CN107265793A - A kind of new plating garden wastewater zero discharge processing unit and technique - Google Patents

A kind of new plating garden wastewater zero discharge processing unit and technique Download PDF

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Publication number
CN107265793A
CN107265793A CN201710699440.4A CN201710699440A CN107265793A CN 107265793 A CN107265793 A CN 107265793A CN 201710699440 A CN201710699440 A CN 201710699440A CN 107265793 A CN107265793 A CN 107265793A
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water
mbr
waste water
film devices
concentration
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CN201710699440.4A
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Chinese (zh)
Inventor
吴军
蒋小友
唐乾茂
李运龙
艾鹏杰
张梅
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Jieyang Surface Treatment Ecological Industrial Park Co Ltd
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Jieyang Surface Treatment Ecological Industrial Park Co Ltd
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Priority to CN201710699440.4A priority Critical patent/CN107265793A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/16Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/05Conductivity or salinity
    • C02F2209/055Hardness
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a kind of new plating garden waste water zero discharge treatment process and device, realized and automatically controlled by DCS electric-control systems, after the adjusted even amount of pond homogeneous of waste water of collection, pollutant is removed into MBR reactors, produce sludge and be discharged into the preliminary volume concentration of sludge concentration tank progress, dewatering press is carried out by filter press system again, AO+MBR biochemical systems were entered in the water outlet of MBR reactors again, and further COD in water removal is removed in decomposition, ammonia nitrogen simultaneously retains activated sludge, then waste water is imported into MBR productions pond, RO multi-stage reverse osmosis systems are promoted to by producing pond, remove most of soluble salt point, COD, ammonia nitrogen etc., wherein the relatively low production water of concentration is direct or enters recovery system through fine filter, the higher production water of concentration passes through sea water desalination membrane, after MFT special membrane multi-stage compressions, crystal salt and distilled water are obtained into evaporation equipment.Waste water treatment efficiency high of the present invention, effect stability can realize that Resource recovery is recycled from waste water, sludge reduction fully achieves zero-emission there is provided the recycle-water of high-quality, terminal.

Description

A kind of new plating garden wastewater zero discharge processing unit and technique
Technical field
The invention belongs to electroplate garden technical field of waste water processing, and in particular to a kind of new plating garden waste water zero-emission Put processing unit and technique.
Background technology
Current Domestic Plating wastewater treatment routine techniques mainly includes:Chemical precipitation method, oxidation-reduction method, ion exchange Method, electrolysis, ferrite process, membrane separation technique, bioanalysis etc..Electroplating enterprise centralized production concentrates pollution treatment to be current to become Gesture, current domestic plating garden is designed and built with qualified discharge standard, and the technology path of qualified discharge causes plating Waste water can not thoroughly pollution treatment, waste water resource.The electroplating wastewater of current side planning is still located using the handling process of zero-emission In bud.
With electroplating industry develop rapidly with environmental requirement continuous improvement, it is necessary to make full use of the excellent of various processing methods Put to reclaim metal ion and water, and be aided with physics, chemistry or biological method, seek both to reclaim metal ion, and recycle-water The decrement discharge technology of resource.Plating garden centralized production, pollutant Concetrated control, the supervision of convenient environmental protection supervision department, this Requirement just to Treatment process and technique is strict, once technology is immature, technique imperfection, the electroplating enterprise of side planning will turn into Concentrated contaminated water source, serious environmental risk is brought to environment.
From the angle of recycling, from the angle of decrement discharge, consider from angle of environmental risk control etc., plating garden gives up Water using process route and the technology of zero-emission be in the urgent need to.The technical matters of zero-emission is come compared with the technique of qualified discharge Say, operation costs, the stability of technique are maximum problems.
The content of the invention
The purpose of the present invention is to overcome the deficiencies in the prior art to be handled there is provided a kind of new plating garden wastewater zero discharge Device and technique, realize that Resource recovery is recycled from waste water, sludge reduction, while providing high-quality recycle-water, waste water Governance efficiency is high, and effect stability, terminal fully achieves zero-emission.
To achieve the above object, the technical scheme that provides of the present invention is:
A kind of new plating garden wastewater zero discharge processing unit, including DCS electric-control systems, collecting pit, regulating reservoir, MBR are anti- Answer device, A+Q+MBR biochemical systems, MBR productions pond, RO multi-stage reverse osmosis system, sea water desalination membrane, 90KG MFT special membranes, remove It is sequentially connected between hardness device, 160KG MFT special membranes and evaporation equipment, each process equipment by pipeline, wherein, the DCS Electric-control system automatically controls current according to online information such as the liquid levels, electrical conductivity, pressure of each equipment working state and water quality current In the output flow of each equipment room, the MBR reactors connection sludge concentration tank, filter press system, the multistage reverse osmosis of the RO Permeable system is made up of the film devices of RO I, the film devices of RO II and the film devices of RO III, and is sequentially connected, and the film devices of RO I and seawater are light Change film connection, the film devices of RO II are connected with reuse water system, and the film devices of RO III and fine filter, reuse water system are successively Connection.
Further, A+O+MBR biochemical systems mesophytization pond conversion zone is filled with floating stuffing, increase strain Bond area, relatively conventional biochemistry pool strain can bond area improve 300%, activated sludge concentration is 8000~ 12000mg/L, relatively conventional sludge concentration improves 50% -80% so that biochemical clearance reaches more than 90%.
A kind of new plating garden waste water zero discharge treatment process, the technique comprises the following steps:
A, enterprise be unified to be discharged into waste water after the waste water accumulated in collecting pit, collecting pit homogenizes into regulating reservoir through homogeneous, first Into MBR reactors, micro flocculant is added, under the efficient crown_interception of film, retention solid pollutant, removal major part have The material such as machine thing and ammonia nitrogen;
B, MBR reactor produce excess sludge and are periodically discharged into the preliminary volume concentration of sludge concentration tank progress, then by filter press system Dewatering press is carried out, solid waste outward transport is produced;
The water outlet of c, MBR reactor enters A+O+MBR biochemical systems, further decomposes and removes most of organic matter and retain activity Sludge, is that follow-up reverse-osmosis treated lightens the load;
The treated waste water of d, A+O+MBR biochemical system imports MBR productions pond, and the film devices of RO I are promoted to by producing pond, using anti- The high rejection and mesolow of permeable membrane remove most of soluble salt, COD, ammonia nitrogen in waste water etc., to Wastewater Pollutant Further processing;
The film device of e, RO I produces water and produces water inflow reuse water system by the low concentration after the further purified treatment of the film devices of RO II, High concentration production water enters the film devices of RO III and flows into reclaiming system through fine filter after treatment;
The concentrated water that the film device of f, RO I and the film devices of RO III are produced, by sea water desalination membrane, 90KG MFT special membranes, except hardness dress Put, 160KG MFT special membranes multistage concentration after, into evaporation equipment evaporate obtain can reuse technical grade crystal salt and distillation Low concentration production water in water, concentration process enters reclaiming system after being handled through the film devices of RO III.
Compared with prior art, the invention has the advantages that:
1st, waste water enters when carrying out the even amount of homogeneous in regulating reservoir, is shunted using the pollution factor difference of each waste water, while sharp The treatment of wastes with processes of wastes against one another is carried out with the characteristic of waste water, makes full use of the acid in waste water, alkali to handle acid in waste water, reduction wastewater treatment process The input of alkali, reduces processing cost.
2nd, film enriching stage is using combination membrane process so that cycles of concentration can reach 25-30 times, realize 5 grades of concentrations, Producing water ratios at different levels reach 60% -85%.
3rd, present invention process handles automatic control system and diversification process combination, and can at utmost bring into play each work The advantage of skill section, lifts treatment effect, efficiently removes pollutant, realizes low energy consumption low cost, and cause the reclamation rate of waste water Reach 99.64%.
4th, present invention process is by RO II, RO III production Water circulation, and ROI, ROIII concentrated water pass through follow-up desalinization Distilled water and crystal salt are divided into by evaporation equipment evaporation after film, the multistage concentration of special membrane, system form one it is complete The circulating system of water zero discharge.
Brief description of the drawings
Fig. 1 is technique and schematic device of the invention.
Description of reference numerals:Collecting pit 1, regulating reservoir 2, MBR reactors 3, sludge concentration tank 4, filter press system 5, A+O+ MBR biochemical systems 6, MBR productions pond 7, the film devices 8 of RO I, the film devices 9 of RO II, sea water desalination membrane 10,90KG MFT special membranes 11, The film devices 12 of RO III, fine filter 13, reuse water system 14, except hardness device 15,160KG MFT special membranes 16, evaporation equipment 17.
Embodiment
The present invention is described in further detail with reference to the accompanying drawings and examples.
A kind of new plating garden wastewater zero discharge processing unit, including DCS electric-control systems, collecting pit 1, regulating reservoir 2, MBR reactors 3, A+Q+MBR biochemical systems 6, MBR productions pond 7, RO multi-stage reverse osmosis system, sea water desalination membrane 10,90KG MFT Special membrane 11, except hardness device 15,160KG MFT special membranes 16 and evaporation equipment 17, between each process equipment by pipeline successively Connection, wherein, the DCS electric-control systems are online according to liquid level, electrical conductivity, pressure of each equipment working state and water quality current etc. Information automatically controls output flow of the current in each equipment room, the connection of MBR reactors 3 sludge concentration tank 4, filter press system System 5, the RO multi-stage reverse osmosis system is made up of the film devices 8 of RO I, the film devices 9 of RO II and the film devices 12 of RO III, and is connected successively Connect, the film devices 8 of RO I are connected with sea water desalination membrane 10, the film devices 9 of RO II are connected with reuse water system 14, the RO III film device 12 is sequentially connected with fine filter 13, reuse water system 14.
Further, the mesophytization pond conversion zone of A+O+MBR biochemical systems 6 is filled with floating stuffing, increases strain Bond area, relatively conventional biochemistry pool strain can bond area improve 300%, activated sludge concentration is 8000~ 12000mg/L, relatively conventional sludge concentration improves 50% -80% so that biochemical clearance reaches more than 90%.
A kind of new plating garden waste water zero discharge treatment process, the technique comprises the following steps:
A, enterprise be unified to be discharged into waste water after the waste water accumulated in collecting pit 1, collecting pit 1 homogenizes into regulating reservoir 2 through homogeneous, head MBR reactors 3 are introduced into, micro flocculant is added, under the efficient crown_interception of film, retention solid pollutant, the big portion of removal Divide the material such as organic matter and ammonia nitrogen;
The generation excess sludge of b, MBR reactor 3 is periodically discharged into sludge concentration tank 4 and carries out preliminary volume concentration, then by filter press system System 5 carries out dewatering press, produces solid waste outward transport;
The water outlet of c, MBR reactor 3 enters A+O+MBR biochemical systems 6, further decomposes and removes most of organic matter and retain work Property sludge, is that follow-up reverse-osmosis treated lightens the load;
The treated waste water of d, A+O+MBR biochemical system 6 imports MBR productions pond 7, is promoted to the film devices 8 of RO I by producing pond 7, profit It is dirty to waste water with most of soluble salt, COD, ammonia nitrogen in high rejection and mesolow the removal waste water of reverse osmosis membrane etc. Dye thing is further handled;
The film device 8 of e, RO I produces water and produces water inflow reuse water system by the low concentration after the further purified treatment of II film devices of RO 9 14, high concentration production water enters the film devices 12 of RO III and flows into reclaiming system 14 through fine filter 13 after treatment;
The concentrated water that the film device 8 of f, RO I and the film devices 9 of RO III are produced, by sea water desalination membrane 10,90KG MFT special membranes 11, is removed After the multistage concentration of hardness device 15,160KG MFT special membranes 16, evaporated into evaporation equipment 17 obtain can reuse technical grade knot Low concentration production water in brilliant salt and distilled water, concentration process enters reclaiming system 14 after being handled through the film devices 12 of RO III.
Table 1 is effluent index of the electroplating wastewater respectively after present invention process and common process processing:
Table 1
Present invention process can efficiently remove the main pollution in waste water compared with common process it can be seen from upper table data Thing, realizes that Resource recovery is recycled from waste water, sludge reduction, while providing high-quality recycle-water, reaches terminal zero-emission The purpose put.
Above example is preferably embodiment, but protection scope of the present invention is not by above-described embodiment of the invention Limitation, other any Spirit Essences without departing from the present invention and the change made under principle, modification, replacement, is combined, and should be Equivalent substitute mode, is included in protection scope of the present invention.

Claims (3)

1. a kind of new plating garden wastewater zero discharge processing unit, it is characterised in that described device includes the automatically controlled systems of DCS System, collecting pit, regulating reservoir, MBR reactors, A+Q+MBR biochemical systems, MBR productions pond, RO multi-stage reverse osmosis system, seawater are light Change film, 90KG MFT special membranes, except hardness device, 160KG MFT special membranes and evaporation equipment, by pipeline between each process equipment It is sequentially connected, wherein, the DCS electric-control systems are according to liquid level, electrical conductivity, pressure of each equipment working state and water quality current etc. Online information automatically controls output flow of the current in each equipment room, the MBR reactors connection sludge concentration tank, filter press System, the RO multi-stage reverse osmosis system is made up of the film devices of RO I, the film devices of RO II and the film devices of RO III, and is sequentially connected, institute State the film devices of RO I to be connected with sea water desalination membrane, the film devices of RO II are connected with reuse water system, the film devices of RO III and essence Filter, reuse water system are sequentially connected.
2. a kind of new plating garden wastewater zero discharge processing unit according to claim 1, it is characterised in that described A+O+MBR biochemical system mesophytizations pond conversion zone is filled with floating stuffing, and activated sludge concentration is 8000~12000mg/L.
3. a kind of new plating garden waste water zero discharge treatment process, it is characterised in that the technique comprises the following steps:
A, enterprise be unified to be discharged into waste water after the waste water accumulated in collecting pit, collecting pit homogenizes into regulating reservoir through homogeneous, first Into MBR reactors, micro flocculant is added, under the efficient crown_interception of film, retention solid pollutant, removal major part have The material such as machine thing and ammonia nitrogen;
B, MBR reactor produce excess sludge and are periodically discharged into the preliminary volume concentration of sludge concentration tank progress, then by filter press system Dewatering press is carried out, solid waste outward transport is produced;
The water outlet of c, MBR reactor enters A+O+MBR biochemical systems, further decomposes and removes most of organic matter and retain activity Sludge, is that follow-up reverse-osmosis treated lightens the load;
The treated waste water of d, A+O+MBR biochemical system imports MBR productions pond, and the film devices of RO I are promoted to by producing pond, using anti- The high rejection and mesolow of permeable membrane remove most of soluble salt, COD, ammonia nitrogen in waste water etc., to Wastewater Pollutant Further processing;
The film device of e, RO I produces water and produces water inflow reuse water system by the low concentration after the further purified treatment of the film devices of RO II, High concentration production water enters the film devices of RO III and flows into reclaiming system through fine filter after treatment;
The concentrated water that the film device of f, RO I and the film devices of RO III are produced, by sea water desalination membrane, 90KG MFT special membranes, except hardness dress Put, 160KG MFT special membranes multistage concentration after, into evaporation equipment evaporate obtain can reuse technical grade crystal salt and distillation Low concentration production water in water, concentration process enters reclaiming system after being handled through the film devices of RO III.
CN201710699440.4A 2017-08-16 2017-08-16 A kind of new plating garden wastewater zero discharge processing unit and technique Pending CN107265793A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110078306A (en) * 2019-05-21 2019-08-02 武汉江扬环境科技股份有限公司 Electroplating wastewater zero technique
CN113289411A (en) * 2021-05-26 2021-08-24 云南云天化红磷化工有限公司 Automatic sequence control method for pressure filter
CN115465998A (en) * 2022-09-29 2022-12-13 常州市飞荣达电子材料有限公司 Heavy metal wastewater treatment method and treatment equipment thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110078306A (en) * 2019-05-21 2019-08-02 武汉江扬环境科技股份有限公司 Electroplating wastewater zero technique
CN113289411A (en) * 2021-05-26 2021-08-24 云南云天化红磷化工有限公司 Automatic sequence control method for pressure filter
CN115465998A (en) * 2022-09-29 2022-12-13 常州市飞荣达电子材料有限公司 Heavy metal wastewater treatment method and treatment equipment thereof

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