CN107266877A - A kind of low smell enhancing flame-retardant PBT material and preparation method thereof - Google Patents
A kind of low smell enhancing flame-retardant PBT material and preparation method thereof Download PDFInfo
- Publication number
- CN107266877A CN107266877A CN201710601118.3A CN201710601118A CN107266877A CN 107266877 A CN107266877 A CN 107266877A CN 201710601118 A CN201710601118 A CN 201710601118A CN 107266877 A CN107266877 A CN 107266877A
- Authority
- CN
- China
- Prior art keywords
- retardant
- flame
- low smell
- pbt
- pbt material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of low smell enhancing flame-retardant PBT material, it is made up of the raw material of following percetage by weight：PBT resin 49.5 58%, fire retardant 11.5 13.5%, toughener 0 3%, glass fibre 30% 33%, other auxiliary agents 0.5 1%.The preparation method of the low smell enhancing flame-retardant PBT material is simple：First PBT resin drying and fire retardant are mixed, remaining composition is added and stirs together, is finally produced in melt extruder with glass extrusion.Compared with prior art, beneficial effects of the present invention are, low smell enhancing flame-retardant PBT material has good heat endurance, ultralow mold deposit is separated out, exempt to wipe mould, particularly injection molding product will not distribute penetrating odor at high temperature heat, available for the production of the heat-resistant parts such as electric cooker, electromagnetic oven, coffee machine, Garment Steamer Machine, electric oven, and be particularly suitable for use in warm-air drier air outlet grate.
Description
Technical field
The invention belongs to polymeric material field, and in particular to a kind of low smell enhancing flame-retardant PBT material and its preparation side
Method.
Background technology
PBT resin is widely used in household electrical appliances, electronic apparatus and automobile industry, because its is cheap, valency in engineering plastics
Lattice are generally the least expensive, and comprehensive mechanical property is excellent, high temperature resistant, easily fire-retardant and modified processing the features such as do not absorb water, and are widely used in household electrical appliances
Heat-resistant part and electronic apparatus, there is greatly the gesture instead of nylon.
National inventing patent [CN201610637935.X], which provides a kind of high fluidity low-melting-point glass fiber, strengthens resistance
PBT/PET materials are fired, national inventing patent [CN201510792921.0] is compound there is provided a kind of high CTI value flame-retardant reinforced PBT
Material, national inventing patent [CN201610124657.8] provides a kind of high glow-wire, high CTI value flame-proof glass fibre enhancing PBT
And preparation method thereof, national inventing patent [CN201410852365.7] also provides a kind of nonflammable resistance of 850 degree of glowing filaments
Combustion enhancing PBT plastic and preparation method thereof.
Enhancing flame-retardant PBT material in national inventing patent there is no particular requirement that for PBT resin, all be commercialization
Common PBT resin, the fire retardant being related to is brominated Polystyrene, brominated epoxy resin, brominated triazine, TDE, bromine
Change makrolon.So many patents are not studied odor problem in the enhancing actual applied at elevated temperature of flame-retardant PBT material.
As domestic household electrical appliances slowly go to the world, Asian, African and Latin American third world countries are not only entered, and enter American-European-Japanese developed country, are write
Name household electrical appliances manufacturer facilitates and splendid life body for the requirement more and more higher of material because they wish that product gives people to provide
Test.Low smell strengthens the plastic items of flame-retardant PBT material manufacture, and penetrating odor will not be distributed in high temperature long-time use
And toxic gas, it is ensured that Product Green environmental protection.
The content of the invention
The present invention provides a kind of low smell enhancing flame-retardant PBT material and preparation method thereof, and it can overcome prior art
Penetrating odor and toxic gas that material is distributed in applied at elevated temperature.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of low smell enhancing flame-retardant PBT material, its feature
It is, is made up of the raw material of following percetage by weight：PBT resin 49.5-58%, fire retardant 11.5-13.5%, toughener 0-
3%, glass fibre 30%-33%, other auxiliary agents 0.5-1%.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
It is preferred that, the PBT resin is obtained by the production of PTA methods, and soluble organic low molecular content (SOC) is almost nil,
Residual tetrahydrofuran is not contained particularly.
Specifically, the fire retardant is mixed by main flame retardant and synergistic flame retardant, main flame retardant is brominated polyphenylene second
Alkene, the synergistic flame retardant is any of antimony oxide and sodium antimonate or two kinds of mixing.
It is preferred that, the weight ratio of the main flame retardant and synergistic flame retardant is 9.5-10.5：3.
It is preferred that, the toughener is low density polyethylene (LDPE), ethylene-acrylate and ethylene-acrylate-glycidol
Any of ester or any a variety of mixing.
It is preferred that, the ethylene-acrylate-ethylene oxidic ester is ethylene-methyl acrylate-metering system
Acid glycidyl ester.
It is preferred that, the glass fibre is alkali-free chopped glass fiber or alkali-free continuous glass-fiber, the diameter 9- of the glass fibre
17um。
It is preferred that, other described auxiliary agents are calcium stearate, PE waxes, pentaerythritol stearate, silicone, antioxidant and nucleation
Any of agent or any a variety of mixing.
Present invention also offers the preparation method that above-mentioned low smell strengthens flame-retardant PBT material, it comprises the following steps：It is first
Then PBT resin is first taken into the PBT trees after drying in drying more than 4h at 115-125 DEG C according to corresponding percetage by weight
Fat and fire retardant are simultaneously stirred and evenly mixed, and add the toughener and other auxiliary agents of corresponding percetage by weight, be again stirring for it is uniform, afterwards
Raw material after mixing is put into extrusion equipment, while by side of the glass fibre of corresponding percetage by weight through the extrusion equipment
Spout or glass fibre import are added, and eventually melting extrusion is produced.
It is preferred that, in dual-screw-stem machine the extrusion temperature of melting extrusion be 180-250 DEG C, screw speed be 330-360 turn/
Point.
Compared with prior art, the beneficial effects of the invention are as follows：
On the one hand, the PBT resin produced from PTA methods, it has a splendid heat endurance, ultralow terminal carboxylate group content and
Ultra low gas volatilizees, and particularly material resin does not contain residual tetrahydrofuran (common PBT resin content of tetrahydrofuran is about
585.1mg/kg)；On the other hand, the fire retardant of penetrating odor is not distributed from long-time high temperature, two aspects, which are combined, to be prepared
Low smell enhancing flame-retardant PBT material is gone out, has solved and discharge penetrating odor during use and poisonous tetrahydrofuran
Problem.The low smell enhancing flame-retardant PBT material that the present invention is provided has good heat endurance, and ultralow mold deposit is separated out, and exempts to wipe mould,
Particularly injection molding product will not distribute penetrating odor at high temperature heat, available for electric cooker, electromagnetic oven, coffee machine,
The production of the heat-resistant parts such as Garment Steamer Machine, electric oven, be particularly suitable for use in warm-air drier air outlet grate.
Embodiment
Technical scheme is described in further detail below in conjunction with specific embodiment, example is served only for
The present invention is explained, the scope of the present invention is not intended to limit.
The method used in following examples of the present invention is conventional method without special instruction, following examples of the present invention
The middle raw material used are commercially available prod without special instruction.Given birth to specifically, PBT resin is Nantong stars company with PTA methods
The starester@HQ- II of production；Main flame retardant is the brominated Polystyrene B-701 that Japanese tail closes production；Synergistic flame retardant is lake
Nan Chen states regular grade antimony oxide, purity 99.8%；Toughener is that the silicone master batch included in Du Pont PTW, other auxiliary agents is
DOW CORNING MB50-002.
Strengthen the preparation method of flame-retardant PBT material the invention provides a kind of low smell, it comprises the following steps：First will
PBT resin is in drying more than 4h (can be effectively by moisture content and some low molecular weight volatile organic matter removals) at 115-125 DEG C, so
Take PBT resin and fire retardant after drying according to corresponding percetage by weight afterwards and be added into homogenizer and mix,
The toughener and other auxiliary agents of corresponding percetage by weight are added, is well mixed in homogenizer, afterwards by after mixing
Raw material is put into double screw extruder, while the glass fibre of corresponding percetage by weight is added through side feeding or glass fibre import
Enter, eventually melting extrusion, produce, in dual-screw-stem machine the extrusion temperature of melting extrusion be 180-250 DEG C, screw speed be
330-360 revs/min.
Each embodiment and comparative example are prepared shown in the raw material table specific as follows used during PBT material：
| Component | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| PBT resin (PTA methods) | 56.5 | 53 | 49.5 | 56.5 | 56.5 | 0 |
| Common PBT resin (DMT methods) | 0 | 0 | 0 | 0 | 0 | 49.5 |
| Brominated Polystyrene | 9.5 | 10 | 10.5 | 0 | 0 | 10.5 |
| Brominated epoxy resin | 0 | 0 | 0 | 9.5 | 0 | 0 |
| Brominated triazine | 0 | 0 | 0 | 0 | 9.5 | 0 |
| Synergistic flame retardant | 3 | 3 | 3 | 3 | 3 | 3 |
| Toughener | 0 | 3 | 3 | 0 | 0 | 3 |
| Antioxidant | 0.3 | 0.3 | 0.2 | 0.3 | 0.3 | 0.2 |
| Calcium stearate | 0.2 | 0.2 | 0.5 | 0.2 | 0.2 | 0.5 |
| Silicone master batch | 0.5 | 0.5 | 0.3 | 0.5 | 0.5 | 0.3 |
| Glass fibre | 30 | 30 | 33 | 30 | 30 | 33 |
Performance test
The anti-flammability of the enhancing flame-retardant PBT material prepared using corresponding national standard to embodiment 1 to 3 and comparative example 1 and 3,
Izod notched impact strength, tensile strength and VOC are tested, as a result as shown in the table：
From the test data of embodiment 1,2,3, material does not distribute 2 with serious penetrating odor, 4,6- tribromo-benzenes
Phenol, 2,6- dibromophenols and toxic gas tetrahydrofuran.Embodiment 1,2 is understood with comparative example 1,2, due to making in comparative example 1,2
It is fire retardant with brominated epoxy resin and brominated triazine fire retardant, therefore obtained PBT material is distributed with serious excitant gas
2,4,6- tribromphenols, the 2,6- dibromophenols of taste；Embodiment 3 is different from the PBT raw materials of comparative example 3, and embodiment 3 is not detected
To tetrahydrofuran, and comparative example 3 detects tetrahydrofuran, it is seen that PBT resin is also the key of low smell.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (10)
1. a kind of low smell enhancing flame-retardant PBT material, it is characterised in that be made up of the raw material of following percetage by weight：PBT resin
49.5-58%, fire retardant 11.5-13.5%, toughener 0-3%, glass fibre 30%-33%, other auxiliary agents 0.5-1%.
2. a kind of low smell enhancing flame-retardant PBT material according to claim 1, it is characterised in that the PBT resin by
The production of PTA methods is obtained.
3. a kind of low smell enhancing flame-retardant PBT material according to claim 1, it is characterised in that the fire retardant is by leading
Fire retardant and synergistic flame retardant are mixed, and main flame retardant is brominated Polystyrene, and the synergistic flame retardant is antimony oxide
With any of sodium antimonate or two kinds of mixing.
4. a kind of low smell enhancing flame-retardant PBT material according to claim 3, it is characterised in that the main flame retardant with
The weight ratio of synergistic flame retardant is 9.5-10.5：3.
5. a kind of low smell enhancing flame-retardant PBT material according to claim 1, it is characterised in that the toughener is low
Any of density polyethylene, ethylene-acrylate and ethylene-acrylate-ethylene oxidic ester or any a variety of mixing.
6. a kind of low smell enhancing flame-retardant PBT material according to claim 5, it is characterised in that the ethylene-acrylic acid
Ester-ethylene oxidic ester is ethylene-methyl acrylate-glyceryl methacrylate.
7. a kind of low smell enhancing flame-retardant PBT material according to claim 1, it is characterised in that the glass fibre is
Alkali-free chopped glass fiber or alkali-free continuous glass-fiber, the diameter 9-17um of the glass fibre.
8. a kind of low smell enhancing flame-retardant PBT material according to any one of claim 1 to 7, it is characterised in that it is described its
His auxiliary agent is any of calcium stearate, PE waxes, pentaerythritol stearate, silicone, antioxidant and nucleator or any many
The mixing planted.
9. a kind of a kind of low smell as described in any one of claim 1 to 8 strengthens the preparation method of flame-retardant PBT material, it is special
Levy and be, comprise the following steps：First by PBT resin in drying more than 4h at 115-125 DEG C, then according to corresponding weight hundred
Fraction take PBT resin and the fire retardant after drying and and stir and evenly mix, add corresponding percetage by weight toughener and its
His auxiliary agent, is again stirring for mixing, the raw material after mixing is put into extrusion equipment afterwards, while by the glass of corresponding percetage by weight
The side spout of the extruded equipment of glass fiber or glass fibre import are added, and eventually melting extrusion is produced.
10. a kind of low smell according to claim 9 strengthens the preparation method of flame-retardant PBT material, it is characterised in that described
Extrusion equipment is double screw extruder, and the extrusion temperature of melting extrusion is 180-250 DEG C, screw speed in double screw extruder
For 330-360 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710601118.3A CN107266877A (en) | 2017-07-21 | 2017-07-21 | A kind of low smell enhancing flame-retardant PBT material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710601118.3A CN107266877A (en) | 2017-07-21 | 2017-07-21 | A kind of low smell enhancing flame-retardant PBT material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107266877A true CN107266877A (en) | 2017-10-20 |
Family
ID=60079412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710601118.3A Pending CN107266877A (en) | 2017-07-21 | 2017-07-21 | A kind of low smell enhancing flame-retardant PBT material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107266877A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1980996A (en) * | 2004-06-29 | 2007-06-13 | 三菱工程塑料株式会社 | Flame-retardant polybutylene terephthalate composition and molded product |
| CN101928449A (en) * | 2010-09-06 | 2010-12-29 | 上海俊尔新材料有限公司 | High glowing filament ignition temperature inflaming retarding reinforced poly(butylene terephthalate) |
-
2017
- 2017-07-21 CN CN201710601118.3A patent/CN107266877A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1980996A (en) * | 2004-06-29 | 2007-06-13 | 三菱工程塑料株式会社 | Flame-retardant polybutylene terephthalate composition and molded product |
| CN101928449A (en) * | 2010-09-06 | 2010-12-29 | 上海俊尔新材料有限公司 | High glowing filament ignition temperature inflaming retarding reinforced poly(butylene terephthalate) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107266880B (en) | A kind of high flow enhuancement flame-retardant PBT material and preparation method thereof | |
| CN105001525B (en) | Low VOC, low smell environment-protection flame-proof fiberglass enhancing PP composites and preparation method thereof | |
| CN102108187B (en) | High glowing filament environmental-friendly inflaming retarding reinforced polybutylece terephthalate (PBT)/acrylonitrile butadiene styrene (ABS) alloy material and preparation method thereof | |
| CN103819866B (en) | A kind of high performance permanent anti-electrostatic fire retardant ABS material and preparation method and application | |
| CN108250586A (en) | A kind of PP/PMMA alloy materials and its preparation method and application | |
| CN102241859A (en) | Flame-retardant reinforced PP (polypropylene)/PA (polyamide) composite material and preparation method thereof | |
| CN103571187A (en) | Preparation technology of high-performance environmentally-friendly flame-retardant reinforced PA66 composite material | |
| CN102532826A (en) | Low-cost flame-retardant fiberglass-reinforced PBT (Polybutylene Terephthalate) engineering plastic and preparation method thereof | |
| CN102634158A (en) | Permanent antistatic polystyrene composite material and preparation method thereof | |
| CN102108188B (en) | Polyethylene terephthalate/acrylonitrile-butadiene-phenethylene alloy and preparation method thereof | |
| CN102952379A (en) | Environment-friendly flame retardant glass fiber reinforced polybutylece terephthalate (PBT) material with high comparative tracking index (CTI) value and high glow wire ignition temperature (GWIT) value and preparation method thereof | |
| CN109401273A (en) | A kind of high scorching hot flame-retardant PPO alloy material and preparation method thereof | |
| CN104693793B (en) | A kind of flame-retardant reinforced nylon composite and preparation method thereof | |
| CN112745630B (en) | Super-tough high-fluidity regenerated ABS/PA6 composite material and preparation method and application thereof | |
| CN103013101B (en) | Flame-retardant glass fiber-reinforced PA6/PA66 alloy material with high CTI value and high GWIT value | |
| CN101440196A (en) | Reinforced environmental-protecting flame-retardant PBT and ABS alloy material | |
| CN107266877A (en) | A kind of low smell enhancing flame-retardant PBT material and preparation method thereof | |
| CN115073891B (en) | PET high-concentration matte master batch and preparation method thereof | |
| CN102775681A (en) | High-temperature precipitation-resistant halogen-free flame-retardant polypropylene composition and preparation method thereof | |
| CN102952381A (en) | Environment-friendly flame retardant glass fiber reinforced polybutylece terephthalate/ polyethylene terephthalate (PBT/ PET) alloy material with high comparative tracking index (CTI) value and high glow wire ignition temperature (GWIT) value and preparation method thereof | |
| CN107828193A (en) | A kind of high flow enhuancement flame-retardant PBT material | |
| CN102352088A (en) | Thermoplastic halogen-free flame-retardant alloy and preparation method thereof | |
| CN105331038A (en) | Basalt fiber enhanced environment-friendly flame-retardant ABS composite material and preparation method thereof | |
| CN108530789A (en) | Environmental protection flame retardant injection grade ACS modified materials and preparation method thereof | |
| CN109161193A (en) | Conductive nylon and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171020 |
|
| RJ01 | Rejection of invention patent application after publication |