CN107303448A - A kind of composite air filtering paper - Google Patents
A kind of composite air filtering paper Download PDFInfo
- Publication number
- CN107303448A CN107303448A CN201610280013.8A CN201610280013A CN107303448A CN 107303448 A CN107303448 A CN 107303448A CN 201610280013 A CN201610280013 A CN 201610280013A CN 107303448 A CN107303448 A CN 107303448A
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- China
- Prior art keywords
- layer
- filter
- glass
- protective layer
- adsorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/08—Filter paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Filtering Materials (AREA)
- Paper (AREA)
Abstract
The present invention is a kind of composite air filtering paper; it is made up of protective layer, adsorption layer and filter layer; filter layer is made up of ultra-fine fibre glass and the chopped silk of alkali-free glass fibre; both intensity entangled to each other for effectively improving filter paper; filter layer both sides respectively with the addition of one layer of adsorption layer and layer protective layer; wherein adsorption layer is located between protective layer and filter layer, and they are bonded together by phenolic resin adhesive.Material used in protective layer is chemical fibre or glass; the problem of ultra-fine fibre glass easily comes off is effectively prevent while filter efficiency is not influenceed; material used in adsorption layer is the mixture of active carbon nanoparticles and nano titanium oxide; wherein activated carbon has the effect of good absorption magazine; and the nano titanium oxide mixed can resolve into the formaldehyde in air, benzene type organic water and carbon dioxide; again both mixtures are evenly applied on grid cloth constitute adsorption layer, effectively improve the efficiency and dust containing capacity of filter paper.
Description
Technical field
The present invention relates to a kind of filter paper, more particularly to a kind of composite air filtering paper belongs to air filtration technical field.
Background technology
With the high speed development of modernization industry, environmental pollution is seriously threaten life and the health of the mankind, and the injury of recent air pollution on human is particularly evident, and extensive haze weather is attacked repeatedly.Continuous improvement of the country to quality of air environment attention degree, PM 2.5 is included new Air Quality Evaluation system.How to reduce pernicious gas in air using efficient filtering material and enter human body or extremely urgent to the pernicious gas progress effectively filtering of discharge.In order to be able to realize the purpose of air cleaning, the filtering material of novel high-quality progressively turns into the study hotspot of researcher.Glass fibre have dimensional stability compared with it is strong, be unlikely to deform, electrical insulating property is good, anti-medicine is good, and with the good characteristic such as acid and alkali-resistance, oil resistant, corrosion-resistant, heat-resist, heat conductivity be small.Thus, all-glass paper has high filter efficiency, good chemical stability and relatively low resistance, the preferred material as efficient and ultra high efficiency air cleaner, it is adaptable to the application of the air cleaning of every field.But, there is also some shortcomings for glass fibre：Fiber Aspect Ratio is big, and surface carries electric charge, easily mutually winds and is difficult to separate；Surface smoother, can not produce wire-dividing broom purification through mashing processing, physical bond is there's almost no between fiber and fiber, the group of hydrogen bond is not formed, page can not produce bond strength naturally yet.Thus there is the defect that physical strength is relatively low, fragility is big in all-glass paper, and during machinery pressure folding, page cracky, glass fibre is often split away off.Therefore, on the basis of ensureing that the good air flow resistance of glass fibre air filter paper crosses rate odds for effectiveness, it is to improve product specification that enhancing processing is carried out to glass filter paper, develops the key problem in technology of glass filter paper kind, is also trend of the filter industry to filtering material requirement.
The U of Publication No. CN 202969162 Chinese patent devises a kind of combined filtration paper; send elsewhere and bright disclose a kind of combined filtration paper; including filter layer; in the one side or two-sided multiple with protective layer of filter layer; filter layer uses the high efficiency filter paper that glass fibre is made; protective layer is using natural or synthetic fibers, and protective layer and filter layer are an entirety by high-temperature laminating.The invention solves the caducous problem of ultra-fine fibre glass, and enhances the mechanical strength of filter paper, makes the application of filter paper wider.But send elsewhere bright simply in the compound layer protective layer of filter layer single or double; the problem of only address only ultra-fine fibre glass " hair loss "; do not improve for filter paper various aspects of performance; design is excessively dull; and it is integrally to be formed by high-temperature laminating; complex process, caking ability is not high, low intensity poor toughness.
The A of Publication No. CN 104532683 Chinese patent devises a kind of antibacterial and mouldproof glass fibre composite air filtering paper, including upper glass fibre and lower glass layer, antibiotic layer is provided between the two, the upper strata glass layer upper surface is compounded with glue spraying layer, and the lowermost fibre layer lower surface is compounded with rubber shoe latex layer；The upper glass fibre and lower glass layer are made up of a diameter of 0.35~6.5 μm of glass fibre cotton.The glass fibre air filter paper of the invention uses multi-layer compound structure, and its antibacterial moisture protection was enhanced while filter efficiency is not influenceed.But the invention only increases the antibacterial moisture protection of filter paper, and filter efficiency is not lifted but, while also not solving the caducous problem of glass fibre, mechanical strength is low, poor toughness.
The content of the invention
The purpose of the present invention is intended to overcome the deficiencies in the prior art, a kind of composite air filtering paper is provided, by in the filter layer both sides made from silk that are chopped as ultra-fine fibre glass and alkali-free glass fibre each compound one layer of adsorption layer and protective layer, bonded together with phenolic resin adhesive and filter paper is made, the adsorption layer is located in the middle of filter layer and protective layer, material used in protective layer is chemical fibre or glass, the problem of ultra-fine fibre glass easily comes off is effectively prevent while filter efficiency is not influenceed, material used in adsorption layer is the mixture of active carbon nanoparticles and nano titanium oxide, wherein activated carbon is used as a kind of porous material, effect with good absorption magazine, and the nano titanium oxide mixed can be by the formaldehyde in air, benzene type organic resolves into water and carbon dioxide, again both mixtures are evenly applied on grid cloth constitute adsorption layer, effectively improve the efficiency and dust containing capacity of filter paper, filter layer uses ultra-fine fibre glass and the chopped silk of alkali-free glass fibre, both are entangled to each other, effectively improve the intensity of filter paper.
For realize the purpose of the present invention use technical scheme be：A kind of composite air filtering paper, by protective layer, adsorption layer and filter layer composition, it is characterized in that the filter layer is 1.0~2.0 μm by avarage fiber diameter, the ultra-fine fibre glass and length that draw ratio is 15~50 are 1~10mm, avarage fiber diameter is constituted for 5~15 μm of the chopped silk of alkali-free glass fibre, filter layer thickness is 0.01~0.5mm, respectively there are one layer of adsorption layer and layer protective layer in filter layer both sides, wherein adsorption layer is all located between protective layer and filter layer, described protective layer, cohered between adsorption layer and filter layer with viscosity for 700~1200mpas phenolic resin adhesives.
Mass ratio shared by ultra-fine fibre glass is 50~70% in the filter layer.
The protective layer is 60~80g/m of grammes per square metre2Chemical fabric or glass-fiber-fabric, thickness be 0.01~0.5mm, mesh aperture size be 60~120mm.
Described adsorption layer is made up of 2~10 thickness degree for 0.3~1.0mm grid cloth, wherein the functional coat of every layer of 3~50 μm of grid cloth surface coating thickness.
The functional coat is that particle diameter is 600~1000nm, 1000~1500m of specific surface area2The mixture of/g porous nanos activated carbon and nano titanium oxide, wherein porous nano activated carbon pore size are 20~80nm, and mass ratio shared by nano titanium oxide is 2~6%.
Brief description of the drawings
Fig. 1 is composite air filtering paper schematic cross-section.
Wherein reference
10- protective layer 20- adsorption layer 30- filter layers
Embodiment
Below in conjunction with Figure of description, the invention will be further described.
Embodiment 1
A kind of composite air filtering paper; it is made up of protective layer, adsorption layer and filter layer; it is characterized in that the filter layer by avarage fiber diameter be 1.0 μm, the ultra-fine fibre glass that draw ratio is 15 and length is 1mm, avarage fiber diameter is 5 μm the alkali-free glass fibre silk that is chopped constitutes; filter layer thickness is 0.01mm; respectively there are one layer of adsorption layer and layer protective layer in filter layer both sides; wherein adsorption layer is all located between protective layer and filter layer, with viscosity is that the cured adhesive of 700mpas phenolic aldehyde trees coheres between described protective layer, adsorption layer and filter layer.
Mass ratio shared by ultra-fine fibre glass is 50% in the filter layer.
The protective layer is grammes per square metre 60g/m2Chemical fabric or glass-fiber-fabric, thickness is 0.01mm, and mesh aperture size is 60mm.
Described adsorption layer is made up of 2 thickness degree for 0.3mm grid cloth, wherein the functional coat of every layer of 3 μm of grid cloth surface coating thickness.
The functional coat is that particle diameter is 600nm, specific surface area 1000m2The mixture of/g porous nanos activated carbon and nano titanium oxide, wherein porous nano activated carbon pore size are 20nm, and mass ratio shared by nano titanium oxide is 2%.
Embodiment 2
A kind of composite air filtering paper; it is made up of protective layer, adsorption layer and filter layer; it is characterized in that the filter layer by avarage fiber diameter be 2.0 μm, the ultra-fine fibre glass that draw ratio is 50 and length is 10mm, avarage fiber diameter is 15 μm the alkali-free glass fibre silk that is chopped constitutes; filter layer thickness is 0.5mm; respectively there are one layer of adsorption layer and layer protective layer in filter layer both sides; wherein adsorption layer is all located between protective layer and filter layer, with viscosity is that 1200mpas phenolic resin adhesives cohere between described protective layer, adsorption layer and filter layer.
Mass ratio shared by ultra-fine fibre glass is 70% in the filter layer.
The protective layer is grammes per square metre 80g/m2Chemical fabric or glass-fiber-fabric, thickness is 0.5mm, and mesh aperture size is 120mm.
Described adsorption layer is made up of 10 thickness degree for 1mm grid cloth, wherein the functional coat of every layer of 50 μm of grid cloth surface coating thickness.
The functional coat is that particle diameter is 1000nm, specific surface area 1500m2The mixture of/g porous nanos activated carbon and nano titanium oxide, wherein porous nano activated carbon pore size are 80nm, and mass ratio shared by nano titanium oxide is 6%.
It the above is only in conjunction with specific embodiments, the present invention is furture elucidated, it should be understood that these embodiments are only illustrative of the invention and is not intended to limit the scope of the invention, after the present invention has been read, modification of the those skilled in the art to the various equivalent form of values of the present invention falls within the application appended claims and limited.
Claims (5)
1. a kind of composite air filtering paper, is made up of protective layer, adsorption layer and filter layer, it is characterised in that the filter layer is by putting down
The ultra-fine fibre glass and length that equal fibre diameter is 1.0~2.0 μm, draw ratio is 15~50 are 1~10mm, avarage fiber diameter
Constituted for the chopped silk of 5~15 μm of alkali-free glass fibres, filter layer thickness is 0.01~0.5mm, and filter layer both sides respectively have one layer
Adsorption layer and layer protective layer, wherein adsorption layer are all located between protective layer and filter layer, described protective layer, adsorption layer and mistake
Cohered between filtering layer with viscosity for 700~1200mpas phenolic resin adhesives.
2. combined filtration paper according to claim 1, it is characterised in that quality shared by ultra-fine fibre glass in the filter layer
Ratio is 50~70%.
3. combined filtration paper according to claim 1, it is characterised in that the protective layer is 60~80g/m of grammes per square metre2Chemical fibre
Cloth or glass-fiber-fabric, thickness are 0.01~0.5mm, and mesh aperture size is 60~120mm.
4. combined filtration paper according to claim 1, it is characterised in that described adsorption layer is by 2~10 thickness degree
0.3~1.0mm grid cloth composition, wherein the functional coat of every layer of 3~50 μm of grid cloth surface coating thickness.
5. the adsorption layer according to claim 1 or 4, it is characterised in that the functional coat be particle diameter be 600~1000nm,
1000~1500m of specific surface area2The mixture of/g porous nanos activated carbon and nano titanium oxide, wherein porous nano activated carbon hole
Footpath is 20~80nm, and mass ratio shared by nano titanium oxide is 2~6%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610280013.8A CN107303448A (en) | 2016-04-22 | 2016-04-22 | A kind of composite air filtering paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610280013.8A CN107303448A (en) | 2016-04-22 | 2016-04-22 | A kind of composite air filtering paper |
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| Publication Number | Publication Date |
|---|---|
| CN107303448A true CN107303448A (en) | 2017-10-31 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610280013.8A Pending CN107303448A (en) | 2016-04-22 | 2016-04-22 | A kind of composite air filtering paper |
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| CN (1) | CN107303448A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107803066A (en) * | 2017-12-06 | 2018-03-16 | 范鸣 | The splice type filtering material for air purifying of one kind of multiple combinations of materials |
| CN108749219A (en) * | 2018-08-02 | 2018-11-06 | 江苏金由新材料有限公司 | A kind of MULTILAYER COMPOSITE filter material on air filter |
| CN110237608A (en) * | 2019-07-04 | 2019-09-17 | 江苏中科睿赛污染控制工程有限公司 | A kind of air filting material and preparation method thereof and purposes |
| CN112501938A (en) * | 2020-12-01 | 2021-03-16 | 南京玻璃纤维研究设计院有限公司 | High-dust-holding and static-dissipation glass fiber filter material and preparation method thereof |
| CN115369692A (en) * | 2022-08-29 | 2022-11-22 | 华南理工大学 | Efficient air filtering material with lasting antibacterial and mildew-proof functions and preparation method thereof |
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| CN2912764Y (en) * | 2006-05-30 | 2007-06-20 | 上海华成针刺材料有限公司 | Ultra-fine glass fiber surface layer thermostable composite filter felt |
| JP2012086183A (en) * | 2010-10-21 | 2012-05-10 | Orion Machinery Co Ltd | Air purifier for compressed air |
| CN104213470A (en) * | 2014-09-09 | 2014-12-17 | 重庆再升科技股份有限公司 | Glass fiber air filter paper repeatedly cleaned and preparation method of glass fiber air filter paper |
| CN204815966U (en) * | 2015-07-22 | 2015-12-02 | 河南省安克林滤业有限公司 | Air filter material of high temperature resistant mould proof |
| CN105233571A (en) * | 2015-10-22 | 2016-01-13 | 南京航空航天大学 | Antibacterial glass-fiber composite filter paper and preparation method thereof |
| CN105396372A (en) * | 2015-10-22 | 2016-03-16 | 南京航空航天大学 | Ultrafine glass fiber composite filter paper and making method thereof |
-
2016
- 2016-04-22 CN CN201610280013.8A patent/CN107303448A/en active Pending
Patent Citations (6)
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| CN2912764Y (en) * | 2006-05-30 | 2007-06-20 | 上海华成针刺材料有限公司 | Ultra-fine glass fiber surface layer thermostable composite filter felt |
| JP2012086183A (en) * | 2010-10-21 | 2012-05-10 | Orion Machinery Co Ltd | Air purifier for compressed air |
| CN104213470A (en) * | 2014-09-09 | 2014-12-17 | 重庆再升科技股份有限公司 | Glass fiber air filter paper repeatedly cleaned and preparation method of glass fiber air filter paper |
| CN204815966U (en) * | 2015-07-22 | 2015-12-02 | 河南省安克林滤业有限公司 | Air filter material of high temperature resistant mould proof |
| CN105233571A (en) * | 2015-10-22 | 2016-01-13 | 南京航空航天大学 | Antibacterial glass-fiber composite filter paper and preparation method thereof |
| CN105396372A (en) * | 2015-10-22 | 2016-03-16 | 南京航空航天大学 | Ultrafine glass fiber composite filter paper and making method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107803066A (en) * | 2017-12-06 | 2018-03-16 | 范鸣 | The splice type filtering material for air purifying of one kind of multiple combinations of materials |
| CN108749219A (en) * | 2018-08-02 | 2018-11-06 | 江苏金由新材料有限公司 | A kind of MULTILAYER COMPOSITE filter material on air filter |
| CN110237608A (en) * | 2019-07-04 | 2019-09-17 | 江苏中科睿赛污染控制工程有限公司 | A kind of air filting material and preparation method thereof and purposes |
| CN112501938A (en) * | 2020-12-01 | 2021-03-16 | 南京玻璃纤维研究设计院有限公司 | High-dust-holding and static-dissipation glass fiber filter material and preparation method thereof |
| CN115369692A (en) * | 2022-08-29 | 2022-11-22 | 华南理工大学 | Efficient air filtering material with lasting antibacterial and mildew-proof functions and preparation method thereof |
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Application publication date: 20171031 |
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