CN107275526A - A kind of high abrasion motorbicycle lead-acid storage battery - Google Patents

A kind of high abrasion motorbicycle lead-acid storage battery Download PDF

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Publication number
CN107275526A
CN107275526A CN201710610292.4A CN201710610292A CN107275526A CN 107275526 A CN107275526 A CN 107275526A CN 201710610292 A CN201710610292 A CN 201710610292A CN 107275526 A CN107275526 A CN 107275526A
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parts
hydroxyapatite
battery
high abrasion
acid storage
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CN201710610292.4A
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Chinese (zh)
Inventor
吴建国
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Wuhu Huali Wuxing Power Technology Co Ltd
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Wuhu Huali Wuxing Power Technology Co Ltd
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Priority to CN201710610292.4A priority Critical patent/CN107275526A/en
Publication of CN107275526A publication Critical patent/CN107275526A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/116Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/147Lids or covers
    • H01M50/155Lids or covers characterised by the material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/20Batteries in motive systems, e.g. vehicle, ship, plane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

The invention discloses a kind of high abrasion motorbicycle lead-acid storage battery, including battery cell body, cell through lid and the component being arranged in battery case body, matrix arrangement has multiple component grooves in battery case body;The component is placed in corresponding component groove, and component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually;Matching on valve opening, valve opening is offered on the cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate;Wherein battery cell body, cell through lid are made using plastics.High abrasion motorbicycle lead-acid storage battery proposed by the present invention, battery cell body, cell through lid surface are smooth, and abrasion resistant effect is fabulous, stretch-proof and excellent in cushion effect, and service life is long.

Description

A kind of high abrasion motorbicycle lead-acid storage battery
Technical field
The present invention relates to Lead-acid Battery Technology field, more particularly to a kind of high abrasion motorbicycle lead-acid storage battery.
Background technology
Lead-acid accumulator is best suitable for applying in renewable sources of energy wind energy, solar power generation energy-storage system, electric power combined floodgate direct current Source system, communication spare power supplies system, the government departments and institutions such as military affairs, public security, commodity inspection, customs, institution of higher learning, scientific research institutions, Hospital, bank, hotel, restaurant, market etc. need the department of stand-by power supply.
Lead-acid sealed battery is by positive and negative pole plate, dividing plate and electrolyte, battery case and connection strap, binding post and exhaust Valve etc. is constituted.One battery is typically combined by 3 single lattices or 6 single lattices.If if each single lattice by dry plate positive plate with Dry plate negative plate, interval overlapping is formed, and centre is isolated with superfine glass fibre partition board.Existing lead-acid sealed battery is still suffered from Wear no resistance, shock resistance is difficult to the technical problem for meeting demand, it would be highly desirable to solve.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of high abrasion motorbicycle lead-acid storage battery, Battery cell body, cell through lid surface are smooth, and abrasion resistant effect is fabulous, stretch-proof and excellent in cushion effect, and service life is long.
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting Matrix arrangement has multiple component grooves in component in battery case body, battery case body;The component is placed on corresponding component groove Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually;It is described Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate;Wherein battery cell body, electricity Pond groove lid is made using plastics.
Preferably, the raw material of plastics includes by weight:80-90 parts of base-material, modified 20-40 parts of microballoon, nanometer titanium dioxide 5-12 parts of silicon, 4-14 parts of glass microballoon, 20-35 parts of carbon black, 4-12 parts of nano titanium oxide, 1-2 parts of compatilizer, Tissuemat E 1- 2 parts, 1-2 parts of zinc stearate, 1-2 parts of dispersant, 1-2 parts of lubricant, 1-2 parts of antioxidant, 1-2 parts of light stabilizer, ultraviolet 1-2 parts of absorbent.
Preferably, modified microballoon is prepared using following technique:PLA, glacial acetic acid are well mixed, chitosan is added and stirs Mix, add hydroxyapatite continuation stirring and obtain pre-processing hydroxyapatite;Atoleine, petroleum ether, sorbester p17 are mixed equal It is even, instill in pretreatment hydroxyapatite, stand, filtering is washed with water filter cake, is dried to obtain modified microballoon.
Preferably, modified microballoon is prepared using following technique:PLA, glacial acetic acid are well mixed, chitosan is added and stirs 30-60min is mixed, hydroxyapatite is added and continues to stir 1-2h, whipping temp is 60-80 DEG C, obtains pre-processing hydroxyapatite; Atoleine, petroleum ether, sorbester p17 are well mixed, the pretreatment hydroxy-apatite that mixing speed is 6200-6800r/min is instilled Shi Zhong, stands, and filter cake is washed with water, and 1-2 DEG C is dried to obtain modified microballoon in filtering.
Preferably, modified microballoon is prepared using following technique:By weight by 10-20 parts of PLAs, 60-100 portions of ice vinegar Acid is well mixed, adds 4-10 parts of chitosan stirring 30-60min, adds 20-40 parts of hydroxyapatites and continue to stir 1-2h, stir Temperature is mixed for 60-80 DEG C, obtains pre-processing hydroxyapatite;By 100 parts of atoleines, 30-50 parts of petroleum ethers, 1-2 parts of sapns 80 are well mixed, and instill mixing speed in 6200-6800r/min pretreatment hydroxyapatite, to stand, filtering is washed with water Filter cake is washed, 1-2 DEG C is dried to obtain modified microballoon.
Preferably, base-material includes by weight:60-80 parts of polyimides, 5-16 parts of nylon, polypropylene grafted maleic anhydride 2-7 parts of polymer.
Preferably, compatilizer includes by weight:1-2 parts of titanate coupling agent, 0.1-0.4 parts of rare earth compound.
Above-mentioned plastics are that the techniques such as batch mixing, injection, shaping, the demoulding are made using the technique of general plastics.
Battery cell body, the cell through lid of the present invention is made using plastics, and wherein plastics are with polyimides, nylon, poly- third Alkene grafted maleic anhydride polymer makes plastics have high impact properties as base-material, good fluidity, easy processing, and wearability is good, makes Use long lifespan;
In modified microballoon, PLA is well mixed with chitosan, is added hydroxyapatite and is made microballoon, dispersion effect Good, interface binding power is strong, increase battery cell body, the intensity of cell through lid, and using atoleine and petroleum ether mixed liquor be continuous Phase, sorbester p17 is as emulsifying agent, and cost of material is low, easily obtains, and the short time just can form microballoon, and technique is simple, into This is low, and microballoon mode of appearance is very good, the visible microsphere features smooth surface under 40 power microscopes, balling-up rounding, good dispersion, size Uniformly;Modified microballoon dispersion effect in polyimides, nylon, polypropylene grafted maleic anhydride polymer is fabulous, with nanometer two Silica, which coordinates, can form network structure suppression flowing, and not only mutual combination degree is high, and makes battery cell body, battery case Cap surface is smooth, and abrasion resistant effect is fabulous, stretch-proof and excellent in cushion effect;
Rare earth compound is compounded with titanate coupling agent, can not only improve major ingredient intensity and viscosity, is improved plastics and is resisted Tensile property, it is ensured that battery cell body, cell through lid stress will not be broken, and the modified microballoon of enhancing, nanometer two can be cooperateed with The compatibility and bond strength of silica, glass microballoon, carbon black, nano titanium oxide in base-material, wear-resisting and shock resistance Further enhance, make battery cell body, cell through lid mechanical property extremely outstanding.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting Matrix arrangement has multiple component grooves in component in battery case body, battery case body;The component is placed on corresponding component groove Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually;It is described Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate;Wherein battery cell body, electricity Pond groove lid is made using plastics.
Embodiment 2
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting Matrix arrangement has multiple component grooves in component in battery case body, battery case body;The component is placed on corresponding component groove Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually;It is described Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate;Wherein battery cell body, electricity Pond groove lid is made using plastics.
The raw material of plastics includes by weight:80 parts of base-material, modified 40 parts of microballoon, 5 parts of nano silicon, glass microballoon 14 parts, 20 parts of carbon black, 12 parts of nano titanium oxide, 1 part of compatilizer, 2 parts of Tissuemat E, 1 part of zinc stearate, 2 parts of dispersant, profit 1 part of lubrication prescription, 2 parts of antioxidant, 1 part of light stabilizer, 2 parts of ultra-violet absorber.
Base-material includes by weight:60 parts of polyimides, 16 parts of nylon, 2 parts of polypropylene grafted maleic anhydride polymer.Phase Hold agent includes by weight:2 parts of titanate coupling agent, 0.1 part of rare earth compound.
Embodiment 3
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting Matrix arrangement has multiple component grooves in component in battery case body, battery case body;The component is placed on corresponding component groove Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually;It is described Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate;Wherein battery cell body, electricity Pond groove lid is made using plastics.
The raw material of plastics includes by weight:90 parts of base-material, modified 20 parts of microballoon, 12 parts of nano silicon, glass is micro- 4 parts of pearl, 35 parts of carbon black, 4 parts of nano titanium oxide, 2 parts of compatilizer, 1 part of Tissuemat E, 2 parts of zinc stearate, 1 part of dispersant, profit 2 parts of lubrication prescription, 1 part of antioxidant, 2 parts of light stabilizer, 1 part of ultra-violet absorber.
Base-material includes by weight:80 parts of polyimides, 5 parts of nylon, 7 parts of polypropylene grafted maleic anhydride polymer.Phase Hold agent includes by weight:1 part of titanate coupling agent, 0.4 part of rare earth compound.
Modified microballoon is prepared using following technique:PLA, glacial acetic acid are well mixed, chitosan stirring is added, adds Hydroxyapatite continues stirring and obtains pre-processing hydroxyapatite;Atoleine, petroleum ether, sorbester p17 are well mixed, instilled Pre-process in hydroxyapatite, stand, filtering is washed with water filter cake, is dried to obtain modified microballoon.
Embodiment 4
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting Matrix arrangement has multiple component grooves in component in battery case body, battery case body;The component is placed on corresponding component groove Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually;It is described Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate;Wherein battery cell body, electricity Pond groove lid is made using plastics.
The raw material of plastics includes by weight:82 parts of base-material, modified 35 parts of microballoon, 8 parts of nano silicon, glass microballoon 12 parts, 25 parts of carbon black, 10 parts of nano titanium oxide, 1.2 parts of compatilizer, 1.7 parts of Tissuemat E, 1.4 parts of zinc stearate, dispersant 1.6 parts, 1.2 parts of lubricant, 1.5 parts of antioxidant, 1.4 parts of light stabilizer, 1.8 parts of ultra-violet absorber.
Base-material includes by weight:65 parts of polyimides, 14 parts of nylon, 3 parts of polypropylene grafted maleic anhydride polymer.Phase Hold agent includes by weight:1.8 parts of titanate coupling agent, 0.2 part of rare earth compound.
Modified microballoon is prepared using following technique:PLA, glacial acetic acid are well mixed, chitosan stirring 45min is added, Add hydroxyapatite to continue to stir 1.5h, whipping temp is 70 DEG C, obtains pre-processing hydroxyapatite;By atoleine, stone Oily ether, sorbester p17 are well mixed, and are instilled mixing speed in 6500r/min pretreatment hydroxyapatite, to stand, are filtered, use Water washing filter cake, 1.5 DEG C are dried to obtain modified microballoon.
Embodiment 5
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting Matrix arrangement has multiple component grooves in component in battery case body, battery case body;The component is placed on corresponding component groove Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually;It is described Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate;Wherein battery cell body, electricity Pond groove lid is made using plastics.
The raw material of plastics includes by weight:88 parts of base-material, modified 25 parts of microballoon, 10 parts of nano silicon, glass is micro- 8 parts of pearl, 30 parts of carbon black, 6 parts of nano titanium oxide, 1.8 parts of compatilizer, 1.3 parts of Tissuemat E, 1.8 parts of zinc stearate, dispersant 1.2 parts, 1.8 parts of lubricant, 1.3 parts of antioxidant, 1.6 parts of light stabilizer, 1.6 parts of ultra-violet absorber.
Base-material includes by weight:75 parts of polyimides, nylon 8 part, 5 parts of polypropylene grafted maleic anhydride polymer.Phase Hold agent includes by weight:1.2 parts of titanate coupling agent, 0.3 part of rare earth compound.
Modified microballoon is prepared using following technique:10 parts of PLAs, 100 parts of glacial acetic acid are well mixed by weight, plus Enter 4 parts of chitosan stirring 60min, add 20 parts of hydroxyapatites and continue to stir 2h, whipping temp is 60 DEG C, obtains pre-processing hydroxyl Base apatite;100 parts of atoleines, 50 parts of petroleum ethers, 1 part of sorbester p17 are well mixed, instillation mixing speed is 6800r/min Pretreatment hydroxyapatite in, stand, filtering, filter cake is washed with water, 1 DEG C is dried to obtain modified microballoon.
Embodiment 6
A kind of high abrasion motorbicycle lead-acid storage battery proposed by the present invention, including battery cell body, cell through lid and setting Matrix arrangement has multiple component grooves in component in battery case body, battery case body;The component is placed on corresponding component groove Interior, component includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually;It is described Matching on valve opening, valve opening is offered on cell through lid and is provided with bonnet, bonnet upper end is provided with battery cover plate;Wherein battery cell body, electricity Pond groove lid is made using plastics.
The raw material of plastics includes by weight:85 parts of base-material, modified 30 parts of microballoon, 9 parts of nano silicon, glass microballoon 10 parts, 26 parts of carbon black, 8 parts of nano titanium oxide, 1.6 parts of compatilizer, 1.5 parts of Tissuemat E, 1.6 parts of zinc stearate, dispersant 1.4 parts, 1.5 parts of lubricant, 1.4 parts of antioxidant, 1.5 parts of light stabilizer, 1.7 parts of ultra-violet absorber.
Base-material includes by weight:70 parts of polyimides, nylon 11 part, 4 parts of polypropylene grafted maleic anhydride polymer.Phase Hold agent includes by weight:1.5 parts of titanate coupling agent, 0.25 part of rare earth compound.
Modified microballoon is prepared using following technique:20 parts of PLAs, 60 parts of glacial acetic acid are well mixed by weight, added 10 parts of chitosans stir 30min, add 40 parts of hydroxyapatites and continue to stir 1h, whipping temp is 80 DEG C, obtains pre-processing hydroxyl Base apatite;100 parts of atoleines, 30 parts of petroleum ethers, 2 parts of sorbester p17s are well mixed, instillation mixing speed is 6200r/min Pretreatment hydroxyapatite in, stand, filtering, filter cake is washed with water, 2 DEG C are dried to obtain modified microballoon.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (7)

1. a kind of high abrasion motorbicycle lead-acid storage battery, it is characterised in that including battery cell body, cell through lid and be arranged on electricity Matrix arrangement has multiple component grooves in component in the cell body of pond, battery case body;The component is placed in corresponding component groove, group Part includes positive plate, negative plate, the dividing plate being arranged between adjacent positive plate and negative plate set gradually;The battery case Cover and offer valve opening, matching is provided with bonnet on valve opening, and bonnet upper end is provided with battery cover plate;Wherein battery cell body, cell through lid It is made using plastics.
2. high abrasion motorbicycle lead-acid storage battery according to claim 1, it is characterised in that the raw material of plastics is by weight Including:80-90 parts of base-material, modified 20-40 parts of microballoon, 5-12 parts of nano silicon, 4-14 parts of glass microballoon, carbon black 20-35 Part, 4-12 parts of nano titanium oxide, 1-2 parts of compatilizer, 1-2 parts of Tissuemat E, 1-2 parts of zinc stearate, 1-2 parts of dispersant, profit 1-2 parts of lubrication prescription, 1-2 parts of antioxidant, 1-2 parts of light stabilizer, 1-2 parts of ultra-violet absorber.
3. high abrasion motorbicycle lead-acid storage battery according to claim 2, it is characterised in that modified microballoon uses following work It is prepared by skill:PLA, glacial acetic acid are well mixed, chitosan stirring is added, hydroxyapatite continuation stirring is added and obtains pre- place Manage hydroxyapatite;Atoleine, petroleum ether, sorbester p17 are well mixed, instills in pretreatment hydroxyapatite, stands, mistake Filter, is washed with water filter cake, is dried to obtain modified microballoon.
4. the high abrasion motorbicycle lead-acid storage battery according to Claims 2 or 3, it is characterised in that modified microballoon is using such as It is prepared by lower technique:PLA, glacial acetic acid are well mixed, chitosan stirring 30-60min is added, adds hydroxyapatite and continue 1-2h is stirred, whipping temp is 60-80 DEG C, obtain pre-processing hydroxyapatite;Atoleine, petroleum ether, sorbester p17 are mixed Uniformly, mixing speed is instilled in 6200-6800r/min pretreatment hydroxyapatite, to stand, and filter cake is washed with water in filtering, 1-2 DEG C is dried to obtain modified microballoon.
5. according to any one of the claim 2-4 high abrasion motorbicycle lead-acid storage batteries, it is characterised in that modified microballoon is adopted Prepared with following technique:10-20 parts of PLAs, 60-100 parts of glacial acetic acid are well mixed by weight, 4-10 parts of shells is added and gathers Sugar stirring 30-60min, adds 20-40 parts of hydroxyapatites and continues to stir 1-2h, whipping temp is 60-80 DEG C, is pre-processed Hydroxyapatite;100 parts of atoleines, 30-50 parts of petroleum ethers, 1-2 parts of sorbester p17s are well mixed, instilling mixing speed is In 6200-6800r/min pretreatment hydroxyapatite, stand, filtering is washed with water filter cake, 1-2 DEG C to be dried to obtain modification micro- Ball.
6. according to any one of the claim 2-5 high abrasion motorbicycle lead-acid storage batteries, it is characterised in that base-material is by weight Part includes:60-80 parts of polyimides, 5-16 parts of nylon, 2-7 parts of polypropylene grafted maleic anhydride polymer.
7. according to any one of the claim 2-6 high abrasion motorbicycle lead-acid storage batteries, it is characterised in that compatilizer is by weight Amount part includes:1-2 parts of titanate coupling agent, 0.1-0.4 parts of rare earth compound.
CN201710610292.4A 2017-07-25 2017-07-25 A kind of high abrasion motorbicycle lead-acid storage battery Pending CN107275526A (en)

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WO2022041417A1 (en) * 2020-08-28 2022-03-03 南京传业环保科技有限公司 Environmentally-friendly soil remediation agent and preparation method therefor

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Application publication date: 20171020