CN107266823A - It is a kind of to be used to produce composite of PVC plastic steel profile and preparation method thereof - Google Patents
It is a kind of to be used to produce composite of PVC plastic steel profile and preparation method thereof Download PDFInfo
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- CN107266823A CN107266823A CN201710621022.3A CN201710621022A CN107266823A CN 107266823 A CN107266823 A CN 107266823A CN 201710621022 A CN201710621022 A CN 201710621022A CN 107266823 A CN107266823 A CN 107266823A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to sash stuff technical field there is provided a kind of composite for being used to produce PVC plastic steel profile and preparation method thereof, the composite includes the raw material of following parts by weight：160 190 parts of PVC, 26 parts of magnesium stearate, 11 13 parts of phenolic resin, 15 25 parts of Tissuemat E, 29 parts of sodium metasilicate, 14 parts of basalt fibre, 1.2 3.5 parts of forsterite powder, 24 parts of age resister, 0.2 3.1 parts of plasticizer, 0.4 2 parts of additive, 12 parts of Nano Silver.The material is using PVC as major ingredient, age resister is compounded to improve the ageing resistace of material, Nano Silver is compounded to improve the mildew resistance of material, basalt fibre is compounded to improve the mechanical property and ageing resistace of material, forsterite powder is compounded to improve the resistance to elevated temperatures of material, plasticizer causes material to have good mechanical performance, so as to reduce ageing rate.
Description
Technical field
The invention belongs to sash stuff technical field, in particular it relates to a kind of composite wood for being used to produce PVC plastic steel profile
Material and preparation method thereof.
Background technology
Plastic-steel section bar abbreviation plastic-steel, main chemical compositions are PVC, therefore are also PVC profile.It is the one kind being widely used
New construction material, the material property is excellent, easy to process, widely used, and push-and-pull is used for generally in building construction, is opened flat
Door and window, guardrail, tubing and ceiling material.
Plastic-steel section bar why can the popularization of large area be applicable, and progressively replace wooden and aluminium door and window, and its is unique excellent
Gesture is undivided.It has the advantage that：
1st, it is durable in use：With antidetonation, weatherproof effect, service life is long.The addition of uvioresistant composition also makes plastic-steel section bar
Weather resisteant be improved, also can be safe to use even if ultraviolet very strong torrid areas.
2nd, good heat insulating：Research shows, room summer of same type using plastic-steel door and window room indoor temperature compared with
Aluminium door and window room it is averagely low 5-7 DEG C, winter different regions to be then higher by 8-15 DEG C.
3rd, cheap, the price of plastics, which is far below, has equality strength and the aluminium in life-span.
4th, rich color：Many good looks for increasing of building are given in being applicable for chromatic plastic-steel section bar.
But existing plastic-steel section bar need to be improved in terms of resistance to ag(e)ing, mildew resistance, high temperature resistant, accordingly, it would be desirable to grind
Sending out a kind of is used to produce the composite of PVC plastic steel profile.
The content of the invention
For defect of the prior art, it is used to produce the compound of PVC plastic steel profile it is an object of the invention to provide a kind of
Material and preparation method.
A kind of composite for being used to produce PVC plastic steel profile provided according to an aspect of the present invention, it is described to be used to produce
The composite of PVC plastic steel profile includes the raw material of following parts by weight：160-190 parts of PVC, 2-6 parts of magnesium stearate, phenolic aldehyde
11-13 parts of resin, 15-25 parts of Tissuemat E, 2-9 parts of sodium metasilicate, 1-4 parts of basalt fibre, forsterite powder 1.2-3.5
Part, 2-4 parts of age resister, 0.2-3.1 parts of plasticizer, 0.4-2 parts of additive, 1-2 parts of Nano Silver.
Preferably, the composite for being used to produce PVC plastic steel profile includes the raw material of following parts by weight：PVC
160-180 parts, 2-5 parts of magnesium stearate, 11-12 parts of phenolic resin, 15-21 parts of Tissuemat E, 2-8 parts of sodium metasilicate, basalt it is fine
1-3 parts of dimension, 1.2-3.1 parts of forsterite powder, 2-3 parts of age resister, 0.2-1.1 parts of plasticizer, 0.4-1 parts of additive, receive
1-2 parts of silver of rice.
Preferably, the composite for being used to produce PVC plastic steel profile includes the raw material of following parts by weight：PVC
170 parts, 3 parts of magnesium stearate, 11 parts of phenolic resin, 18 parts of Tissuemat E, 5 parts of sodium metasilicate, 2 parts of basalt fibre, forsterite
1.7 parts of powder, 2 parts of age resister, 0.7 part of plasticizer, 0.6 part of additive, 1 part of Nano Silver.
Preferably, the additive is PVDF hollow fiber membrane.
Preferably, the age resister includes the raw material of following parts by weight：9-12 parts of stearoyl lactylates zinc, poly- butyl is double
6-12 parts of phenol, 3-6 parts of isproportionated potassium rosinate, N- isopropyls-N ' -2-5 parts of diphenyl-para-phenylene diamine, 6-10 parts of vinylation phenol.
Preferably, the preparation method of the age resister is：Each raw material is weighed according to the parts by weight of claim 5,
Mixed under normal pressure and be warming up to 105 DEG C, stirring 35min, you can.
Preferably, described plasticiser component includes epoxy aliphatic acid methyl ester and chlorinated aliphatic acids methyl esters, the epoxidised fatty
Sour methyl esters is 2 with chlorinated aliphatic acids methyl esters mass ratio:3.
There is provided a kind of composite material and preparation method thereof for being used to produce PVC plastic steel profile, institute according to another aspect of the present invention
The method of stating comprises the following steps：
Step 1: weighing PVC, magnesium stearate, phenolic resin, Tissuemat E, silicic acid according to the parts by weight described in claim 1
Sodium, basalt fibre, forsterite powder, age resister, plasticizer, additive, Nano Silver；
Step 2: putting into each raw material described in step one to high speed mixer, pelleter is extruded through engineering plastics extruder after stirring
Pelletizing, you can.
Compared with prior art, the present invention has following beneficial effect：
1st, a kind of composite for being used to produce PVC plastic steel profile that the present invention is provided, the material is using PVC as major ingredient, and compounding is anti-
Aging agent improves the ageing resistace of material, compounding Nano Silver improves the mildew resistance of material, and compounding basalt fibre is carried
The mechanical property and ageing resistace of high material, compound forsterite powder to improve the resistance to elevated temperatures of material, compounding plasticising
Agent causes material to have good mechanical performance, so as to reduce ageing rate.The composite prepared by the inventive method has excellent
Resistance to ag(e)ing, mildew resistance, resistance to elevated temperatures more, preparation method are simple, easy.
2nd, added in a kind of composite for being used to produce PVC plastic steel profile that the present invention is provided, composite-material formula
Age resister ageing resistace is excellent, especially in terms of aberration and glossiness, subtracts with the extension aging speed of ageing time
Slowly, commercially available age resister is accelerated with the extension aging speed of ageing time.And the composition toxicity in the age resister
It is extremely low, environment-friendly and green.
3rd, added in a kind of composite for being used to produce PVC plastic steel profile that the present invention is provided, composite-material formula
Nano Silver particle diameter has mostly in 25 rans to the tens of kinds of pathogenic microorganisms such as Escherichia coli, gonococcus, chlamydia trachomatis
Strong suppression and killing action.The composite is prepared with Nano Silver, but material has preferable anti-mold effect.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than limitation the scope of the present invention.
Embodiment 1
A kind of composite for being used to produce PVC plastic steel profile that the present embodiment is provided, it is described to be used to produce PVC plastic steel profile
Composite includes the raw material of following parts by weight：190 parts of PVC, 2 parts of magnesium stearate, 13 parts of phenolic resin, Tissuemat E 15
Part, 9 parts of sodium metasilicate, 1 part of basalt fibre, 3.5 parts of forsterite powder, 2 parts of age resister, 3.1 parts of plasticizer, additive
0.4 part, 2 parts of Nano Silver.
Wherein, the additive is PVDF hollow fiber membrane.
Wherein, the age resister includes the raw material of following parts by weight：12 parts of stearoyl lactylates zinc, poly- butyl bis-phenol 6
Part, 6 parts of isproportionated potassium rosinate, N- isopropyls-N ' -2 parts of diphenyl-para-phenylene diamine, 10 parts of vinylation phenol.
Wherein, the preparation method of the age resister is：Each raw material is weighed according to the parts by weight of claim 5, normal
Pressure mixes and is warming up to 105 DEG C, stirring 35min, you can.
Wherein, described plasticiser component includes epoxy aliphatic acid methyl ester and chlorinated aliphatic acids methyl esters, the epoxyfatty acid
Methyl esters is 2 with chlorinated aliphatic acids methyl esters mass ratio:3.
There is provided a kind of composite material and preparation method thereof for being used to produce PVC plastic steel profile, institute according to another aspect of the present invention
The method of stating comprises the following steps：
Step 1: weighing PVC, magnesium stearate, phenolic resin, Tissuemat E, silicic acid according to the parts by weight described in claim 1
Sodium, basalt fibre, forsterite powder, age resister, plasticizer, additive, Nano Silver；
Step 2: putting into each raw material described in step one to high speed mixer, pelleter is extruded through engineering plastics extruder after stirring
Pelletizing, you can.
Embodiment 2
A kind of composite for being used to produce PVC plastic steel profile that the present embodiment is provided, it is described to be used to produce PVC plastic steel profile
Composite includes the raw material of following parts by weight：160 parts of PVC, 6 parts of magnesium stearate, 11 parts of phenolic resin, Tissuemat E 25
Part, 2 parts of sodium metasilicate, 4 parts of basalt fibre, 1.2 parts of forsterite powder, 4 parts of age resister, 0.2 part of plasticizer, additive 2
Part, 1 part of Nano Silver.
Wherein, the additive is PVDF hollow fiber membrane.
Wherein, the age resister includes the raw material of following parts by weight：9 parts of stearoyl lactylates zinc, poly- butyl bis-phenol 12
Part, 3 parts of isproportionated potassium rosinate, N- isopropyls-N ' -5 parts of diphenyl-para-phenylene diamine, 6 parts of vinylation phenol.
Wherein, the preparation method of the age resister is：Each raw material is weighed according to the parts by weight of claim 5, normal
Pressure mixes and is warming up to 105 DEG C, stirring 35min, you can.
Wherein, described plasticiser component includes epoxy aliphatic acid methyl ester and chlorinated aliphatic acids methyl esters, the epoxyfatty acid
Methyl esters is 2 with chlorinated aliphatic acids methyl esters mass ratio:3.
There is provided a kind of composite material and preparation method thereof for being used to produce PVC plastic steel profile, institute according to another aspect of the present invention
The method of stating comprises the following steps：
Step 1: weighing PVC, magnesium stearate, phenolic resin, Tissuemat E, silicic acid according to the parts by weight described in claim 1
Sodium, basalt fibre, forsterite powder, age resister, plasticizer, additive, Nano Silver；
Step 2: putting into each raw material described in step one to high speed mixer, pelleter is extruded through engineering plastics extruder after stirring
Pelletizing, you can.
Embodiment 3
A kind of composite for being used to produce PVC plastic steel profile that the present embodiment is provided, it is described to be used to produce PVC plastic steel profile
Composite includes the raw material of following parts by weight：180 parts of PVC, 2 parts of magnesium stearate, 12 parts of phenolic resin, Tissuemat E 15
Part, 8 parts of sodium metasilicate, 1 part of basalt fibre, 3.1 parts of forsterite powder, 2 parts of age resister, 1.1 parts of plasticizer, additive
0.4 part, 2 parts of Nano Silver.
Wherein, the additive is PVDF hollow fiber membrane.
Wherein, the age resister includes the raw material of following parts by weight：11 parts of stearoyl lactylates zinc, poly- butyl bis-phenol 7
Part, 5 parts of isproportionated potassium rosinate, N- isopropyls-N ' -3 parts of diphenyl-para-phenylene diamine, 8 parts of vinylation phenol.
Wherein, the preparation method of the age resister is：Each raw material is weighed according to the parts by weight of claim 5, normal
Pressure mixes and is warming up to 105 DEG C, stirring 35min, you can.
Wherein, described plasticiser component includes epoxy aliphatic acid methyl ester and chlorinated aliphatic acids methyl esters, the epoxyfatty acid
Methyl esters is 2 with chlorinated aliphatic acids methyl esters mass ratio:3.
There is provided a kind of composite material and preparation method thereof for being used to produce PVC plastic steel profile, institute according to another aspect of the present invention
The method of stating comprises the following steps：
Step 1: weighing PVC, magnesium stearate, phenolic resin, Tissuemat E, silicic acid according to the parts by weight described in claim 1
Sodium, basalt fibre, forsterite powder, age resister, plasticizer, additive, Nano Silver；
Step 2: putting into each raw material described in step one to high speed mixer, pelleter is extruded through engineering plastics extruder after stirring
Pelletizing, you can.
Embodiment 4
A kind of composite for being used to produce PVC plastic steel profile that the present embodiment is provided, it is described to be used to produce PVC plastic steel profile
Composite includes the raw material of following parts by weight：160 parts of PVC, 5 parts of magnesium stearate, 11 parts of phenolic resin, Tissuemat E 21
Part, 2 parts of sodium metasilicate, 3 parts of basalt fibre, 1.2 parts of forsterite powder, 3 parts of age resister, 0.2 part of plasticizer, additive 1
Part, 1 part of Nano Silver.
Wherein, the additive is PVDF hollow fiber membrane.
Wherein, the age resister includes the raw material of following parts by weight：11 parts of stearoyl lactylates zinc, poly- butyl bis-phenol 8
Part, 5 parts of isproportionated potassium rosinate, N- isopropyls-N ' -5 parts of diphenyl-para-phenylene diamine, 10 parts of vinylation phenol.
Wherein, the preparation method of the age resister is：Each raw material is weighed according to the parts by weight of claim 5, normal
Pressure mixes and is warming up to 105 DEG C, stirring 35min, you can.
Wherein, described plasticiser component includes epoxy aliphatic acid methyl ester and chlorinated aliphatic acids methyl esters, the epoxyfatty acid
Methyl esters is 2 with chlorinated aliphatic acids methyl esters mass ratio:3.
There is provided a kind of composite material and preparation method thereof for being used to produce PVC plastic steel profile, institute according to another aspect of the present invention
The method of stating comprises the following steps：
Step 1: weighing PVC, magnesium stearate, phenolic resin, Tissuemat E, silicic acid according to the parts by weight described in claim 1
Sodium, basalt fibre, forsterite powder, age resister, plasticizer, additive, Nano Silver；
Step 2: putting into each raw material described in step one to high speed mixer, pelleter is extruded through engineering plastics extruder after stirring
Pelletizing, you can.
Embodiment 5
A kind of composite for being used to produce PVC plastic steel profile that the present embodiment is provided, it is described to be used to produce PVC plastic steel profile
Composite includes the raw material of following parts by weight：170 parts of PVC, 3 parts of magnesium stearate, 11 parts of phenolic resin, Tissuemat E 18
Part, 5 parts of sodium metasilicate, 2 parts of basalt fibre, 1.7 parts of forsterite powder, 2 parts of age resister, 0.7 part of plasticizer, additive
0.6 part, 1 part of Nano Silver.
Wherein, the additive is PVDF hollow fiber membrane.
Wherein, the age resister includes the raw material of following parts by weight：11 parts of stearoyl lactylates zinc, poly- butyl bis-phenol 8
Part, 5 parts of isproportionated potassium rosinate, N- isopropyls-N ' -3 parts of diphenyl-para-phenylene diamine, 7 parts of vinylation phenol.
Wherein, the preparation method of the age resister is：Each raw material is weighed according to the parts by weight of claim 5, normal
Pressure mixes and is warming up to 105 DEG C, stirring 35min, you can.
Wherein, described plasticiser component includes epoxy aliphatic acid methyl ester and chlorinated aliphatic acids methyl esters, the epoxyfatty acid
Methyl esters is 2 with chlorinated aliphatic acids methyl esters mass ratio:3.
There is provided a kind of composite material and preparation method thereof for being used to produce PVC plastic steel profile, institute according to another aspect of the present invention
The method of stating comprises the following steps：
Step 1: weighing PVC, magnesium stearate, phenolic resin, Tissuemat E, silicic acid according to the parts by weight described in claim 1
Sodium, basalt fibre, forsterite powder, age resister, plasticizer, additive, Nano Silver；
Step 2: putting into each raw material described in step one to high speed mixer, pelleter is extruded through engineering plastics extruder after stirring
Pelletizing, you can.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of composite for being used to produce PVC plastic steel profile, it is characterised in that：It is described to be used to produce PVC plastic steel profile
Composite includes the raw material of following parts by weight：It is 160-190 parts of PVC, 2-6 parts of magnesium stearate, 11-13 parts of phenolic resin, poly-
15-25 parts of ethylene waxes, 2-9 parts of sodium metasilicate, 1-4 parts of basalt fibre, 1.2-3.5 parts of forsterite powder, age resister 2-4
Part, 0.2-3.1 parts of plasticizer, 0.4-2 parts of additive, 1-2 parts of Nano Silver.
2. a kind of composite for being used to produce PVC plastic steel profile according to claim 1, it is characterised in that：It is described to use
Include the raw material of following parts by weight in the composite of production PVC plastic steel profile：160-180 parts of PVC, magnesium stearate 2-5
Part, 11-12 parts of phenolic resin, 15-21 parts of Tissuemat E, 2-8 parts of sodium metasilicate, 1-3 parts of basalt fibre, forsterite powder
1.2-3.1 parts, 2-3 parts of age resister, 0.2-1.1 parts of plasticizer, 0.4-1 parts of additive, 1-2 parts of Nano Silver.
3. a kind of composite for being used to produce PVC plastic steel profile according to claim 1, it is characterised in that：It is described to use
Include the raw material of following parts by weight in the composite of production PVC plastic steel profile：170 parts of PVC, 3 parts of magnesium stearate, phenolic aldehyde
11 parts of resin, 18 parts of Tissuemat E, 5 parts of sodium metasilicate, 2 parts of basalt fibre, 1.7 parts of forsterite powder, 2 parts of age resister,
0.7 part of plasticizer, 0.6 part of additive, 1 part of Nano Silver.
4. a kind of composite for being used to produce PVC plastic steel profile according to claim 1, it is characterised in that：It is described to add
Plus agent is PVDF hollow fiber membrane.
5. a kind of composite for being used to produce PVC plastic steel profile according to claim 1, it is characterised in that：It is described anti-
Aging agent includes the raw material of following parts by weight：9-12 parts of stearoyl lactylates zinc, poly- 6-12 parts of butyl bis-phenol, disproportionated rosin acid potassium
3-6 parts of soap, N- isopropyls-N ' -2-5 parts of diphenyl-para-phenylene diamine, 6-10 parts of vinylation phenol.
6. a kind of composite for being used to produce PVC plastic steel profile according to claim 5, it is characterised in that：It is described anti-
The preparation method of aging agent is：Each raw material is weighed according to the parts by weight of claim 5, mixes at ambient pressure and is warming up to 105
DEG C, stir 35min, you can.
7. a kind of composite for being used to produce PVC plastic steel profile according to claim 1, it is characterised in that：It is described to increase
Moulding agent composition includes epoxy aliphatic acid methyl ester and chlorinated aliphatic acids methyl esters, the epoxy aliphatic acid methyl ester and chlorinated aliphatic acids methyl esters
Mass ratio is 2:3.
8. a kind of preparation method for being used to produce the composite of PVC plastic steel profile as described in claim any one of 1-7, its
It is characterised by：The preparation method comprises the following steps：
Step 1: weighing PVC, magnesium stearate, phenolic resin, Tissuemat E, silicic acid according to the parts by weight described in claim 1
Sodium, basalt fibre, forsterite powder, age resister, plasticizer, additive, Nano Silver；
Step 2: putting into each raw material described in step one to high speed mixer, pelleter is extruded through engineering plastics extruder after stirring
Pelletizing, you can.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710621022.3A CN107266823A (en) | 2017-07-27 | 2017-07-27 | It is a kind of to be used to produce composite of PVC plastic steel profile and preparation method thereof |
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| CN201710621022.3A CN107266823A (en) | 2017-07-27 | 2017-07-27 | It is a kind of to be used to produce composite of PVC plastic steel profile and preparation method thereof |
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| CN107266823A true CN107266823A (en) | 2017-10-20 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109306141A (en) * | 2018-10-11 | 2019-02-05 | 安徽省金鹏节能科技有限公司 | A kind of composite material that the plastic-steel section bar for color coextrusion produces |
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| CN106800718A (en) * | 2016-12-15 | 2017-06-06 | 滁州市自然空间建材有限公司 | A kind of fire resistant flame retardant PVC plastic-steel door window section bars |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103880449A (en) * | 2014-03-27 | 2014-06-25 | 中钢集团洛阳耐火材料研究院有限公司 | Preparation method of low-carbon aluminum-carbon refractory material for use in continuous casting |
| CN104004303A (en) * | 2014-06-16 | 2014-08-27 | 福建致尚生物质材料发展有限公司 | Compound type biological ester plasticizer |
| CN105670220A (en) * | 2016-04-11 | 2016-06-15 | 广州煌垅生物科技有限公司 | Rubber anti-aging agent composition and application thereof |
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Application publication date: 20171020 |
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