CN107311390A - The processing method of port cabin washing wastewater - Google Patents

The processing method of port cabin washing wastewater Download PDF

Info

Publication number
CN107311390A
CN107311390A CN201610408751.6A CN201610408751A CN107311390A CN 107311390 A CN107311390 A CN 107311390A CN 201610408751 A CN201610408751 A CN 201610408751A CN 107311390 A CN107311390 A CN 107311390A
Authority
CN
China
Prior art keywords
washing wastewater
cabin washing
processing
port cabin
waste water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610408751.6A
Other languages
Chinese (zh)
Inventor
陈金合
慕晶霞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Chemical Corp
Sinopec Qingdao Safety Engineering Institute
Original Assignee
China Petroleum and Chemical Corp
Sinopec Qingdao Safety Engineering Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Chemical Corp, Sinopec Qingdao Safety Engineering Institute filed Critical China Petroleum and Chemical Corp
Priority to CN201610408751.6A priority Critical patent/CN107311390A/en
Publication of CN107311390A publication Critical patent/CN107311390A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/008Originating from marine vessels, ships and boats, e.g. bilge water or ballast water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/02Temperature
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/44Time
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/08Aerobic processes using moving contact bodies
    • C02F3/085Fluidized beds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/104Granular carriers
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/105Characterized by the chemical composition
    • C02F3/107Inorganic materials, e.g. sand, silicates

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The present invention relates to a kind of processing method of port cabin washing wastewater, mainly solve easily to pollute in the prior art, the problem of economy is bad.The present invention is by using a kind of processing method of port cabin washing wastewater, sequentially pass through regulating reservoir processing, the technical scheme that biological fluidized bed is handled, ozonation aerated biofilter integrated apparatus is handled and preferably solve above mentioned problem, available in the processing of port cabin washing wastewater.

Description

The processing method of port cabin washing wastewater
Technical field
The present invention relates to a kind of processing method of port cabin washing wastewater.
Background technology
Harbor chemical wastewater means that Liquid Chemicals in Bulk cargo ship needs cleaning or change the sewage produced during cargo type (such as to wash Cabin, cleaning of evaporator etc.).Major pollutant in water is sweeping, the residual substance of cleaning of evaporator after unloading.The sewage is not only because it contains There are the chemicals for being difficult to biological treatment, the cleaning agent as used in styrene, acrylonitrile, formaldehyde, cleaning cabin, and Make wastewater flow rate and concentration that there is polytropy and randomness because dispersion single user wharf intermittent action, pollutant are various in style etc..One As it is thought that the larger waste water of a class intractability.
Domestic liquid chemical freight volume is larger for Shanghai, Ningbo, Dalian, α Cygni Port, and chemical wastewater is by code Head receive conveying tank field storage after enter wastewater treatment equipment, its wastewater treatment mainly using materialization-biochemistry combination process as Main, most of materialization uses air supporting, biochemical then have the techniques such as biomembrane, oxidation ditch according to different water quality.China's harbour gives up The processing of water has waste water processing station also in starting stage, only four Ports, according to the requirement of sustainable development, it is necessary to big The process range into harbor chemical wastewater is pushed, makes shipping safer, ocean is more cleaned.
Chinese patent application CN104355383A discloses a kind of composite flocculation agent solution for being used to handle harbor oil-containing wastewater, The formula of the flocculant solution is:Aluminum sulfate 4%-8%, ferric sulfate 4%-10% and chitosan 0.5%-2.5%.This hair The bright preparation method for also disclosing above-mentioned composite flocculation agent solution.Effect using present invention processing waste water is significantly larger than single type The treatment effect of flocculant, efficiency high, consumption is few, has the advantage of aluminum salt flocculant and Ferric Salt Flocculants concurrently, while having height Molecular flocculant consumption is few, flco is formed soon, the advantage that settling property is waited well, and compensate for that each component is single to be used It is not enough.It is particularly suitable for use in the coagulating treatment of harbor oil-containing wastewater, water ballast, tank washings.
It is more single for current handling process, it can only meet the processing requirement of specific water quality, Difficulty, and it is existing big Most harbour sewage disposal systems are big due to that can not adapt to chemical cleaning of evaporator water change of water quality, the characteristics of strong toxicity, cause harbour dirty Water treatment system, which can not be stablized, normally to be run.The characteristics of for current China's harbour chemicals cleaning of evaporator water, develop a kind of shock resistance Ability is strong, is adapted to the group technology of different chemical product waste water, reaches economic, efficient processing, disposable waste water is entered Row reuse, meets the trend of current construction conservation-minded society.
The content of the invention
The technical problems to be solved by the invention be easily pollute in the prior art, there is provided a kind of new the problem of economy is bad The processing method of port cabin washing wastewater.This method has the advantages that pollution-free, discharged wastewater met the national standard, good economy performance.
To solve the above problems, the technical solution adopted by the present invention is as follows:A kind of processing method of port cabin washing wastewater, including Following steps:
(1) regulating reservoir is handled:Port cabin washing wastewater enters regulating reservoir, and the COD of the port cabin washing wastewater is not less than 100 Mg/L, oil content is not less than 80mg/L, and SS (suspension) is not less than in 50mg/L, the port cabin washing wastewater regulating reservoir Residence time be 1-3d, 10-15 DEG C of regulating reservoir water temperature;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) enters biological fluidized bed, and hydraulic detention time is 2-3d (my god), gas-water ratio is 5-10:1;
(3) ozonation aerated biofilter integrated apparatus processing:Ozonation aerated biofilter integrated apparatus is by ozone oxidation system With BAF composition, the waste water after step (2) processing is stopped after 1~2h in intermediate regulations pond, exposed into ozone Gas biofilter integrated apparatus, ozone is mixed by pipeline dosing method with waste water, and ozone dosage is 300-500mg/L; Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 6~12h;
(4) discharged wastewater met the national standard after above-mentioned processing, COD is not more than 80mg/L, and oil content is not more than 0.5mg/L, SS is not more than 5mg/L.
In above-mentioned technical proposal, it is preferable that the filler of biological fluidized bed is used as carrier using haydite.
In above-mentioned technical proposal, it is preferable that the filler of BAF is used as carrier using haydite.
In above-mentioned technical proposal, it is preferable that the COD of the port cabin washing wastewater is 100-300mg/L, oil content is 80-400mg/L, SS are 50-100mg/L.
In above-mentioned technical proposal, it is preferable that the discharged wastewater met the national standard after step (4) processing, COD is 24-80mg/L, Oil content is 0.2-0.5mg/L, and SS is 2-5mg/L.
Present invention process is ripe, treatment effect is stable, there is good treatment effect, about 2.2 yuan of wastewater treatment expense to waste water /m3, after the group technology advanced treating, the water outlet of washing of tanks chemical wastewater can make fire-fighting, greening water, with good ring Border benefit and economic benefit, achieve preferable technique effect.
Below by embodiment, the invention will be further elaborated, but is not limited only to the present embodiment.
Embodiment
Embodiment 1
Monthly cleaning of evaporator waste water water is about 100t at Yangzhou harbour, and the COD (COD) of water inlet is 200-250mg/L, Oil content is 300mg/L, and SS (suspension) is 100mg/L.
(1) regulating reservoir is handled:Port cabin washing wastewater stops 1d, 10 DEG C of regulating reservoir water temperature in regulating reservoir;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) is pumped into biological fluidized bed, and hydraulic detention time is 2d, Gas-water ratio is 5:1;
(3) ozonation aerated biofilter integrated apparatus processing:Waste water after step (2) processing stops 1h in intermediate regulations pond Afterwards, ozonation aerated biofilter integrated apparatus is pumped into, ozone is mixed by pipeline dosing method with waste water, ozone dosage For 300mg/L;Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 6h.
The filler of biological fluidized bed is using haydite as carrier, and the filler of BAF is used as carrier using haydite.
The waste water COD of last gained is 80mg/L, and oil content is 0.5mg/L, and SS is 5mg/L, reaches country-level discharge Standard.
It is computed, wastewater treatment expense is 2.25 yuan/m3
Embodiment 2
Monthly cleaning of evaporator waste water water is about 300t at Zhuhai harbour, and the COD of water inlet is 100mg/L, and oil content is 400mg/L, SS is 60mg/L.
(1) regulating reservoir is handled:Stop 3d of the port cabin washing wastewater in regulating reservoir, 10 DEG C of regulating reservoir water temperature;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) is pumped into biological fluidized bed, and hydraulic detention time is 2-3d, Gas-water ratio is 10:1;
(3) ozonation aerated biofilter integrated apparatus processing:Waste water after step (2) processing stops 2h in intermediate regulations pond Afterwards, ozonation aerated biofilter integrated apparatus is pumped into, ozone is mixed by pipeline dosing method with waste water, ozone dosage For 500mg/L;Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 12h.
The waste water COD of last gained is 50mg/L, and oil content is 0.2mg/L, and SS is 2mg/L, reaches that country's life is used mixedly Water circulation standard, can be afforested, carwash, the reuse such as fire-fighting.
It is computed, wastewater treatment expense is 2.38 yuan/m3
Embodiment 3
According to the condition and step described in embodiment 1:
(1) regulating reservoir is handled:Port cabin washing wastewater stops 3d in regulating reservoir;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) is pumped into biological fluidized bed, and hydraulic detention time is 3d, Gas-water ratio is 10:1;
(3) ozonation aerated biofilter integrated apparatus processing:Waste water after step (2) processing stops 2h in intermediate regulations pond Afterwards, ozonation aerated biofilter integrated apparatus is pumped into, ozone is mixed by pipeline dosing method with waste water, ozone dosage For 500mg/L;Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 12h.
The waste water COD of last gained is 60mg/L, and oil content is 0.4mg/L, and SS is 3mg/L, reaches country-level row Put standard.
It is computed, wastewater treatment expense is 2.32 yuan/m3
Embodiment 4
According to the condition and step described in embodiment 1:
(1) regulating reservoir is handled:Port cabin washing wastewater stops 2d in regulating reservoir;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) is pumped into biological fluidized bed, and hydraulic detention time is 2.5d, Gas-water ratio is 7:1;
(3) ozonation aerated biofilter integrated apparatus processing:Waste water after step (2) processing is stopped in intermediate regulations pond After 1.5h, ozonation aerated biofilter integrated apparatus is pumped into, ozone is mixed by pipeline dosing method with waste water, ozone is thrown Dosage is 400mg/L;Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 8
The waste water COD of last gained is 58mg/L, and oil content is 0.3mg/L, and SS is 4mg/L, reaches country-level row Put standard.
It is computed, wastewater treatment expense is 2.35 yuan/m3

Claims (5)

1. a kind of processing method of port cabin washing wastewater, comprises the following steps:
(1) regulating reservoir is handled:Port cabin washing wastewater enters regulating reservoir, and the COD of the port cabin washing wastewater is not less than 100 Mg/L, oil content is not less than 80mg/L, and SS is not less than the residence time in 50mg/L, the port cabin washing wastewater regulating reservoir For 1-3d, 10-15 DEG C of regulating reservoir water temperature;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) enters biological fluidized bed, and hydraulic detention time is 2-3d, Gas-water ratio is 5-10:1;
(3) ozonation aerated biofilter integrated apparatus processing:Ozonation aerated biofilter integrated apparatus is by ozone oxidation system With BAF composition, the waste water after step (2) processing is stopped after 1~2h in intermediate regulations pond, exposed into ozone Gas biofilter integrated apparatus, ozone is mixed by pipeline dosing method with waste water, and ozone dosage is 300-500mg/L; Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 6~12h;
(4) discharged wastewater met the national standard after above-mentioned processing, COD is not more than 80mg/L, and oil content is not more than 0.5mg/L, SS is not more than 5mg/L.
2. the processing method of port cabin washing wastewater according to claim 1, it is characterised in that the filler of biological fluidized bed is with haydite It is used as carrier.
3. the processing method of port cabin washing wastewater according to claim 1, it is characterised in that the filler of BAF is to make pottery Grain is used as carrier.
4. the processing method of port cabin washing wastewater according to claim 1, it is characterised in that the COD of the port cabin washing wastewater For 100-300mg/L, oil content is 80-400mg/L, and SS is 50-100mg/L.
5. the processing method of port cabin washing wastewater according to claim 1, it is characterised in that useless after step (4) processing Water qualified discharge, COD is 24-80mg/L, and oil content is 0.2-0.5mg/L, and SS is 2-5mg/L.
CN201610408751.6A 2016-06-12 2016-06-12 The processing method of port cabin washing wastewater Pending CN107311390A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610408751.6A CN107311390A (en) 2016-06-12 2016-06-12 The processing method of port cabin washing wastewater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610408751.6A CN107311390A (en) 2016-06-12 2016-06-12 The processing method of port cabin washing wastewater

Publications (1)

Publication Number Publication Date
CN107311390A true CN107311390A (en) 2017-11-03

Family

ID=60185676

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610408751.6A Pending CN107311390A (en) 2016-06-12 2016-06-12 The processing method of port cabin washing wastewater

Country Status (1)

Country Link
CN (1) CN107311390A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110921981A (en) * 2019-11-19 2020-03-27 交通运输部天津水运工程科学研究所 Method and equipment for treating chemical tank washing water by combining internal electrolysis method and biological method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6365048B1 (en) * 2000-07-19 2002-04-02 Board Of Trustees Of Michigan State University Method for treatment of organic matter contaminated drinking water
CN101508506A (en) * 2009-03-25 2009-08-19 华南理工大学 Harbor chemical wastewater processing method
CN101704617A (en) * 2009-12-08 2010-05-12 大连善水德水务工程有限责任公司 Equipment for reclaiming and processing petrified enterprise sewage and process technology thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6365048B1 (en) * 2000-07-19 2002-04-02 Board Of Trustees Of Michigan State University Method for treatment of organic matter contaminated drinking water
CN101508506A (en) * 2009-03-25 2009-08-19 华南理工大学 Harbor chemical wastewater processing method
CN101704617A (en) * 2009-12-08 2010-05-12 大连善水德水务工程有限责任公司 Equipment for reclaiming and processing petrified enterprise sewage and process technology thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110921981A (en) * 2019-11-19 2020-03-27 交通运输部天津水运工程科学研究所 Method and equipment for treating chemical tank washing water by combining internal electrolysis method and biological method

Similar Documents

Publication Publication Date Title
CN103466768B (en) Floc reflux coagulation process for treating biochemical printing and dyeing effluent
CN105481177A (en) Low-consumption nitrification and denitrification coal chemical wastewater advanced treatment device
CN102259980B (en) Biological aerated filter and sewage treatment process thereof
CN104016511A (en) Ozone / photocatalysis oxidation-membrane separation integrated method and integrated set for advanced wastewater treatment
CN106242163A (en) A kind of processing method of percolate embrane method concentrated solution
CN103613254B (en) The deep treatment method of fine chemistry industry garden sewage work organic wastewater with difficult degradation thereby
CN105906164A (en) Method for removing ammonia nitrogen in waste water
CN106495359A (en) A kind of highly difficult advanced waste treatment apparatus and method
CN101781048B (en) Low ammonia nitrogen waste water treatment and recycling method
CN106882906A (en) It is exclusively used in the efficient low-consume denitrifying method of trade effluent
CN106186554A (en) A kind of to PTA sewage after double film desalination reuses the preprocess method of the remaining dense water of RO
CN202881052U (en) Device for removing phosphorus chemically and forcibly by adopting A2O, membrane separation and cloth filter filtering
CN104876315A (en) Water treatment flocculant
CN102603065B (en) Treatment method for deeply dephosphorizing and denitrifying domestic sewage
CN107311390A (en) The processing method of port cabin washing wastewater
JP2018535093A (en) Improvement of phosphorus precipitation and membrane flux in membrane bioreactors
CN205974184U (en) Processing system of landfill leachate embrane method concentrate
CN102329050B (en) Process and device for efficiently treating wheat straw pulp intermediate wastewater by alkaline method
KR101109763B1 (en) underwater mixer/stirrer apparatus for treatment of wasted-water
CN103755108A (en) Municipal wastewater purification treatment method
CN208667385U (en) A kind of wastewater treatment integrating device
CN106430846A (en) Efficient treatment integrated process for recalcitrant wastewater with low organic matter content
CN114149140A (en) Caprolactam production wastewater treatment method
CN104609671B (en) Multistage reflux powdered activated carbon bioactive sewage treatment device
CN113582463A (en) Direct-discharge treatment method for high-salinity fracturing flowback fluid

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20171103