CN107275526A - A kind of high abrasion motorbicycle lead-acid storage battery - Google Patents
A kind of high abrasion motorbicycle lead-acid storage battery Download PDFInfo
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- CN107275526A CN107275526A CN201710610292.4A CN201710610292A CN107275526A CN 107275526 A CN107275526 A CN 107275526A CN 201710610292 A CN201710610292 A CN 201710610292A CN 107275526 A CN107275526 A CN 107275526A
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- parts
- hydroxyapatite
- battery
- high abrasion
- acid storage
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- 239000002253 acid Substances 0.000 title claims abstract description 24
- 238000005299 abrasion Methods 0.000 title claims abstract description 23
- 210000005056 cell body Anatomy 0.000 claims abstract description 26
- 210000004027 cell Anatomy 0.000 claims abstract description 25
- 239000004033 plastic Substances 0.000 claims abstract description 22
- 229920003023 plastic Polymers 0.000 claims abstract description 22
- 239000011159 matrix material Substances 0.000 claims abstract description 9
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 25
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 20
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 17
- -1 polypropylene Polymers 0.000 claims description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 11
- 229920001661 Chitosan Polymers 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 229960000583 acetic acid Drugs 0.000 claims description 10
- 239000012065 filter cake Substances 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000004642 Polyimide Substances 0.000 claims description 9
- 239000012362 glacial acetic acid Substances 0.000 claims description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 9
- 229920001721 polyimide Polymers 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000004677 Nylon Substances 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 8
- NWGKJDSIEKMTRX-MDZDMXLPSA-N Sorbitan oleate Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)OCC(O)C1OCC(O)C1O NWGKJDSIEKMTRX-MDZDMXLPSA-N 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 239000006229 carbon black Substances 0.000 claims description 8
- 239000007822 coupling agent Substances 0.000 claims description 8
- 230000005611 electricity Effects 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229920001778 nylon Polymers 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- 238000007781 pre-processing Methods 0.000 claims description 8
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 7
- 230000003078 antioxidant effect Effects 0.000 claims description 7
- 239000002270 dispersing agent Substances 0.000 claims description 7
- 239000004611 light stabiliser Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 7
- 239000005543 nano-size silicon particle Substances 0.000 claims description 6
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 6
- 150000002170 ethers Chemical class 0.000 claims description 4
- 238000005461 lubrication Methods 0.000 claims description 3
- 239000011806 microball Substances 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 239000003795 chemical substances by application Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052586 apatite Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/155—Lids or covers characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Secondary Cells (AREA)
Abstract
The invention discloses a kind of high abrasion motorbicycle lead-acid storage battery, including battery cell body, cell through lid and the component being arranged in battery case body, matrix arrangement has multiple component grooves in battery case body；The component is placed in corresponding component groove, and component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually；Matching on valve opening, valve opening is offered on the cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate；Wherein battery cell body, cell through lid are made using plastics.High abrasion motorbicycle lead-acid storage battery proposed by the present invention, battery cell body, cell through lid surface are smooth, and abrasion resistant effect is fabulous, stretch-proof and excellent in cushion effect, and service life is long.
Description
Technical field
The present invention relates to Lead-acid Battery Technology field, more particularly to a kind of high abrasion motorbicycle lead-acid storage battery.
Background technology
Lead-acid accumulator is best suitable for applying in renewable sources of energy wind energy, solar power generation energy-storage system, electric power combined floodgate direct current
Source system, communication spare power supplies system, the government departments and institutions such as military affairs, public security, commodity inspection, customs, institution of higher learning, scientific research institutions,
Hospital, bank, hotel, restaurant, market etc. need the department of stand-by power supply.
Lead-acid sealed battery is by positive and negative pole plate, dividing plate and electrolyte, battery case and connection strap, binding post and exhaust
Valve etc. is constituted.One battery is typically combined by 3 single lattices or 6 single lattices.If if each single lattice by dry plate positive plate with
Dry plate negative plate, interval overlapping is formed, and centre is isolated with superfine glass fibre partition board.Existing lead-acid sealed battery is still suffered from
Wear no resistance, shock resistance is difficult to the technical problem for meeting demand, it would be highly desirable to solve.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of high abrasion motorbicycle lead-acid storage battery,
Battery cell body, cell through lid surface are smooth, and abrasion resistant effect is fabulous, stretch-proof and excellent in cushion effect, and service life is long.
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting
Matrix arrangement has multiple component grooves in component in battery case body, battery case body；The component is placed on corresponding component groove
Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually；It is described
Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate；Wherein battery cell body, electricity
Pond groove lid is made using plastics.
Preferably, the raw material of plastics includes by weight：80-90 parts of base-material, modified 20-40 parts of microballoon, nanometer titanium dioxide
5-12 parts of silicon, 4-14 parts of glass microballoon, 20-35 parts of carbon black, 4-12 parts of nano titanium oxide, 1-2 parts of compatilizer, Tissuemat E 1-
2 parts, 1-2 parts of zinc stearate, 1-2 parts of dispersant, 1-2 parts of lubricant, 1-2 parts of antioxidant, 1-2 parts of light stabilizer, ultraviolet
1-2 parts of absorbent.
Preferably, modified microballoon is prepared using following technique：PLA, glacial acetic acid are well mixed, chitosan is added and stirs
Mix, add hydroxyapatite continuation stirring and obtain pre-processing hydroxyapatite；Atoleine, petroleum ether, sorbester p17 are mixed equal
It is even, instill in pretreatment hydroxyapatite, stand, filtering is washed with water filter cake, is dried to obtain modified microballoon.
Preferably, modified microballoon is prepared using following technique：PLA, glacial acetic acid are well mixed, chitosan is added and stirs
30-60min is mixed, hydroxyapatite is added and continues to stir 1-2h, whipping temp is 60-80 DEG C, obtains pre-processing hydroxyapatite；
Atoleine, petroleum ether, sorbester p17 are well mixed, the pretreatment hydroxy-apatite that mixing speed is 6200-6800r/min is instilled
Shi Zhong, stands, and filter cake is washed with water, and 1-2 DEG C is dried to obtain modified microballoon in filtering.
Preferably, modified microballoon is prepared using following technique：By weight by 10-20 parts of PLAs, 60-100 portions of ice vinegar
Acid is well mixed, adds 4-10 parts of chitosan stirring 30-60min, adds 20-40 parts of hydroxyapatites and continue to stir 1-2h, stir
Temperature is mixed for 60-80 DEG C, obtains pre-processing hydroxyapatite；By 100 parts of atoleines, 30-50 parts of petroleum ethers, 1-2 parts of sapns
80 are well mixed, and instill mixing speed in 6200-6800r/min pretreatment hydroxyapatite, to stand, filtering is washed with water
Filter cake is washed, 1-2 DEG C is dried to obtain modified microballoon.
Preferably, base-material includes by weight：60-80 parts of polyimides, 5-16 parts of nylon, polypropylene grafted maleic anhydride
2-7 parts of polymer.
Preferably, compatilizer includes by weight：1-2 parts of titanate coupling agent, 0.1-0.4 parts of rare earth compound.
Above-mentioned plastics are that the techniques such as batch mixing, injection, shaping, the demoulding are made using the technique of general plastics.
Battery cell body, the cell through lid of the present invention is made using plastics, and wherein plastics are with polyimides, nylon, poly- third
Alkene grafted maleic anhydride polymer makes plastics have high impact properties as base-material, good fluidity, easy processing, and wearability is good, makes
Use long lifespan；
In modified microballoon, PLA is well mixed with chitosan, is added hydroxyapatite and is made microballoon, dispersion effect
Good, interface binding power is strong, increase battery cell body, the intensity of cell through lid, and using atoleine and petroleum ether mixed liquor be continuous
Phase, sorbester p17 is as emulsifying agent, and cost of material is low, easily obtains, and the short time just can form microballoon, and technique is simple, into
This is low, and microballoon mode of appearance is very good, the visible microsphere features smooth surface under 40 power microscopes, balling-up rounding, good dispersion, size
Uniformly；Modified microballoon dispersion effect in polyimides, nylon, polypropylene grafted maleic anhydride polymer is fabulous, with nanometer two
Silica, which coordinates, can form network structure suppression flowing, and not only mutual combination degree is high, and makes battery cell body, battery case
Cap surface is smooth, and abrasion resistant effect is fabulous, stretch-proof and excellent in cushion effect；
Rare earth compound is compounded with titanate coupling agent, can not only improve major ingredient intensity and viscosity, is improved plastics and is resisted
Tensile property, it is ensured that battery cell body, cell through lid stress will not be broken, and the modified microballoon of enhancing, nanometer two can be cooperateed with
The compatibility and bond strength of silica, glass microballoon, carbon black, nano titanium oxide in base-material, wear-resisting and shock resistance
Further enhance, make battery cell body, cell through lid mechanical property extremely outstanding.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting
Matrix arrangement has multiple component grooves in component in battery case body, battery case body；The component is placed on corresponding component groove
Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually；It is described
Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate；Wherein battery cell body, electricity
Pond groove lid is made using plastics.
Embodiment 2
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting
Matrix arrangement has multiple component grooves in component in battery case body, battery case body；The component is placed on corresponding component groove
Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually；It is described
Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate；Wherein battery cell body, electricity
Pond groove lid is made using plastics.
The raw material of plastics includes by weight：80 parts of base-material, modified 40 parts of microballoon, 5 parts of nano silicon, glass microballoon
14 parts, 20 parts of carbon black, 12 parts of nano titanium oxide, 1 part of compatilizer, 2 parts of Tissuemat E, 1 part of zinc stearate, 2 parts of dispersant, profit
1 part of lubrication prescription, 2 parts of antioxidant, 1 part of light stabilizer, 2 parts of ultra-violet absorber.
Base-material includes by weight：60 parts of polyimides, 16 parts of nylon, 2 parts of polypropylene grafted maleic anhydride polymer.Phase
Hold agent includes by weight：2 parts of titanate coupling agent, 0.1 part of rare earth compound.
Embodiment 3
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting
Matrix arrangement has multiple component grooves in component in battery case body, battery case body；The component is placed on corresponding component groove
Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually；It is described
Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate；Wherein battery cell body, electricity
Pond groove lid is made using plastics.
The raw material of plastics includes by weight：90 parts of base-material, modified 20 parts of microballoon, 12 parts of nano silicon, glass is micro-
4 parts of pearl, 35 parts of carbon black, 4 parts of nano titanium oxide, 2 parts of compatilizer, 1 part of Tissuemat E, 2 parts of zinc stearate, 1 part of dispersant, profit
2 parts of lubrication prescription, 1 part of antioxidant, 2 parts of light stabilizer, 1 part of ultra-violet absorber.
Base-material includes by weight：80 parts of polyimides, 5 parts of nylon, 7 parts of polypropylene grafted maleic anhydride polymer.Phase
Hold agent includes by weight：1 part of titanate coupling agent, 0.4 part of rare earth compound.
Modified microballoon is prepared using following technique：PLA, glacial acetic acid are well mixed, chitosan stirring is added, adds
Hydroxyapatite continues stirring and obtains pre-processing hydroxyapatite；Atoleine, petroleum ether, sorbester p17 are well mixed, instilled
Pre-process in hydroxyapatite, stand, filtering is washed with water filter cake, is dried to obtain modified microballoon.
Embodiment 4
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting
Matrix arrangement has multiple component grooves in component in battery case body, battery case body；The component is placed on corresponding component groove
Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually；It is described
Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate；Wherein battery cell body, electricity
Pond groove lid is made using plastics.
The raw material of plastics includes by weight：82 parts of base-material, modified 35 parts of microballoon, 8 parts of nano silicon, glass microballoon
12 parts, 25 parts of carbon black, 10 parts of nano titanium oxide, 1.2 parts of compatilizer, 1.7 parts of Tissuemat E, 1.4 parts of zinc stearate, dispersant
1.6 parts, 1.2 parts of lubricant, 1.5 parts of antioxidant, 1.4 parts of light stabilizer, 1.8 parts of ultra-violet absorber.
Base-material includes by weight：65 parts of polyimides, 14 parts of nylon, 3 parts of polypropylene grafted maleic anhydride polymer.Phase
Hold agent includes by weight：1.8 parts of titanate coupling agent, 0.2 part of rare earth compound.
Modified microballoon is prepared using following technique：PLA, glacial acetic acid are well mixed, chitosan stirring 45min is added,
Add hydroxyapatite to continue to stir 1.5h, whipping temp is 70 DEG C, obtains pre-processing hydroxyapatite；By atoleine, stone
Oily ether, sorbester p17 are well mixed, and are instilled mixing speed in 6500r/min pretreatment hydroxyapatite, to stand, are filtered, use
Water washing filter cake, 1.5 DEG C are dried to obtain modified microballoon.
Embodiment 5
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting
Matrix arrangement has multiple component grooves in component in battery case body, battery case body；The component is placed on corresponding component groove
Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually；It is described
Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate；Wherein battery cell body, electricity
Pond groove lid is made using plastics.
The raw material of plastics includes by weight：88 parts of base-material, modified 25 parts of microballoon, 10 parts of nano silicon, glass is micro-
8 parts of pearl, 30 parts of carbon black, 6 parts of nano titanium oxide, 1.8 parts of compatilizer, 1.3 parts of Tissuemat E, 1.8 parts of zinc stearate, dispersant
1.2 parts, 1.8 parts of lubricant, 1.3 parts of antioxidant, 1.6 parts of light stabilizer, 1.6 parts of ultra-violet absorber.
Base-material includes by weight：75 parts of polyimides, nylon 8 part, 5 parts of polypropylene grafted maleic anhydride polymer.Phase
Hold agent includes by weight：1.2 parts of titanate coupling agent, 0.3 part of rare earth compound.
Modified microballoon is prepared using following technique：10 parts of PLAs, 100 parts of glacial acetic acid are well mixed by weight, plus
Enter 4 parts of chitosan stirring 60min, add 20 parts of hydroxyapatites and continue to stir 2h, whipping temp is 60 DEG C, obtains pre-processing hydroxyl
Base apatite；100 parts of atoleines, 50 parts of petroleum ethers, 1 part of sorbester p17 are well mixed, instillation mixing speed is 6800r/min
Pretreatment hydroxyapatite in, stand, filtering, filter cake is washed with water, 1 DEG C is dried to obtain modified microballoon.
Embodiment 6
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting
Matrix arrangement has multiple component grooves in component in battery case body, battery case body；The component is placed on corresponding component groove
Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually；It is described
Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate；Wherein battery cell body, electricity
Pond groove lid is made using plastics.
The raw material of plastics includes by weight：85 parts of base-material, modified 30 parts of microballoon, 9 parts of nano silicon, glass microballoon
10 parts, 26 parts of carbon black, 8 parts of nano titanium oxide, 1.6 parts of compatilizer, 1.5 parts of Tissuemat E, 1.6 parts of zinc stearate, dispersant
1.4 parts, 1.5 parts of lubricant, 1.4 parts of antioxidant, 1.5 parts of light stabilizer, 1.7 parts of ultra-violet absorber.
Base-material includes by weight：70 parts of polyimides, nylon 11 part, 4 parts of polypropylene grafted maleic anhydride polymer.Phase
Hold agent includes by weight：1.5 parts of titanate coupling agent, 0.25 part of rare earth compound.
Modified microballoon is prepared using following technique：20 parts of PLAs, 60 parts of glacial acetic acid are well mixed by weight, added
10 parts of chitosans stir 30min, add 40 parts of hydroxyapatites and continue to stir 1h, whipping temp is 80 DEG C, obtains pre-processing hydroxyl
Base apatite；100 parts of atoleines, 30 parts of petroleum ethers, 2 parts of sorbester p17s are well mixed, instillation mixing speed is 6200r/min
Pretreatment hydroxyapatite in, stand, filtering, filter cake is washed with water, 2 DEG C are dried to obtain modified microballoon.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of high abrasion motorbicycle lead-acid storage battery, it is characterised in that including battery cell body, cell through lid and be arranged on electricity
Matrix arrangement has multiple component grooves in component in the cell body of pond, battery case body；The component is placed in corresponding component groove, group
Part includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually；The battery case
Cover and offer valve opening, matching is provided with bonnet on valve opening, and bonnet upper end is provided with battery cover plate；Wherein battery cell body, cell through lid
It is made using plastics.
2. high abrasion motorbicycle lead-acid storage battery according to claim 1, it is characterised in that the raw material of plastics is by weight
Including：80-90 parts of base-material, modified 20-40 parts of microballoon, 5-12 parts of nano silicon, 4-14 parts of glass microballoon, carbon black 20-35
Part, 4-12 parts of nano titanium oxide, 1-2 parts of compatilizer, 1-2 parts of Tissuemat E, 1-2 parts of zinc stearate, 1-2 parts of dispersant, profit
1-2 parts of lubrication prescription, 1-2 parts of antioxidant, 1-2 parts of light stabilizer, 1-2 parts of ultra-violet absorber.
3. high abrasion motorbicycle lead-acid storage battery according to claim 2, it is characterised in that modified microballoon uses following work
It is prepared by skill：PLA, glacial acetic acid are well mixed, chitosan stirring is added, hydroxyapatite continuation stirring is added and obtains pre- place
Manage hydroxyapatite；Atoleine, petroleum ether, sorbester p17 are well mixed, instills in pretreatment hydroxyapatite, stands, mistake
Filter, is washed with water filter cake, is dried to obtain modified microballoon.
4. the high abrasion motorbicycle lead-acid storage battery according to Claims 2 or 3, it is characterised in that modified microballoon is using such as
It is prepared by lower technique：PLA, glacial acetic acid are well mixed, chitosan stirring 30-60min is added, adds hydroxyapatite and continue
1-2h is stirred, whipping temp is 60-80 DEG C, obtain pre-processing hydroxyapatite；Atoleine, petroleum ether, sorbester p17 are mixed
Uniformly, mixing speed is instilled in 6200-6800r/min pretreatment hydroxyapatite, to stand, and filter cake is washed with water in filtering,
1-2 DEG C is dried to obtain modified microballoon.
5. according to any one of the claim 2-4 high abrasion motorbicycle lead-acid storage batteries, it is characterised in that modified microballoon is adopted
Prepared with following technique：10-20 parts of PLAs, 60-100 parts of glacial acetic acid are well mixed by weight, 4-10 parts of shells is added and gathers
Sugar stirring 30-60min, adds 20-40 parts of hydroxyapatites and continues to stir 1-2h, whipping temp is 60-80 DEG C, is pre-processed
Hydroxyapatite；100 parts of atoleines, 30-50 parts of petroleum ethers, 1-2 parts of sorbester p17s are well mixed, instilling mixing speed is
In 6200-6800r/min pretreatment hydroxyapatite, stand, filtering is washed with water filter cake, 1-2 DEG C to be dried to obtain modification micro-
Ball.
6. according to any one of the claim 2-5 high abrasion motorbicycle lead-acid storage batteries, it is characterised in that base-material is by weight
Part includes：60-80 parts of polyimides, 5-16 parts of nylon, 2-7 parts of polypropylene grafted maleic anhydride polymer.
7. according to any one of the claim 2-6 high abrasion motorbicycle lead-acid storage batteries, it is characterised in that compatilizer is by weight
Amount part includes：1-2 parts of titanate coupling agent, 0.1-0.4 parts of rare earth compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710610292.4A CN107275526A (en) | 2017-07-25 | 2017-07-25 | A kind of high abrasion motorbicycle lead-acid storage battery |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710610292.4A CN107275526A (en) | 2017-07-25 | 2017-07-25 | A kind of high abrasion motorbicycle lead-acid storage battery |
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| CN107275526A true CN107275526A (en) | 2017-10-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710610292.4A Pending CN107275526A (en) | 2017-07-25 | 2017-07-25 | A kind of high abrasion motorbicycle lead-acid storage battery |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2022041417A1 (en) * | 2020-08-28 | 2022-03-03 | 南京传业环保科技有限公司 | Environmentally-friendly soil remediation agent and preparation method therefor |
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Application publication date: 20171020 |