CN107324445A - A kind of light catalytic waste water processing device - Google Patents

A kind of light catalytic waste water processing device Download PDF

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Publication number
CN107324445A
CN107324445A CN201710662391.7A CN201710662391A CN107324445A CN 107324445 A CN107324445 A CN 107324445A CN 201710662391 A CN201710662391 A CN 201710662391A CN 107324445 A CN107324445 A CN 107324445A
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CN
China
Prior art keywords
inclined tube
treatment tank
layer
waste water
processing device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710662391.7A
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Chinese (zh)
Inventor
胡家富
杜宇
周凝
孙淑雲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Hehai Environmental Research Institute Co Ltd
Original Assignee
Nanjing Hehai Environmental Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Hehai Environmental Research Institute Co Ltd filed Critical Nanjing Hehai Environmental Research Institute Co Ltd
Priority to CN201710662391.7A priority Critical patent/CN107324445A/en
Publication of CN107324445A publication Critical patent/CN107324445A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses a kind of light catalytic waste water processing device, including treatment tank, treatment tank includes water inlet, delivery port, aerator, inclined tube device, ultraviolet light source, the bottom for the treatment of tank is provided with water inlet, top is provided with delivery port, bottom of pond is provided with aerator, inclined tube device includes installing net, inclined tube, Gu phosphorus fixed nitrogen layer, net is installed to be connected on treatment tank pool wall, inclined tube, which is arranged on, installs online side, provided with solid phosphorus fixed nitrogen layer in inclined tube, on inclined tube tube wall photocatalysis layer is equipped with installation net surface, at least two ultraviolet light sources are also uniformly provided with treatment tank pool wall, ultraviolet light source includes uviol lamp, quartz container, universal joint.The present invention is simple in construction, set reasonable, easy to operate, and photocatalysis effect is good, and speed is fast, and the organic matter in effective purification sewage, good purification, use cost is low, easy to maintenance, practical;And play the effect of the solid phosphorus of fixed nitrogen, it is to avoid body eutrophication.

Description

A kind of light catalytic waste water processing device
Technical field
The present invention relates to sewage treatment area, specially a kind of light catalytic waste water processing device.
Background technology
Photocatalytic redox is using n-type semiconductor as catalyst, such as TiO2、ZnO、Fe2O3、SnO2、WO3Deng.TiO2Due to Chemical property and spectrochemical property are sufficiently stable, and nontoxic inexpensive, and the source of goods is abundant, so photocatalytic redox removes depollution Thing is generally with TiO2It is used as photochemical catalyst.Photochemical catalyst redox mechanism is mainly catalyst by light irradiation, absorbs luminous energy, hair Raw electron transition, generation " electronics-hole " is right, the pollutant to being adsorbed in surface, directly carries out redox, or oxidation table The hydroxyl OH- of face absorption, the hydroxyl radical free radical OH of generation strong oxidizing property aoxidizes pollutant.Utilize TiO2Photocatalytic degradation water, Pollutant in compression ring border turns into one of focus that environmental area is studied.Various countries environmental science worker is carried out in this field Extensive and deep exploration, achieves many gratifying achievements, and applied in terms of environmental protection.Numerous studies confirmation, hydrocarbon The organic matter such as class and polycyclic aromatic hydrocarbon, halogenated aromatic compound, dyestuff, surfactant, agricultural chemicals, oils, cyanide can be effective Ground carries out light-catalyzed reaction, and decolouring, detoxification, mineralising are non-toxic inorganic small-molecule substance, so as to eliminate the pollution to environment.Together When, titanium dioxide optical catalyst has very high chemical stability, and nontoxic, and cost is low, high catalytic efficiency.
That the light catalytic waste water processing device used in the prior art is used is all TiO2Photochemical catalyst.The solar energy of early stage Photocatalysis sewage processing system is usually using TiO2Powder is dissolved in sewage as catalyst, and photocatalytic-oxidation is carried out in the sun Change, the organic matter in processing sewage is reclaimed, realization is reused after the completion of processing to powder filter.But suspended state TiO2Though So there is higher degradation efficiency, but it has TiO after reaction2It is difficult to the shortcoming separated, this not only influences effluent quality, and With the lasting progress of reaction, TiO need to be continuously replenished2, so as to cause the increase of processing cost, separation difficulty is reclaimed, is added to This.Common technology means of the prior art are 1, by TiO2Powder immobilization, TiO2Powder is immobilized onto on other materials, Such as glass marble, titanium plate, titanium net, reduce and separate and recover cost, but TiO2Catalysis effect can be reduced by being reduced with the contact area of sewage Really;2nd, using nano-TiO2, nano-photocatalyst material than general catalysis material promote light-catalyzed reaction active function on, Photocatalyst granular size is smaller, and total surface area is bigger, and efficiency of light absorption is higher, and electronics and hole are moved to the several of surface Rate is also bigger, is conducive to the absorption to reactant, so as to increase reaction probabilities;As TiO2 crystallite dimensions are reduced to from 30 nm During 10 nm, the activity of its Photocatalytic Degradation of Phenol improves nearly 45%, but the high expensive of nanometer technology in itself.
Existing light catalytic waste water processing device can only effectively purify the organic matter in sewage, for lake, river, water Nitrogen, phosphorus can not be removed effectively in storehouse or landscape water body, cause the content of nitrogen and phosphorous it is excessive caused by algae overpreading formation Body eutrophication, Dissolved Oxygen in Water declines rapidly, causes the contamination phenomenon of planktonic organism, plant, fish decline or even disappearance. China is annual because body eutrophication causes huge economic loss and ecocatastrophe.
The content of the invention
To solve the above problems, the invention discloses a kind of light catalytic waste water processing device.Realizing at photocatalysis sewage While reason, effectively body eutrophication is solved the problems, such as.
A kind of light catalytic waste water processing device, including treatment tank, the treatment tank include water inlet, water outlet Mouth, aerator, inclined tube device, ultraviolet light source, the bottom of the treatment tank are provided with water outlet provided with water inlet, top Mouthful, the bottom of pond of the treatment tank is provided with aerator, and the inclined tube device includes installing net, inclined tube, solid phosphorus fixed nitrogen layer, institute State installation net to be connected on treatment tank pool wall, the inclined tube, which is arranged on, installs online square, in the inclined tube provided with solid phosphorus consolidates Nitrogen layer, the solid phosphorus fixed nitrogen layer includes activated carbon granule layer, zeolite layer;It is all provided with the inclined tube tube wall with the installation net surface Have and at least two ultraviolet light sources, the ultraviolet light source bag are also uniformly provided with photocatalysis layer, the treatment tank pool wall Uviol lamp, quartz container, universal joint are included, the uviol lamp is located in quartz container, and the quartz container universal-joint is described Universal joint connects treatment tank pool wall.
Further, the photocatalysis layer is TiO2Photocatalysis layer.
Further, the activated carbon granule layer is active fruit shell carbon stratum granulosum.
Further, the inclined tube is transparent inclined tube.
Further, overflow pipe is provided with above the inclined tube of the treatment tank, the overflow pipe is provided with overfall, described to overflow Flow tube connects delivery port.
Further, the installation net bottom face is connected post, and net, other end connection are installed in fixed column one end connection Treatment tank bottom of pond, the fixed column surface is provided with photocatalysis layer.Fixed column plays a part of that net is fixedly mounted.
The course of work and operation principle of the present invention:Sewage enters treatment tank from water inlet, then enters through installing net Enter in inclined tube, then discharged through delivery port.Photocatalysis layer of the organic matter through inclined tube tube wall and installation net surface in waste water is catalyzed Oxidation, organic matter is broken down into the materials such as water and carbon dioxide, realizes purifying organic without any toxicity and side effects;In waste water Nitrogen, phosphorus can be adsorbed by the activated carbon granule layer in solid phosphorus fixed nitrogen layer, zeolite layer, while activated carbon granule layer, zeolite layer also have The effect of organic matter is adsorbed, organic matter also can be by photocatalysis Decomposition;The effect of inclined tube is to increase connecing for sewage and photocatalysis layer Contacting surface is accumulated and time of contact, the rational space using treatment tank, and contact area is increased in effective space;Aeration dress Put realization aeration, aeration not only makes in pond liquid-to-air contact oxygenation, and due to agitation liquid, accelerate in air oxygen to Shifted in liquid, so as to complete the purpose of oxygenation;In the present invention, ultraviolet light source is set up, strengthens photocatalytic speed, while purple Outer lamp universal-joint, the position of uviol lamp can be adjusted by universal joint, the irradiation of omnibearing stereo is realized, accelerate photocatalysis effect Really.
In summary, it is an advantage of the invention that:Simple in construction, setting is reasonable, easy to operate, and photocatalysis effect is good, speed It hurry up, the organic matter in effective purification sewage, good purification, use cost is low, easy to maintenance, practical;And play solid The effect of the solid phosphorus of nitrogen, it is to avoid body eutrophication.
Brief description of the drawings
Fig. 1, the present invention structural representation;
A partial enlarged drawings in Fig. 2, Fig. 1;
Fig. 3, inclined tube sectional view.
Wherein:Treatment tank 100, water inlet 1, delivery port 2, aerator 3, inclined tube device 4, installation net 41, inclined tube 42nd, solid phosphorus fixed nitrogen layer 43, activated carbon granule layer 431, zeolite layer 432, ultraviolet light source 5, uviol lamp 51, quartz container 52, ten thousand To section 53, photocatalysis layer 6, overflow pipe 7, overfall 71, fixed column 8, baffle plate 9.
Embodiment
With reference to the accompanying drawings and detailed description, the present invention is furture elucidated, it should be understood that following embodiments are only For illustrating the present invention rather than limitation the scope of the present invention.
As shown in Figure 1, Figure 2, Figure 3 shows, a kind of light catalytic waste water processing device, including treatment tank 100, treatment tank Including water inlet 1, delivery port 2, aerator 3, inclined tube device 4, ultraviolet light source 5.Be provided with the bottom for the treatment of tank into The mouth of a river, delivery port is provided with the top for the treatment of tank, and aerator is provided with the bottom of pond for the treatment of tank.Wherein water inlet is set Put in lower section, delivery port is disposed over, realize that sewage flows from bottom to top, the effect of sedimentation, the opposing party does not can be achieved in aspect Face sewage increases in the reaction time of processing pond, can further increase the light-catalysed time, extension sewage is in processing pond Residence time;Meanwhile, the setting of inclined tube can also extend residence time of the sewage in inclined tube, and increase sewage and photocatalysis layer Contact area.Inclined tube device includes installing net 41, inclined tube 42, solid phosphorus fixed nitrogen layer 43, and installation net is stainless steel cloth, fixed weldering It is connected on treatment tank pool wall, inclined tube, which is arranged on, installs online side, and inclined tube, which can be rest directly upon, installs online, can also use Means of the prior art, are flexibly connected or are fixedly connected on installation online.Provided with solid phosphorus fixed nitrogen layer in inclined tube, Gu phosphorus fixed nitrogen Layer includes activated carbon granule layer 431, zeolite layer 432;It is equipped with inclined tube tube wall with installation net surface at photocatalysis layer 6, sewage At least two ultraviolet light sources are also uniformly provided with reason pond pool wall, and ultraviolet light source includes uviol lamp 51, quartz container 52, universal Section 53, uviol lamp is located in quartz container, quartz container universal-joint, universal joint connection treatment tank pool wall.
In the present embodiment, photocatalysis layer is TiO2Photocatalysis layer.
In the present embodiment, activated carbon granule layer is active fruit shell carbon stratum granulosum.Active fruit shell carbon can the solid phosphorus of fixed nitrogen, simultaneously Cost is low, environmental protection, recoverable.
In the present embodiment, inclined tube is transparent inclined tube, can select the inclined tube that transparent plastics are made.Transparent inclined tube can increase Catalytic effect of the big light source to photochemical catalyst.
Further, overflow pipe 7 is provided with above the inclined tube for the treatment of tank, overflow pipe is provided with overfall 71, described to overflow Flow tube connects delivery port.Setting up for overflow pipe, can control the sewage quantity in treatment tank.
Further, net bottom face is installed to be connected post 8, fixed column selects stainless steel wire post, and the welding of fixed column one end connects Installation net is connect, the other end welds treatment tank bottom of pond, and fixed column surface is provided with photocatalysis layer.Fixed column plays fixed installation net Effect.
In the present embodiment, photocatalysis layer is TiO2Photocatalysis layer, TiO is sprayed on the inside and outside wall of inclined tube2Formed TiO2Photocatalysis layer, installs the same spraying TiO of net2Form TiO2Photocatalysis layer, fixed column outer wall spraying TiO2Form TiO2 Photocatalysis layer.
It is circle that inclined tube, which can select section, in the present embodiment, and the section of inclined tube can be square, rule in other embodiments Shape or irregular shape then.When inclined tube is installed, because inclined tube is obliquely installed, in the bottom and pond of inclined tube Certain interval is left between wall, herein interval in set baffle plate 9, baffle plate setting install net top, can avoid sewage from Pass through in this gap, stagnant water is formed between inclined tube and pool wall.
In the present embodiment, treatment tank is square pond, on the center of every face pool wall for the treatment of tank One ultraviolet light source is set, and ultraviolet light source is arranged on the top of overflow pipe, it is to avoid ultraviolet light source contacts sewage.
Technological means disclosed in the present invention program is not limited only to the technological means disclosed in above-mentioned embodiment, in addition to Constituted technical scheme is combined by above technical characteristic.It should be pointed out that for those skilled in the art For, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as Protection scope of the present invention.

Claims (5)

1. a kind of light catalytic waste water processing device, it is characterised in that:Including treatment tank, the treatment tank includes water inlet Mouth, delivery port, aerator, inclined tube device, ultraviolet light source, the bottom of the treatment tank are set provided with water inlet, top There is delivery port, the bottom of pond of the treatment tank is provided with aerator, and the inclined tube device includes installation net, inclined tube, solid phosphorus and consolidated Nitrogen layer, the installation net is connected on treatment tank pool wall, and the inclined tube is arranged on to install and is provided with online side, the inclined tube Gu phosphorus fixed nitrogen layer, the solid phosphorus fixed nitrogen layer includes activated carbon granule layer, zeolite layer;With the installation netlist on the inclined tube tube wall Face is equipped with photocatalysis layer, the treatment tank pool wall and is also uniformly provided with least two ultraviolet light sources, the uviol lamp Light source includes uviol lamp, quartz container, universal joint, and the uviol lamp is located in quartz container, and the quartz container connection is universal Section, the universal joint connects treatment tank pool wall.
2. a kind of light catalytic waste water processing device as claimed in claim 1, it is characterised in that:The photocatalysis layer is TiO2Light Catalytic Layer.
3. a kind of light catalytic waste water processing device as claimed in claim 1, it is characterised in that:The inclined tube is transparent inclined tube.
4. a kind of light catalytic waste water processing device as claimed in claim 1, it is characterised in that:The inclined tube of the treatment tank Top is provided with overflow pipe, and the overflow pipe is provided with overfall, and the overflow pipe connects delivery port.
5. a kind of light catalytic waste water processing device as claimed in claim 1, it is characterised in that:Installation net bottom face connection is solid Net is installed in fixed column, fixed column one end connection, and the other end connects treatment tank bottom of pond, and the fixed column surface is urged provided with light Change layer.
CN201710662391.7A 2017-08-04 2017-08-04 A kind of light catalytic waste water processing device Pending CN107324445A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710662391.7A CN107324445A (en) 2017-08-04 2017-08-04 A kind of light catalytic waste water processing device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710662391.7A CN107324445A (en) 2017-08-04 2017-08-04 A kind of light catalytic waste water processing device

Publications (1)

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CN107324445A true CN107324445A (en) 2017-11-07

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000237543A (en) * 1999-02-23 2000-09-05 Tao:Kk Photocatalytic device
CN103086469A (en) * 2013-02-19 2013-05-08 江苏大地益源环境修复有限公司 Efficient photocatalysis water treatment method and device
CN204661354U (en) * 2015-05-25 2015-09-23 徐州工程学院 For the photocatalytic reaction device of organic pollutant degradation
CN204689799U (en) * 2015-05-24 2015-10-07 西安科技大学 Based on the photocatalytic oxidation reactor of activated carbon supported nano TiO 2
CN207294255U (en) * 2017-08-04 2018-05-01 南京河海环境研究院有限公司 A kind of light catalytic waste water processing device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000237543A (en) * 1999-02-23 2000-09-05 Tao:Kk Photocatalytic device
CN103086469A (en) * 2013-02-19 2013-05-08 江苏大地益源环境修复有限公司 Efficient photocatalysis water treatment method and device
CN204689799U (en) * 2015-05-24 2015-10-07 西安科技大学 Based on the photocatalytic oxidation reactor of activated carbon supported nano TiO 2
CN204661354U (en) * 2015-05-25 2015-09-23 徐州工程学院 For the photocatalytic reaction device of organic pollutant degradation
CN207294255U (en) * 2017-08-04 2018-05-01 南京河海环境研究院有限公司 A kind of light catalytic waste water processing device

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Application publication date: 20171107