CN107265645A - The apparatus and method of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low carbon source urban sewages - Google Patents

The apparatus and method of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low carbon source urban sewages Download PDF

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CN107265645A
CN107265645A CN201710668903.0A CN201710668903A CN107265645A CN 107265645 A CN107265645 A CN 107265645A CN 201710668903 A CN201710668903 A CN 201710668903A CN 107265645 A CN107265645 A CN 107265645A
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concentration
anammox
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CN107265645B (en
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彭永臻
王志彬
刘文龙
王淑莹
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Beijing University of Technology
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/308Biological phosphorus removal
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • C02F3/307Nitrification and denitrification treatment characterised by direct conversion of nitrite to molecular nitrogen, e.g. by using the Anammox process
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
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    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • C02F2203/006Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections
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    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F2209/14NH3-N
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F2209/16Total nitrogen (tkN-N)
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F2209/22O2
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F2209/44Time
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/04Flow arrangements
    • C02F2301/046Recirculation with an external loop
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

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Abstract

The present invention relates to a kind of device and application process of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low carbon source urban sewages, it belongs to technical field of biological sewage treatment.The apparatus main body is made up of municipal sewage raw water box, continuous stream A/O dephosphorization apparatus, intermediate water tank and the part of multistage A/O autotrophic denitrification devices four;Wherein continuous stream A/O dephosphorization apparatus is made up of one section of anaerobic reaction area, three sections of aerobic reactor zones and the first rearmounted settling zone, progress Enhanced Biological Phosphorus Removal effect in it;Multistage A/O autotrophic denitrification devices are alternately made up of and the second rearmounted settling zone three sections of short distance nitration reaction zones and three sections of Anammox reaction zones (inside sets Anammox sponge fillers), short distance nitration reaction and Anammox reaction occur in it, and then realizes the denitrogenation dephosphorizing of low carbon source urban sewage.

Description

Continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low-carbon-sources city is dirty The apparatus and method of water
Technical field
The invention belongs to technical field of biological sewage treatment, and in particular to a kind of continuous stream A/O dephosphorization series multistages A/O is certainly Support device and application process that denitrification process handles low carbon source urban sewage.
Background technology
Traditional biological denitrogenation technology is made up of two processes of nitrification and denitrification, and nitrification is exactly nitrifier by ammonia nitrogen oxygen Nitrate nitrogen is turned to, denitrification is exactly that nitrate nitrogen is reduced to nitrogen by denitrifying bacterium by the use of organic matter as carbon source, from And reach the purpose for removing nitrogen from water.Biological phosphate-eliminating technology mainly absorbs organic matter releaser using polyP bacteria in anaerobic zone Interior phosphorus, excessive suction phosphorus effect then occurs in aerobic zone and is absorbed into the phosphorus in water in vivo, takes off phosphorus from water so as to reach The purpose removed.Biological denitrificaion is can be seen that from the principle of above biological carbon and phosphorous removal and biological phosphate-eliminating is required for organic carbon source, because This, organic carbon source will result in the two competition for organic carbon source when not enough, and then cause bio-denitrifying sewage phosphor-removing effect It is deteriorated.
Generally setting and drainage pipeline networks due to China's septic tank is longer, causes municipal sewage organic carbon source to lack, it is impossible to Meet demand of the traditional biological denitrification dephosphorization technique to organic carbon source.In this case municipal sewage plant is for row up to standard Put, typically demand of the biological carbon and phosphorous removal to organic carbon source is met by adding outer carbon source (e.g., methanol), so as to cause sewage Processing cost is significantly increased.In recent years, continuing to develop with sewage treatment area, some new biological carbon and phosphorous removal skills Art has obtained significantly developing, including:Synchronous nitration and denitrification technology, short-cut nitrification and denitrification technology, denitrification are removed Phosphorus technology, Anammox denitrification process and whole process autotrophic denitrification technology etc..Wherein Anammox autotrophic denitrification technique needs By the NH of part4 +It is oxidized to NO2 -, the NO then obtained2 -Reoxidize the NH of remainder4 +, it is finally reached the purpose of denitrogenation.This During 1mol NH4 +0.8mol O only need to be consumed2;Only with CO2As carbon source, the consumption without organic matter.With traditional biological Denitrification process is compared, and Anammox autotrophic denitrification technology can save 100% organic carbon source consumption, can save 60% aeration Amount, can reduce by 90% sludge yield, so as to greatly reduce the direct energy consumption and operating cost of sewage treatment process, detest simultaneously The raw water organic carbon source that anaerobic ammonium oxidation biological denitrificaion is saved, can fully meet demand of the system for biological phosphate-eliminating.
Therefore, to meet the energy-saving requirement of sewage disposal, while realizing that the water outlet nitrogen phosphorus of low carbon source urban sewage reaches Mark, researches and develops the municipal sewage denitrification dephosphorization technique based on anaerobic ammonia oxidation process and has important practical significance, In addition successful application of the anaerobic ammonia oxidation process in high-ammonia-nitrogen sewage such as sludge-digestion liquid and percolate is that the technology exists Popularization and application in municipal sewage provide technical support.
The content of the invention
The purpose of the present invention is to propose to a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low-carbon-sources The device and application process of municipal sewage.The technique is separated using biological, by heterotrophism polyP bacteria and Autotrophic nitrification bacterium/anaerobism ammonia Oxidizing bacteria is cultivated in two devices respectively, solves the problem of heterotroph is different with the sludge age of autotrophic bacterium, simultaneously Organic matter in water inlet removed in continuous stream A/O dephosphorization apparatus, it is to avoid because organic matter is present, denitrifying bacteria meeting The problem of competition being produced with anaerobic ammonium oxidizing bacteria.Low carbon source urban sewage initially enters continuous stream A/O dephosphorization apparatus, is had Machine thing and phosphatic removal, do not occur nitration reaction;The water outlet of dephosphorization apparatus enters multistage A/O autotrophic denitrification devices, it is scarce/ In aerobic alternate environment, acted on using short distance nitration and Anammox acts on and realizes going for nitrogen in municipal sewage Remove, it is ensured that effluent quality, while scarce/aerobic alternate mode ensure that the steady in a long-term of device short distance nitration.
The present invention relates to a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low carbon source urban sewages Device.Device is by municipal sewage raw water box, continuous stream A/O dephosphorization apparatus, intermediate water tank and multistage A/O autotrophic denitrification devices four Part is constituted;Water inlet pipe, the first overflow pipe and the first blow-down pipe are set on described municipal sewage raw water box;Described middle water Second overflow pipe and the second blow-down pipe are set on case;Described continuous stream A/O dephosphorization apparatus is divided into four regions by perforate dividing plate, One section of anaerobic reaction area, three sections of aerobic reactor zones and the first rearmounted settling zone are followed successively by along water inlet direction;Described municipal sewage Raw water box is connected using intake pump with one section of anaerobic reaction area;One section of described anaerobic reaction area is provided with the first agitator;It is described The bottoms of three sections of aerobic reactor zones be equipped with aerator and DO sensors, aerator passes through by the first air compressor One air robot flowmeter is connected with the first glutinous sand lump aeration head, and the first DO sensors are connected by data wire and the first DO analyzers Connect;First rearmounted settling zone bottom is connected by the first returned sludge control valve and the first sludge reflux pump and one section of anaerobic reaction area Logical, excess sludge passes through the first excess sludge exhaust-control valve discharge system;Described multistage A/O autotrophic denitrification devices are by perforate Dividing plate is divided into six regions, is followed successively by three sections of Anammox reaction zones along water (flow) direction and three sections of short distance nitration reaction zones replace Distribution, the second rearmounted settling zone and outlet pipe;Described intermediate water tank is reacted using middle water pump with first paragraph Anammox Area is connected;It is equipped with the second agitator in three sections of described Anammox reaction zones, and using polyurethane sponge as filling out Material;The bottom of three sections of described short distance nitration reaction zones is equipped with aerator and DO sensors, and aerator is by the second air Compressor is connected by the second air robot flowmeter with the second glutinous sand lump aeration head, and the 2nd DO sensors are by data wire and second DO analyzers are connected;Second rearmounted settling zone bottom passes through the second returned sludge control valve and the second sludge reflux pump and first paragraph Anammox reaction zone is connected, and excess sludge passes through the second excess sludge exhaust-control valve discharge system.
Described perforate dividing plate is staggered above and below by the way of flowing hole according to water (flow) direction and is attached each lattice Room;The size range of described sponge filler is 1.5cm × 1.5cm × 1.5cm-2.0cm × 2.0cm × 2.0cm.
Based on the experimental rig of the present invention, the handling process of municipal sewage is:
Municipal sewage is mixed into one section of anaerobic reaction by the mud mixture of raw water box and the first rearmounted settling zone backflow Area, polyP bacteria carries out anaerobic phosphorus release reaction using the organic carbon source in raw water, and the volatile fatty acid VFA in raw water is converted into Polyhydroxyalkanoates in cell body, while discharging PO into water4 3-;Then the mud mixture of anaerobic reaction area enters Aerobic reactor zone, polyP bacteria is with O2For electron acceptor, occur aerobic phosphorus absorption reaction using the PHA in cell body, largely absorb water PO in body4 3-, realize that biological phosphate-eliminating reacts;The mud mixture of aerobic zone enters the first rearmounted settling zone completion muddy water afterwards Separation, returned sludge is back to one section of anaerobic reaction area by the first sludge reflux pump, and excess sludge passes through the first excess sludge The regular discharge system of drain valve, the supernatant of the first rearmounted settling zone enters intermediate water tank under gravity.After dephosphorization Sewage is mixed into first paragraph Anammox reaction zone by the mud mixture of intermediate water tank and the second rearmounted settling zone backflow, Anaerobic ammonia oxidizing bacteria on sponge filler is by the NO in water2 -And NH4 +It is converted into N2With a small amount of NO3 -, carry out biological denitrificaion reaction; Then the mud mixture of the Anammox reaction zone of first paragraph enters first paragraph short distance nitration reaction zone, in the effect of oxygen Lower generation short distance nitration reaction, ammonia oxidizing bacteria AOB will participate in the NH of Anammox reaction using oxygen4 +Partial oxidation is NO2 -, substrate is provided for next section of Anammox reaction;Repeat anaerobism ammonia oxygen in ensuing anoxic zone and aerobic zone Change reaction and short distance reaction, further complete the biological denitrificaion for sewage;The mud mixture of three sections of short distance nitration reaction zones Mud-water separation is carried out into the second rearmounted settling zone, and supernatant is as water outlet by outlet pipe discharger, and precipitating sludge passes through the Two sludge reflux pumps are back to first paragraph Anammox reaction zone.
A kind of application of above-mentioned continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low carbon source urban sewages Method, it is characterised in that:Comprise the following steps:
1) it is inoculated with startup stage
Inoculation is except phosphorus sludge is in continuous stream A/O devices, and it is 3000~4000mg/L to control sludge concentration, with municipal sewage For process object, return sludge ratio is that the DO concentration control in 50~100%, three sections of aerobic reactor zones is 0.5~2.0mg/L, Hydraulic detention time HRT controls are 2~4h, and sludge retention time SRT controls are 4~6d, and shorter HRT and SRT ensure that company The enrichment and the elutriation of nitrobacteria of polyP bacteria, have ensured the phosphor-removing effect of device in afterflow A/O devices.When settling zone water outlet PO4 3-<0.5mg/L and when being stably maintained for more than 15 days, illustrates that continuous stream A/O dephosphorization apparatus starts successfully;
Short distance nitration sludge is inoculated with multistage A/O autotrophic denitrification devices, it is 2000~3000mg/L to control sludge concentration, It is inoculated with simultaneously in three sections of Anammox reaction zones of the Anammox sponge fillers in multistage A/O autotrophic denitrification devices, packing ratio For 30~40%, it is process object to start the water outlet of successful continuous stream A/O dephosphorization apparatus, and water temperature control is 30~35 DEG C, HRT Control as 8~12h, reactor not spoil disposal.Monitor the DO concentration inside short distance nitration reaction zone, maintain DO concentration be 0.3~ 1.0mg/L, while according to each Anammox reaction zone water outlet NO2 -- N concentration and the NH of the second rearmounted settling zone water outlet4 +- N is dense The DO concentration and HRT of each short distance nitration reaction zone of degree regulation, as the water outlet NO of some Anammox reaction zone2 -- N concentration is more than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +When-N concentration is less than 0.5mg/L, this Anammox reaction zone institute is reduced right The DO concentration for the leading portion short distance nitration reaction zone answered is 0.3~0.5mg/L, while it is 8~10h to shorten HRT;When some anaerobism ammonia The water outlet NO of oxidation reaction zone2 -- N concentration is less than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +- N concentration is more than 10mg/L When, the DO concentration for improving the leading portion short distance nitration reaction zone corresponding to this Anammox reaction zone is 0.5~1.0mg/L, together Shi Tigao HRT are
10~12h.In start-up course, as the NH in water outlet4 +5mg/L and below 15mg/L is respectively reached with TN concentration, and When outlet effect maintains to be up to more than 60 days, then illustrate that multistage A/O autotrophic denitrification devices start successfully;
2) stable operation stage
After continuous stream A/O dephosphorization apparatus and multistage A/O autotrophic denitrification device all start completions, two devices are connected To build a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification techniques, carried out by process object of municipal sewage long-term steady Fixed operation, monitors the DO concentration and Inlet and outlet water water quality inside aerobic reactor zone, while according to each Anammox reaction zone in real time Water outlet NO2 -- N concentration and the NH of the second rearmounted settling zone water outlet4 +- N concentration adjust each short distance nitration reaction zone DO concentration and HRT, as the water outlet NO of some Anammox reaction zone2 -- N concentration is more than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +- When N concentration is less than 0.5mg/L, the DO concentration for reducing the leading portion short distance nitration reaction zone corresponding to this Anammox reaction zone is 0.3~0.5mg/L, while it is 8~10h to shorten HRT;As the water outlet NO of some Anammox reaction zone2 -- N concentration is less than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +When-N concentration is more than 10mg/L, improve corresponding to this Anammox reaction zone Leading portion short distance nitration reaction zone DO concentration be 0.5~1.0mg/L, while improve HRT be 10~12h.Such adjusting means The operation of system.As the NH in water outlet4 +5mg/L and below 15mg/L (meeting one-level emission standard A) are respectively reached with TN concentration, And during outlet effect maintenance more than 100d, then illustrate that device realizes operation steady in a long-term.Hereafter, according to 35 DEG C → 30 DEG C → 25 DEG C The mode of → 20 DEG C → 15 DEG C → 10 DEG C (reducing by 5 DEG C every 15d) gradually reduces the running temperature of device, realizes under cryogenic conditions The stable operation of low carbon source urban sewage continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification devices.
A kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low-carbon-sources city of the present invention is dirty The device and application process of water, compared with prior art, with advantages below:
(1) present invention uses Anammox autotrophic denitrification technology, and solve traditional handicraft makes to draw because carbon source is not enough The problem of water nitrogen phosphorus is difficult to qualified discharge, the aeration energy consumption and carbon source for reducing device is added;
(2) continuous stream A/O dephosphorization apparatus not only causes the water outlet PO of system by enhanced biological phosphorus removal4 3-Concentration is less than 0.5mg/L, and take full advantage of the carbon source in raw water, it is to avoid water inlet organic carbon source is filled to follow-up multistage A/O autotrophic denitrifications The adverse effect put;
(3) present invention is separated with biofacies, is made heterotrophism polyP bacteria and is distinguished with Autotrophic nitrification bacterium/anaerobic ammonium oxidizing bacteria It is arranged in two sets of reaction units, solves the heterotroph contradiction different with autotrophic bacterium sludge age, while de- in multistage A/O autotrophys Anaerobic ammonium oxidizing bacteria is enriched with using sponge filler in nitrogen device, it is to avoid anaerobic ammonium oxidizing bacteria enter aerobic section and by oxygen The suppression of gas;
(4) multistage A/O autotrophic denitrification devices lack the/setting of aerobic alternant, are conducive to the long-term of system short distance nitration It is stable to maintain, while the NO that three sections of short distance nitration reaction zones are produced2 -- N can be utilized by anaerobic ammonia oxidizing bacteria faster, it is to avoid be produced Higher NO2 -Influences of-the N to device denitrification effect;
(5) it is relatively easy to the upgrading of existing water factory, it is easy to popularization and application.
Brief description of the drawings
Fig. 1 is dirty for a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low-carbon-sources city in the present invention The schematic diagram of water installations,
Wherein 1 represents that municipal sewage raw water box, 2 represent that continuous stream A/O dephosphorization apparatus, 3 represent the first rearmounted settling zone, 4 Represent that intermediate water tank, 5 represent that multistage A/O autotrophic denitrification devices, 1.1 represent that raw water box water inlet pipe, 1.2 represent first case overflow Pipe, 1.3 represent that first case blow-down pipe, 2.1 represent that one section of anaerobic reaction area, 2.2 represent that three sections of aerobic reactor zones, 2.3 represent the One agitator, 2.4 represent that the first air compressor, 2.5 represent that the first air robot flowmeter, 2.6 represent that the first glutinous sand lump exposes Gas head, 2.7 represent that the first sludge reflux pumps, 2.8 represent that the first DO analyzers, 2.9 represent that the first DO sensors, 3.1 represent the One returned sludge control valve, 3.2 represent that the first excess sludge exhaust-control valve, 3.3 represent that dephosphorization outlet pipe, 4.1 represent second Overflow pipe, 4.2 represent that the second blow-down pipe, 4.3 represent that middle water pump, 5.1 represent that three sections of Anammox reaction zones, 5.2 are represented Three sections of short distance nitration reaction zones, 5.3 represent that the second agitator, 5.4 represent that the second air compressor, 5.5 represent that the second air turns Subflow gauge, 5.6 represent the second glutinous sand lump aeration heads, 5.7 represent the second sludge reflux pumps, 5.8 represent polyurethane sponge fillers, 5.9 represent that the 2nd DO analyzers, 5.10 represent that the 2nd DO sensors, 6.1 represent that outlet pipe, 6.2 represent the second returned sludge control Valve processed, 6.3 represent the second excess sludge exhaust-control valve.
Fig. 2 is the partial structural diagram of apparatus of the present invention.
Embodiment
Technical solution of the present invention is not limited to act embodiment set forth below, in addition between each embodiment Any combination.
Embodiment one:With reference to shown in Fig. 1, present embodiment is related to a kind of continuous stream A/O dephosphorization series multistages A/O The device of autotrophic denitrification PROCESS FOR TREATMENT low carbon source urban sewage, it is characterised in that device is by municipal sewage raw water box (1), continuous stream A/O dephosphorization apparatus (2), intermediate water tank (4) and the part of multistage A/O autotrophic denitrification devices (5) four composition;Described municipal sewage is former Water inlet pipe (1.1), the first overflow pipe (1.2) and the first blow-down pipe (1.3) are set on water tank (1);On described intermediate water tank (4) Second overflow pipe (4.1) and the second blow-down pipe (4.2) are set;Described continuous stream A/O dephosphorization apparatus (2) is divided into by perforate dividing plate Four regions, are followed successively by one section of anaerobic reaction area (2.1), three sections of aerobic reactor zones (2.2) and first rearmounted heavy along water inlet direction Shallow lake area (3);Described municipal sewage raw water box (1) is connected using intake pump (1.4) with one section of anaerobic reaction area (2.1);It is described One section of anaerobic reaction area (2.1) be provided with the first agitator (2.3);The bottom of three sections of described aerobic reactor zones (2.2) is all provided with There are aerator and DO sensors, aerator passes through the first air robot flowmeter (2.5) by the first air compressor (2.4) Connected with the first glutinous sand lump aeration head (2.6), the first DO sensors (2.9) are connected by data wire with the first DO analyzers (2.8); Detested by the first returned sludge control valve (3.1) and the first sludge reflux pump (2.7) with one section the first rearmounted settling zone (3) bottom Oxygen reaction zone (2.1) is connected, and excess sludge passes through first excess sludge exhaust-control valve (3.2) discharge system;Described multistage A/O autotrophic denitrification devices (5) are divided into six regions by perforate dividing plate, and three sections of Anammox reaction zones are followed successively by along water (flow) direction (5.1) it is alternately distributed with three sections of short distance nitration reaction zones (5.2), the second rearmounted settling zone (6) and outlet pipe (6.1);Described Intermediate water tank (4) is connected using middle water pump (4.3) with first paragraph Anammox reaction zone (5.1);Three sections of described anaerobism The second agitator (5.3) is equipped with ammoxidation reaction area (5.1), and filler is used as using polyurethane sponge (5.8);It is described The bottoms of three sections of short distance nitration reaction zones (5.2) be equipped with aerator and DO sensors, aerator is by the second air pressure Contracting machine (5.4) is connected by the second air robot flowmeter (5.5) with the second glutinous sand lump aeration head (5.6), the 2nd DO sensors (5.10) it is connected by data wire with the 2nd DO analyzers (5.9);Second rearmounted settling zone (6) bottom passes through the second returned sludge control Valve (6.2) processed and the second sludge reflux pump (5.7) are connected with first paragraph Anammox reaction zone (5.1), and excess sludge passes through Second excess sludge exhaust-control valve (6.3) discharge system.
Embodiment two:Present embodiment is related to a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification techniques The application process of low carbon source urban sewage device is handled, is carried out according to the following steps:
1) it is inoculated with startup stage
Inoculation is except phosphorus sludge is in continuous stream A/O devices, and it is 3000~4000mg/L to control sludge concentration, with municipal sewage For process object, return sludge ratio is that the DO concentration control in 50~100%, three sections of aerobic reactor zones is 0.5~2.0mg/L, Hydraulic detention time HRT controls are 2~4h, and sludge retention time SRT controls are 4~6d, and shorter HRT and SRT ensure that company The enrichment and the elutriation of nitrobacteria of polyP bacteria, have ensured the phosphor-removing effect of device in afterflow A/O devices.When settling zone water outlet PO4 3-<0.5mg/L and when being stably maintained for more than 15 days, illustrates that continuous stream A/O dephosphorization apparatus starts successfully;
Short distance nitration sludge is inoculated with multistage A/O autotrophic denitrification devices, it is 2000~3000mg/L to control sludge concentration, It is inoculated with simultaneously in three sections of Anammox reaction zones of the Anammox sponge fillers in multistage A/O autotrophic denitrification devices, packing ratio For 30~40%, it is process object to start the water outlet of successful continuous stream A/O dephosphorization apparatus, and water temperature control is 30~35 DEG C, HRT Control as 8~12h, reactor not spoil disposal.Monitor the DO concentration inside short distance nitration reaction zone, maintain DO concentration be 0.3~ 1.0mg/L, while according to each Anammox reaction zone water outlet NO2 -- N concentration and the NH of the second rearmounted settling zone water outlet4 +- N is dense The DO concentration and HRT of each short distance nitration reaction zone of degree regulation, as the water outlet NO of some Anammox reaction zone2 -- N concentration is more than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +When-N concentration is less than 0.5mg/L, this Anammox reaction zone institute is reduced right The DO concentration for the leading portion short distance nitration reaction zone answered is 0.3~0.5mg/L, while it is 8~10h to shorten HRT;When some anaerobism ammonia The water outlet NO of oxidation reaction zone2 -- N concentration is less than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +- N concentration is more than 10mg/L When, the DO concentration for improving the leading portion short distance nitration reaction zone corresponding to this Anammox reaction zone is 0.5~1.0mg/L, together Shi Tigao HRT are 10~12h.In start-up course, as the NH in water outlet4 +5mg/L and below 15mg/L is respectively reached with TN concentration, And outlet effect is maintained when more than 60 days, then illustrate that multistage A/O autotrophic denitrification devices start successfully;
2) stable operation stage
After continuous stream A/O dephosphorization apparatus and multistage A/O autotrophic denitrification device all start completions, two devices are connected To build a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification techniques, carried out by process object of municipal sewage long-term steady Fixed operation, monitors the DO concentration and Inlet and outlet water water quality inside aerobic reactor zone, while according to each Anammox reaction zone in real time Water outlet NO2 -- N concentration and the NH of the second rearmounted settling zone water outlet4 +- N concentration adjust each short distance nitration reaction zone DO concentration and HRT, as the water outlet NO of some Anammox reaction zone2 -- N concentration is more than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +- When N concentration is less than 0.5mg/L, the DO concentration for reducing the leading portion short distance nitration reaction zone corresponding to this Anammox reaction zone is 0.3~0.5mg/L, while it is 8~10h to shorten HRT;As the water outlet NO of some Anammox reaction zone2 -- N concentration is less than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +When-N concentration is more than 10mg/L, improve corresponding to this Anammox reaction zone Leading portion short distance nitration reaction zone DO concentration be 0.5~1.0mg/L, while improve HRT be 10~12h.Such adjusting means The operation of system.As the NH in water outlet4 +5mg/L and below 15mg/L (meeting one-level emission standard A) are respectively reached with TN concentration, And during outlet effect maintenance more than 100d, then illustrate that device realizes operation steady in a long-term.Hereafter, according to 35 DEG C → 30 DEG C → 25 DEG C The mode of → 20 DEG C → 15 DEG C → 10 DEG C (reducing by 5 DEG C every 15d) gradually reduces the running temperature of device, realizes under cryogenic conditions The stable operation of low carbon source urban sewage continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification devices.
Embodiment three:Present embodiment from unlike embodiment one, described perforate dividing plate according to Water (flow) direction is staggered by the way of flowing hole above and below and is attached each cell compartment.Other steps and parameter and specific implementation Mode one is identical.
Embodiment four:Present embodiment from unlike embodiment two, the dephosphorization described in step one Sludge source is in municipal sewage plant's second pond returned sludge.Other steps and parameter are identical with embodiment two.
Embodiment five:Present embodiment from unlike embodiment two, the anaerobism described in step one The size range for the polyurethane sponge filler that ammoxidation reaction area is added be 1.5cm × 1.5cm × 1.5cm-2.0cm × 2.0cm×2.0cm.Other steps and parameter are identical with embodiment two.
Embodiment six:Present embodiment from unlike embodiment two, the short distance described in step one Nitrifying sludge is in the SBR short distance nitration reactors of stable operation.Other steps and parameter and embodiment two-phase Together.
Embodiment seven:Present embodiment from unlike embodiment two, described in step one Anammox sponge fillers derive from sludge-digestion liquid Anammox engineerings.Other steps and parameter and embodiment two-phase Together.
Beneficial effects of the present invention are verified using following examples:
Embodiment:
With reference to shown in Fig. 1, a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low-carbon-sources city is dirty The application process of water installations, is carried out according to the following steps:
1) it is inoculated with startup stage
Inoculation is except phosphorus sludge is in continuous stream A/O devices, and it is 3000~4000mg/L to control sludge concentration, with municipal sewage For process object, return sludge ratio is that the DO concentration control in 50~100%, three sections of aerobic reactor zones is 0.5~2.0mg/L, Hydraulic detention time HRT controls are 2~4h, and sludge retention time SRT controls are 4~6d, and shorter HRT and SRT ensure that company The enrichment and the elutriation of nitrobacteria of polyP bacteria, have ensured the phosphor-removing effect of device in afterflow A/O devices.When settling zone water outlet PO4 3-<0.5mg/L and when being stably maintained for more than 15 days, illustrates that continuous stream A/O dephosphorization apparatus starts successfully;
Short distance nitration sludge is inoculated with multistage A/O autotrophic denitrification devices, it is 2000~3000mg/L to control sludge concentration, It is inoculated with simultaneously in three sections of Anammox reaction zones of the Anammox sponge fillers in multistage A/O autotrophic denitrification devices, packing ratio For 30~40%, it is process object to start the water outlet of successful continuous stream A/O dephosphorization apparatus, and water temperature control is 30~35 DEG C, HRT Control as 8~12h, reactor not spoil disposal.Monitor the DO concentration inside short distance nitration reaction zone, maintain DO concentration be 0.3~ 1.0mg/L, while according to each Anammox reaction zone water outlet NO2 -- N concentration and the NH of the second rearmounted settling zone water outlet4 +- N is dense The DO concentration and HRT of each short distance nitration reaction zone of degree regulation, as the water outlet NO of some Anammox reaction zone2 -- N concentration is more than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +When-N concentration is less than 0.5mg/L, this Anammox reaction zone institute is reduced right The DO concentration for the leading portion short distance nitration reaction zone answered is 0.3~0.5mg/L, while it is 8~10h to shorten HRT;When some anaerobism ammonia The water outlet NO of oxidation reaction zone2 -- N concentration is less than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +- N concentration is more than 10mg/L When, the DO concentration for improving the leading portion short distance nitration reaction zone corresponding to this Anammox reaction zone is 0.5~1.0mg/L, together Shi Tigao HRT are 10~12h.In start-up course, as the NH in water outlet4 +5mg/L and below 15mg/L is respectively reached with TN concentration, And outlet effect is maintained when more than 60 days, then illustrate that multistage A/O autotrophic denitrification devices start successfully;
2) stable operation stage
After continuous stream A/O dephosphorization apparatus and multistage A/O autotrophic denitrification device all start completions, two devices are connected To build a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification techniques, carried out by process object of municipal sewage long-term steady Fixed operation, monitors the DO concentration and Inlet and outlet water water quality inside aerobic reactor zone, while according to each Anammox reaction zone in real time Water outlet NO2 -- N concentration and the NH of the second rearmounted settling zone water outlet4 +- N concentration adjust each short distance nitration reaction zone DO concentration and HRT, as the water outlet NO of some Anammox reaction zone2 -- N concentration is more than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +- When N concentration is less than 0.5mg/L, the DO concentration for reducing the leading portion short distance nitration reaction zone corresponding to this Anammox reaction zone is 0.3~0.5mg/L, while it is 8~10h to shorten HRT;As the water outlet NO of some Anammox reaction zone2 -- N concentration is less than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +When-N concentration is more than 10mg/L, improve corresponding to this Anammox reaction zone Leading portion short distance nitration reaction zone DO concentration be 0.5~1.0mg/L, while improve HRT be 10~12h.Such adjusting means The operation of system.As the NH in water outlet4 +5mg/L and below 15mg/L (meeting one-level emission standard A) are respectively reached with TN concentration, And during outlet effect maintenance more than 100d, then illustrate that device realizes operation steady in a long-term.Hereafter, according to 35 DEG C → 30 DEG C → 25 DEG C The mode of → 20 DEG C → 15 DEG C → 10 DEG C (reducing by 5 DEG C every 15d) gradually reduces the running temperature of device, realizes under cryogenic conditions The stable operation of low carbon source urban sewage continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification devices.
Dephosphorization sludge source in the present embodiment step one is in municipal sewage plant of Gaobeidian City second pond returned sludge, step Short distance nitration sludge source in rapid one is in the SBR short distance nitration reactors of laboratory stable operation, in step one Anammox sponge fillers derive from Beijing draining group sludge-digestion liquid Anammox engineerings.
The size model for the polyurethane sponge filler that Anammox reaction zone described in the present embodiment step one is added Enclose for 1.5cm × 1.5cm × 1.5cm -2.0cm × 2.0cm × 2.0cm.
The present embodiment is using Primary Settling Tanks of Municipal Wastewater Treatment Plant water outlet as raw water, and specific water quality is as follows:COD concentration is 153.12~215.21mg/L, PO4 3-- P concentration is 4.91~7.64mg/L,Concentration is 29.31~67.12mg/L,Concentration is 0.00~0.98mg/L,Concentration is 0.00~0.89mg/L.Experimental rig is as shown in figure 1, wherein Raw water box dischargeable capacity is 160L, and continuous stream A/O dephosphorization apparatus dischargeable capacity is 25L, and intermediate water tank dischargeable capacity is 100L, many Level A/O autotrophic denitrification devices dischargeable capacity is 40L, and water tank and device are made of lucite.Using with communicating pipe Multistage A/O autotrophic denitrification devices and multistage A/O autotrophic denitrification devices are respectively divided into four reaction areas and six reaction zones by dividing plate, Aerobic volumetric ratio can be lacked according to system to be adjusted, the dischargeable capacity of the first rearmounted settling zone and the second rearmounted settling zone is respectively 10L and 16L.
Result of the test shows:After stable, effluent COD concentration is 29.32~43.12mg/L, water outlet PO4 3-- P concentration For 0.02~0.17mg/L, water outletConcentration is 0.23~3.56mg/L, water outletConcentration is 2.11~3.23mg/ L, water outletConcentration is 2.32~8.41mg/L, and water outlet TN concentration is 7.89~13.81mg/L, water outlet It is dense with TN Degree reaches the requirement of one-level emission standard A.

Claims (6)

1. the device of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low carbon source urban sewages, its feature exists In:It is de- that device includes municipal sewage raw water box (1), continuous stream A/O dephosphorization apparatus (2), intermediate water tank (4) and multistage A/O autotrophys Nitrogen device (5);Water inlet pipe (1.1), the first overflow pipe (1.2) and the first emptying are set on described municipal sewage raw water box (1) Manage (1.3);The second overflow pipe (4.1) and the second blow-down pipe (4.2) are set on described intermediate water tank (4);Described continuous stream A/O dephosphorization apparatus (2) is divided into four regions by perforate dividing plate, along water inlet direction be followed successively by one section of anaerobic reaction area (2.1), three sections Aerobic reactor zone (2.2), continuous stream A/O dephosphorization apparatus (2) sets the first rearmounted settling zone (3) afterwards;Described municipal sewage is former Water tank (1) is connected using intake pump (1.4) with one section of anaerobic reaction area (2.1);One section of described anaerobic reaction area (2.1) is provided with First agitator (2.3);The bottom of three sections of described aerobic reactor zones (2.2) is equipped with aerator and DO sensors, aeration Device is connected by the first air compressor (2.4) by the first air robot flowmeter (2.5) with the first glutinous sand lump aeration head (2.6) Logical, the first DO sensors (2.9) are connected by data wire with the first DO analyzers (2.8);First rearmounted settling zone (3) bottom passes through First returned sludge control valve (3.1) and the first sludge reflux pump (2.7) are connected with one section of anaerobic reaction area (2.1), remaining dirty Mud passes through first excess sludge exhaust-control valve (3.2) discharge system;Described multistage A/O autotrophic denitrification devices (5) are by perforate Dividing plate is divided into six regions, is followed successively by three sections of Anammox reaction zones (5.1) along water (flow) direction and three sections of short distance nitrations react Area (5.2) is alternately distributed, and multistage A/O autotrophic denitrification devices (5) set the second rearmounted settling zone (6) and outlet pipe (6.1) afterwards;Institute The intermediate water tank (4) stated is connected using middle water pump (4.3) with first paragraph Anammox reaction zone (5.1);Described three sections The second agitator (5.3) is equipped with Anammox reaction zone (5.1), and filler is used as using polyurethane sponge (5.8); The bottom of three sections of described short distance nitration reaction zones (5.2) is equipped with aerator and DO sensors, and aerator is empty by second Air compressor (5.4) is connected by the second air robot flowmeter (5.5) with the second glutinous sand lump aeration head (5.6), and the 2nd DO is passed Sensor (5.10) is connected by data wire with the 2nd DO analyzers (5.9);Second rearmounted settling zone (6) bottom is dirty by the second backflow Mud control valve (6.2) and the second sludge reflux pump (5.7) are connected with first paragraph Anammox reaction zone (5.1), excess sludge Pass through second excess sludge exhaust-control valve (6.3) discharge system.
2. a kind of application continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low-carbon-sources as claimed in claim 1 The method of municipal sewage device, it is characterised in that carry out according to the following steps:
1) it is inoculated with startup stage
Inoculation is except phosphorus sludge is in continuous stream A/O dephosphorization apparatus (2), and it is 3000~4000mg/L to control sludge concentration, with city Sewage is process object, and return sludge ratio is 50~100%, the DO concentration control in three sections of aerobic reactor zones for 0.5~ 2.0mg/L, hydraulic detention time HRT control are 2~4h, and sludge retention time SRT controls are 4~6d,;When settling zone water outlet PO4 3-<0.5mg/L and when being stably maintained for more than 15 days, illustrates that continuous stream A/O dephosphorization apparatus starts successfully;
Short distance nitration sludge is inoculated with multistage A/O autotrophic denitrification devices, it is 2000~3000mg/L to control sludge concentration, simultaneously It is inoculated with three sections of Anammox reaction zones of the Anammox sponge fillers in multistage A/O autotrophic denitrification devices, packing ratio is 30 ~40%, it is process object to start the water outlet of successful continuous stream A/O dephosphorization apparatus, and water temperature control is 30~35 DEG C, HRT controls For 8~12h, multistage A/O autotrophic denitrification devices not spoil disposal;The DO concentration inside short distance nitration reaction zone is monitored, DO concentration is maintained For 0.3~1.0mg/L, while according to each Anammox reaction zone water outlet NO2 -- N concentration and the second rearmounted settling zone water outlet NH4 +- N concentration adjusts the DO concentration and HRT of each short distance nitration reaction zone, as the water outlet NO of some Anammox reaction zone2 --N Concentration is more than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +When-N concentration is less than 0.5mg/L, this Anammox is reduced anti- The DO concentration for answering the leading portion short distance nitration reaction zone corresponding to area is 0.3~0.5mg/L, while it is 8~10h to shorten HRT;When certain The water outlet NO of individual Anammox reaction zone2 -- N concentration is less than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +- N concentration is big When 10mg/L, improve the DO concentration of leading portion short distance nitration reaction zone corresponding to this Anammox reaction zone for 0.5~ 1.0mg/L, while it is 10~12h to improve HRT;In start-up course, as the NH in water outlet4 +With TN concentration respectively reach 5mg/L and Below 15mg/L, and outlet effect maintenance illustrates that multistage A/O autotrophic denitrification devices start successfully when more than 60 days, then;
2) stable operation stage
After continuous stream A/O dephosphorization apparatus and multistage A/O autotrophic denitrification device all start completions, two devices are connected, Using municipal sewage as process object, the DO concentration and Inlet and outlet water water quality inside monitoring aerobic reactor zone in real time, while according to respectively detesting Anaerobic ammonium oxidation reaction zone water outlet NO2 -- N concentration and the NH of the second rearmounted settling zone water outlet4 +- N concentration adjusts each short distance nitration reaction The DO concentration and HRT in area, as the water outlet NO of some Anammox reaction zone2 -- N concentration is more than 1.0mg/L and second is rearmounted heavy Shallow lake area water outlet NH4 +When-N concentration is less than 0.5mg/L, the leading portion short distance nitration reaction corresponding to this Anammox reaction zone is reduced The DO concentration in area is 0.3~0.5mg/L, while it is 8~10h to shorten HRT;As the water outlet NO of some Anammox reaction zone2 -- N concentration is less than 1.0mg/L and the second rearmounted settling zone water outlet NH4 +When-N concentration is more than 10mg/L, this Anammox is improved anti- The DO concentration for answering the leading portion short distance nitration reaction zone corresponding to area is 0.5~1.0mg/L, while it is 10~12h to improve HRT;;When NH in water outlet4 +5mg/L and below 15mg/L is respectively reached with TN concentration, and during outlet effect maintenance more than 100d, is then illustrated Device realizes operation steady in a long-term;Hereafter, gradually dropped in the way of 35 DEG C → 30 DEG C → 25 DEG C → 20 DEG C → 15 DEG C → 10 DEG C The running temperature of low device, 5 DEG C are reduced every 15d, realize that low carbon source urban sewage continuous stream A/O dephosphorization is connected under cryogenic conditions The stable operation of multistage A/O autotrophic denitrification devices.
3. method according to claim 2, it is characterised in that described perforate dividing plate is according to water (flow) direction using friendship up and down Mistake sets the mode of flowing hole to be attached each cell compartment.
4. method according to claim 2, it is characterised in that step 1) described in dephosphorization sludge source in municipal sewage Treatment plant's second pond returned sludge.
5. a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low-carbon-sources city according to claim 2 The application process of city's sewage device, it is characterised in that step 1) described in the poly- ammonia that is added of three sections of Anammox reaction zones The size range of ester sponge filler is 1.5cm × 1.5cm × 1.5cm-2.0cm × 2.0cm × 2.0cm.
6. a kind of continuous stream A/O dephosphorization series multistage A/O autotrophic denitrification PROCESS FOR TREATMENT low-carbon-sources city according to claim 2 The application process of city's sewage device, it is characterised in that step 1) described in Anammox sponge fillers derive from sludge-digestion liquid Anammox engineerings.
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