CN107308788A - A kind of microbubble industrial waste gas processing system - Google Patents

A kind of microbubble industrial waste gas processing system Download PDF

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Publication number
CN107308788A
CN107308788A CN201710558960.3A CN201710558960A CN107308788A CN 107308788 A CN107308788 A CN 107308788A CN 201710558960 A CN201710558960 A CN 201710558960A CN 107308788 A CN107308788 A CN 107308788A
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China
Prior art keywords
microbubble
waste gas
industrial waste
processing system
gas processing
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CN201710558960.3A
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Chinese (zh)
Inventor
周剑光
贺明
杨玉艺
钟会琴
李玟谚
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Priority to CN201710558960.3A priority Critical patent/CN107308788A/en
Publication of CN107308788A publication Critical patent/CN107308788A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B01D53/323Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 by electrostatic effects or by high-voltage electric fields
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • B01D53/261Drying gases or vapours by adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C13/00Disintegrating by mills having rotary beater elements ; Hammer mills
    • B02C13/14Disintegrating by mills having rotary beater elements ; Hammer mills with vertical rotor shaft, e.g. combined with sifting devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C13/00Disintegrating by mills having rotary beater elements ; Hammer mills
    • B02C13/26Details
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C13/00Disintegrating by mills having rotary beater elements ; Hammer mills
    • B02C13/26Details
    • B02C13/28Shape or construction of beater elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/104Ozone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/12Methods and means for introducing reactants
    • B01D2259/124Liquid reactants

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to industrial waste gas processing system, more particularly to a kind of microbubble industrial waste gas processing system.The system includes microbubble breaker, and microbubble breaker, which hits a diameter of 50 500 nanometers of microbubble, to be divided, and quantity of formation is more, the smaller microbubble of diameter, so as to improve the treatment effect of industrial waste gas.And microbubble breaker can form sinuous flow area in treating column, extremely many extreme physical environments are formed in sinuous flow area, form high-voltage corona electric field, the oxygen molecule in electric field or around electric field is set to occur electrochemical reaction, so as to manufacture ozone, ozone produces oxidation reaction with the compound in air, preferably realizes catharsis.

Description

A kind of microbubble industrial waste gas processing system
【Technical field】
The present invention relates to industrial waste gas processing system, more particularly to a kind of microbubble industrial waste gas processing system.
【Background technology】
VOC materials refer to the general name of organic substance readily volatilized at normal temperatures, common are formaldehyde, toluene and dimethylbenzene Etc..Traditional spraying industry uses substantial amounts of nitrate paint raw and auxiliary material in product spraying process, and nitrate paint raw and auxiliary material contains There is substantial amounts of machine solvent, the aromatic hydrocarbon that especially high volatile solvent such as dimethylbenzene, toluene, benzene contains was not only poisonous but also inflammable, and Highly volatile causes to have discharged numerous VOC into air into environment, pollutes atmospheric environment and is detrimental to health.Organise Compound not only has a stimulation to human body, and wherein many to the toxic effect of internal organ, also have plenty of mutagen with it is carcinogenic Thing.Alkene and some arene compounds in organic compound, in an atmosphere, can also be with nitrogen oxygen in the presence of sunlight Compound reacts to form the photochemical fog or industrial photochemical fog of Los Angeles type, causes secondary pollution.
And pass through many experiments and find, nano level microbubble, which can be realized, to be divided the VOC gases contained in air Solution, concrete principle is as follows:Nanoscale microbubble is in collapse blasting process, and moment can produce 4000K high temperature, 50MPa high pressures, After last microseconds, focus is cooled down therewith, and with strong shock wave and the microjet up to 100m/s speed.These conditions It is enough to make organic matter that chemical bond rupture, aqueous phase burning, pyrolytic or radical reaction occur in nanoscale microbubble, is VOC degraded creates an extreme physical environment.When liquid is in ultrasonic field, pressure waveform is sufficient into condition of high voltage To open the stronger chemical bond of adhesion so that hydrone H2O is decomposed into-H and-OH free radicals or generation H2O2, the oxygen of generation Change free love base to be diffused into water body, then reacted by way of nanometer microbubble with VOC so that VOC is degraded.
And in above-mentioned course of reaction, show through many experiments, the diameter of microbubble is smaller, more obvious to VOC degradations, But the smaller microbubble of diameter is sprayed by nozzle, prior art is not accomplished also.Therefore the diameter of reduction microbubble is needed, Also need to by other means realize.And in microbubble and air in compound course of reaction, if necessary to in air The compound progress oxidation reaction contained, which is only filled with ozone, to be realized.Therefore offer one kind is needed to reduce microbubble diameter With can automatically generate the industrial waste gas processing system of ozone.
【The content of the invention】
Present invention seek to address that above mentioned problem and providing a kind of reduce microbubble diameter and can automatically generate the one of ozone Plant microbubble industrial waste gas processing system
To achieve the above object, a kind of microbubble industrial waste gas processing system of the invention, includes the processing of U-shaped design Air inlet 11 and air outlet 12 are provided with tower 10, described treating column 10, described air inlet 11 and air outlet 12 is set respectively Put on the two ends for the treatment of column 10, water body input pipe 40, the described end of water body input pipe 40 are provided with described air inlet 11 End is connected with some microbubble nozzles 50, and the water spray that described microbubble nozzle 50 inputs water body input pipe 40 is into a diameter of Microbubble breaker, the broken dress of described microbubble are additionally provided with 50-500 nanometers of microbubble, described treating column 10 Put including a rotary shaft 60 and some broken rods 61 being arranged in rotary shaft 60, described broken rod 61 is around rotary shaft 60 It is rotated in treating column 10 and forms air sinuous flow area, micro- gas that the industrial waste gas that air inlet 11 enters sprays with microbubble nozzle 50 Bubble is sufficiently mixed in sinuous flow area.
Further, the cross sectional shape of described broken rod 61 is circle, triangle, square, trapezoidal one of which.
Further, the rotary speed of described rotary shaft 60 is 5-15 turns of each second.
Further, some spines 62 are additionally provided with described broken rod 61.
Further, described treating column 10U types bottom fills the purification liquid 30 that depth is 30-50 centimetres, described Purify the longitudinal section of the not submerged impinging jet tower 10U types bottom of liquid 30.
Further, described treating column 10 is additionally provided with some layer of air screen packs 70, some layer of air screen packs 70 Height be not less than 30 centimetres.
Further, described airstrainer 70 is adsorbed with water droplet.
Further, the wind speed of described air inlet 11 is not more than 5 meter per seconds, the section of air inlet 11 and cutting for treating column Face ratio is 1: 5-15.
Further, blower fan 20 is additionally provided with described air outlet 12, described blower fan 20 is axial flow blower.
The contribution of the present invention is the provision of a kind of microbubble industrial waste gas processing system, and the system is set below nozzle There is microbubble breaker, breaker includes rotary shaft and broken rod, and rotary shaft drives what broken rod rotation sprayed nozzle Microbubble is smashed, and a big microbubble of diameter is hit into several small microbubbles of diameter, is formed more microbubbles and is caught The hazardous compound in air is caught, makes discomposing effect more preferable.Spine is additionally provided with breaker, spine also can be helped preferably Realize the division to microbubble.Rotary shaft, which is rotated in treating column, forms sinuous flow area, and some air is towards nozzle direction Motion, is so more beneficial for air and is mixed with the microbubble that nozzle is formed.Meanwhile, due to the quantity of microbubble explosion in sinuous flow area Sharply increase, more 4000K of formation high temperature, the local environment of 50MPa high pressures, so as to form high-voltage corona electric field, make electricity Electrochemical reaction occurs for the oxygen molecule in or around electric field, so as to automatically generate ozone, oxygen is carried out to the compound in air Change, without being additionally filled with ozone.
【Brief description of the drawings】
Fig. 1 is structural representation of the invention.
Fig. 2 is that the broken rod section of the present invention is circular microbubble breaker structural representation.
Fig. 3 is the microbubble breaker structural representation that the broken rod section of the present invention is triangle.
【Embodiment】
The following example is being explained further and supplementing to the present invention, and the present invention is not limited in any way.
Embodiment 1
As shown in Figure 1, 2, 3, a kind of microbubble industrial waste gas processing system of the present embodiment, includes the place of U-shaped design Manage and be provided with air inlet 11 and air outlet 12 on tower 10, described treating column 10, described air inlet 11 and air outlet 12 is distinguished On the two ends for being arranged on treating column 10, water body input pipe 40, described water body input pipe 40 are provided with described air inlet 11 End is connected with some microbubble nozzles 50, and the water spray that described microbubble nozzle 50 inputs water body input pipe 40 is into diameter For 50-500 nanometers of microbubble, microbubble breaker is additionally provided with described treating column 10, described microbubble is crushed Device includes a rotary shaft 60 and some broken rods 61 being arranged in rotary shaft 60, and described broken rod 61 is around rotary shaft It is micro- that 60 industrial waste gases and microbubble nozzle 50 for being rotated in the entrance of formation air sinuous flow area air inlet 11 in treating column 10 spray Bubble is sufficiently mixed in sinuous flow area.Air inlet 11 is passed through the industrial waste gas containing VOC, is passed through after industrial waste gas, microbubble nozzle 50 spray a diameter of 50-500 nanometers of microbubble, and are mixed with industrial waste gas, because microbubble is through nozzle by water in itself Formed after ejection, therefore itself has certain adhesive force, explosion after microbubble is mixed with the compound in air, moment can produce Raw 4000K high temperature, 50MPa high pressures, so as to be the molecular scission of compound, reach degraded VOC purpose.Due to microbubble Diameter is smaller, and the effect for the VOC that degrades is more obvious.Microbubble breaker is also provided with the present embodiment below nozzle 50, it is micro- Bubble breaking device is a rotary shaft 60 and some broken rods 61, and the rotation of rotary shaft 60 drives broken rod 61 and microbubble high Speed collision, makes a microbubble split into several microbubbles, while increase microbubble quantity, also can preferably realize micro- gas Steep and the compound contained in air is caught, sufficiently complete degraded.The other rotation of rotary shaft 60 can be in treating column 10 The combination probability of compound and microbubble can also be increased by forming the various collisions formed in sinuous flow area, sinuous flow area.Nozzle 50 is down Microbubble is sprayed, and rotary shaft 60 can also form upward air-flow, air clashes with microbubble, and microbubble catches the several of compound Rate can also increase.Simultaneously as microbubble explosion can produce the physical environment of local extreme, high-voltage corona electric field is formed, is made Electrochemical reaction occurs for the oxygen molecule in electric field or around electric field, so as to automatically generate ozone, the compound in air is carried out Oxidation, without being additionally filled with ozone.
Embodiment 2
As shown in Figure 1, 2, 3, the cross sectional shape of described broken rod 61 be circle, triangle, square, it is trapezoidal wherein It is a kind of.The rotary speed of described rotary shaft 60 is 5-15 turns of each second.Some spines are additionally provided with described broken rod 61 62.Circular broken rod 51 forms swirling eddy after air is scratched in rotary course, makes air in sinuous flow area towards difference Direction is operated, the success rate that increase microbubble is combined with compound.And the broken rod 61 of triangle divides air after rotating at a high speed Isolate, negative pressure is formed by part, then air filling head-on collision, the success rate that increase microbubble is combined with compound, simultaneously The broken rod of triangle can also form upward air-flow, the probability for the microbubble head-on collision that increase air sprays with nozzle.Spine 62 can help to puncture microbubble, form the smaller microbubble of more more dense, diameters.
Embodiment 3
As shown in figure 1, described treating column 10U types bottom fills the purification liquid 30 that depth is 30-50 centimetres, it is described Purify the longitudinal section of the not submerged impinging jet tower 10U types bottom of liquid 30.Because microbubble is to pass through microbubble nozzle 50 by water in itself Formed after atomization, therefore be also to form vaporific small water droplet after its explosion, small water droplet is attached in compound, when increasing small Can form the globule after water droplet attachment, so as to fall, drop into purification liquid 30, purification liquid 30 can be water or There is the solvent of clean-up effect.The longitudinal section of purification liquid 30 not submerged impinging jet tower 10U types bottom is to ensure that ventilation is smooth.
Embodiment 4
As shown in figure 1, described treating column 10 is additionally provided with some layer of air screen packs 70, some layer of air screen packs 70 Height be not less than 30 centimetres.Described airstrainer 70 is adsorbed with water droplet.When the air containing industrial waste gas passes through sinuous flow Area, and during by purification liquid 30, contained compounds content polar region in it, but in order to preferably realize purification effect Really, it is also provided with being adsorbed with water droplet on airstrainer 70, airstrainer 70 before air outlet 12, further realization pair The purification of air.
Although being disclosed by above example to the present invention, protection scope of the present invention is not limited thereto, Under conditions of without departing from present inventive concept, deformation, replacement that each component is done to more than etc. will fall into the right of the present invention In claimed range.

Claims (9)

1. a kind of microbubble industrial waste gas processing system, is included on the treating column (10) of U-shaped design, described treating column (10) Air inlet (11) and air outlet (12) are provided with, described air inlet (11) and air outlet (12) is separately positioned on treating column (10) Two ends on, it is characterised in that:Described air inlet (11) place is provided with water body input pipe (40), described water body input pipe (40) end is connected with some microbubble nozzles (50), the water that described microbubble nozzle (50) inputs water body input pipe (40) Spray into a diameter of 50-500 nanometers microbubble, described treating column (10) and be additionally provided with microbubble breaker, it is described Microbubble breaker include a rotary shaft (60) and some broken rods (61) being arranged in rotary shaft (60), it is described Broken rod (61) be rotated in around rotary shaft (60) in treating column (10) and form air sinuous flow area, the industry that air inlet (11) enters The microbubble that waste gas sprays with microbubble nozzle (50) is sufficiently mixed in sinuous flow area.
2. a kind of microbubble industrial waste gas processing system as claimed in claim 1, it is characterised in that:Described broken rod (61) Cross sectional shape be circle, triangle, square, trapezoidal one of which.
3. a kind of microbubble industrial waste gas processing system as claimed in claim 1, it is characterised in that:Described rotary shaft (60) Rotary speed for each second 5-15 turn.
4. a kind of microbubble industrial waste gas processing system as claimed in claim 3, it is characterised in that:Described broken rod (61) On be additionally provided with some spines (62).
5. a kind of microbubble industrial waste gas processing system as claimed in claim 1, it is characterised in that:Described treating column (10) It is 30-50 centimetres of purification liquid (30) that U-shaped bottom, which fills depth, described purification liquid (30) not submerged impinging jet tower (10) U The longitudinal section of type bottom.
6. a kind of microbubble industrial waste gas processing system as claimed in claim 5, it is characterised in that:Described treating column (10) Some layer of air screen packs (70) are additionally provided with, the height of some layer of air screen packs (70) is not less than 30 centimetres.
7. a kind of microbubble industrial waste gas processing system as claimed in claim 6, it is characterised in that:Described airstrainer (70) it is adsorbed with water droplet.
8. a kind of microbubble industrial waste gas processing system as described in claim 1-7 is any, it is characterised in that:Described air intake The wind speed of mouth (11) is not more than 5 meter per seconds, and the section of air inlet (11) and the section ratio for the treatment of column are 1: 5-15.
9. a kind of microbubble industrial waste gas processing system as claimed in claim 1, it is characterised in that:Described air outlet (12) Place is additionally provided with blower fan (20), and described blower fan (20) is axial flow blower.
CN201710558960.3A 2017-07-11 2017-07-11 A kind of microbubble industrial waste gas processing system Pending CN107308788A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117619254A (en) * 2024-01-25 2024-03-01 东北大学 Nanoparticle generation device and generation method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013027855A (en) * 2011-07-26 2013-02-07 Yamaguchi Kogyo:Kk Cavitation bubble cleaning device
CN103933832A (en) * 2014-05-06 2014-07-23 石博天 Device for eliminating haze and atmospheric pollutant
CN104941353A (en) * 2015-07-10 2015-09-30 河南五星科技有限公司 Purifier
CN206935072U (en) * 2017-07-11 2018-01-30 钟会琴 A kind of microbubble industrial waste gas processing system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013027855A (en) * 2011-07-26 2013-02-07 Yamaguchi Kogyo:Kk Cavitation bubble cleaning device
CN103933832A (en) * 2014-05-06 2014-07-23 石博天 Device for eliminating haze and atmospheric pollutant
CN104941353A (en) * 2015-07-10 2015-09-30 河南五星科技有限公司 Purifier
CN206935072U (en) * 2017-07-11 2018-01-30 钟会琴 A kind of microbubble industrial waste gas processing system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117619254A (en) * 2024-01-25 2024-03-01 东北大学 Nanoparticle generation device and generation method
CN117619254B (en) * 2024-01-25 2024-06-04 东北大学 Nanoparticle generation device and generation method

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Application publication date: 20171103