CN107311537B - High-hardness heat-preservation multifunctional soft porcelain decorative material and preparation method thereof - Google Patents

High-hardness heat-preservation multifunctional soft porcelain decorative material and preparation method thereof Download PDF

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CN107311537B
CN107311537B CN201710538256.1A CN201710538256A CN107311537B CN 107311537 B CN107311537 B CN 107311537B CN 201710538256 A CN201710538256 A CN 201710538256A CN 107311537 B CN107311537 B CN 107311537B
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soft porcelain
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徐实现
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Wan Zhuo (jiangsu) New Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/023Fired or melted materials
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Finishing Walls (AREA)

Abstract

The invention discloses a high-hardness heat-preservation multifunctional soft porcelain decorative material, which is mainly characterized in that a first layer of soft porcelain material contains a far infrared ceramic material, a second layer of soft porcelain material contains anion powder, and glass fiber mesh cloth attached with low-temperature heating wires is laid below the second layer. According to the invention, through setting the structure of the soft porcelain material, the hardness of the soft porcelain material can be obviously improved, meanwhile, the soft porcelain material is endowed with certain heat preservation and heating functions, and through the design of the ingredients, the mechanical property of the soft porcelain material can be improved.

Description

High-hardness heat-preservation multifunctional soft porcelain decorative material and preparation method thereof
Technical Field
The invention belongs to the field of building decoration materials, and relates to a preparation method of a high-hardness heat-preservation multifunctional soft porcelain decoration material.
Background
the soft porcelain is a novel flexible planar decorative material, is obtained by molding and processing water-based polymer emulsion and inorganic substances such as cement, soil, quartz sand or mineral powder and the like, and is an ecological environment-friendly building material. The appearance of the soft porcelain is exactly like the porcelain, but the soft porcelain lacks the ice-cold, heavy and fragile texture of the traditional ceramic material, has the characteristics of light weight, thin body, water and air permeability, natural color, various patterns, flexibility, elasticity and the like, is easy to cut and paste, has low cost and convenient construction, is suitable for building decoration of external walls, internal walls, ground and the like, and greatly enriches and beautifies the living and working environments of people.
with the development of the technology, people develop various and colorful soft porcelain materials such as stone imitation materials, leather imitation patterns, wood imitation grains and the like in succession, and the soft porcelain materials meet the requirement of building nature returning. Along with the improvement of living standard of people, the requirements of people on living environment are higher and higher, such as the requirements of odor elimination, bacteriostasis, antibiosis, warmness, comfort and the like. In addition, the soft porcelain material with smooth surface has good hand feeling and is more graded in decoration. There have been many studies on soft porcelain in the prior art, but few reports have been made on the multifunction and excellent mechanical properties of soft porcelain materials.
In the prior published documents, for example, patent application publication No. CN101823860A discloses a high-strength reactive powder fiber concrete panel and a method for manufacturing the same, in which fibers are directly mixed with a slurry, and the surface of the prepared panel is rough and is not a decorative material.
Patent application publication No. CN104831891A discloses a composite ceramic board facing integrated board using glass fiber as a roll, and does not mention how to prepare a board, which has a surface not smooth enough and has the problems of uneven mixing and undesirable strength.
At present, most of soft porcelain materials on the market have relatively poor strength, the surface hardness of the soft porcelain materials is low, the soft porcelain materials are easy to scrape flowers, meanwhile, the soft porcelain materials with the heating function are rarely seen on the market, and in addition, when the soft porcelain materials are prepared, the production cost of the multifunctional soft porcelain materials is high.
Disclosure of Invention
In order to solve the problems in the prior art, the invention prepares a high-hardness heat-preservation multifunctional soft porcelain decorative material, so that the material has the functions of far infrared and generating negative ions under the condition of not losing mechanical properties, obviously reduces the production cost, and has the function of relieving heat.
A preparation method of a high-hardness heat-preservation multifunctional soft porcelain decorative material is characterized by comprising the following steps:
preparing an emulsion in step (1): adding 20-30 parts of silicone-acrylic emulsion and 1-3 parts of inorganic pigment into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material;
Preparing a far infrared ceramic powder layer in the step (2): adding 10-20 parts of far infrared ceramic powder, 5-30 parts of cement, 25-35 parts of quartz sand and 1-3 parts of coupling agent into a kneader and uniformly mixing to obtain first mixed powder;
preparing a negative ion powder layer: adding 10-20 parts of anion powder, 5-30 parts of cement, 25-35 parts of quartz sand and 1-3 parts of coupling agent into a kneader and uniformly mixing to obtain second mixed powder;
preparing a mixed material in the step (4): adding the first mixed powder obtained in the step (2) into the mixed emulsion material obtained in the step (1), and stirring to obtain a first mixed material; adding the second mixed powder obtained in the step (3) into the mixed emulsion material obtained in the step (1), and stirring to obtain a second mixed material;
Step (5) moulding: pouring the first mixed material into a mold, pouring 1/4-1/2 of the total amount of the mold, pouring the second mixed material after the materials are naturally dried, filling the mold, and laying glass fiber mesh containing a low-temperature heating wire;
and (6) sending the mould into an oven, curing, forming, drying and demoulding to obtain the multifunctional soft porcelain decorative material with smooth surface and high strength.
in the process of curing and forming the soft porcelain material, due to the volatilization of the solvent, certain gaps actually exist in the structure of the soft porcelain material, and small molecules such as air and the like can pass through the micro holes in the soft porcelain material, so that the negative ions generated by the negative ion powder can be released out of the structure of the soft porcelain material through the holes.
The soft porcelain material prepared by the invention comprises two layers, a far infrared ceramic layer contacted with air and an anion layer between the far infrared ceramic layer and the glass fiber mesh cloth of the low-temperature heating wire, the arrangement can ensure that the radiation efficiency released by the far infrared layer is higher, simultaneously, the surface hardness of the soft porcelain material can be improved due to the high hardness of the far infrared ceramic material, and simultaneously, the anions generated by the anion layer can be released out of the soft porcelain structure due to the existence of gaps of the soft porcelain material. And (3) respectively preparing the far infrared ceramic powder and the anion powder into two mixed powder materials, so that the concentration of the mixed powder materials in each layer is increased, the far infrared ceramic powder or the anion powder is less when the same far infrared heat preservation performance or the same anion generation amount is achieved, and the preparation cost can be obviously reduced.
The particle size of the far infrared ceramic powder selected by the invention is 50-150 nanometers, and the particle size of the anion powder is 100-500 nanometers.
The far infrared ceramic powder with a smaller grain diameter is selected, the apparent regularity of the soft ceramic material can be improved, and meanwhile, the mechanical property of the soft ceramic material is improved to a certain extent due to the interface effect of the nano particles.
In the process of mixing materials, the mechanical property of the soft porcelain material can be influenced by the use amount of the mixed emulsion material and the mixed powder, the mass ratio of the first mixed powder to the mixed emulsion material in the step (4) is 1:0.8-1, and the mass ratio of the second mixed powder to the mixed emulsion material is 1: 0.8-1.
When the main components in the slurry are different, the miscibility of the slurry is reduced, and when the layered soft porcelain material is prepared, the components in the two slurries have larger difference, the generated layering phenomenon is obvious, and the mechanical property of the soft porcelain material is reduced.
specifically, the cement, quartz sand and coupling agent in the first mixed powder obtained in the step (2) and the second mixed powder in the step (3) are used in the same amount, and the far infrared ceramic powder in the step (2) and the negative ion powder in the step (3) are used in the same amount.
The invention also uses the glass fiber gridding cloth of the low-temperature heating wire to endow the soft porcelain material with certain capability of converting electric energy into heat energy, wherein the thickness of the glass fiber gridding cloth of the low-temperature heating wire in the step (5) is less than 2mm, and the arrangement can ensure that the thickness of the soft porcelain material is moderate and can achieve better heating performance. .
And (5) heating wires in the glass fiber mesh cloth of the low-temperature heating wire in the step (5) are one or two of iron-chromium-aluminum or nickel-chromium heating wires.
The temperature and time of curing will have an effect on the production cost, and it is preferred in the present invention that the curing conditions in step (6) are curing at 110 ℃ and 130 ℃ for 10-20 minutes.
The light soft porcelain decorative material with adjustable humidity, which is prepared by adopting the technical scheme, has the following advantages:
by designing the same dosage of quartz sand and cement in the first mixed powder and the second mixed powder, the mechanical property of the soft porcelain material is enhanced, and the surface of the prepared soft porcelain material is smooth; the soft porcelain material prepared by the scheme of the invention has higher hardness, because the appearance of the soft porcelain material is rich in far infrared ceramic powder, the particle structure is small, the hardness is improved, and meanwhile, the thermal performance of the material can be obviously improved by the far infrared powder; in addition, the soft porcelain material is rich in a hole structure, so that the negative ion release performance of the soft porcelain material cannot be greatly influenced due to layered arrangement.
Detailed Description
The technical solution of the present invention will be further described with reference to the following embodiments.
Example 1
A preparation method of a multifunctional soft porcelain decorative material with smooth surface and high strength is characterized by comprising the following steps:
Preparing an emulsion in step (1): and adding 25 parts of silicone-acrylic emulsion and the inorganic pigment 3 into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material.
Preparing a far infrared ceramic powder layer in the step (2): and adding 15 parts of far infrared ceramic powder, 20 parts of cement, 25 parts of quartz sand and 2 parts of coupling agent into a kneader and uniformly mixing to obtain first mixed powder.
preparing a negative ion powder layer: and adding 15 parts of anion powder, 20 parts of cement, 25 parts of quartz sand and 2 parts of coupling agent into a kneader and uniformly mixing to obtain second mixed powder.
Preparing a mixed material in the step (4): adding the first mixed powder obtained in the step (2) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the first mixed powder to the mixed emulsion material is 1:1, and stirring to obtain a first mixed material; adding the second mixed powder obtained in the step (3) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the second mixed powder to the mixed emulsion material is 1:1, and stirring to obtain a second mixed material;
and (5) molding, pouring the first mixed material into a mold, wherein the pouring amount is 1/2 of the total amount of the mold, pouring the second mixed material after the materials are naturally dried, filling the mold, and laying glass fiber mesh cloth containing a low-temperature heating wire.
And (6) sending the mould into an oven, curing, forming, drying and demoulding to obtain the multifunctional soft porcelain decorative material with smooth surface and high strength.
Example 2
A preparation method of a multifunctional soft porcelain decorative material with smooth surface and high strength is characterized by comprising the following steps:
Preparing an emulsion in step (1): and adding 25 parts of silicone-acrylic emulsion and the inorganic pigment 3 into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material.
Preparing a far infrared ceramic powder layer in the step (2): and adding 20 parts of far infrared ceramic powder, 20 parts of cement, 25 parts of quartz sand and 2 parts of coupling agent into a kneader and uniformly mixing to obtain first mixed powder.
Preparing a negative ion powder layer: and adding 20 parts of anion powder, 20 parts of cement, 25 parts of quartz sand and 2 parts of coupling agent into a kneader and uniformly mixing to obtain second mixed powder.
Preparing a mixed material in the step (4): adding the first mixed powder obtained in the step (2) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the first mixed powder to the mixed emulsion material is 1:0.8, and stirring to obtain a first mixed material; adding the second mixed powder obtained in the step (3) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the second mixed powder to the mixed emulsion material is 1:0.8, and stirring to obtain a second mixed material;
And (5) molding, pouring the first mixed material into a mold, wherein the pouring amount is 1/2 of the total amount of the mold, pouring the second mixed material after the materials are naturally dried, filling the mold, and laying glass fiber mesh cloth containing a low-temperature heating wire.
And (6) sending the mould into an oven, curing, forming, drying and demoulding to obtain the multifunctional soft porcelain decorative material with smooth surface and high strength.
Example 3
A preparation method of a multifunctional soft porcelain decorative material with smooth surface and high strength is characterized by comprising the following steps:
Preparing an emulsion in step (1): and adding 25 parts of silicone-acrylic emulsion and the inorganic pigment 3 into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material.
Preparing a far infrared ceramic powder layer in the step (2): and adding 15 parts of far infrared ceramic powder, 25 parts of cement, 30 parts of quartz sand and 2 parts of coupling agent into a kneader and uniformly mixing to obtain first mixed powder.
Preparing a negative ion powder layer: and adding 15 parts of anion powder, 15 parts of cement, 20 parts of quartz sand and 2 parts of coupling agent into a kneader and uniformly mixing to obtain second mixed powder.
Preparing a mixed material in the step (4): adding the first mixed powder obtained in the step (2) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the first mixed powder to the mixed emulsion material is 1:0.8, and stirring to obtain a first mixed material; adding the second mixed powder obtained in the step (3) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the second mixed powder to the mixed emulsion material is 1:0.8, and stirring to obtain a second mixed material;
And (5) molding, pouring the first mixed material into a mold, wherein the pouring amount is 1/4 of the total amount of the mold, pouring the second mixed material after the materials are naturally dried, filling the mold, and laying glass fiber mesh cloth containing a low-temperature heating wire.
and (6) sending the mould into an oven, curing, forming, drying and demoulding to obtain the multifunctional soft porcelain decorative material with smooth surface and high strength.
Example 4
A preparation method of a multifunctional soft porcelain decorative material with smooth surface and high strength is characterized by comprising the following steps:
Preparing an emulsion in step (1): and adding 25 parts of silicone-acrylic emulsion and the inorganic pigment 3 into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material.
Preparing a far infrared ceramic powder layer in the step (2): and adding 15 parts of far infrared ceramic powder, 20 parts of cement, 25 parts of quartz sand and 2 parts of coupling agent into a kneader and uniformly mixing to obtain first mixed powder.
Preparing a negative ion powder layer: and adding 15 parts of anion powder, 20 parts of cement, 25 parts of quartz sand and 2 parts of coupling agent into a kneader and uniformly mixing to obtain second mixed powder.
Preparing a mixed material in the step (4): adding the first mixed powder obtained in the step (2) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the first mixed powder to the mixed emulsion material is 1:0.8, and stirring to obtain a first mixed material; adding the second mixed powder obtained in the step (3) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the second mixed powder to the mixed emulsion material is 1:1, and stirring to obtain a second mixed material;
and (5) molding, pouring the first mixed material into a mold, wherein the pouring amount is 1/2 of the total amount of the mold, pouring the second mixed material after the materials are naturally dried, filling the mold, and laying glass fiber mesh cloth containing a low-temperature heating wire.
And (6) sending the mould into an oven, curing, forming, drying and demoulding to obtain the multifunctional soft porcelain decorative material with smooth surface and high strength.
Comparative example 1
The preparation method of the soft porcelain decorative material is characterized by comprising the following steps:
And (1) adding 25 parts of silicone-acrylic emulsion and inorganic pigment 2 into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material.
And (2) adding 25 parts of cement, 30 parts of quartz sand and 2 parts of coupling agent into a kneader, and uniformly mixing to obtain mixed powder.
adding the obtained mixed powder into the obtained mixed emulsion material, and stirring in a stirrer to obtain a mixed material;
Pouring the mixed material into a mold;
And (5) sending the mould into an oven, curing, forming, drying and demoulding to obtain the soft porcelain decorative material.
Comparative example 2
a preparation method of a multifunctional soft porcelain decorative material with smooth surface and high strength is characterized by comprising the following steps:
Preparing an emulsion in step (1): and adding 25 parts of silicone-acrylic emulsion and the inorganic pigment 3 into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material.
Preparing a far infrared ceramic powder layer in the step (2): and adding 15 parts of far infrared ceramic powder, 15 parts of anion powder, 40 parts of cement, 50 parts of quartz sand and 4 parts of coupling agent into a kneader and uniformly mixing to obtain mixed powder.
Preparing a mixed material in the step (3): adding the mixed powder obtained in the step (2) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the first mixed powder to the mixed emulsion material is 1:0.8, and stirring to obtain a mixed material;
and (4) molding, pouring the first mixed material into a mold, filling the mold, and laying glass fiber mesh cloth containing a low-temperature heating wire.
And (5) sending the mould into an oven, curing, forming, drying and demoulding to obtain the multifunctional soft porcelain decorative material with smooth surface and high strength.
Comparative example 3
A preparation method of a multifunctional soft porcelain decorative material with smooth surface and high strength is characterized by comprising the following steps:
preparing an emulsion in step (1): and adding 25 parts of silicone-acrylic emulsion and the inorganic pigment 3 into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material.
Preparing a far infrared ceramic powder layer in the step (2): and adding 15 parts of far infrared ceramic powder, 15 parts of anion powder, 40 parts of cement, 50 parts of quartz sand and 4 parts of coupling agent into a kneader and uniformly mixing to obtain mixed powder.
Preparing a mixed material in the step (3): adding the mixed powder obtained in the step (2) into the mixed emulsion material obtained in the step (1), wherein the mass ratio of the first mixed powder to the mixed emulsion material is 1:0.8, and stirring to obtain a mixed material;
And (4) molding, pouring the first mixed material into a mold, and filling the mold.
and (5) sending the mould into an oven, curing, forming, drying and demoulding to obtain the multifunctional soft porcelain decorative material with smooth surface and high strength.
the performance test method comprises the following steps:
and (3) testing mechanical properties: the products obtained in examples 1 to 4 and comparative examples 1 to 3 were subjected to a performance test, the breaking strength was measured by a strength test apparatus, and the density of the soft porcelain material was measured by a density tester.
and (3) far infrared performance test, namely irradiating the soft porcelain material for 10 minutes by using an infrared light source, observing the apparent temperature change of the soft porcelain material, testing the initial temperature to be 25 ℃, and characterizing the far infrared performance as T-T x -25, wherein T x represents the temperature after ten minutes of radiation.
The negative ion floor detector measures the negative ion release performance, and the tester model is IT-10, Shenzhen Shenqin Wanji science and technology Limited.
The hardness of the soft porcelain is measured by the Mohs hardness method.
table 1 shows the mechanical properties and the apparent states of the soft porcelain materials
TABLE 1
From the comparison results of the comparative example and the example, it can be seen that when the amounts of quartz sand and cement in the first mixed powder and the second mixed powder are the same, the mechanical properties of the soft porcelain material are enhanced, and the surface of the prepared soft porcelain material is smooth, mainly because the particle size of the used far infrared ceramic powder is smaller, the appearance of the soft porcelain material can be improved; the soft porcelain material prepared by the scheme of the invention has higher hardness, because the surface layer of the soft porcelain material is rich in far infrared ceramic powder, the particle structure is small, the hardness is improved, and meanwhile, the thermal performance of the material can be obviously improved by the far infrared powder; in addition, the soft porcelain material of the example and the comparative example has a structure rich in pores, so that the negative ion release performance of the soft porcelain material is comparable.

Claims (8)

1. A preparation method of a high-hardness heat-preservation multifunctional soft porcelain decorative material is characterized by comprising the following steps:
Preparing an emulsion in step (1): adding 20-30 parts of silicone-acrylic emulsion and 1-3 parts of inorganic pigment into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material;
Preparing a far infrared ceramic powder layer in the step (2): adding 10-20 parts of far infrared ceramic powder, 5-30 parts of cement, 25-35 parts of quartz sand and 1-3 parts of coupling agent into a kneader and uniformly mixing to obtain first mixed powder;
Preparing a negative ion powder layer: adding 10-20 parts of anion powder, 5-30 parts of cement, 25-35 parts of quartz sand and 1-3 parts of coupling agent into a kneader and uniformly mixing to obtain second mixed powder;
preparing a mixed material in the step (4): adding the first mixed powder obtained in the step (2) into the mixed emulsion material obtained in the step (1), and stirring to obtain a first mixed material; adding the second mixed powder obtained in the step (3) into the mixed emulsion material obtained in the step (1), and stirring to obtain a second mixed material;
Step (5) moulding: pouring the first mixed material into a mold, pouring 1/4-1/2 of the total amount of the mold, pouring the second mixed material after the materials are naturally dried, filling the mold, and laying glass fiber mesh containing a low-temperature heating wire;
And (6) sending the mould into an oven, curing, forming, drying and demoulding to obtain the multifunctional soft porcelain decorative material with smooth surface and high strength.
2. The preparation method of the high-hardness heat-preservation multifunctional soft porcelain decoration material as claimed in claim 1, is characterized in that: in the step (4), the mass ratio of the first mixed powder to the mixed emulsion material is 1:0.8-1, and the mass ratio of the second mixed powder to the mixed emulsion material is 1: 0.8-1.
3. the preparation method of the high-hardness heat-preservation multifunctional soft porcelain decoration material as claimed in claim 1, is characterized in that: and (3) the first mixed powder obtained in the step (2) and the second mixed powder obtained in the step (3) have the same dosage of cement, quartz sand and coupling agent.
4. The preparation method of the high-hardness heat-preservation multifunctional soft porcelain decoration material as claimed in claim 3, is characterized in that: the far infrared ceramic powder in the step (2) and the second anion powder in the step (3) are the same in dosage.
5. The preparation method of the high-hardness heat-preservation multifunctional soft porcelain decoration material as claimed in claim 1, is characterized in that: and (5) the thickness of the glass fiber mesh cloth of the low-temperature heating wire in the step (5) is less than 2 mm.
6. The preparation method of the high-hardness heat-preservation multifunctional soft porcelain decoration material as claimed in claim 1, is characterized in that: and (5) heating wires in the glass fiber mesh cloth of the low-temperature heating wire in the step (5) are one or two of iron-chromium-aluminum or nickel-chromium heating wires.
7. the preparation method of the high-hardness heat-preservation multifunctional soft porcelain decoration material as claimed in claim 1, is characterized in that: the curing condition in the step (6) is curing at 110-130 ℃ for 10-20 minutes.
8. A high-hardness heat-insulating multifunctional soft porcelain decorative material prepared by the preparation method of any one of claims 1 to 6.
CN201710538256.1A 2017-07-04 2017-07-04 High-hardness heat-preservation multifunctional soft porcelain decorative material and preparation method thereof Active CN107311537B (en)

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