CN107268273A - A kind of and crude oil makes and the use in fabric performance is improved - Google Patents
A kind of and crude oil makes and the use in fabric performance is improved Download PDFInfo
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- CN107268273A CN107268273A CN201710594900.7A CN201710594900A CN107268273A CN 107268273 A CN107268273 A CN 107268273A CN 201710594900 A CN201710594900 A CN 201710594900A CN 107268273 A CN107268273 A CN 107268273A
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- crude oil
- fabric
- anionic surfactant
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/13—Alginic acid or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Made the present invention relates to a kind of and crude oil and the use in fabric performance is improved, the hair and oil include：High molecular polymer, softening agent, emulsifying agent, organic metal salt, the auxiliary agent of non-ionic and anionic surfactant compounding；Its preparation method includes：Above-mentioned raw materials are formed through Over emulsfication stirring；Its improve fabric performance in application method, including：At fabric preceding working procedure, 20 DEG C 30 DEG C, apply and crude oil on kapok or crystal cotton fiber, be subsequently placed in balance 12h 48h in thermostatic constant wet chamber, follow-up fabric process is carried out again afterwards breaing up to be well mixed.The present invention and crude oil are easy to remove, and ecological, environmental protective, applying method is easy to operate, more saves, it is easy to industrialization production；The present invention and crude oil can make bombax cotton and crystal cotton fiber have more preferable cotton carding, into bar and fabric property, overcome fabric bottleneck of the fiber in field of textiles.
Description
Technical field
The invention belongs to crude oil and making and use field, more particularly to a kind of and crude oil is made with being knitted in improvement fiber
Use in physical performance.
Background technology
Crystal cotton fiber is the trade name of akund.Akund is grown out from the seed of Calotropis gigantea
A kind of natural plant fibre, its composition is mainly cellulose.Have many similar on bombax cotton and crystal cotton fiber structure
The characteristics of, bombax cotton and the longitudinal outward appearance of crystal cotton fiber are in cylinder, and surface is smooth, almost without a turn song, good luster, therefore wood
Cotton and crystal cotton fiber are compared with cotton fiber, it appears more soft, and gloss is preferable, but strength is poor, elastic also poor.Observed by SEM
It was found that, bombax cotton cross section is circular or ellipse, and stage casing is thicker, and top end is thinner, and closed at both ends, full of sky in cell
Gas, degree of hollowness reaches as high as 97% up to more than 80%；Crystal cotton fiber cross section is circle, and degree of hollowness seems than bombax cotton
It is bigger, and fibre wall has some differences with bombax cotton.Although the two some difference in structure and performance, on wood
The fabric property of cotton fiber and crystal cotton fiber, the characteristics of the two has very much like.Bombax cotton and crystal cotton fiber are first
Because its hollowness of fibre is big, cause that the line density of fiber is minimum, fiber is very light；Secondly as bombax cotton and crystal cotton are fine
Natural curling of the dimension without similar cotton fiber, and the surface of fiber and its it is smooth, make in terms of fabric fiber it
Between cohesive force it is too poor, and the relative warping rigidity of fiber is also bigger than glass fibre, and this can cause fiber twisting efficiency
Reduction.Because bombax cotton length is shorter, cohesive force is poor between low intensity, fiber, great difficulty is brought to fabric knitting,
So being difficult to separate fabric with the cloth process of cotton or hair, this is never big former using the one of this fiber well in the past
Cause.Currently in order to improving similar bombax cotton and crystal cotton fiber fabric property, it is necessary to set about considering in terms of two, first：Must
The weight of fiber must be increased by certain means, fiber of the fiber during fabric is reduced by increasing the weight of fiber
Random fly phenomenon.Second：The frictional force of fiber must be increased by certain means, by the friction for increasing fiber
Power increases the cohesive force between fiber.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of and crude oil and made and in fabric performance is improved
Use, emulsification should be easy to crude oil, it is easy to remove, ecological, environmental protective, applying method is easy to operate, normal-temperature operation is more saved；Should
With crude oil bombax cotton and crystal cotton fiber can be made to there is more preferable cotton carding, into bar and fabric property.
One kind and crude oil of the present invention, including：High molecular polymer, softening agent, emulsifying agent, organic metal salt, nonionic
The auxiliary agent of type and anionic surfactant compounding；Wherein the concentration of high molecular polymer is 1-10g/L, organic metal
The concentration of salt is 10-100g/L, and the assistant concentration that non-ionic and anionic surfactant is compounded is 0.2-3g/L,
Softer consistency is 0.5-2g/L, and emulsifier concentration is 0.5-10g/L, and hair and oily pH value are 7.0-7.5.
Described high molecular polymer is polyacrylic acid, polyacrylate or sodium alginate.
Described softening agent is AEO, and emulsifying agent is neopelex, and organic metal salt is
Calcium acetate.
The auxiliary agent of described non-ionic and anionic surfactant compounding be by mass ratio for 1: 1 it is non-from
Subtype and anionic surfactant are soluble in water obtained, and wherein nonionic surface active agent is aliphatic alcohol polyethenoxy
Ether, anionic surfactant is neopelex.
A kind of preparation method of the and crude oil of the present invention, including：
By high molecular polymer, softening agent, emulsifying agent, organic metal salt, non-ionic and anionic surfactant compounding
Auxiliary agent through Over emulsfication stirring form, wherein high molecular polymer be polyacrylic acid, polyacrylate or sodium alginate, it is soft
Soft dose is AEO, and emulsifying agent is neopelex, and organic metal salt is calcium acetate；It is non-ionic and
Anionic surfactant compounding auxiliary agent be by mass ratio be 1: 1 non-ionic and anionic surfactant
Soluble in water obtained, wherein nonionic surface active agent is AEO, and anionic surfactant is
Neopelex.
A kind of and crude oil of the present invention improves the application method in fabric performance, including：
At fabric preceding working procedure, 20 DEG C -30 DEG C, apply and crude oil on kapok or crystal cotton fiber, be then 25 in temperature
± 2 DEG C, relative humidity is to balance 12h-48h in 65 ± 2%, break up it is well mixed after carry out follow-up fabric process again.
Described apply hair and the kapok after oil or the rate of body weight gain of crystal cotton fiber is 10%~20%.
Described application and crude oil is to use spray pattern.
Present disclosure is mainly develops a class and crude oil by certain technical method, passes through such and crude oil processing
Bombax cotton and crystal cotton fiber, make the fabric property of similar bombax cotton and crystal cotton fiber be effectively improved, so that
The fiber is set to obtain the use of industrialization in textile industry.Pass through the kapok treated with crude oil of the present invention and crystal
Cotton (Calotropis gigantea) fiber, cohesive force and weight during fiber cotton carding are significantly heightened, and networking is easy when fiber is combed, web
It is uniform and clear；There is the characteristics of antistatic, smooth and convergence is good during into bar；Strong into the cohesive force after bar, flyings fuds fuddled is few,
Spinnability is strong.
Beneficial effect：
(1) of the invention and crude oil is easy to emulsification, it is easy to removes, ecological, environmental protective, and makes simple, cost is low.
(2) this law and crude oil applying method be normal-temperature operation, it is easy to operate, it is easy to industrialization production, more save.
(3) of the invention and crude oil can make bombax cotton and crystal cotton fiber have more preferable cotton carding, into bar and fabric
Performance, overcomes fabric bottleneck of the fiber in field of textiles.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than limitation the scope of the present invention.In addition, it is to be understood that after the content of the invention lectured has been read, people in the art
Member can make various changes or modifications to the present invention, and these equivalent form of values equally fall within the application appended claims and limited
Scope.
Embodiment 1
It is 52g/L with crude oil concentration, wherein the concentration of high molecular polymer PMA is 1g/L, organic metal salt acetic acid
The concentration of calcium is 47g/L, and the assistant concentration that non-ionic and anionic surfactant is compounded is 2g/L, softening agent fat
Fat alcohol APEO concentration is 1.5g/L, and emulsifying agent neopelex concentration is 0.5g/L；Wherein it is non-ionic and
Anionic surfactant compounding auxiliary agent be by mass ratio be 1: 1 non-ionic and anionic surfactant
Soluble in water obtained, wherein nonionic surface active agent is AEO, and anionic surfactant is
Neopelex.Temperature is 20 DEG C, and the pH value of solution is 7.0, in fabric preceding working procedure, fine to kapok with this and crude oil
Dimension is applied using spray pattern, it is treated after again thermostatic constant wet chamber (temperature (25 ± 2) DEG C, relative humidity (65 ±
2) %) equilibration time is 24h, then breaks up well mixed, controls again to enter after certain humidity (relative humidity (65 ± 2) %)
The follow-up fabric process of row.With the present invention's and after crude oil processing, fiber rate of body weight gain reaches embracing between 10.56%, fiber
Make a concerted effort to have obtained significant raising, it is possible to achieve the smooth cotton carding of fiber, into bar and fabric, blending rate is up to 70%, Ke Yifang
The yarn of up to 30-50.
Embodiment 2
It is 83g/L with crude oil concentration, wherein the concentration of high molecular polymer polyethyl acrylate is 1g/L, organic metal salt acetic acid
The concentration of calcium is 76g/L, and the assistant concentration that non-ionic and anionic surfactant is compounded is 3g/L, softening agent fat
Fat alcohol APEO concentration is 1.5g/L, and emulsifying agent neopelex concentration is 1.5g/L.Temperature is 25 DEG C, solution
PH value be 7.2, in fabric preceding working procedure, crystal cotton fiber is applied using spray pattern with this and crude oil, it is treated
Balanced again in thermostatic constant wet chamber (temperature (25 ± 2) DEG C, relative humidity (65 ± 2) %) afterwards, the time is 12h, then breaks up mixing
Uniformly, control certain humidity (relative humidity (65 ± 2) %) and carry out follow-up fabric process again afterwards.
With the present invention's and after crude oil processing, fiber rate of body weight gain reaches that the cohesive force between 13.70%, fiber is obtained
Significant to improve, it is possible to achieve the smooth cotton carding of fiber, into bar and fabric, blending rate is up to 80%, can spin up to 20-
The yarn of 50.
Embodiment 3
It is 27g/L with crude oil concentration, wherein the concentration of high molecular polymer butyl polyacrylate is 1g/L, organic metal salt acetic acid
The concentration of calcium is 24g/L, and (both mass ratioes 1: 1, are dissolved in the auxiliary agent that non-ionic and anionic surfactant is compounded
Water, wherein nonionic surface active agent are AEO, and anionic surfactant is detergent alkylate sulphur
Sour sodium) concentration be 1g/L, softening agent AEO concentration be 0.5g/L, emulsifying agent neopelex concentration
For 0.5g/L.
Temperature is 30 DEG C, and the pH value of solution is 7.5, and in fabric preceding working procedure, bombax cotton is applied with this and crude oil
Plus, balanced again in thermostatic constant wet chamber (temperature (25 ± 2) DEG C, relative humidity (65 ± 2) %) after treating, the time is 24h, so
After break up well mixed, control and carry out follow-up fabric process again after certain humidity (relative humidity (65 ± 2) %).With this
After the processing of invent and crude oil, frictional coefficient of fiber is dramatically increased, and the cohesive force met between fabric requirement, fiber is obtained
Significant raising is arrived, it is possible to achieve the smooth cotton carding of fiber, into bar and fabric, blending rate is up to 60%, can spin up to 10
The yarn of branch -30.
Embodiment 4
It is 15g/L with crude oil concentration, wherein the concentration of high molecular polymer polyisobutyl acrylate is 0.5g/L, organic metal salt
The concentration of calcium acetate is 13g/L, auxiliary agent that non-ionic and anionic surfactant is compounded (both mass ratioes 1: 1,
Water is dissolved in, wherein nonionic surface active agent is AEO, and anionic surfactant is dodecyl
Benzene sulfonic acid sodium salt) concentration be 0.5g/L, softening agent AEO concentration be 0.5g/L, emulsifying agent DBSA
Na concn is 0.5g/L.Temperature is 25 DEG C, and the pH value of solution is 7.0, in fabric preceding working procedure, fine to crystal cotton with this and crude oil
Dimension is applied using spray pattern, it is treated after again thermostatic constant wet chamber (temperature (25 ± 2) DEG C, relative humidity (65 ±
2) %) balance, the time is 24h, obtains applying the crystal cotton fiber after hair and oil, is then well mixed fabric thrashing, controls
Follow-up fabric process is carried out again after good certain humidity (relative humidity (65 ± 2) %).It is handled with the present invention's and crude oil
Afterwards, frictional coefficient of fiber significantly increases, and meets the cohesive force between fabric requirement, fiber and has obtained significant raising,
The smooth cotton carding of fiber can be realized, into bar and fabric, blending rate is up to 70%, can spin the yarn of up to 10-40.
Embodiment 5
It is 62g/L with crude oil concentration, wherein the concentration of high molecular polymer sodium alginate is 1g/L, organic metal salt calcium acetate
Concentration is 57g/L, auxiliary agent that non-ionic and anionic surfactant is compounded (both mass ratioes 1: 1, are dissolved in water,
Wherein nonionic surface active agent is AEO, and anionic surfactant is DBSA
Sodium) concentration is 2g/L, softening agent AEO concentration is 1.0g/L, and emulsifying agent neopelex concentration is
1g/L.Temperature is 25 DEG C, and the pH value of solution is 7.5, in fabric preceding working procedure, crystal cotton fiber is used with crude oil with this and sprayed
Mode is applied, and is balanced again in thermostatic constant wet chamber (temperature (25 ± 2) DEG C, relative humidity (65 ± 2) %) after treating, the time
For 24h, obtain applying the crystal cotton fiber after hair and oil, then fabric thrashing is well mixed, certain humidity is controlled (relative
Humidity (65 ± 2) %) follow-up fabric process is carried out again afterwards.With the present invention's and after crude oil processing, fiber rate of body weight gain reaches
To 11.20%, and the coefficient of friction of fiber is effectively improved, and the cohesive force between fiber has obtained significant raising,
The smooth cotton carding of fiber can be realized, into bar and fabric, blending rate is up to 80%, can spin the yarn of up to 10-50.
Embodiment 6
It is 93g/L with crude oil concentration, wherein the concentration of high molecular polymer sodium alginate is 2g/L, organic metal salt calcium acetate
Concentration is 86g/L, auxiliary agent that non-ionic and anionic surfactant is compounded (both mass ratioes 1: 1, are dissolved in water,
Wherein nonionic surface active agent is AEO, and anionic surfactant is DBSA
Sodium) concentration is 1g/L, softening agent AEO concentration is 2g/L, and emulsifying agent neopelex concentration is
2g/L。
Temperature is 30 DEG C, and the pH value of solution is 7.5, in fabric preceding working procedure, bombax cotton is used with crude oil with this and sprayed
Mist mode is applied, and is balanced again in thermostatic constant wet chamber (temperature (25 ± 2) DEG C, relative humidity (65 ± 2) %) after treating,
Time is 12h, obtains applying the bombax cotton after hair and oil, is then well mixed fabric thrashing, controls certain humidity (phase
To humidity (65 ± 2) %) follow-up fabric process is carried out again afterwards.Balanced again in thermostatic constant wet chamber after treated, the time from
24h.With the present invention's and after crude oil processing, fiber rate of body weight gain reaches 15.24%, and the coefficient of friction of fiber is obtained effectively
Raising, the cohesive force between fiber obtained significant raising, it is possible to achieve the smooth cotton carding of fiber, into bar and fabric, blending
Ratio is up to 80%, can spin the yarn of up to 20-50.
Claims (8)
1. a kind of and crude oil, should include with crude oil：It is high molecular polymer, softening agent, emulsifying agent, organic metal salt, non-ionic
The auxiliary agent compounded with anionic surfactant；Wherein the concentration of high molecular polymer is 1-10g/L, organic metal
The concentration of salt is 10-100g/L, and the assistant concentration that non-ionic and anionic surfactant is compounded is 0.2-3g/L,
Softer consistency is 0.5-2g/L, and emulsifier concentration is 0.5-10g/L, and hair and oily pH value are 7.0-7.5.
2. a kind of and crude oil according to claim 1, it is characterised in that：Described high molecular polymer be polyacrylic acid,
Polyacrylate or sodium alginate.
3. a kind of and crude oil according to claim 1, it is characterised in that：Described softening agent is aliphatic alcohol polyethenoxy
Ether, emulsifying agent is neopelex, and organic metal salt is calcium acetate.
4. a kind of and crude oil according to claim 1, it is characterised in that：Live on described non-ionic and anionic surface
Property agent compounding auxiliary agent be that mass ratio is soluble in water obtained for 1: 1 non-ionic and anionic surfactant
, wherein nonionic surface active agent is AEO, and anionic surfactant is detergent alkylate sulphur
Sour sodium.
5. a kind of and crude oil preparation method, including：By high molecular polymer, softening agent, emulsifying agent, organic metal salt, it is non-from
Subtype and the auxiliary agent of anionic surfactant compounding are formed through Over emulsfication stirring, and wherein high molecular polymer is poly- third
Olefin(e) acid, polyacrylate or sodium alginate, softening agent are AEO, and emulsifying agent is neopelex,
Organic metal salt is calcium acetate；It by mass ratio is 1: 1 that the auxiliary agent that non-ionic and anionic surfactant is compounded, which is,
Non-ionic and anionic surfactant it is soluble in water obtained, wherein nonionic surface active agent is poly alkyl alcohol
Oxygen vinethene, anionic surfactant is neopelex；A kind of and crude oil is used to improve kapok or crystal cotton
Fabric performance.
6. a kind of and crude oil as claimed in claim 6 is used to improve kapok or crystal cotton fiber fabric property, it is characterised in that：
Its application method, including：At fabric preceding working procedure, 20 DEG C -30 DEG C, apply and crude oil on kapok or crystal cotton fiber, so
Be afterwards 25 ± 2 DEG C in temperature, relative humidity is to balance 12h-48h in 65 ± 2%, breaing up it is well mixed after carry out again it is follow-up
Fabric process.
7. a kind of and crude oil as claimed in claim 6 is used to improve kapok or crystal cotton fiber fabric property, it is characterised in that：
The rate of body weight gain of kapok or crystal cotton fiber after described application and crude oil is 10%~20%.
8. a kind of and crude oil as claimed in claim 6 is used to improve kapok or crystal cotton fiber fabric property, it is characterised in that：
Described application and crude oil is to use spray pattern.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710594900.7A CN107268273A (en) | 2017-07-20 | 2017-07-20 | A kind of and crude oil makes and the use in fabric performance is improved |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710594900.7A CN107268273A (en) | 2017-07-20 | 2017-07-20 | A kind of and crude oil makes and the use in fabric performance is improved |
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| CN107268273A true CN107268273A (en) | 2017-10-20 |
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| CN201710594900.7A Withdrawn CN107268273A (en) | 2017-07-20 | 2017-07-20 | A kind of and crude oil makes and the use in fabric performance is improved |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486895A (en) * | 2018-04-28 | 2018-09-04 | 苏州大学 | A kind of Carlow silk fiber modification process |
-
2017
- 2017-07-20 CN CN201710594900.7A patent/CN107268273A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486895A (en) * | 2018-04-28 | 2018-09-04 | 苏州大学 | A kind of Carlow silk fiber modification process |
| CN108486895B (en) * | 2018-04-28 | 2021-08-03 | 苏州大学 | Carlo silk fiber modification treatment process |
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