CN107266766A - A kind of high-intensity packing material and preparation method thereof - Google Patents

A kind of high-intensity packing material and preparation method thereof Download PDF

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Publication number
CN107266766A
CN107266766A CN201710494793.0A CN201710494793A CN107266766A CN 107266766 A CN107266766 A CN 107266766A CN 201710494793 A CN201710494793 A CN 201710494793A CN 107266766 A CN107266766 A CN 107266766A
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CN
China
Prior art keywords
packing material
nano silicon
intensity packing
intensity
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201710494793.0A
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Chinese (zh)
Inventor
甄坤华
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Taishan Shiheng Packaging Material Co Ltd
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Taishan Shiheng Packaging Material Co Ltd
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Priority to CN201710494793.0A priority Critical patent/CN107266766A/en
Publication of CN107266766A publication Critical patent/CN107266766A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of high-intensity packing material and preparation method thereof, the high-intensity packing material is prepared from by the following components counted by weight:Polyvinyl resin:90~110 parts;Cornstarch:0~80 part;Nylon fiber:20~40 parts;Nano silicon:10~20 parts;Octamethylcy-clotetrasiloxane:0.1~0.3 part;Coupling agent:0.2~1 part;Antioxidant:0.1~0.5 part;Epoxy modified silicone resin:10~20 parts.Relative to prior art, a kind of high-intensity packing material that the present invention is provided, plastics are modified by adding nylon fiber, nano silicon and octamethylcy-clotetrasiloxane, wherein octamethylcy-clotetrasiloxane reacts to improve its hydrophobic performance with nano silicon, nylon fiber and nano silicon effectively increase the wearability of plastic package material, so that product possesses high intensity, wear-resisting scratch-resistant, corrosion resistant premium properties, it is ensured that good packaging effect.

Description

A kind of high-intensity packing material and preparation method thereof
Technical field
The present invention relates to packaging material field, and in particular to a kind of high-intensity packing material and preparation method thereof.
Background technology
Packaging material refers to meet product packaging for manufacturing packing container, packing and decorating, packages printing, packed and transported etc. It is required that used material.The packaging of product is the important component of product, and it not only plays the work of protection in transportation With, and it is directly connected to the integrated quality of product.Packaging material both includes metal, plastics, glass, ceramics, paper, bamboo sheet, open country The main packaging material such as raw mushroom class, natural fiber, chemical fibre, composite, includes coating, adhesive, strapping, dress again The auxiliary materials such as pool, printing material.
Plastic package material is to apply a kind of extremely wide packaging material, and its key property is:First, density is small, than Intensity is high, can obtain higher packaging yield, the i.e. " packaging volume or packaging size of unit mass.Second, it is most of The chemical resistance of plastics is good, there is good acidproof, alkaline-resisting, resistance to all kinds of organic Rong's agent, long-term to place, and does not aoxidize.3rd, into Easily, required shaping energy consumption is less than metal materials such as steels for type.4th, with the good transparency, ease of coloring.5th, tool There is good intensity, the strength character of Unit Weight is high, and impact resistance is easily modified.6th, processing cost is low.7th, insulating properties It is excellent.
But the plastic package material of prior art, especially plastic sheeting still suffer from some defects, such as insufficient strength, easily tear Split, it is perishable etc., do not have good packaging effect.
The content of the invention
Based on this, it is an object of the present invention to provide a kind of height is high, wear-resisting scratch-resistant, corrosion resistant high-intensity packing material Material.
A kind of high-intensity packing material, it is prepared from by the following components counted by weight:
A kind of high-intensity packing material provided relative to prior art, the present invention, by adding nylon fiber, nanometer two Silica and octamethylcy-clotetrasiloxane are modified to plastics, and wherein octamethylcy-clotetrasiloxane occurs with nano silicon Reaction is so as to improve its hydrophobic performance, and nylon fiber and nano silicon effectively increase the wearability of plastic package material, So that product possesses high intensity, wear-resisting scratch-resistant, corrosion resistant premium properties, it is ensured that good packaging effect.
Further, the nano silicon is gas phase nano silica, and its particle diameter is 7~40nm.
Further, the coupling agent is KH570.
Further, the antioxidant is Hinered phenols antioxidant.Antioxidant can select the monomethyl benzene of 2,8 1 di-t-butyl -4 It is any in phenol, antioxidant lU1U.
Preferably, the high-intensity packing material, it is prepared from by the following components counted by weight:
The invention also discloses a kind of preparation method of above-mentioned high-intensity packing material, comprise the following steps:
S1:Each raw material components are weighed by weight;
S2:Nano silicon and octamethylcy-clotetrasiloxane are mixed into high speed agitator, stirs 10~20 minutes, obtains To modified nano silicon;
S3:The modified nano silicon that step S2 is obtained is added in kneading machine fully with remaining each raw material components Stir, obtain raw mixture;
S4:Raw mixture is added in extruder, extrusion forming, then through supercooling, obtain plastic package material finished product.
A kind of preparation method of the high-intensity packing material provided compared to prior art, the present invention, passes through high-speed stirred Siloxanes and silanol is reacted with silane and silazane, occur chemical modification, improve the hydrophobicity of nano silicon; The nano silicon after processing and other components are sufficiently mixed rear extrusion forming again, preparation method is simple, and obtained production Product have good wear-resisting scratch-resistant and Corrosion Protection.
Further, whipping temp is 120~150 DEG C in step S2, and mixer rotating speed is 1200~1500r/min.
Further, mixing time is 10~30min in step S3, and temperature is 80~90 DEG C.
In order to more fully understand and implement, the following detailed description of the present invention.
Embodiment
Further to illustrate the present invention to reach technological means and its technique effect that predetermined goal of the invention is taken, with Under in conjunction with the embodiments, a kind of high-intensity packing material proposed by the present invention and preparation method thereof embodiment is carried out detailed Illustrate, it is specific as follows.
Embodiment 1
A kind of preparation method of high-intensity packing material of the present embodiment, comprises the following steps:
S1:Each raw material components are weighed by following weight:
S2:Nano silicon and octamethylcy-clotetrasiloxane are mixed into high speed agitator, it is 130 to set whipping temp DEG C, mixer rotating speed is 1300r/min.Stirring 15 minutes, obtains modified nano silicon;
S3:The modified nano silicon that step S2 is obtained is added in kneading machine with remaining each raw material components, control Temperature processed is 85 DEG C, stirs 20min, obtains raw mixture;
S4:Raw mixture is added in extruder, extrusion forming, then through supercooling, obtain plastic package material finished product.
Embodiment 2
A kind of preparation method of high-intensity packing material of the present embodiment, comprises the following steps:
S1:Each raw material components are weighed by following weight:
S2:Nano silicon and octamethylcy-clotetrasiloxane are mixed into high speed agitator, it is 130 to set whipping temp DEG C, mixer rotating speed is 1300r/min.Stirring 15 minutes, obtains modified nano silicon;
S3:The modified nano silicon that step S2 is obtained is added in kneading machine with remaining each raw material components, control Temperature processed is 85 DEG C, stirs 20min, obtains raw mixture;
S4:Raw mixture is added in extruder, extrusion forming, then through supercooling, obtain plastic package material finished product.
Embodiment 3
A kind of preparation method of high-intensity packing material of the present embodiment, comprises the following steps:
S1:Each raw material components are weighed by following weight:
S2:Nano silicon and octamethylcy-clotetrasiloxane are mixed into high speed agitator, it is 130 to set whipping temp DEG C, mixer rotating speed is 1300r/min.Stirring 15 minutes, obtains modified nano silicon;
S3:The modified nano silicon that step S2 is obtained is added in kneading machine with remaining each raw material components, control Temperature processed is 85 DEG C, stirs 20min, obtains raw mixture;
S4:Raw mixture is added in extruder, extrusion forming, then through supercooling, obtain plastic package material finished product.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that coming for one of ordinary skill in the art Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention Scope.

Claims (8)

1. a kind of high-intensity packing material, it is characterised in that:It is prepared from by the following components counted by weight:
2. a kind of high-intensity packing material according to claim 1, it is characterised in that:The nano silicon is gas phase Nano silicon, its particle diameter is 7~40nm.
3. a kind of high-intensity packing material according to claim 1, it is characterised in that:The coupling agent is KH570.
4. a kind of high-intensity packing material according to claim 1, it is characterised in that:The antioxidant is anti-for Hinered phenols Oxygen agent.
5. a kind of high-intensity packing material according to claim 1, it is characterised in that:It is following by what is counted by weight Component is prepared from:
6. a kind of preparation method of high-intensity packing material as described in any one of Claims 1 to 5, it is characterised in that:Including Following steps:
S1:Each raw material components are weighed by weight;
S2:Nano silicon and octamethylcy-clotetrasiloxane are mixed into high speed agitator, stirs 10~20 minutes, is changed Nano silicon after property;
S3:The modified nano silicon that step S2 is obtained is added with remaining each raw material components and is sufficiently stirred in kneading machine Uniformly, raw mixture is obtained;
S4:Raw mixture is added in extruder, extrusion forming, then through supercooling, obtain plastic package material finished product.
7. a kind of preparation method of high-intensity packing material according to claim 6, it is characterised in that:Stirred in step S2 Temperature is 120~150 DEG C, and mixer rotating speed is 1200~1500r/min.
8. a kind of preparation method of high-intensity packing material according to claim 6, it is characterised in that:Stirred in step S3 Time is 10~30min, and temperature is 80~90 DEG C.
CN201710494793.0A 2017-06-26 2017-06-26 A kind of high-intensity packing material and preparation method thereof Pending CN107266766A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107641243A (en) * 2017-11-13 2018-01-30 桐城市中汇塑业有限公司 A kind of high-strength degradable polyethylene packaging material
CN107828109A (en) * 2017-11-13 2018-03-23 桐城市中汇塑业有限公司 A kind of anti-aging polyethylene packaging material of antibacterial
CN111205626A (en) * 2020-03-12 2020-05-29 江西正博实业有限公司 Preparation process of wear-resistant anti-slip sole

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1321702A (en) * 2001-05-11 2001-11-14 湖北大学化学与材料科学学院 Polyethylene/nylon blend separation material
CN1754908A (en) * 2005-05-20 2006-04-05 湖南大学 HDPE/PA-6 high-barrier polymer laminated blending material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1321702A (en) * 2001-05-11 2001-11-14 湖北大学化学与材料科学学院 Polyethylene/nylon blend separation material
CN1754908A (en) * 2005-05-20 2006-04-05 湖南大学 HDPE/PA-6 high-barrier polymer laminated blending material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107641243A (en) * 2017-11-13 2018-01-30 桐城市中汇塑业有限公司 A kind of high-strength degradable polyethylene packaging material
CN107828109A (en) * 2017-11-13 2018-03-23 桐城市中汇塑业有限公司 A kind of anti-aging polyethylene packaging material of antibacterial
CN111205626A (en) * 2020-03-12 2020-05-29 江西正博实业有限公司 Preparation process of wear-resistant anti-slip sole

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Application publication date: 20171020