CN107311513A - A kind of heat-preserving dry-mixed mortar base-material and preparation method thereof - Google Patents

A kind of heat-preserving dry-mixed mortar base-material and preparation method thereof Download PDF

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Publication number
CN107311513A
CN107311513A CN201710741974.9A CN201710741974A CN107311513A CN 107311513 A CN107311513 A CN 107311513A CN 201710741974 A CN201710741974 A CN 201710741974A CN 107311513 A CN107311513 A CN 107311513A
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CN
China
Prior art keywords
parts
heat
red mud
rare earth
dry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710741974.9A
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Chinese (zh)
Inventor
马志涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Sheng Sheng Building Insulation Engineering Co Ltd
Original Assignee
Henan Sheng Sheng Building Insulation Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Sheng Sheng Building Insulation Engineering Co Ltd filed Critical Henan Sheng Sheng Building Insulation Engineering Co Ltd
Priority to CN201710741974.9A priority Critical patent/CN107311513A/en
Publication of CN107311513A publication Critical patent/CN107311513A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials

Abstract

The present invention provides a kind of heat-preserving dry-mixed mortar base-material and preparation method thereof, it is related to thermal insulation mortar field, red mud and half rare earth pulvis will be added water to form slurry, and add fixedness acid solution and be adjusted, slurry pH value is adjusted standby to dry milling after 78, then red mud, rare earth pulvis mixed-powder made from limestone powder, re-dispersible glue powder and powdered anticracking additive, second half rare earth pulvis and step are mixed into i.e. obtained heat-preserving dry-mixed mortar base-material.Red mud is effectively utilized, red mud comprehensive utilization is inadequate, existing heat-preserving dry-mixed mortar base-material is produced can not meet two technical problems the need for people while solving.Add water when using, the components such as the CaO in Y2O3, La2O3, Sm2O3, La2O3, Fe2O3 and lime stone in rare earth pulvis can produce gas after reacting to each other, form the stomata of closing, so that there is uniform sealed porosity using the warming plate of product of the present invention, uniform insulated cavity is formed, so that heat-insulating property is good.

Description

A kind of heat-preserving dry-mixed mortar base-material and preparation method thereof
Technical field
The present invention relates to thermal insulation mortar field, and in particular to a kind of heat-preserving dry-mixed mortar base-material and preparation method thereof.
Background technology
Main component is used for Al2O3、SiO2Gangue, during the thick desiliconization of flyash prepares aluminium hydroxide, can produce A large amount of red muds, but in actual production, actual production for many years is found, and it is less than 3 for alumina silica ratio:1 even below 2:1 low product Position aluminium ore production, if being produced again with this proportioning, aluminium recovery is low, and productivity effect is low, but China's alum clay resource is more It is less than 3 for alumina silica ratio:1 even below 2:1 low-grade Al materials, so that it cannot develop;Simultaneously before silicone content is high Put, high calcium causes to produce more red mud amounts than auxiliary material, while because substantial amounts of alkaline matter is added, causing production Raw red mud is the high alkalinity red mud for being difficult to apply, and then pollutes environment.
The country having at present red mud is discharged into it is marine, but because of the Marine Pollution containing harmful substances such as alkali, harm fishery life Production.What is had is stacked on land, takes farmland, pollutes water system, is waved with the wind after drying, and air is polluted again;Received for the pin of red mud What is mainly taken is the method that disposal is stacked on seabed or land, but with the development of aluminum i ndustry, the red mud of production aluminum oxide discharge Amount also increasingly increases, and stores up the brought a series of problems of disposal and goes out therewith, causes serious environmental problem;Red mud is in heap During putting in addition to taking a large amount of soils, due also to the chemical composition in red mud, which infiltrates soil, easily causes soil alkalization, underground Water pollution, these materials of people's taken long-term, will necessarily influence healthy.The major pollutants of red mud are alkali, fluoride, sodium And aluminium etc., its content is higher, exceeded discharge standard as defined in China national (《Non-ferrous metals industry solid waste pollution is controlled Standard》GB5058-85).
Now, China is to the utilization substantially vacancy of red mud, and constantly aluminium ore, which is developed, promotes the volume of cargo in storage of red mud constantly to increase Greatly, the environmental pollution caused is increasingly severe, red mud comprehensive utilization is turned into one urgent need to solve the problem of aluminum smelting industry;And In modern development, the growth of population promotes people also growing to the demand of building, for extremely frigid zones, to insulation base The demand of material even more increasingly increases, the need for existing heat-preserving dry-mixed mortar base-material production can not meet people.
The content of the invention
The present invention provides a kind of heat-preserving dry-mixed mortar base-material and preparation method thereof, to solve above-mentioned red mud comprehensive utilization not Enough, existing heat-preserving dry-mixed mortar base-material production can not meet technical problem the need for people.
To solve the above problems, the technical solution adopted by the present invention is as follows:
A kind of heat-preserving dry-mixed mortar base-material, is made up of the component of following parts by weight:
25-30 parts of red mud;
5-10 parts of lime stone;
5-10 parts of rare earth pulvis;
3-5 parts of re-dispersible glue powder;
Powdered 3-5 parts of anticracking additive.
Preferably, the powdered anticracking additive is made up of the component of following parts by weight:
Carbon conjugated triene-the 9,11,13- of epoxidation 18 5-10 parts of glyceryl esters of acid;
2-3 parts of lignocellulosic;
2-3 parts of HEMA;
1-2 parts of dibutyl tin laurate.
A kind of preparation method of heat-preserving dry-mixed mortar base-material, comprises the following steps:
(1) red mud and half rare earth pulvis are added water to form slurry, and adds fixedness acid solution and be adjusted, by slurry It is standby that pH value adjusts to 7-8 dry milling;
(2) by limestone powder, re-dispersible glue powder and powdered anticracking additive, second half rare earth pulvis and step (1) red mud powder made from, which is mixed, is made heat-preserving dry-mixed mortar base-material.
In summary, by adopting the above-described technical solution, the beneficial effects of the invention are as follows:
(1) in the present invention, red mud is effectively utilized, while solving red mud comprehensively utilizes inadequate, existing heat insulation dry-mixing sand Slurry base-material production can not meet two technical problems the need for people;
(2) red mud contains Al2O3, because the component in rare earth pulvis such as Y2O3, La2O3, Sm2O3 etc. are good surfaces Active material, can improve the wettability of the red mud containing Al2O3, so in preparation process, can promote red mud fully and water Uniform sizing material is combined to form, is easy to even regulation pH value;
(3) add water in use, CaO in Y2O3, La2O3, Sm2O3, La2O3, Fe2O3 and lime stone in rare earth pulvis Gas can be produced after being reacted to each other etc. component, the stomata of closing is formed so that is had using the warming plate of product of the present invention uniform Sealed porosity, uniform insulated cavity is formed, so that heat-insulating property is good;
(4) the carbon conjugated triene -9,11,13- of epoxidation 18 acid glyceryl ester is by illumination in powdered anticracking additive Curable and viscous stickiness excellent, using this product, can be such that building was dried in 24 hours, substantially reduce drying time, The splendid viscous stickiness of the carbon conjugated triene -9,11,13- of epoxidation 18 acid glyceryl esters plays excellent bonding effect to each component Really, so as to prevent cracking, adapt to require high building to cracking resistance completely;Whole only to add water using process, product is without having Evil waste is produced, extremely friendly to environment;Preparation method is simple, and production cost is low, can produce and apply extensively.
Embodiment
All features disclosed in this specification, can be with any in addition to mutually exclusive feature and/or step Mode is combined.
Embodiment 1
Produce 100 kilograms of powdered anticracking additives, then by the carbon conjugated triene -9,11 of epoxidation 18,13- acid triglycerins 50 kilograms of ester (5 parts by weight), 20 kilograms of lignocellulosic (2 parts by weight), 20 kilograms of (2 weight of HEMA Part) and 10 kilograms of dibutyl tin laurate (1 parts by weight) be put into mixer dry-mixed uniform (mixed 20 minutes or so) Anticracking additive.
500 kilograms of heat-preserving dry-mixed mortar base products of the present invention are produced, then by 300 kilograms of red mud, 30 kilograms of rare earth pulvis Add water to form slurry, and add fixedness acid solution and be adjusted, slurry pH value is adjusted to 7-8 into dry milling obtains powder End, and the powder and 50 kilograms of lime stone, 30 kilograms of rare earth pulvis, 50 kilograms of re-dispersible glue powder, powdered anticracking are added 40 kilograms of agent mixing finished product.
Embodiment 2
128 kilograms of powdered anticracking additives are produced, then respectively by the carbon conjugated triene -9,11 of epoxidation 18,13- acid three 80 kilograms of glyceride (10 parts by weight), 24 kilograms of lignocellulosic (3 parts by weight), 16 kilogram (2 of HEMA Parts by weight) and 8 kilograms of dibutyl tin laurate (1 parts by weight) be put into mixer dry-mixed uniform (mixed 20 minutes or so) i.e. Into finished product.
500 kilograms of heat-preserving dry-mixed mortar base products of the present invention are produced, then by 250 kilograms of red mud, 50 kilograms of rare earth pulvis Add water to form slurry, and add fixedness acid solution and be adjusted, slurry pH value is adjusted to 7-8 into dry milling obtains powder End, and the powder and 50 kilograms of lime stone, 50 kilograms of rare earth pulvis, 50 kilograms of re-dispersible glue powder, powdered anticracking are added 50 kilograms of agent mixing finished product.
Embodiment 3
The warming plate specification with existing sale is made in heat-preserving dry-mixed mortar base product obtained by embodiment 1, embodiment 2 Size identical warming plate, tests its heat-insulating property, and test process is as follows:
Three pieces of warming plates are uniformly placed on to the edge of logical one circular test board, and in the centre position of circular test board The fireworks of sustained combustion are placed, every the inside and outside wall temperature of the three pieces of warming plates of test in 10 minutes.
Final heat-insulating property test result such as table 1.
The heat-insulating property test result of table 1
The specific implementation of the invention is not to be limited to these illustrations for above content, is led for technology belonging to the present invention For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, The scope of patent protection that the present invention is determined by the claims submitted should be all considered as belonging to.

Claims (3)

1. a kind of heat-preserving dry-mixed mortar base-material, it is characterised in that be made up of the component of following parts by weight:
25-30 parts of red mud;
5-10 parts of lime stone;
5-10 parts of rare earth pulvis;
3-5 parts of re-dispersible glue powder;
Powdered 3-5 parts of anticracking additive.
2. a kind of heat-preserving dry-mixed mortar base-material as claimed in claim 1, it is characterised in that the powdered anticracking additive by The component composition of following parts by weight:
Carbon conjugated triene-the 9,11,13- of epoxidation 18 5-10 parts of glyceryl esters of acid;
2-3 parts of lignocellulosic;
2-3 parts of HEMA;
1-2 parts of dibutyl tin laurate.
3. a kind of preparation method of heat-preserving dry-mixed mortar base-material as claimed in claim 1 or 2, it is characterised in that including as follows Step:
(1) red mud and half rare earth pulvis are added water to form slurry, and adds fixedness acid solution and be adjusted, by slurry pH value Regulation is standby to dry milling after 7-8;
(2) by limestone powder, re-dispersible glue powder and powdered anticracking additive, second half rare earth pulvis and step (1) Obtained red mud powder, which is mixed, is made heat-preserving dry-mixed mortar base-material.
CN201710741974.9A 2017-08-25 2017-08-25 A kind of heat-preserving dry-mixed mortar base-material and preparation method thereof Pending CN107311513A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710741974.9A CN107311513A (en) 2017-08-25 2017-08-25 A kind of heat-preserving dry-mixed mortar base-material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710741974.9A CN107311513A (en) 2017-08-25 2017-08-25 A kind of heat-preserving dry-mixed mortar base-material and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107311513A true CN107311513A (en) 2017-11-03

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102299121A (en) * 2011-05-20 2011-12-28 电子科技大学 Method for packaging photoelectronic device
CN102336553A (en) * 2010-07-26 2012-02-01 贵州中建建筑科研设计院有限公司 Preparation method of composite insulating mortar with red mud as a water-retaining thickener
CN105294013A (en) * 2015-11-25 2016-02-03 诸暨市兆山天峰干混砂浆有限公司 Dry mixing building mortar

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102336553A (en) * 2010-07-26 2012-02-01 贵州中建建筑科研设计院有限公司 Preparation method of composite insulating mortar with red mud as a water-retaining thickener
CN102299121A (en) * 2011-05-20 2011-12-28 电子科技大学 Method for packaging photoelectronic device
CN105294013A (en) * 2015-11-25 2016-02-03 诸暨市兆山天峰干混砂浆有限公司 Dry mixing building mortar

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Application publication date: 20171103