CN107311390A - The processing method of port cabin washing wastewater - Google Patents
The processing method of port cabin washing wastewater Download PDFInfo
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- CN107311390A CN107311390A CN201610408751.6A CN201610408751A CN107311390A CN 107311390 A CN107311390 A CN 107311390A CN 201610408751 A CN201610408751 A CN 201610408751A CN 107311390 A CN107311390 A CN 107311390A
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- washing wastewater
- cabin washing
- processing
- port cabin
- waste water
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/008—Originating from marine vessels, ships and boats, e.g. bilge water or ballast water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/02—Temperature
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/08—Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/10—Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/44—Time
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/08—Aerobic processes using moving contact bodies
- C02F3/085—Fluidized beds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/10—Packings; Fillings; Grids
- C02F3/104—Granular carriers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/10—Packings; Fillings; Grids
- C02F3/105—Characterized by the chemical composition
- C02F3/107—Inorganic materials, e.g. sand, silicates
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The present invention relates to a kind of processing method of port cabin washing wastewater, mainly solve easily to pollute in the prior art, the problem of economy is bad.The present invention is by using a kind of processing method of port cabin washing wastewater, sequentially pass through regulating reservoir processing, the technical scheme that biological fluidized bed is handled, ozonation aerated biofilter integrated apparatus is handled and preferably solve above mentioned problem, available in the processing of port cabin washing wastewater.
Description
Technical field
The present invention relates to a kind of processing method of port cabin washing wastewater.
Background technology
Harbor chemical wastewater means that Liquid Chemicals in Bulk cargo ship needs cleaning or change the sewage produced during cargo type (such as to wash
Cabin, cleaning of evaporator etc.).Major pollutant in water is sweeping, the residual substance of cleaning of evaporator after unloading.The sewage is not only because it contains
There are the chemicals for being difficult to biological treatment, the cleaning agent as used in styrene, acrylonitrile, formaldehyde, cleaning cabin, and
Make wastewater flow rate and concentration that there is polytropy and randomness because dispersion single user wharf intermittent action, pollutant are various in style etc..One
As it is thought that the larger waste water of a class intractability.
Domestic liquid chemical freight volume is larger for Shanghai, Ningbo, Dalian, α Cygni Port, and chemical wastewater is by code
Head receive conveying tank field storage after enter wastewater treatment equipment, its wastewater treatment mainly using materialization-biochemistry combination process as
Main, most of materialization uses air supporting, biochemical then have the techniques such as biomembrane, oxidation ditch according to different water quality.China's harbour gives up
The processing of water has waste water processing station also in starting stage, only four Ports, according to the requirement of sustainable development, it is necessary to big
The process range into harbor chemical wastewater is pushed, makes shipping safer, ocean is more cleaned.
Chinese patent application CN104355383A discloses a kind of composite flocculation agent solution for being used to handle harbor oil-containing wastewater,
The formula of the flocculant solution is:Aluminum sulfate 4%-8%, ferric sulfate 4%-10% and chitosan 0.5%-2.5%.This hair
The bright preparation method for also disclosing above-mentioned composite flocculation agent solution.Effect using present invention processing waste water is significantly larger than single type
The treatment effect of flocculant, efficiency high, consumption is few, has the advantage of aluminum salt flocculant and Ferric Salt Flocculants concurrently, while having height
Molecular flocculant consumption is few, flco is formed soon, the advantage that settling property is waited well, and compensate for that each component is single to be used
It is not enough.It is particularly suitable for use in the coagulating treatment of harbor oil-containing wastewater, water ballast, tank washings.
It is more single for current handling process, it can only meet the processing requirement of specific water quality, Difficulty, and it is existing big
Most harbour sewage disposal systems are big due to that can not adapt to chemical cleaning of evaporator water change of water quality, the characteristics of strong toxicity, cause harbour dirty
Water treatment system, which can not be stablized, normally to be run.The characteristics of for current China's harbour chemicals cleaning of evaporator water, develop a kind of shock resistance
Ability is strong, is adapted to the group technology of different chemical product waste water, reaches economic, efficient processing, disposable waste water is entered
Row reuse, meets the trend of current construction conservation-minded society.
The content of the invention
The technical problems to be solved by the invention be easily pollute in the prior art, there is provided a kind of new the problem of economy is bad
The processing method of port cabin washing wastewater.This method has the advantages that pollution-free, discharged wastewater met the national standard, good economy performance.
To solve the above problems, the technical solution adopted by the present invention is as follows:A kind of processing method of port cabin washing wastewater, including
Following steps:
(1) regulating reservoir is handled:Port cabin washing wastewater enters regulating reservoir, and the COD of the port cabin washing wastewater is not less than 100
Mg/L, oil content is not less than 80mg/L, and SS (suspension) is not less than in 50mg/L, the port cabin washing wastewater regulating reservoir
Residence time be 1-3d, 10-15 DEG C of regulating reservoir water temperature;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) enters biological fluidized bed, and hydraulic detention time is 2-3d
(my god), gas-water ratio is 5-10:1;
(3) ozonation aerated biofilter integrated apparatus processing:Ozonation aerated biofilter integrated apparatus is by ozone oxidation system
With BAF composition, the waste water after step (2) processing is stopped after 1~2h in intermediate regulations pond, exposed into ozone
Gas biofilter integrated apparatus, ozone is mixed by pipeline dosing method with waste water, and ozone dosage is 300-500mg/L;
Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 6~12h;
(4) discharged wastewater met the national standard after above-mentioned processing, COD is not more than 80mg/L, and oil content is not more than 0.5mg/L,
SS is not more than 5mg/L.
In above-mentioned technical proposal, it is preferable that the filler of biological fluidized bed is used as carrier using haydite.
In above-mentioned technical proposal, it is preferable that the filler of BAF is used as carrier using haydite.
In above-mentioned technical proposal, it is preferable that the COD of the port cabin washing wastewater is 100-300mg/L, oil content is
80-400mg/L, SS are 50-100mg/L.
In above-mentioned technical proposal, it is preferable that the discharged wastewater met the national standard after step (4) processing, COD is 24-80mg/L,
Oil content is 0.2-0.5mg/L, and SS is 2-5mg/L.
Present invention process is ripe, treatment effect is stable, there is good treatment effect, about 2.2 yuan of wastewater treatment expense to waste water
/m3, after the group technology advanced treating, the water outlet of washing of tanks chemical wastewater can make fire-fighting, greening water, with good ring
Border benefit and economic benefit, achieve preferable technique effect.
Below by embodiment, the invention will be further elaborated, but is not limited only to the present embodiment.
Embodiment
Embodiment 1
Monthly cleaning of evaporator waste water water is about 100t at Yangzhou harbour, and the COD (COD) of water inlet is 200-250mg/L,
Oil content is 300mg/L, and SS (suspension) is 100mg/L.
(1) regulating reservoir is handled:Port cabin washing wastewater stops 1d, 10 DEG C of regulating reservoir water temperature in regulating reservoir;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) is pumped into biological fluidized bed, and hydraulic detention time is 2d,
Gas-water ratio is 5:1;
(3) ozonation aerated biofilter integrated apparatus processing:Waste water after step (2) processing stops 1h in intermediate regulations pond
Afterwards, ozonation aerated biofilter integrated apparatus is pumped into, ozone is mixed by pipeline dosing method with waste water, ozone dosage
For 300mg/L;Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 6h.
The filler of biological fluidized bed is using haydite as carrier, and the filler of BAF is used as carrier using haydite.
The waste water COD of last gained is 80mg/L, and oil content is 0.5mg/L, and SS is 5mg/L, reaches country-level discharge
Standard.
It is computed, wastewater treatment expense is 2.25 yuan/m3。
Embodiment 2
Monthly cleaning of evaporator waste water water is about 300t at Zhuhai harbour, and the COD of water inlet is 100mg/L, and oil content is 400mg/L,
SS is 60mg/L.
(1) regulating reservoir is handled:Stop 3d of the port cabin washing wastewater in regulating reservoir, 10 DEG C of regulating reservoir water temperature;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) is pumped into biological fluidized bed, and hydraulic detention time is 2-3d,
Gas-water ratio is 10:1;
(3) ozonation aerated biofilter integrated apparatus processing:Waste water after step (2) processing stops 2h in intermediate regulations pond
Afterwards, ozonation aerated biofilter integrated apparatus is pumped into, ozone is mixed by pipeline dosing method with waste water, ozone dosage
For 500mg/L;Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 12h.
The waste water COD of last gained is 50mg/L, and oil content is 0.2mg/L, and SS is 2mg/L, reaches that country's life is used mixedly
Water circulation standard, can be afforested, carwash, the reuse such as fire-fighting.
It is computed, wastewater treatment expense is 2.38 yuan/m3。
Embodiment 3
According to the condition and step described in embodiment 1:
(1) regulating reservoir is handled:Port cabin washing wastewater stops 3d in regulating reservoir;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) is pumped into biological fluidized bed, and hydraulic detention time is 3d,
Gas-water ratio is 10:1;
(3) ozonation aerated biofilter integrated apparatus processing:Waste water after step (2) processing stops 2h in intermediate regulations pond
Afterwards, ozonation aerated biofilter integrated apparatus is pumped into, ozone is mixed by pipeline dosing method with waste water, ozone dosage
For 500mg/L;Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 12h.
The waste water COD of last gained is 60mg/L, and oil content is 0.4mg/L, and SS is 3mg/L, reaches country-level row
Put standard.
It is computed, wastewater treatment expense is 2.32 yuan/m3。
Embodiment 4
According to the condition and step described in embodiment 1:
(1) regulating reservoir is handled:Port cabin washing wastewater stops 2d in regulating reservoir;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) is pumped into biological fluidized bed, and hydraulic detention time is 2.5d,
Gas-water ratio is 7:1;
(3) ozonation aerated biofilter integrated apparatus processing:Waste water after step (2) processing is stopped in intermediate regulations pond
After 1.5h, ozonation aerated biofilter integrated apparatus is pumped into, ozone is mixed by pipeline dosing method with waste water, ozone is thrown
Dosage is 400mg/L;Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 8
The waste water COD of last gained is 58mg/L, and oil content is 0.3mg/L, and SS is 4mg/L, reaches country-level row
Put standard.
It is computed, wastewater treatment expense is 2.35 yuan/m3。
Claims (5)
1. a kind of processing method of port cabin washing wastewater, comprises the following steps:
(1) regulating reservoir is handled:Port cabin washing wastewater enters regulating reservoir, and the COD of the port cabin washing wastewater is not less than 100
Mg/L, oil content is not less than 80mg/L, and SS is not less than the residence time in 50mg/L, the port cabin washing wastewater regulating reservoir
For 1-3d, 10-15 DEG C of regulating reservoir water temperature;
(2) biological fluidized bed is handled:Waste water after being handled through step (1) enters biological fluidized bed, and hydraulic detention time is 2-3d,
Gas-water ratio is 5-10:1;
(3) ozonation aerated biofilter integrated apparatus processing:Ozonation aerated biofilter integrated apparatus is by ozone oxidation system
With BAF composition, the waste water after step (2) processing is stopped after 1~2h in intermediate regulations pond, exposed into ozone
Gas biofilter integrated apparatus, ozone is mixed by pipeline dosing method with waste water, and ozone dosage is 300-500mg/L;
Waste water passes through BAF biochemical treatment again after ozone oxidation, and hydraulic detention time is 6~12h;
(4) discharged wastewater met the national standard after above-mentioned processing, COD is not more than 80mg/L, and oil content is not more than 0.5mg/L,
SS is not more than 5mg/L.
2. the processing method of port cabin washing wastewater according to claim 1, it is characterised in that the filler of biological fluidized bed is with haydite
It is used as carrier.
3. the processing method of port cabin washing wastewater according to claim 1, it is characterised in that the filler of BAF is to make pottery
Grain is used as carrier.
4. the processing method of port cabin washing wastewater according to claim 1, it is characterised in that the COD of the port cabin washing wastewater
For 100-300mg/L, oil content is 80-400mg/L, and SS is 50-100mg/L.
5. the processing method of port cabin washing wastewater according to claim 1, it is characterised in that useless after step (4) processing
Water qualified discharge, COD is 24-80mg/L, and oil content is 0.2-0.5mg/L, and SS is 2-5mg/L.
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CN201610408751.6A CN107311390A (en) | 2016-06-12 | 2016-06-12 | The processing method of port cabin washing wastewater |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110921981A (en) * | 2019-11-19 | 2020-03-27 | 交通运输部天津水运工程科学研究所 | Method and equipment for treating chemical tank washing water by combining internal electrolysis method and biological method |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6365048B1 (en) * | 2000-07-19 | 2002-04-02 | Board Of Trustees Of Michigan State University | Method for treatment of organic matter contaminated drinking water |
CN101508506A (en) * | 2009-03-25 | 2009-08-19 | 华南理工大学 | Harbor chemical wastewater processing method |
CN101704617A (en) * | 2009-12-08 | 2010-05-12 | 大连善水德水务工程有限责任公司 | Equipment for reclaiming and processing petrified enterprise sewage and process technology thereof |
-
2016
- 2016-06-12 CN CN201610408751.6A patent/CN107311390A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6365048B1 (en) * | 2000-07-19 | 2002-04-02 | Board Of Trustees Of Michigan State University | Method for treatment of organic matter contaminated drinking water |
CN101508506A (en) * | 2009-03-25 | 2009-08-19 | 华南理工大学 | Harbor chemical wastewater processing method |
CN101704617A (en) * | 2009-12-08 | 2010-05-12 | 大连善水德水务工程有限责任公司 | Equipment for reclaiming and processing petrified enterprise sewage and process technology thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110921981A (en) * | 2019-11-19 | 2020-03-27 | 交通运输部天津水运工程科学研究所 | Method and equipment for treating chemical tank washing water by combining internal electrolysis method and biological method |
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Application publication date: 20171103 |