glycerol three ester, are again heated to 110 DEG C, 20 points of stirring insulation
Clock, 500 revs/min of mixing speed；
（4）To step（3）Mixture injection high-temperature vapor, continue be incubated 60 minutes；
（5）By step（4）Mixture and lutidines, zinc ricinate, barium metaborate, triphenyl phosphite injection reaction
Kettle mesohigh homogenizer, is mixed, and mixing speed is 500 revs/min, and pressure is adjusted to 15MPa, and the reaction time is 60 points
Clock, reaction temperature is 105 DEG C；
（6）By step（5）In reactant as spinning under ar gas environment, handled by drawing, deaerate drying, be cooled to room temperature
Get product, spinning speed is 2000m/min, drying temperature is 60 DEG C, drying time 2 hours.
The performance test results of the obtained antistatic textile material added with natural fiber are as shown in table 1.
Comparative example 2
（1）25 parts of acid fiber by polylactic, 22 parts of chitin, 25 parts of silk fiber, 16 parts of soybean fiber, milk are weighed according to parts by weight
15 parts of azelon, 15 parts of bamboo fiber, 10 parts of sisal hemp, 5 parts of PET, 12 parts of diglycidyl ether, sugarcane
Sugared 9 parts of stearate, 3 parts of silicone grease ethyl ester, 7 parts of sorbierite, 10 parts of sodium alginate, 8 parts of tannic acid, 10 parts of methyl valerolactone, partially
Just own 3 parts of the ester of 4 parts of silicic acid trimethyl, acetyl citrate three, 5 parts of lutidines, 2 parts of zinc ricinate, barium metaborate 2
Part, 5 parts of dibutyl phthalate, 5 parts of vinylsulfonate, 4 parts of orange osmanthus acid esters；
（2）By acid fiber by polylactic, chitin, silk fiber, soybean fiber, milk protein fiber, bamboo fiber, sisal hemp, poly- pair
Polyethylene terephthalate, diglycidyl ether, sucrose stearate, silicone grease ethyl ester, sorbierite, vinylsulfonate add reaction
Kettle, is stirred and evenly mixed, and is heated to 160 DEG C, stirring insulation 30 minutes, 600 revs/min of mixing speed；
（3）By step（2）In reactant be cooled to room temperature, add sodium alginate, tannic acid, methyl valerolactone, metasilicic acid three
The just own ester of methyl esters, acetyl citrate three, orange osmanthus acid esters, are again heated to 125 DEG C, stirring insulation 30 minutes, mixing speed 600
Rev/min；
（4）To step（3）Mixture injection high-temperature vapor, continue be incubated 60 minutes；
（5）By step（4）Mixture and lutidines, zinc ricinate, barium metaborate, dibutyl phthalate injection
Reactor mesohigh homogenizer, is mixed, and mixing speed is 600 revs/min, and pressure is adjusted to 20MPa, and the reaction time is 60
Minute, reaction temperature is 105 DEG C；
（6）By step（5）In reactant as spinning under ar gas environment, handled by drawing, deaerate drying, be cooled to room temperature
Get product, spinning speed is 2500m/min, drying temperature is 75 DEG C, drying time 3 hours.
The performance test results of the obtained antistatic textile material added with natural fiber are as shown in table 1.
Antistatic textile material added with natural fiber made from embodiment 1-4 and comparative example 1-2 is subjected to tension
Intensity, tearing toughness, this several performance tests of point-to-point resistance.
Table 1
The antistatic textile material added with natural fiber of the present invention, with acid fiber by polylactic, chitin, silk fiber, coconut
Fiber, soybean fiber, milk protein fiber, bamboo fiber, sisal hemp, polyvinyl butyral resin, PET, two
Glycidol ether, sucrose stearate, silicone grease ethyl ester, sorbierite are main component, by adding sodium alginate, tannic acid, first
The just own ester of base valerolactone, stearate, metasilicic acid trimethyl, acetyl citrate three, lutidines, zinc ricinate, partially
Barium borate, adhesive, heat stabilizer, dispersant, are aided with heating response, uniform stirring, steam activation, pressurized dispersion, drawing spinning
The techniques such as silk, degassing drying so that the antistatic textile material added with natural fiber being prepared from, its antistatic property
Good, natural environmental-protective is non-stimulated, disclosure satisfy that the requirement of industry, with preferable application prospect.Being added with for the present invention is natural fine
Dimension antistatic textile material raw material is cheap, technique simple, used suitable for heavy industrialization, it is practical.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (8)
1. a kind of antistatic textile material added with natural fiber, it is characterised in that：It is made from the following raw materials in parts by weight：It is poly-
17-25 parts of acid fiber, 12-22 parts of chitin, 15-25 parts of silk fiber, 12-18 parts of cocoanut fiber, soybean fiber 10-16
It is part, 5-15 parts of milk protein fiber, 8-15 parts of bamboo fiber, 4-10 parts of sisal hemp, 2-6 parts of polyvinyl butyral resin, poly- to benzene two
2-5 parts of formic acid second diester, 7-12 parts of diglycidyl ether, 6-9 parts of sucrose stearate, 1-3 parts of silicone grease ethyl ester, sorbierite 4-7
Part, 5-10 parts of sodium alginate, 3-8 parts of tannic acid, 8-10 parts of methyl valerolactone, 3-7 parts of stearate, metasilicic acid trimethyl 1-4
Part, just own ester 1-3 parts acetyl citrate three, 3-5 parts of lutidines, 1-2 parts of zinc ricinate, 1-2 parts of barium metaborate,
2-5 parts of adhesive, 2-5 parts of dispersant, 1-4 parts of heat stabilizer.
2. the antistatic textile material according to claim 1 added with natural fiber, it is characterised in that：The adhesive
Selected from triphenyl phosphite, 5-sulphosalicylic acid dihydrate, trisodium citrate monocalcium salt compound and dibutyl phthalate
In one or more.
3. the antistatic textile material according to claim 1 added with natural fiber, it is characterised in that：Described
One or more of the dispersant in taurate, aminoguanidine sulfonate, lignosulfonates and vinylsulfonate.
4. the antistatic textile material according to claim 1 added with natural fiber, it is characterised in that：Described heat is steady
Determine one or more of the agent in certain herbaceous plants with big flowers acid glycerol three ester, iodine propilolic alcohol butyl mephenesin Carbamate, maleate and orange osmanthus acid esters.
5. according to the preparation method of any described antistatic textile material added with natural fiber of Claims 1 to 4, it is special
Levy and be, comprise the following steps：
（1）Each raw material is weighed according to parts by weight；
（2）By acid fiber by polylactic, chitin, silk fiber, cocoanut fiber, soybean fiber, milk protein fiber, bamboo fiber,
Sisal hemp, polyvinyl butyral resin, PET, diglycidyl ether, sucrose stearate, silicone grease ethyl ester, mountain
Pears alcohol, dispersant add reactor, stir and evenly mix, and are heated to 130-160 DEG C, stirring insulation 30 minutes, mixing speed 500-600
Rev/min；
（3）By step（2）In reactant be cooled to room temperature, add sodium alginate, tannic acid, methyl valerolactone, stearate,
The just own ester of metasilicic acid trimethyl, acetyl citrate three, heat stabilizer, are again heated to 110-125 DEG C, stirring insulation 20-30
Minute, 500-600 revs/min of mixing speed；
（4）To step（3）Mixture injection high-temperature vapor, continue be incubated 60 minutes；
（5）By step（4）Mixture and lutidines, zinc ricinate, barium metaborate, adhesive injection reactor in it is high
Homogenizer is pressed, is mixed, mixing speed is 500-600 revs/min, pressure is adjusted to 15-20MPa, the reaction time is 60 points
Clock, reaction temperature is 105 DEG C；
（6）By step（5）In reactant as spinning under inert gas environment, handled by drawing, deaerate drying, be cooled to
Room temperature is got product.
6. the preparation method of the antistatic textile material according to claim 5 added with natural fiber, it is characterised in that：
Step（6）The inert gas is argon gas.
7. the preparation method of the antistatic textile material according to claim 5 added with natural fiber, it is characterised in that：
Step（6）The spinning speed is 2000-2500m/min.
8. the preparation method of the antistatic textile material according to claim 5 added with natural fiber, it is characterised in that：
Step（6）The drying temperature is 60-75 DEG C, drying time 2-3 hours.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108193312A (en) * | 2017-12-29 | 2018-06-22 | 付主枝 | A kind of preparation method and applications of composite fibre textile material |
| CN108286126A (en) * | 2018-01-24 | 2018-07-17 | 上海理工大学 | A kind of preparation method of quick-acting haemostatic powder composite cellulosic membrane |
| CN108360116A (en) * | 2018-02-26 | 2018-08-03 | 合肥远科服装设计有限公司 | A kind of preparation method of textile material |
| CN108754862A (en) * | 2018-06-01 | 2018-11-06 | 吴江康欣医用敷料有限公司 | The preparation method of waterproof and breathable dressing non-woven fabrics |
| CN108755281A (en) * | 2018-06-01 | 2018-11-06 | 吴江康欣医用敷料有限公司 | The preparation method of bacteriostatic non-woven cloth containing organic filler |
| CN111020872A (en) * | 2019-11-29 | 2020-04-17 | 吉祥三宝高科纺织有限公司 | Process for preparing nanofiber-based waterproof moisture-permeable membrane material by utilizing electrostatic spinning technology |
| CN111214058A (en) * | 2020-01-09 | 2020-06-02 | 江西省优典实业有限公司 | Latex pillow for infants |
| CN111592767A (en) * | 2020-06-16 | 2020-08-28 | 浦江环彩纺织有限公司 | Novel health-care material and preparation method thereof |
| CN114921858A (en) * | 2022-06-08 | 2022-08-19 | 江门职业技术学院 | Antistatic textile material added with natural fibers, preparation method and device |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108193312A (en) * | 2017-12-29 | 2018-06-22 | 付主枝 | A kind of preparation method and applications of composite fibre textile material |
| CN108286126A (en) * | 2018-01-24 | 2018-07-17 | 上海理工大学 | A kind of preparation method of quick-acting haemostatic powder composite cellulosic membrane |
| CN108360116A (en) * | 2018-02-26 | 2018-08-03 | 合肥远科服装设计有限公司 | A kind of preparation method of textile material |
| CN108754862A (en) * | 2018-06-01 | 2018-11-06 | 吴江康欣医用敷料有限公司 | The preparation method of waterproof and breathable dressing non-woven fabrics |
| CN108755281A (en) * | 2018-06-01 | 2018-11-06 | 吴江康欣医用敷料有限公司 | The preparation method of bacteriostatic non-woven cloth containing organic filler |
| CN111020872A (en) * | 2019-11-29 | 2020-04-17 | 吉祥三宝高科纺织有限公司 | Process for preparing nanofiber-based waterproof moisture-permeable membrane material by utilizing electrostatic spinning technology |
| CN111214058A (en) * | 2020-01-09 | 2020-06-02 | 江西省优典实业有限公司 | Latex pillow for infants |
| CN111592767A (en) * | 2020-06-16 | 2020-08-28 | 浦江环彩纺织有限公司 | Novel health-care material and preparation method thereof |
| CN114921858A (en) * | 2022-06-08 | 2022-08-19 | 江门职业技术学院 | Antistatic textile material added with natural fibers, preparation method and device |
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