CN107325379A - A kind of water-soluble plastic packaging bag and preparation method thereof - Google Patents

A kind of water-soluble plastic packaging bag and preparation method thereof Download PDF

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Publication number
CN107325379A
CN107325379A CN201710699058.3A CN201710699058A CN107325379A CN 107325379 A CN107325379 A CN 107325379A CN 201710699058 A CN201710699058 A CN 201710699058A CN 107325379 A CN107325379 A CN 107325379A
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CN
China
Prior art keywords
parts
water
packaging bag
plastic packaging
soluble plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710699058.3A
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Chinese (zh)
Inventor
程海生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Cat Soft Packing Co Ltd
Original Assignee
Anhui Cat Soft Packing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Cat Soft Packing Co Ltd filed Critical Anhui Cat Soft Packing Co Ltd
Priority to CN201710699058.3A priority Critical patent/CN107325379A/en
Publication of CN107325379A publication Critical patent/CN107325379A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention provides a kind of water-soluble plastic packaging bag and preparation method thereof, include the component of following parts by weight meter:10 40 parts of polyethylene, 10 30 parts of soybean starch, 5 20 parts of plasticizer, 6 15 parts of zinc oxide, 15 parts of pine tar, 8 18 parts of allethrin, double 5 10 parts of benzyls of vulcanization, 8 20 parts of salicylic acid, 38 parts of surfactant, 5 12 parts of antitack agent, 6 15 parts of APEO, 2 10 parts of pH adjusting agent, 5 13 parts of preservative.The water soluble package of the present invention can be completely dissolved in water, not produce harmful substance, and Degradable environment protection safety is degraded rapidly in soil, do not interfere with the environment of surrounding;Heat resistance is strong;To packaged product non-hazardous, extend the life cycle of product;Under 180 DEG C of hot conditions, heat-stable time can reach more than 40 minutes, be hardly damaged.

Description

A kind of water-soluble plastic packaging bag and preparation method thereof
Technical field
The invention belongs to plastic products technology field, and in particular to a kind of water-soluble plastic packaging bag and preparation method thereof.
Background technology
Plastic packaging bag is widely used in the packaging of various products, such as agricultural chemicals, chemical fertilizer, dye as a kind of packaging material Material, water treatment agent, concrete reinforced material and chemical reagent of gardening nursing etc.;It is safe and convenient to use, it is to avoid user is direct Contact packed article, the packaging available for harmful article.But plastic packaging bag is not degradable, severe contamination environment; Although some places are handled plastic packaging bag, the product of degradation treatment equally can more or less cause danger to environment Evil, so as to form secondary pollution.Vinyon packing articles.Belong to non-returnable container articles for use, it is cheap, in daily life It is widely used.Value is recycled due to there is no, the rate of recovery is extremely low, caused by its light weight with the characteristic for being difficult to degrade With wind drift, contaminated land and the water surface, the chief component accounted in the established white garbage of China.At present, China is bright Order is forbidden the producing and selling of ultrathin membrane polybag and used.The present invention provides a kind of water-soluble plastic packaging bag, to solve plastics The waste pollution problem that packaging bag is caused.
The content of the invention
To solve the above problems, it is an object of the invention to provide a kind of water-soluble plastic packaging bag and preparation method thereof, Specifically technical scheme is:
A kind of water-soluble plastic packaging bag, includes the component of following parts by weight meter:10-40 parts of polyethylene, soybean starch 10- 30 parts, 5-20 parts of plasticizer, 6-15 parts of zinc oxide, 1-5 parts of pine tar, 8-18 parts of allethrin, it is double vulcanization 5-10 parts of benzyl, bigcatkin willow Sour 8-20 parts, 3-8 parts of surfactant, 5-12 parts of antitack agent, 6-15 parts of APEO, 2-10 parts of pH adjusting agent, preservative 5-13 parts.
Further, the plasticizer is dibutyl phthalate.
Further, the surfactant is PVP.
Further, the antitack agent is one kind in glass microballoon, diatomite, talcum or calcium carbonate.
Further, the preservative is nitrite or sodium benzoate.
Further, the pH adjusting agent is sodium carbonate or potassium carbonate.
A kind of preparation method of water-soluble plastic packaging bag of the present invention, comprises the following steps:
Water-soluble glue is made by mass parts are well mixed in raw material, then cast coat is on mirror face stainless steel band, into dry Dry room drying to moisture is the stripping from steel band after 3-6%, film forming, trimming winding.
Beneficial effect:The invention provides a kind of water-soluble plastic packaging bag and preparation method thereof, water solubility of the invention Packaging bag can be completely dissolved in water, not produce harmful substance, and Degradable environment protection safety is degraded rapidly in soil, will not Environment around influenceing;Heat resistance is strong;Its tensile strength is in 120MPa, break-draw rate only 2% or so;Volatile content exists Below 2.5mg/100ml, to packaged product non-hazardous, extends the life cycle of product;Under 180 DEG C of hot conditions, heat Stabilization time can reach more than 40 minutes, be hardly damaged.
Embodiment
The invention will now be further described with reference to specific embodiments, and following examples are only the optimal implementation of the present invention Example, does not constitute any limitation to the scope of the present invention.It will be understood by those skilled in the art that without departing from the present invention's The details and form of technical solution of the present invention can be modified or replaced under spirit and scope, but these modifications and replacement are equal Fall within the scope of protection of the present invention.
Embodiment 1
A kind of water-soluble plastic packaging bag, includes the component of following parts by weight meter:20 parts of polyethylene, 15 parts of soybean starch, 14 parts of plasticizer, 12 parts of zinc oxide, 3 parts of pine tar, 15 parts of allethrin, double 8 parts of benzyls of vulcanization, 15 parts of salicylic acid, surface-active 5 parts of agent, 8 parts of antitack agent, 10 parts of APEO, 7 parts of pH adjusting agent, 9 parts of preservative.
Further, the plasticizer is dibutyl phthalate.
Further, the surfactant is PVP.
Further, the antitack agent is glass microballoon.
Further, the preservative is nitrite.
Further, the pH adjusting agent is sodium carbonate.
A kind of preparation method of water-soluble plastic packaging bag of the present invention, comprises the following steps:
Water-soluble glue is made by mass parts are well mixed in raw material, then cast coat is on mirror face stainless steel band, into dry Dry room drying to moisture is the stripping from steel band after 5%, film forming, trimming winding.
Embodiment 2
A kind of water-soluble plastic packaging bag, includes the component of following parts by weight meter:10 parts of polyethylene, 10 parts of soybean starch, 5 parts of plasticizer, 6 parts of zinc oxide, 1 part of pine tar, 8 parts of allethrin, double 5 parts of benzyls of vulcanization, 8 parts of salicylic acid, surfactant 3 Part, 5 parts of antitack agent, 6 parts of APEO, 2 parts of pH adjusting agent, 5 parts of preservative.
Further, the plasticizer is dibutyl phthalate.
Further, the surfactant is PVP.
Further, the antitack agent is diatomite.
Further, the preservative is sodium benzoate.
Further, the pH adjusting agent is potassium carbonate.
A kind of preparation method of water-soluble plastic packaging bag of the present invention, comprises the following steps:
Water-soluble glue is made by mass parts are well mixed in raw material, then cast coat is on mirror face stainless steel band, into dry Dry room drying to moisture is the stripping from steel band after 3%, film forming, trimming winding.
Embodiment 3
A kind of water-soluble plastic packaging bag, it is characterised in that include the component of following parts by weight meter:It is 40 parts of polyethylene, big 30 parts of beans starch, 20 parts of plasticizer, 15 parts of zinc oxide, 5 parts of pine tar, 18 parts of allethrin, double 10 parts of benzyls of vulcanization, salicylic acid 8- 20 parts, 8 parts of surfactant, 12 parts of antitack agent, 15 parts of APEO, 10 parts of pH adjusting agent, 13 parts of preservative.
Further, the plasticizer is dibutyl phthalate.
Further, the surfactant is PVP.
Further, the antitack agent is calcium carbonate.
Further, the preservative is nitrite.
Further, the pH adjusting agent is sodium carbonate.
A kind of preparation method of water-soluble plastic packaging bag of the present invention, comprises the following steps:
Water-soluble glue is made by mass parts are well mixed in raw material, then cast coat is on mirror face stainless steel band, into dry Dry room drying to moisture is the stripping from steel band after 6%, film forming, trimming winding.

Claims (7)

1. a kind of water-soluble plastic packaging bag, it is characterised in that include the component of following parts by weight meter:It is 10-40 parts of polyethylene, big 10-30 parts of beans starch, 5-20 parts of plasticizer, 6-15 parts of zinc oxide, 1-5 parts of pine tar, 8-18 parts of allethrin, double vulcanization benzyl 5- 10 parts, 8-20 parts of salicylic acid, 3-8 parts of surfactant, 5-12 parts of antitack agent, 6-15 parts of APEO, pH adjusting agent 2-10 Part, 5-13 parts of preservative.
2. water-soluble plastic packaging bag according to claim 1, it is characterised in that the plasticizer is phthalic acid two Butyl ester.
3. water-soluble plastic packaging bag according to claim 1, it is characterised in that the surfactant is PVP.
4. water-soluble plastic packaging bag according to claim 1, it is characterised in that the antitack agent is glass microballoon, silicon One kind in diatomaceous earth, talcum or calcium carbonate.
5. water-soluble plastic packaging bag according to claim 1, it is characterised in that the preservative is nitrite or benzene Sodium formate.
6. water-soluble plastic packaging bag according to claim 1, it is characterised in that the pH adjusting agent is sodium carbonate or carbon Sour potassium.
7. the preparation method of the water-soluble plastic packaging bag described in a kind of claim 1, it is characterised in that comprise the following steps:
Water-soluble glue is made by mass parts are well mixed in raw material, then cast coat is on mirror face stainless steel band, into hothouse Dry and peeled off after being 3-6%, film forming to moisture from steel band, trimming winding.
CN201710699058.3A 2017-08-15 2017-08-15 A kind of water-soluble plastic packaging bag and preparation method thereof Pending CN107325379A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710699058.3A CN107325379A (en) 2017-08-15 2017-08-15 A kind of water-soluble plastic packaging bag and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710699058.3A CN107325379A (en) 2017-08-15 2017-08-15 A kind of water-soluble plastic packaging bag and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107325379A true CN107325379A (en) 2017-11-07

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109883402A (en) * 2019-03-01 2019-06-14 浙江星天海洋科学技术有限公司 Enter water from shedding mechanism and its water-soluble bottom cover and water-soluble connector processing method
US10982017B2 (en) 2018-06-18 2021-04-20 Baker Hughes, A Ge Company, Llc Methods of manufacturing polyolefin drag reducing agents
US11199296B2 (en) 2019-06-14 2021-12-14 Baker Hughes Oilfield Operations Llc Drag reducing agents

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102140216A (en) * 2011-03-14 2011-08-03 珠海市比格尔生物科技有限公司 Dry-type fused water-soluble biodegradable film and preparation method thereof
CN103289266A (en) * 2013-06-24 2013-09-11 苏州新区佳合塑胶有限公司 Water-soluble plastic packaging bag and preparation method thereof
CN104629226A (en) * 2015-01-26 2015-05-20 北京工商大学 Special cold-water instant packaging film for laundry detergent
CN105646948A (en) * 2016-02-17 2016-06-08 柳州市乾阳机电设备有限公司 Plastic packaging bag and preparing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102140216A (en) * 2011-03-14 2011-08-03 珠海市比格尔生物科技有限公司 Dry-type fused water-soluble biodegradable film and preparation method thereof
CN103289266A (en) * 2013-06-24 2013-09-11 苏州新区佳合塑胶有限公司 Water-soluble plastic packaging bag and preparation method thereof
CN104629226A (en) * 2015-01-26 2015-05-20 北京工商大学 Special cold-water instant packaging film for laundry detergent
CN105646948A (en) * 2016-02-17 2016-06-08 柳州市乾阳机电设备有限公司 Plastic packaging bag and preparing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10982017B2 (en) 2018-06-18 2021-04-20 Baker Hughes, A Ge Company, Llc Methods of manufacturing polyolefin drag reducing agents
CN109883402A (en) * 2019-03-01 2019-06-14 浙江星天海洋科学技术有限公司 Enter water from shedding mechanism and its water-soluble bottom cover and water-soluble connector processing method
US11199296B2 (en) 2019-06-14 2021-12-14 Baker Hughes Oilfield Operations Llc Drag reducing agents
US11248748B2 (en) 2019-06-14 2022-02-15 Baker Hughes Oilfield Operations Llc Drag reducing agents

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Application publication date: 20171107