CN107315045A - The preparation and application of a kind of graphene/zinc oxide nano popped rice/ITO electrode - Google Patents
The preparation and application of a kind of graphene/zinc oxide nano popped rice/ITO electrode Download PDFInfo
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Abstract
The present invention relates to the preparation and application of a kind of graphene/zinc oxide nano popped rice/ITO electrode, belong to new function material and biology sensor detection technique field.Preparation method step includes：Hydrothermal synthesis method, automatic spraying process, chemical vapour deposition technique.The present invention is with electro-conductive glass（ITO）As substrate, zinc oxide nano popped rice is sprayed on ITO, and in its surface deposited graphite alkene.The graphene prepared/zinc oxide nano popped rice/ITO electrode is applied to field of biosensors, with high sensitivity, good selectivity is good, repeated and the advantages of good stability, solve current material and the problem of levodopa sensitivity is relatively low is detected in biological sensor.
Description
Technical field
The present invention relates to the preparation and its application of a kind of graphene/zinc oxide nano popped rice/ITO electrode.
Background technology
Zinc oxide is a kind of Group II-VI semiconductor material, it is that zinc oxide nanowire has a morphology controllable and be easily-synthesized it is excellent
Point, with excellent bio-compatibility, outside chemical stability, can be provided straight when biology sensor detects biomolecule
Connect, quick electron channel.And the zinc oxide nano popped rice for the three-dimensional structure being made up of nano wire has big porosity and bigger
Specific surface area, and with it is bigger with the contact area of solution.The method of conventional synthesizing zinc oxide nano flower is hydrothermal synthesis method,
This method has cost low, the simple advantage of building-up process.
Graphene is a kind of two-dimentional carbon material of only individual layer atomic thickness, with excellent electric conductivity, mechanical performance and
Chemical stability, in biomedicine, sensor, the field such as ultracapacitor has a wide range of applications.Stone was found since 2004
After black alkene, current main preparation methods have mechanical stripping method, chemical vapour deposition technique and reduction-oxidation graphite method.Wherein, it is chemical
The suitable preparation structure of vapor deposition method is complete, high-quality graphene.
Parkinson's are a kind of common nervous system degeneration diseases, and topmost pathological change is substantia nigra of midbrain dopamine
The denaturation of serotonergic neuron is dead, thus causes DOPAMINE CONTENT IN RABBIT to substantially reduce and cause a disease.Levodopa（L-dopa）Also known as it is left many
Bar, can generate dopamine, to make up brain dopamine by blood cerebral disorders and in the presence of aromatic amino acid decarboxylase
Deficiency, be a kind of antiparkinsonian drug, be mainly used to treat Parkinson disease.But, levodopa content is excessive in human body
Toxic side effect can be produced.So, accurately content of the detection levodopa in human body has very important significance.
The content of the invention
The invention solves the problems that the easy Adsorption for Biomolecules of zinc oxide nano popped rice higher isoelectric point, also has its low electrical conductance, in life
The problem of sensitivity is low during thing sensor application.Zinc oxide nano popped rice is prepared and then with automatic spraying process by oxygen by hydro-thermal method
Change zinc nano flower to be sprayed on ITO, finally deposit a layer graphene on zinc oxide nano popped rice surface with chemical vapour deposition technique, obtain
Graphene/zinc oxide nano popped rice/ITO electrode is obtained, for detecting levodopa.
A kind of preparation method of graphene that the present invention is provided/zinc oxide nano popped rice/ITO electrode is to enter according to the following steps
OK：
First, hydrothermal synthesis method
1）The solvent zinc nitrate solution that compound concentration is 0.03mol/L~0.07mol/L respectively, 0.03mol/ are used as with distilled water
L~0.07mol/L hexa solution, 0.03mol/L~0.07mol/L ammonia spirit and 3mmol/L~
7mmol/L polyetherimide solution, and by four kinds of solution it is well mixed after with 450r/min~550r/min rotating speed magnetic force
Stir 3 min~5min and obtain hydro-thermal reaction solution；
2）By step one 1）Obtained hydro-thermal reaction solution is poured into reactor, covers reactor lid, at 90 DEG C~120 DEG C
10~14h is reacted under temperature conditionss, then takes out and naturally cools to room temperature in atmosphere, zinc oxide nano popped rice is obtained, opens anti-
Answer kettle distilled water that material clean is clean, and the zinc oxide nano popped rice after filtering is transferred in culture dish, be put into drying box
In at 70 DEG C~90 DEG C dry 1 ~ 3h obtain zinc oxide nano popped rice；
2nd, automatic spraying process
1）The deionized water of 0.01g ~ 0.03g zinc oxide nano popped rice and 20mL is mixed to get zinc oxide nano popped rice suspension；
2）ITO is cleaned by ultrasonic after 20min in acetone soln, ethanol solution and deionized water respectively, at room temperature natural cooling
Dry, six pieces of ITO electro-conductive glass are fixed in spraying equipment heating plate, ITO electro-conductive glass is pressed from both sides into electrode wires with adhesive tape
Side is covered, it is ensured that electrode wires are directly contacted with ITO electro-conductive glass；
3）Finely dispersed zinc oxide nano popped rice suspension is placed in spray gun, zinc-oxide nano is prepared using automatic spraying process
Flower/ITO electrode, whole spraying process is carried out under 10psi air inlet pressures, and the distance of nozzle to ITO is 15cm, and heating dish temperature is
100 DEG C, zinc oxide nano popped rice suspension is stirred continuously with mini-sized blender in spraying process；
3rd, chemical vapour deposition technique
By step 23）In obtained zinc oxide nano popped rice/ITO electrode be placed on quartz tube furnace gas outlet side, protected in argon gas
900 DEG C ~ 1100 DEG C are heated to from room temperature with 10 DEG C/min ~ 20 DEG C/min heating rate under shield, in 900 DEG C ~ 1100 DEG C conditions
Lower insulation 40min ~ 60min, is passed through when temperature is 900 DEG C ~ 1100 DEG C into tube furnace with 10 sccm ~ 20sccm speed
Methane gas, is then cooled to room with 10 DEG C/min ~ 20 DEG C/min cooldown rate by quartz tube furnace from 900 DEG C ~ 1100 DEG C
Temperature, obtains graphene/zinc oxide nano popped rice/ITO electrode, wherein the flow velocity of the argon gas described in step 3 be 450sccm ~
550sccm。
Advantages of the present invention：
1）The present invention prepares zinc oxide nano popped rice using hydrothermal synthesis method, is sprayed after then zinc oxide is mixed with deionized water
Onto ito glass, finally a kind of high-ratio surface is obtained in zinc oxide nano popped rice surface deposited graphite alkene with chemical vapour deposition technique
Product, graphene/zinc oxide nano popped rice/ITO electrode of high conductivity;
2）The zinc-oxide nano floral material that the present invention is prepared maintain the excellent biocompatibility of original zinc oxide and directly,
Outside quick electron channel, the big specific surface area of zinc oxide nano popped rice makes the contact area of itself and solution become big, while utilizationization
Learn vapour deposition process and compensate for zinc oxide nano popped rice low electrical conductance and biological adsorption in itself in zinc oxide surface coated graphite alkene
Property, improve its chemical property so that the sensitivity of Electrochemical Detection levodopa reaches 0.32 μ A μM-1。
Brief description of the drawings：
Fig. 1 is the stereoscan photograph that the zinc oxide nano popped rice that experiment is prepared amplifies 10000 times；
Fig. 2 is the stereoscan photograph that graphene/zinc oxide nano popped rice that experiment is prepared amplifies 10000 times；
Fig. 3 is the energy spectrum diagram of graphene/zinc oxide nano popped rice；
Fig. 4 is the Raman collection of illustrative plates of graphene/zinc oxide nano popped rice；
Fig. 5 is the differential pulse voltammetry curve of graphene/zinc oxide nano popped rice prepared by experiment；
The Linear Fit Chart of levodopa concentration and oxidation peak current when Fig. 6 is differential pulse method detection levodopa.
Embodiment
Embodiment one：A kind of preparation method of graphene/zinc-oxide nano/ITO electrode in present embodiment, tool
Body is carried out according to the following steps：
First, hydrothermal synthesis method
1）The solvent zinc nitrate solution that compound concentration is 0.03mol/L~0.07mol/L respectively, 0.03mol/ are used as with distilled water
L~0.07mol/L hexa solution, 0.03mol/L~0.07mol/L ammonia spirit and 3mmol/L~
7mmol/L polyetherimide solution, and by four kinds of solution it is well mixed after with 450r/min~550r/min rotating speed magnetic force
Stirring 3min~5min obtains hydro-thermal reaction solution；
2）By step one 1）Obtained hydro-thermal reaction solution is poured into reactor, covers reactor lid, at 90 DEG C~120 DEG C
10~14h is reacted under temperature conditionss, then takes out and naturally cools to room temperature in atmosphere, zinc oxide nano popped rice is obtained, opens anti-
Answer kettle distilled water that material clean is clean, and the zinc oxide nano popped rice after filtering is transferred in culture dish, be put into drying box
In at 70 DEG C~90 DEG C dry 1 ~ 3h obtain zinc oxide nano popped rice；
2nd, automatic spraying process
1）The deionized water of 0.01g ~ 0.03g zinc oxide nano popped rice and 20mL is mixed to get zinc oxide nano popped rice suspension；
2）ITO is cleaned by ultrasonic after 20min in acetone soln, ethanol solution and deionized water respectively, at room temperature natural cooling
Dry, six pieces of ITO electro-conductive glass are fixed in spraying equipment heating plate, ITO electro-conductive glass is pressed from both sides into electrode wires with adhesive tape
Side is covered, it is ensured that electrode wires are directly contacted with ITO electro-conductive glass；
3）Finely dispersed zinc oxide nano popped rice suspension is placed in spray gun, zinc-oxide nano is prepared using automatic spraying process
Flower/ITO electrode, whole spraying process is carried out under 10psi air inlet pressures, and the distance of nozzle to ITO is 15cm, and heating dish temperature is
100 DEG C, zinc oxide nano popped rice suspension is stirred continuously with mini-sized blender in spraying process；
3rd, chemical vapour deposition technique
By step 23）In obtained zinc oxide nano popped rice/ITO electrode be placed on quartz tube furnace gas outlet side, protected in argon gas
900 DEG C ~ 1100 DEG C are heated to from room temperature with 10 DEG C/min ~ 20 DEG C/min heating rate under shield, in 900 DEG C ~ 1100 DEG C conditions
Lower insulation 40min ~ 60min, is passed through when temperature is 900 DEG C ~ 1100 DEG C into tube furnace with 10 sccm ~ 20sccm speed
Methane gas, is then cooled to room with 10 DEG C/min ~ 20 DEG C/min cooldown rate by quartz tube furnace from 900 DEG C ~ 1100 DEG C
Temperature, obtains graphene/zinc oxide nano popped rice/ITO electrode, wherein the flow velocity of the argon gas described in step 3 be 450sccm ~
550sccm。
Embodiment two:Present embodiment from unlike embodiment one：Step one 1）In use distilled water
It is 0.04mol/L~0.06mol/L zinc nitrate solution, 0.04mol/L~0.06mol/L to distinguish compound concentration as solvent
The PEI of hexa solution, 0.04mol/L~0.06mol/L ammonia spirit and 4mmol/L~6mmol/L
Solution, and by four kinds of solution it is well mixed after obtained with 450r/min~500r/min rotating speed magnetic agitation 4min~5min
Hydro-thermal reaction solution；It is other identical with embodiment one.
Embodiment three:Present embodiment from unlike embodiment one or two：By step one 2）It is middle to incite somebody to action
Step one 1）Obtained hydro-thermal reaction solution is poured into reactor, covers reactor lid, in 95 DEG C~105 DEG C of temperature strip
11~13h is reacted under part, then takes out and naturally cools to room temperature in atmosphere, zinc oxide nano popped rice is obtained, reactor is opened and uses
Distilled water is clean by material clean, and the zinc oxide nano popped rice after filtering is transferred in culture dish, is put into drying box 70
DEG C~90 DEG C at dry 1 ~ 3h obtain zinc oxide nano popped rice；It is other identical with one of embodiment one or two.
Embodiment four:Present embodiment from unlike embodiment one to three：Step 21）It is middle to incite somebody to action
0.015g ~ 0.025g zinc oxide nano popped rice and 20 mL deionized water are mixed to get zinc oxide nano popped rice suspension；It is other with
One of embodiment one to three is identical.
Embodiment five:Present embodiment from unlike embodiment one to four：By step in step 3
23）In obtained zinc oxide nano popped rice/ITO electrode be placed on quartz tube furnace gas outlet side, from room temperature under argon gas protection
950 DEG C ~ 1050 DEG C are heated to 10 DEG C/min ~ 20 DEG C/min heating rate, is incubated under the conditions of 950 DEG C ~ 1050 DEG C
40min ~ 60min, methane gas is passed through when temperature is 950 DEG C ~ 1050 DEG C into tube furnace with 10 sccm ~ 20sccm speed
Body, is then cooled to room temperature from 950 DEG C ~ 1050 DEG C with 10 DEG C/min ~ 20 DEG C/min cooldown rate by quartz tube furnace, obtains
Graphene/zinc oxide nano popped rice/ITO electrode, the wherein flow velocity of the argon gas described in step 3 are 450sccm ~ 550sccm；It is other
It is identical with one of embodiment one to four.
Present embodiment is that a kind of graphene/zinc oxide nano popped rice/ITO electrode is used as working electrode, passes through pulse
Voltammetric method test obtains curve of the material to the levodopa of various concentrations, so as to play a part of detecting levodopa.
Using following verification experimental verifications effect of the present invention：
Experiment one：A kind of preparation method of graphene of this experiment/zinc oxide nano popped rice/ITO electrode is step by the following method
Realize：
First, hydrothermal synthesis method：
1）The solvent zinc nitrate solution that compound concentration is 0.05mol/L respectively, 0.05mol/L hexa-methylene are used as with distilled water
The polyetherimide solution of four amine aqueous solutions, 0.05mol/L ammonia spirit and 5mmol/L, and by four kinds of solution it is well mixed after
Hydro-thermal reaction solution is obtained with 500r/min rotating speed magnetic agitation 5min；
2）By step one 1）Obtained hydro-thermal reaction solution is poured into reactor, covers reactor lid, in 100 DEG C of temperature strip
12h is reacted under part, then takes out and naturally cools to room temperature in atmosphere, zinc oxide nano popped rice is obtained, reactor distillation is opened
Water is clean by material clean, and the zinc oxide nano popped rice after filtering is transferred in culture dish, is put into drying box at 80 DEG C
Dry 2h；
2nd, automatic spraying process
1）The deionized water of 0.02 g zinc oxide nano popped rice and 20mL is mixed to get zinc oxide nano popped rice suspension；
2）ITO electro-conductive glass is cleaned by ultrasonic after 20min in acetone soln, ethanol solution and deionized water respectively, at room temperature
Natural cooling is dried.Six pieces of ITO electro-conductive glass are fixed in spraying equipment heating plate, with adhesive tape by ITO electro-conductive glass
Press from both sides the covering of electrode wires side, it is ensured that electrode wires are directly contacted with ITO electro-conductive glass；
3）Finely dispersed zinc oxide suspension is placed in spray gun zinc oxide nano popped rice/ITO electricity is prepared using automatic spraying process
Pole, whole spraying process is carried out under 10psi air inlet pressures, and the distance of nozzle to ITO electro-conductive glass is 15cm, and heating dish temperature is
100 DEG C, zinc oxide nano popped rice suspension is stirred continuously with mini-sized blender in spraying process；
3rd, chemical vapour deposition technique
By step 23）In obtained zinc oxide nano popped rice/ITO electrode be placed on quartz tube furnace gas outlet side, protected in argon gas
1000 DEG C are heated to from room temperature with 10 DEG C/min heating rate under shield, 60min is incubated under the conditions of 1000 DEG C, is in temperature
Methane gas is passed through with 20sccm speed into tube furnace at 1000 DEG C, quartz tube furnace is then cooled to room from 1000 DEG C
Temperature, obtains graphene/zinc oxide nano popped rice/ITO electrode, the wherein flow velocity of the argon gas described in step 3 is 500 sccm.
Fig. 1 is to test the stereoscan photograph that a zinc oxide nano popped rice prepared amplifies 10000 times.As can be seen that oxygen
Change zinc nano flower to be made up of nano wire, about 2.5 microns of the length of nano wire, about 50 nanometers of diameter.
Fig. 2 is to test the stereoscan photograph that a graphene prepared/zinc oxide nano popped rice amplifies 10000 times.Due to
Graphene simply forms several layers on zinc oxide nano popped rice surface, so the pattern and size of graphene/zinc oxide nano popped rice are basic
It is unchanged.
Fig. 3 is the energy spectrum diagram for testing a graphene/zinc oxide nano popped rice prepared.As can be seen that in zinc oxide surface
There is the presence of carbon.
Fig. 4 is the Raman collection of illustrative plates for testing a graphene/zinc oxide nano popped rice prepared, wherein in 1364cm-1,
1576cm-1With 2651 cm-1Occur the characteristic peak of three correspondence graphenes at position, be respectively by SP3Orbital hybridization carbon atom
D bands, SP caused by coplanar vibration2G bands caused by the coplanar vibration of the carbon atom of hydridization and because double resonance Raman scattering causes
2D bands, and in 340cm-1,427cm-1There are zinc oxide signature peaks in place, and it is the graphene and oxygen by multilayer to show the material
Change zinc composition.
Experiment two：Graphene/zinc oxide nano popped rice/ITO detects the experiment of levodopa, concrete operations as working electrode
It is as follows：
Using graphene/zinc oxide nano popped rice/ITO as working electrode, effective material area is 0.7cm2, silver/silver chlorate work
For reference electrode, platinum filament is tested as to electrode using traditional three-electrode system by pulse voltammetry, current potential increase 50mV,
Pulse height 4mV, sweep speed 8mV/s, so as to obtain differential pulse voltammetry curve of the material to various concentrations levodopa；
Described graphene/zinc oxide nano popped rice/ITO is prepared by experiment one.
Fig. 5 is the differential pulse voltammetry curve for the levodopa for testing two obtained detection various concentrations.As can be seen that left
The oxidation potential for revolving DOPA is main in 0.18V or so, with the growth oxidation peak current increase of levodopa concentration.
Fig. 6 is to test levodopa concentration and oxidation peak current when two obtained differential pulse voltammetries detect levodopa
Linear Fit Chart.In the concentration range of 1 ~ 60 μM of test, levodopa concentration change is linear with oxidation peak current
Straight line, sensitivity of the graphene/zinc oxide nano popped rice/ITO electrode to levodopa is 0.32 μ A μM-1。
Claims (7)
1. the preparation method of a kind of graphene/zinc oxide nano popped rice/TIO electrodes, it is characterised in that specifically carry out according to the following steps
's：
First, hydrothermal synthesis method
1）The solvent zinc nitrate solution that compound concentration is 0.03mol/L~0.07mol/L respectively, 0.03mol/ are used as with distilled water
L~0.07mol/L hexa solution, 0.03mol/L~0.07mol/L ammonia spirit and 3mmol/L~
7mmol/L polyetherimide solution, and by four kinds of solution it is well mixed after with 450r/min~550r/min rotating speed magnetic force
Stirring 3min~5min obtains hydro-thermal reaction solution；
2）By step one 1）Obtained hydro-thermal reaction solution is poured into reactor, covers reactor lid, at 90 DEG C~120 DEG C
10~14h is reacted under temperature conditionss, then takes out and naturally cools to room temperature in atmosphere, zinc oxide nano popped rice is obtained, opens anti-
Answer kettle distilled water that material clean is clean, and the zinc oxide nano popped rice after filtering is transferred in culture dish, be put into drying box
In at 70 DEG C~90 DEG C dry 1 ~ 3h obtain zinc oxide nano popped rice；
2nd, automatic spraying process
1）The deionized water of 0.01g ~ 0.03g zinc oxide nano popped rice and 20mL is mixed to get zinc oxide nano popped rice suspension；
2）ITO is cleaned by ultrasonic after 20min in acetone soln, ethanol solution and deionized water respectively, at room temperature natural cooling
Dry, six pieces of ITO electro-conductive glass are fixed in spraying equipment heating plate, ITO electro-conductive glass is pressed from both sides into electrode wires with adhesive tape
Side is covered, it is ensured that electrode wires are directly contacted with ITO electro-conductive glass；
3）Finely dispersed zinc oxide nano popped rice suspension is placed in spray gun, zinc-oxide nano is prepared using automatic spraying process
Flower/ITO electrode, whole spraying process is carried out under 10psi air inlet pressures, and the distance of nozzle to ITO is 15cm, and heating dish temperature is
100 DEG C, zinc oxide nano popped rice suspension is stirred continuously with mini-sized blender in spraying process；
3rd, chemical vapour deposition technique
By step 23）In obtained zinc oxide nano popped rice/ITO electrode be placed on quartz tube furnace gas outlet side, protected in argon gas
900 DEG C ~ 1100 DEG C are heated to from room temperature with 10 DEG C/min ~ 20 DEG C/min heating rate under shield, in 900 DEG C ~ 1100 DEG C conditions
Lower insulation 40min ~ 60min, is passed through when temperature is 900 DEG C ~ 1100 DEG C into tube furnace with 10 sccm ~ 20sccm speed
Methane gas, is then cooled to room with 10 DEG C/min ~ 20 DEG C/min cooldown rate by quartz tube furnace from 900 DEG C ~ 1100 DEG C
Temperature, obtains graphene/zinc oxide nano popped rice/ITO electrode, wherein the flow velocity of the argon gas described in step 3 be 450sccm ~
550sccm。
2. a kind of preparation method of graphene according to claim 1/zinc oxide nano popped rice/ITO electrode, it is characterised in that
By step one 1）It is middle with distilled water as the solvent zinc nitrate solution that compound concentration is 0.03mol/L~0.07mol/L respectively,
0.03mol/L~0.07mol/L hexa solution, 0.03mol/L~0.07mol/L ammonia spirit and 3mmol/
L~7mmol/L polyetherimide solution, and by four kinds of solution it is well mixed after with 450r/min~550r/min rotating speed
Magnetic agitation 3min~5min obtains hydro-thermal reaction solution.
3. a kind of preparation method of graphene according to claim 1/zinc oxide nano popped rice/ITO electrode, it is characterised in that
Step 21）It is suspended that the middle deionized water by 0.01g ~ 0.03g zinc oxide nano popped rice and 20mL is mixed to get zinc oxide nano popped rice
Liquid.
4. a kind of preparation method of graphene according to claim 1/zinc oxide nano popped rice/ITO electrode, it is characterised in that
Step 22）Middle ITO electro-conductive glass is cleaned by ultrasonic after 10min in acetone soln, ethanol solution and deionized water respectively, in room
The lower natural cooling of temperature is dried, and six pieces of ITO are fixed in spraying equipment heating plate, ITO is pressed from both sides into electrode wires side with adhesive tape
Covering, it is ensured that electrode wires are clean free of contamination with the direct contact positions of ITO.
5. a kind of preparation method of graphene according to claim 1/zinc oxide nano popped rice/ITO electrode, it is characterised in that
Step 23）Middle zinc oxide nano popped rice suspension is placed in spray gun prepares zinc oxide nano popped rice/ITO electricity using automatic spraying process
Pole, whole spraying process is carried out under 10psi air inlet pressures, and the distance of nozzle to ITO electro-conductive glass is 15cm, and heating dish temperature is
100 DEG C, zinc oxide nano popped rice suspension is stirred continuously with mini-sized blender in spraying process.
6. a kind of preparation method of graphene according to claim 1/zinc oxide nano popped rice/ITO electrode, it is characterised in that
By step 23）In obtained zinc oxide nano popped rice/ITO electrode be placed on quartz tube furnace gas outlet side, under argon gas protection
900 DEG C ~ 1100 DEG C are heated to from room temperature with 10 DEG C/min ~ 20 DEG C/min heating rate, is protected under the conditions of 900 DEG C ~ 1100 DEG C
Warm 40min ~ 60min, methane is passed through when temperature is 900 DEG C ~ 1100 DEG C into tube furnace with 10sccm ~ 20sccm speed
Gas, is then cooled to room temperature from 900 DEG C ~ 1100 DEG C with 10 DEG C/min ~ 20 DEG C/min cooldown rate by quartz tube furnace, obtains
To graphene/zinc oxide nano popped rice/ITO electrode, the wherein flow velocity of the argon gas described in step 3 is 450sccm ~ 550sccm.
7. a kind of application of graphene/zinc oxide nano popped rice/ITO electrode, it is characterised in that graphene/zinc oxide nano popped rice/ITO
Electrode is used as working electrode in biology sensor.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486544A (en) * | 2018-02-08 | 2018-09-04 | 佛山市顺德区中山大学研究院 | A kind of preparation method and applications of the graphene zinc oxide micro-nano grading function material with automatically cleaning super lyophoby characteristic |
| CN109239154A (en) * | 2018-08-23 | 2019-01-18 | 哈尔滨理工大学 | A kind of preparation and application of zinc oxide nano popped rice-graphene composite material |
| CN109599534A (en) * | 2018-11-29 | 2019-04-09 | 西交利物浦大学 | Nanometer flower-shaped silicon copper electrode material based on graphene and the preparation method and application thereof |
| CN111024792A (en) * | 2020-01-07 | 2020-04-17 | 哈尔滨理工大学 | Electrochemical sensing electrode based on flower-like zinc oxide @ ferrocene functionalized three-dimensional graphene |
| CN114512681A (en) * | 2022-01-29 | 2022-05-17 | 辽宁大学 | Electrode material for biofuel cell and preparation method and application thereof |
| CN114544725A (en) * | 2020-11-25 | 2022-05-27 | 五鼎生物技术股份有限公司 | Biochemical test piece |
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| CN103558273A (en) * | 2013-10-15 | 2014-02-05 | 哈尔滨理工大学 | Preparation method of zinc oxide nanowire array/ foamy graphene composite material and application thereof |
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Cited By (11)
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| CN108486544A (en) * | 2018-02-08 | 2018-09-04 | 佛山市顺德区中山大学研究院 | A kind of preparation method and applications of the graphene zinc oxide micro-nano grading function material with automatically cleaning super lyophoby characteristic |
| CN108486544B (en) * | 2018-02-08 | 2020-06-05 | 佛山市顺德区中山大学研究院 | Preparation method and application of graphene zinc oxide micro-nano grading functional material with self-cleaning and super-lyophobic characteristics |
| CN109239154A (en) * | 2018-08-23 | 2019-01-18 | 哈尔滨理工大学 | A kind of preparation and application of zinc oxide nano popped rice-graphene composite material |
| CN109239154B (en) * | 2018-08-23 | 2020-11-06 | 哈尔滨理工大学 | Preparation and application of zinc oxide nano-flower-graphene composite material |
| CN109599534A (en) * | 2018-11-29 | 2019-04-09 | 西交利物浦大学 | Nanometer flower-shaped silicon copper electrode material based on graphene and the preparation method and application thereof |
| CN109599534B (en) * | 2018-11-29 | 2021-04-27 | 西交利物浦大学 | Graphene-based nano flower-shaped silicon-copper alloy electrode material and preparation method and application thereof |
| CN111024792A (en) * | 2020-01-07 | 2020-04-17 | 哈尔滨理工大学 | Electrochemical sensing electrode based on flower-like zinc oxide @ ferrocene functionalized three-dimensional graphene |
| CN111024792B (en) * | 2020-01-07 | 2023-04-25 | 哈尔滨理工大学 | Electrochemical sensing electrode based on flower-like zinc oxide@ferrocene functionalized three-dimensional graphene |
| CN114544725A (en) * | 2020-11-25 | 2022-05-27 | 五鼎生物技术股份有限公司 | Biochemical test piece |
| CN114512681A (en) * | 2022-01-29 | 2022-05-17 | 辽宁大学 | Electrode material for biofuel cell and preparation method and application thereof |
| CN114512681B (en) * | 2022-01-29 | 2024-02-20 | 辽宁大学 | Electrode material for biofuel cell and preparation method and application thereof |
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