CN107268285A - 一种扩散保护的硅烷涂布全芳香聚酰胺人造革 - Google Patents

一种扩散保护的硅烷涂布全芳香聚酰胺人造革 Download PDF

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CN107268285A
CN107268285A CN201610205688.6A CN201610205688A CN107268285A CN 107268285 A CN107268285 A CN 107268285A CN 201610205688 A CN201610205688 A CN 201610205688A CN 107268285 A CN107268285 A CN 107268285A
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silane
aromatic polyamide
wholly aromatic
artificial leather
silane coating
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朱广和
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Jiangyin Huadong Plastic Products Co Ltd
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Jiangyin Huadong Plastic Products Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/125—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/065—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/066—Silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

本发明涉及一种扩散保护的硅烷涂布全芳香聚酰胺人造革，是在全芳香聚酰胺基底表面涂饰一层硅烷涂布材料并固化，硅烷涂布材料是用反应物掺混一种或多种未预缩合或部分预缩合的硅烷。硅烷的分子量大于200。硅烷在有机侧链中具有适于形成氢桥键的极性化基团。全芳香聚酰胺人造革表面经硅烷涂布材料保护后，使全芳香聚酰胺人造革具有更好的扩散保护特性，提高了全芳香聚酰胺人造革的使用品质。

Description

一种扩散保护的硅烷涂布全芳香聚酰胺人造革
技术领域
本发明属于全芳香聚酰胺人造革技术领域，具体涉及一种扩散保护的硅烷涂布的全芳香聚酰胺人造革。
背景技术
人造革是一种外观、手感似皮革并可代替其使用的塑料制品。通常以织物为底基，涂覆合成树脂及各种塑料添加制成。上世纪八十年代，昂贵的皮衣皮料一般人消费不起，应市场需求，仿冒皮革的人造革一度流行起来，被广泛应用于制衣、制包。
硅树脂生产的硅烷涂层是已知的，经过不断的发展，应该硅烷涂层作为人造革的保护层可以提高人造革的使用质量。
发明内容
本发明的目的是提供一种扩散保护的硅烷涂布全芳香聚酰胺人造革。
本发明解决上述问题所采用的技术方案为：一种扩散保护的硅烷涂布全芳香聚酰胺人造革，是在全芳香聚酰胺基底表面涂饰一层硅烷涂布材料并固化，所述硅烷涂布材料是用反应物掺混一种或多种未预缩合或部分预缩合的硅烷，并且硅烷涂布材料中包含交联分散剂。
根据本发明，所述硅烷的分子量大于200，更优选大于300，尤其是大于500，并且最优选大于1000。
本发明的范畴内，所述硅烷在有机侧链中具有适于形成氢桥键的极性化基团。
较合理的设置是，在所述固化之前，将所述硅烷与同系或非同系的硅烷或者与有机单体、低聚物或聚合物进行有机交联反应。
本发明的一项改进是在硅烷涂布材料中加入溶剂，包括醇、醋酸酯、醚或反应稀释剂。
进一步地，向全芳香聚酰胺基底上湿化学涂覆硅烷涂布材料，包括喷雾、浸渍、流涂、辊涂、涂抹、压涂、离心涂布、刮涂或真空蒸发。
与现有技术相比，本发明的优点在于：提供了一种硅烷涂布的全芳香聚酰胺人造革，经过本发明的硅烷涂布材料保护后，使全芳香聚酰胺具有更好的扩散保护特性，提高了全芳香聚酰胺人造革的使用品质。
具体实施方式
以下结合实施例对本发明作进一步详细描述。
实施例1
将11.8g己二醇和49.5g异氰酸根合丙基三乙氧基硅烷（ICTES）搅拌加热至50℃并惨混入0.1g二月桂酸二丁基锡。50℃下进一步搅拌30分钟，之后冷却至室温。
将5g上述物料溶解于10g1-甲氧基-2-丙醇中并掺混入0.2g乙酰丙酮铝和0.3g交联分散剂。
采用流涂的方式将所获得的硅烷涂布材料涂饰到全芳香聚酰胺人造革表面，之后在120℃下在通风炉中固化50分钟。
本实施例所得全芳香聚酰胺人造革具有很好的扩散保护特性。
实施例2
将30.0gDesmophen1145和4.3g异氰酸根合丙基三乙氧基硅烷（ICTES）搅拌加热至50℃并惨混入0.15g二月桂酸二丁基锡。50℃下进一步搅拌60分钟，之后冷却至室温。
将10g上述物料溶解于8g1-甲氧基-2-丙醇中并掺混入0.1g乙酰丙酮铝和0.2g交联分散剂。
采用喷雾的方式将所获得的硅烷涂布材料涂饰到全芳香聚酰胺人造革表面，之后在150℃下在通风炉中固化60分钟。
本实施例所得全芳香聚酰胺人造革具有很好的扩散保护特性。
实施例3
45℃下将22.1g氨基丙基三乙氧基硅烷和27.8g缩水甘油氧基丙基三乙氧基硅烷搅拌并在该温度下置留45分钟。
将10g反应混合物溶于12g异丙醇中并掺混入0.3g乙酰丙酮和0.2g交联分散剂。
再流涂到全芳香聚酰胺人造革表面，将涂层于120℃下在通风炉中固化20分钟。
本实施例所得全芳香聚酰胺人造革具有很好的扩散保护特性。

Claims (6)

1.一种扩散保护的硅烷涂布全芳香聚酰胺人造革，其特征在于：是在全芳香聚酰胺基底表面涂饰一层硅烷涂布材料并固化，所述硅烷涂布材料是用反应物掺混一种或多种未预缩合或部分预缩合的硅烷，并且硅烷涂布材料中包含交联分散剂。
2.根据权利要求1所述的扩散保护的硅烷涂布全芳香聚酰胺人造革，其特征在于：所述硅烷的分子量大于200。
3.根据权利要求2所述的扩散保护的硅烷涂布全芳香聚酰胺人造革，其特征在于：所述硅烷在有机侧链中具有适于形成氢桥键的极性化基团。
4.根据权利要求1所述的扩散保护的硅烷涂布全芳香聚酰胺人造革，其特征在于：在所述固化之前，将所述硅烷与同系或非同系的硅烷或者与有机单体、低聚物或聚合物进行有机交联反应。
5.根据权利要求1所述的扩散保护的硅烷涂布全芳香聚酰胺人造革，其特征在于：在硅烷涂布材料中加入溶剂，包括醇、醋酸酯、醚或反应稀释剂。
6.根据权利要求1所述的扩散保护的硅烷涂布全芳香聚酰胺人造革，其特征在于：向全芳香聚酰胺基底上湿化学涂覆硅烷涂布材料，包括喷雾、浸渍、流涂、辊涂、涂抹、压涂、离心涂布、刮涂或真空蒸发。
CN201610205688.6A 2016-04-06 2016-04-06 一种扩散保护的硅烷涂布全芳香聚酰胺人造革 Pending CN107268285A (zh)

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