CN107286699A - Adsorb on-slip sheet material and preparation method thereof - Google Patents
Adsorb on-slip sheet material and preparation method thereof Download PDFInfo
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- CN107286699A CN107286699A CN201710640749.6A CN201710640749A CN107286699A CN 107286699 A CN107286699 A CN 107286699A CN 201710640749 A CN201710640749 A CN 201710640749A CN 107286699 A CN107286699 A CN 107286699A
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- refining
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- sheet material
- slip sheet
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
One kind absorption on-slip sheet material, it is made up of the following raw material matched by weight：0.005 0.006 parts of TPR1 parts, 1 part of natural rubber, 0.1 0.5 parts of butadiene-styrene rubber, 0.001 0.003 parts of antiaging agent, 0.001 0.003 parts of ultra-violet absorber and lubricant, obtain raw material, prepare coagulation glue, carry out conjunction refining and obtain blob of viscose；By the input glue melting box melting of obtained blob of viscose, melt is obtained；Melt pipe pass of the obtained melt by being connected with glue melting box is equably scraped on the mould release membrance of travel condition by frictioning head to frictioning head, through cooling down and winding, obtains finished product.Improve non-skid property, good toughness, applicability is wide, and process procedure is few, energy consumption can be saved, reduction prepares cost.
Description
Technical field
The invention belongs to mankind's daily living article technical field, and in particular to one kind absorption on-slip sheet material, and also relate to
And preparation method thereof.
Background technology
Above mentioned mankind's daily living article such as ground cushion, oil suction dirt pad, Indoor environment skirting go along with sb. to guard him pad, interior
Metope protection pad and sanitary ware shield decorations pad, etc..Ground cushion is such as laid down into the mat of entry door entrance hall terrace, such as CN202537060U
(Anti-slip ground cushion), CN203735949U (gluing Anti-slip ground cushion) and CN205493447U (water-proof skid-proof ground cushion), etc.；Oil suction is dirty
Pad, which such as encloses, to be invested the kitchen range top and encloses the cleaning pad for investing range hood surrounding；Indoor environment skirting protection pad, which such as encloses, is attached to building
In thing room through paint and the smooth Wood skirting line surface in surface or using for marble skirting surface increase Indoor Air
Atmosphere encloses pad；Indoor wall protection pad understands that it is attached to the wall pad that surface of wall promotes decorative effect by from the paraphrase of its word；
Sanitary ware shield decorations pad such as encloses the decorations pad for investing water closet or bathtub outer surface.
The structure that above-mentioned ground cushion, oil suction dirt pad, building skirting go along with sb. to guard him pad, metope protection pad and sanitary ware protection pad is phase
With, specifically it is made up of finish coat and adsorption layer and can be as needed to finish coat back to a side surface of adsorption layer
A side surface i.e. under use state outside assigns various patterns and/or word, can also be by finish coat back to adsorption layer
One side surface forms lint face, with sharp soil pick-up；Adsorption layer is finish coat and carrier (entrance hall terrace as the aforementioned, sanitary equipment outer wall, is kicked
Payment to a porter surface etc.) transition mutually depended on ensures layer.In addition foregoing ground cushion, the dirty pad of oil suction, metope protection pad, skirting protection pad and health
Sanitary equipment shield decorations pad etc. has common requirement：First, relatively cheap and use and meet popular consumption demand；Second, need not
By adhesive can be securely attached to carrier or as needed taken off at any time from carrier use embody use it is convenient
Property；Third, it is without any side effects to carrier and use ensure use in security；Fourth, can it is once purged reuse and
Use the preferable service life of embodiment and economized on resources.
Foregoing finish coat generally occurs in the form of non-woven fabrics, non-woven mat, printing bonded fabric or stamp non-woven mat, and preceding
The adsorption layer stated generally occurs in the form of being intended to rubbery diaphragm, and both be combined with each other and common Yang Qichang, short with its is pressed down.
Pass through the described above of applicant and the professional general knowledge of combination；Adsorption layer is foregoing absorption on-slip sheet material
Absorption non-skid property be consider whole pad quality good or not whether or technical indicator key factor whether really up to the mark.
The technical information related to foregoing pad can be seen in disclosed Chinese patent, such as CN104095504B recommends to have
" manufacture method of rubber floor mat ", the positive effect of the patent is energy saving and cost lowering and environmental protection, but purposes is single, adsorption reliability
Property and antiskid property can not reach that the expection of industry is its shortcoming.
Typical " a kind of high slip preventing abrasive rubber sheet material and preparation method thereof " provided such as CN104774350A, the patent
The high slip preventing abrasive rubber sheet material of application is made up of the following raw material matched by weight：40-60 parts of rubber, butadiene rubber
40-60 parts, 3-7 parts of zinc oxide, 1-3 parts of stearic acid, 1-3 parts of accelerator, 1-3 parts of age resistor, 3-7 parts of white carbon and fiber 8-12
Part, although the patent application scheme can embody the technique effect of the 0018th section of record of its specification, there is following shortcoming：
First, due to introducing white carbon in formula, and hard charcoal black track producing particle is small, active big and hydrophily is strong, thus be difficult during mixing
It is uniformly dispersed, especially when addition is big, gel is easily generated during mixing, sizing material is hardened and is had a strong impact on product
Absorption property；Second, due to introducing zinc oxide in formula, and zinc oxide is a kind of white powder, has one to human body
Fixed harmfulness, for example suck zinc oxide fumes zinc can be caused dry, damp and hot and show as having in oral cavity metallic taste to feel, it is thirsty,
Dry throat, appetite not just, uncomfortable in chest, dry cough and it is dizzy even cause papule, eczema etc., thus lose environmental protection safety；Third, because
White carbon easy heat when being kneaded with other raw materials, in addition to making product stiff and influenceing absorption property, physical property change
It is more apparent, as elongation at break can significantly diminish.
The content of the invention
The task of the present invention, which is that offer is a kind of, to be helped to significantly improve non-skid property, is conducive to ensureing reliable with carrier
Adsorption effect, it is beneficial to embody good toughness, has and be good at expanding adaptability to application vector, have and be easy to improve anti-aging anti-
UV resistance and the absorption on-slip sheet material increased the service life.
Another task of the present invention is to provide a kind of preparation method for adsorbing on-slip sheet material, and this method helps to simplify work
Skill, the amount of coming into operation for advantageously reducing equipment, it is beneficial to save, has and be easy to improve preparation efficiency and the absorption on-slip can be ensured
The technique effect of sheet material is able to embody comprehensively.
What the task of the present invention was performed by, one kind absorption on-slip sheet material, it is matched by weight by following
Raw material composition：TPR1 parts, 1 part of natural rubber, 0.1-0.5 parts of butadiene-styrene rubber, 0.001-0.003 parts of antiaging agent, ultraviolet
0.005-0.006 parts of 0.001-0.003 parts of absorbent and lubricant.
In the specific embodiment of the present invention, described antiaging agent is antioxidant.
In another specific embodiment of the present invention, described ultra-violet absorber is UV-326.
In another specific embodiment of the present invention, described lubricant is stearic acid.
In another specific embodiment of the present invention, described antioxidant is antioxidant 2246.
To embody another task for completing the present invention, the technical scheme that the present invention is provided is；A kind of absorption on-slip sheet material
Preparation method, comprises the following steps：
A) raw material prepares, and following raw material is weighed by weight：：TPR1 parts, 1 part of natural rubber, butadiene-styrene rubber 0.1-0.5
Part, 0.001-0.003 parts of antiaging agent, 0.001-0.003 parts of ultra-violet absorber and 0.005-0.006 parts of lubricant, are obtained
Raw material；
B elastomeric compound) is prepared, first by step A) described in TPR1 parts put into the first refining glue device and refining glue and control
The refining glue time, obtain TPR glue, then by step A) described in 1 part of first refining glue device of input of natural rubber kneaded simultaneously with TPR glue
And control mixing time, obtain elastomeric compound；
C blob of viscose) is prepared, first by step A) described in 0.1-0.5 parts of butadiene-styrene rubber the second refining glue devices of input refined
Glue and the time for controlling refining glue, obtain butadiene-styrene rubber sizing material, then by the butadiene-styrene rubber sizing material and step B) obtained elastomeric compound
Carry out conjunction refining, then add step A) described in 0.001-0.003 part of antiaging agent so that close refine, be subsequently added into step A) in
0.001-0.003 parts of described ultra-violet absorber further closes refining, followed by adding step A) described in lubricant
0.005-0.006 parts are closed refining again, are gone out the second refining glue device and stripping and slicing, are obtained blob of viscose；
D) prepare melt, will be by step C) obtained blob of viscose input glue melting box melting, obtain melt；
E) film-making, by by step D) obtained melt by the melt pipe pass that is connected with glue melting box to frictioning head, by scraping
Glue head is equably scraped on the mould release membrance of travel condition, through cooling down and winding, and obtains adsorbing on-slip sheet material.
Also have a specific embodiment in the present invention, step B) described in control refining glue time when being by refining glue
Between control be 15-25min, it is described controls mixing time be by mixing time control be 10-20min.
In a still more specific embodiment of the invention, step C) described in time of control refining glue be by refining glue
Time control be 8-12min；The time of described conjunction refining is 5-15min；Time that is described and then closing refining is 4-6min；It is described
The time for further closing refining is 4-6min；The time for closing refining again is 5-15min.
The present invention so that in a specific embodiment, step D) described in glue melting box melting temperature be 140-
160 DEG C, the melting time is 20-30S, and the viscosity of the melt is 10000-12000 centipoises.
Step E in yet a further embodiment of the present invention) described in the gait of march of mould release membrance be 10-
50m/min, described is cooled to natural cooling；The grammes per square metre of described absorption on-slip sheet material is 50-1000g/m2。
One of technique effect of technical scheme that the present invention is provided, TPR has been used due to being selected in formula, thus is able to significantly
Improve non-skid property while the resilience that is improved, wearability, damping property and flexibility；Two, due in formula plus
Natural rubber is entered, thus the reliable adsorption effect with carrier can be ensured；Three, due to adding butadiene-styrene rubber in formula,
Good toughness thus can be embodied；Four, due to introducing antiaging agent and ultra-violet absorber in formula, thus can be significantly
Increase the service life；Five, due to good pliability and resistance to acids and bases, thus can be according to need to be cleaned；Six, due to
Can be attracting with the carrier of marble surface, application surface of wall, sanitary equipment surface, kitchen surfaces, building skirting surface etc
It is attached and be not in travelling situation, thus applicability is wide；Seven there is provided preparation method process procedure it is few, without harsh work
Skill key element and the equipment that comes into operation are few, can not only meet industrial amplification production requirement, and can save energy consumption, prepared by reduction
Cost.
Embodiment
Embodiment 1：
Absorption on-slip sheet material is prepared according to the following steps：
A) raw material prepares, and following raw material is weighed by weight：TPR1 parts, it is 1 part of natural rubber, 0.3 part of butadiene-styrene rubber, anti-
0.006 part of 2,246 0.002 parts of oxygen agent, 0.002 part of UV-326 and stearic acid, obtain raw material；
B elastomeric compound) is prepared, first by step A) described in TPR1 parts put into the first refining glue device such as banbury progress refining glue
(also referred to as " banburying ", as follows) and control the refining glue time to be 25min, obtain TPR glue, then by step A) described in natural rubber
1 part of glue the first refining glue device of input and the mixing of TPR glue (also can " banburying ") and control mixing time to be called 10min, mixed
Refining glue；
C blob of viscose) is prepared, first by step A) described in 0.3 part of butadiene-styrene rubber the second refining glue device of input carry out refining glue simultaneously
And it is 10min to control time of refining glue, obtains butadiene-styrene rubber sizing material, then by the butadiene-styrene rubber sizing material and step B) obtained mixing
Glue carry out conjunction refining, the conjunctions refining time be 15min, then add step A) described in 0.002 part of antioxidant 2246 so that close refine,
And then it is 4min to close the time of refining, is subsequently added into step A) described in 0.002 part of UV-326 further close refining, further close
The time of refining is 6min, followed by adding step A) described in 0.006 part of stearic acid close refining again, the time that refining is closed again is
15min, goes out the second refining glue device and stripping and slicing, obtains blob of viscose；
D) prepare melt, will be by step C) obtained blob of viscose input glue melting box melting, melting temperature is 160 DEG C, during melting
Between be 20S, obtain viscosity be 12000 centipoises melt；
E) film-making, by by step D) obtained melt by the melt pipe pass that is connected with glue melting box to frictioning head, by scraping
Glue head is equably scraped in travel condition and gait of march, through natural cooling and is wound, and is obtained
Grammes per square metre is 1000g/m2Absorption on-slip sheet material.
Embodiment 2：
Absorption on-slip sheet material is prepared according to the following steps：
A) raw material prepares, and following raw material is weighed by weight：TPR1 parts, it is 1 part of natural rubber, 0.5 part of butadiene-styrene rubber, anti-
0.005 part of 2,246 0.001 parts of oxygen agent, 0.003 part of UV-326 and stearic acid, obtain raw material；
B elastomeric compound) is prepared, first by step A) described in TPR1 parts put into the first refining glue device such as banbury progress refining glue
(also referred to as " banburying ", as follows) and control the refining glue time to be 20min, obtain TPR glue, then by step A) described in natural rubber
1 part of glue the first refining glue device of input and the mixing of TPR glue (also can " banburying ") and control mixing time to be called 20min, mixed
Refining glue；
C blob of viscose) is prepared, first by step A) described in 0.5 part of butadiene-styrene rubber the second refining glue device of input carry out refining glue simultaneously
And it is 8min to control time of refining glue, obtains butadiene-styrene rubber sizing material, then by the butadiene-styrene rubber sizing material and step B) obtained mixing
Glue carry out conjunction refining, the conjunctions refining time be 5min, then add step A) described in 0.001 part of antioxidant 2246 so that close refine, enter
And the time for closing refining is 6min, be subsequently added into step A) described in 0.003 part of UV-326 further close refining, further close refining
Time be 5min, followed by adding step A) described in 0.005 part of stearic acid close refining again, the time that refining is closed again is
5min, goes out the second refining glue device and stripping and slicing, obtains blob of viscose；
D) prepare melt, will be by step C) obtained blob of viscose input glue melting box melting, melting temperature is 140 DEG C, during melting
Between be 30S, obtain viscosity be 10000 centipoises melt；
E) film-making, by by step D) obtained melt by the melt pipe pass that is connected with glue melting box to frictioning head, by scraping
Glue head is equably scraped in travel condition and gait of march, through natural cooling and is wound, and is obtained
Grammes per square metre is 50g/m2Absorption on-slip sheet material.
Embodiment 3：
Absorption on-slip sheet material is prepared according to the following steps：
A) raw material prepares, and following raw material is weighed by weight：TPR1 parts, it is 1 part of natural rubber, 0.1 part of butadiene-styrene rubber, anti-
0.0055 part of 2,246 0.003 parts of oxygen agent, 0.001 part of UV-326 and stearic acid, obtain raw material；
B elastomeric compound) is prepared, first by step A) described in TPR1 parts put into the first refining glue device such as banbury progress refining glue
(also referred to as " banburying ", as follows) and control the refining glue time to be 15min, obtain TPR glue, then by step A) described in natural rubber
1 part of glue the first refining glue device of input and the mixing of TPR glue (also can " banburying ") and control mixing time to be called 15min, mixed
Refining glue；
C blob of viscose) is prepared, first by step A) described in 0.1 part of butadiene-styrene rubber the second refining glue device of input carry out refining glue simultaneously
And it is 12min to control time of refining glue, obtains butadiene-styrene rubber sizing material, then by the butadiene-styrene rubber sizing material and step B) obtained mixing
Glue carry out conjunction refining, the conjunctions refining time be 10min, then add step A) described in 0.003 part of antioxidant 2246 so that close refine,
And then it is 5min to close the time of refining, is subsequently added into step A) described in 0.001 part of UV-326 further close refining, further close
The time of refining be 4min, followed by add step A) described in 0.0055 part of stearic acid close refining again, the time of refining is closed again
For 10min, go out the second refining glue device and stripping and slicing, obtain blob of viscose；
D) prepare melt, will be by step C) obtained blob of viscose input glue melting box melting, melting temperature is 150 DEG C, during melting
Between be 25S, obtain viscosity be 11000 centipoises melt；
E) film-making, by by step D) obtained melt by the melt pipe pass that is connected with glue melting box to frictioning head, by scraping
Glue head is equably scraped in travel condition and gait of march, through natural cooling and is wound, and is obtained
Grammes per square metre is 525g/m2Absorption on-slip sheet material.
The absorption on-slip sheet material that above-described embodiment 1 to 3 is obtained can be used as ground cushion, Indoor environment skirt after being combined with surface layer
Line protection pad, enclose invest kitchen range oil suction dirt pad, etc..
The absorption on-slip sheet material obtained by above-described embodiment 1 to 3 is sampled and entrusts mark detection research institute of Qingdao section limited
Company's detection (number by examining report：SCTA-C20170630-010N) there is the technical indicator shown in following table.
The detection foundation of each data is in upper table：GB/T3923.1-2013, cloth fabric tension performance part 1 of weaving：It is disconnected
Split strength and the measure (galley proof method) of elongation at break；GB/T10006-1988 plastic sheetings and thin slice measuring friction coefficient side
Method.
Claims (10)
1. one kind absorption on-slip sheet material, it is characterised in that it is made up of the following raw material matched by weight：TPR1 parts, day
Right 1 part of rubber, 0.1-0.5 parts of butadiene-styrene rubber, 0.001-0.003 parts of antiaging agent, 0.001-0.003 parts of ultra-violet absorber and
0.005-0.006 parts of lubricant.
2. absorption on-slip sheet material according to claim 1, it is characterised in that described antiaging agent is antioxidant.
3. absorption on-slip sheet material according to claim 1, it is characterised in that described ultra-violet absorber is UV-326.
4. absorption on-slip sheet material according to claim 1, it is characterised in that described lubricant is stearic acid.
5. absorption on-slip sheet material according to claim 2, it is characterised in that described antioxidant is antioxidant 2246.
6. a kind of preparation method of absorption on-slip sheet material as claimed in claim 1, it is characterised in that comprise the following steps：
A) raw material prepares, and following raw material is weighed by weight：：TPR1 parts, 1 part of natural rubber, 0.1-0.5 parts of butadiene-styrene rubber,
0.005-0.006 parts of 0.001-0.003 parts of antiaging agent, 0.001-0.003 parts of ultra-violet absorber and lubricant, obtain original
Material；
B elastomeric compound) is prepared, first by step A）Described in TPR1 parts put into the first refining glue device and carry out refining glue and control refining glue
Time, obtain TPR glue, then by step A）Described in 1 part of natural rubber the first refining glue device of input and the mixing of TPR glue and control
Mixing time processed, obtains elastomeric compound；
C blob of viscose) is prepared, first by step A）Described in 0.1-0.5 parts of butadiene-styrene rubber the second refining glue devices of input carry out refining glues simultaneously
And the time of control refining glue, obtain butadiene-styrene rubber sizing material, then by the butadiene-styrene rubber sizing material and step B）Obtained elastomeric compound is carried out
Refining is closed, step A is then added）Described in 0.001-0.003 parts of antiaging agent so that close refining, be subsequently added into step A）Described in
0.001-0.003 parts of ultra-violet absorber further close refining, followed by adding step A）Described in lubricant 0.005-
0.006 part is closed refining again, is gone out the second refining glue device and stripping and slicing, is obtained blob of viscose；
D melt) is prepared, will be by step C）Obtained blob of viscose input glue melting box melting, obtains melt；
E) film-making, will be by step D）Obtained melt by the melt pipe pass that is connected with glue melting box to frictioning head, by frictioning head
Equably scrape on the mould release membrance of travel condition, through cooling down and winding, obtain adsorbing on-slip sheet material.
7. the preparation method of absorption on-slip sheet material according to claim 6, it is characterised in that step B）Described in control
It by refining glue time control is 15-25min that the refining glue time, which is, it is described control mixing time be by mixing time control be 10-
20min。
8. the preparation method of absorption on-slip sheet material according to claim 6, it is characterised in that step C）Described in control
The time of refining glue be by the time control of refining glue be 8-12min；The time of described conjunction refining is 5-15min；Described and then conjunction refining
Time be 4-6min；The further time for closing refining is 4-6min；The time for closing refining again is 5-15min.
9. the preparation method of absorption on-slip sheet material according to claim 6, it is characterised in that step D）Described in melten gel
The temperature of case melting is 140-160 DEG C, and the melting time is 20-30S, and the viscosity of the melt is 10000-12000 centipoises.
10. the preparation method of absorption on-slip sheet material according to claim 6, it is characterised in that step E）Described in mould release membrance
Gait of march be 10-50m/min, described is cooled to natural cooling；The grammes per square metre of described absorption on-slip sheet material is 50-
1000g/m2。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710640749.6A CN107286699A (en) | 2017-07-31 | 2017-07-31 | Adsorb on-slip sheet material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710640749.6A CN107286699A (en) | 2017-07-31 | 2017-07-31 | Adsorb on-slip sheet material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107286699A true CN107286699A (en) | 2017-10-24 |
Family
ID=60103956
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710640749.6A Pending CN107286699A (en) | 2017-07-31 | 2017-07-31 | Adsorb on-slip sheet material and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN107286699A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04198293A (en) * | 1990-11-27 | 1992-07-17 | Ohtsu Tire & Rubber Co Ltd :The | Antislipping agent |
| CN103205026A (en) * | 2013-04-02 | 2013-07-17 | 福建快节奏体育用品有限公司 | Ultralight high-elastic rubber sole material and preparation method thereof |
| CN103910916A (en) * | 2014-04-01 | 2014-07-09 | 安徽金科橡塑制品有限公司 | Lightweight wear-resistant antiskid rubber |
| CN106380650A (en) * | 2016-04-28 | 2017-02-08 | 东莞市康诚鞋材有限公司 | Synthetic material for outsole of footwear |
| CN106750703A (en) * | 2017-01-07 | 2017-05-31 | 东莞市伟鑫橡胶制品有限公司 | A kind of rubber sole formula and integral forming process |
-
2017
- 2017-07-31 CN CN201710640749.6A patent/CN107286699A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04198293A (en) * | 1990-11-27 | 1992-07-17 | Ohtsu Tire & Rubber Co Ltd :The | Antislipping agent |
| CN103205026A (en) * | 2013-04-02 | 2013-07-17 | 福建快节奏体育用品有限公司 | Ultralight high-elastic rubber sole material and preparation method thereof |
| CN103910916A (en) * | 2014-04-01 | 2014-07-09 | 安徽金科橡塑制品有限公司 | Lightweight wear-resistant antiskid rubber |
| CN106380650A (en) * | 2016-04-28 | 2017-02-08 | 东莞市康诚鞋材有限公司 | Synthetic material for outsole of footwear |
| CN106750703A (en) * | 2017-01-07 | 2017-05-31 | 东莞市伟鑫橡胶制品有限公司 | A kind of rubber sole formula and integral forming process |
Non-Patent Citations (1)
| Title |
|---|
| 王扬 等: "《飞行器制造工艺与装备》", 31 May 2015, 哈尔滨工业大学出版社 * |
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