CN107265587A - A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies - Google Patents

A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies Download PDF

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Publication number
CN107265587A
CN107265587A CN201710545224.4A CN201710545224A CN107265587A CN 107265587 A CN107265587 A CN 107265587A CN 201710545224 A CN201710545224 A CN 201710545224A CN 107265587 A CN107265587 A CN 107265587A
Authority
CN
China
Prior art keywords
waste water
raw material
alcohol
total
many raw
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710545224.4A
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Chinese (zh)
Inventor
孙振江
李永恒
李志鹏
许旺发
梁坤国
王禹
高峰
李臣支
郭春雷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGXI COFCO BIO-ENERGY Co Ltd
Original Assignee
GUANGXI COFCO BIO-ENERGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGXI COFCO BIO-ENERGY Co Ltd filed Critical GUANGXI COFCO BIO-ENERGY Co Ltd
Priority to CN201710545224.4A priority Critical patent/CN107265587A/en
Publication of CN107265587A publication Critical patent/CN107265587A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • C02F2103/325Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters from processes relating to the production of wine products

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Treatment By Sorption (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies.Method is in many raw material alcohol waste water and clear liquids, 5.5~6.5kg/t sewage polyaluminum sulfate iron adsorbent 50~60ppm polyacrylamide flocculants are put into successively, separation of solid and liquid is being carried out by tilted plate separator, solid goes to the dehydration of plate frame filter press, and waste liquid, which enters, enters alcohol waste water processing system after Clear liquid tank.Waste liquid nitrogen removal rate is 47.54%~52.84%, and total tp removal rate is 44.08%~58.02%.The present invention solves the qualified technical problem of waste liquid total nitrogen total phosphorus key index in fermentation alcohol industry.The processing method of the alcohol waste water to many raw materials is provided for a large amount of Alcohol Plants, this method investment is small, with good application prospect.

Description

A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies
Technical field
The invention belongs to the technical field of alcohol waste water processing, specifically a kind of many raw material alcohol waste water total nitrogen total phosphorus removal sides Method.
Background technology
Alcohol industry is the important basic material industry of national economy, and alcohol is widely used in chemical industry, food industry, day The fields such as change, medical and health.The raw material of current China Alcohol Production is mainly the starchy materials such as corn, potato class, paddy rice.Because Maize raw material crude protein 8~10%, rice crude protein 7.7% or so, potato class is generally 3% or so, therefore corn alcohol waste water and big Rice alcohol waste water total nitrogen total phosphorus content is more, it is common to use protein feed product is made in evaporation concentration device, produces low concentration and steams Send out condensate wastewater;And the relatively low nutriment of waste liquid total nitrogen content of potato class is low, need directly to handle row up to standard by biochemical process Put.
Current country GB 27631-2011<Fermentation alcohol and Liquor-making industry pollution discharge standard>Have to total nitrogen total phosphorus Limitation requires that wherein total nitrogen discharges total nitrogen≤50mg/l, total phosphorus≤3mg/l indirectly.If realizing cassava, jade on same production line Many raw material alcohol wastewater treatments such as rice, paddy rice, it is necessary to effective pre-treatment is carried out to the total nitrogen total phosphorus in corn and rice waste water, Otherwise original follow-up water treatment efficiency can be influenceed, it is impossible to qualified discharge.
The content of the invention
The present invention is to carry out pre-treatment to alcohol clear liquid using bodied ferric sulfate and polyacrylamide, and waste water is greatly lowered In total nitrogen total phosphorus refer to calibration method.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:
A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies, in many raw material alcohol waste water and clear liquids, put into 5.5 successively ~6.5kg/t sewage polyaluminum sulfate iron adsorbent 50~60ppm polyacrylamide flocculants, are consolidated by tilted plate separator Liquid is separated, and solid goes to the dehydration of plate frame filter press, and waste liquid, which enters, enters alcohol waste water processing system, waste liquid total nitrogen after Clear liquid tank Clearance is 47.54%~52.84%, and total tp removal rate is 44.08%~58.02%;Many raw material alcohol waste water and clear liquids It is that, with corn, potato class, paddy rice is the waste water that raw material produces alcohol.
Advantages of the present invention is as follows:
(1) most total nitrogen total phosphorus is anticipated to clear liquid by the inventive method, the processing for reducing subsequent handling is difficult Degree.
(2) inventive method saves the medicament usage amount of subsequent handling.
(3) inventive method, by the procedure, nitrogen removal rate 47.54%-52.84%, total tp removal rate 44.08%- More than 58.02%.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies, in many raw material alcohol waste water and clear liquids, put into successively 5.5kg/t sewage polyaluminum sulfate iron adsorbent 50ppm polyacrylamide flocculants, after sloping plate deposition solid-liquid separation, give up Liquid nitrogen removal rate is 47.54%, and total tp removal rate is 44.08%.
Embodiment 2
A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies, in many raw material alcohol waste water and clear liquids, put into successively 6kg/t sewage polyaluminum sulfate iron adsorbent 55ppm polyacrylamide flocculants, after sloping plate deposition solid-liquid separation, waste liquid Nitrogen removal rate is 50.46%, and total tp removal rate is 52.38%.
Embodiment 3
A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies, in many raw material alcohol waste water and clear liquids, put into successively 6.5kg/t sewage polyaluminum sulfate iron adsorbent 60ppm polyacrylamide flocculants, after sloping plate deposition solid-liquid separation, give up Liquid nitrogen removal rate is 52.84%, and total tp removal rate is 58.02%.

Claims (1)

1. a kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies, in many raw material alcohol waste water and clear liquids, put into 5.5 successively~ 6.5kg/t sewage polyaluminum sulfate iron adsorbent 50~60ppm polyacrylamide flocculants, solid-liquid is being carried out by tilted plate separator Separation, solid goes to the dehydration of plate frame filter press, and waste liquid, which enters, enters alcohol waste water processing system after Clear liquid tank, waste liquid total nitrogen is gone Except rate is 47.54%~52.84%, total tp removal rate is 44.08%~58.02%;Many raw material alcohol waste water and clear liquids are With corn, potato class, paddy rice is the waste water that raw material produces alcohol.
CN201710545224.4A 2017-07-06 2017-07-06 A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies Pending CN107265587A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710545224.4A CN107265587A (en) 2017-07-06 2017-07-06 A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710545224.4A CN107265587A (en) 2017-07-06 2017-07-06 A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies

Publications (1)

Publication Number Publication Date
CN107265587A true CN107265587A (en) 2017-10-20

Family

ID=60072230

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710545224.4A Pending CN107265587A (en) 2017-07-06 2017-07-06 A kind of many raw material alcohol waste water total nitrogen total phosphorus minimizing technologies

Country Status (1)

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CN (1) CN107265587A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107572643A (en) * 2017-11-02 2018-01-12 重庆大学 A kind of preparation technology of compound coagulant and its application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101269904A (en) * 2008-04-29 2008-09-24 安徽瑞福祥食品有限公司 Method for wastewater treatment of fermentation groove liquid and uses thereof
CN104591440A (en) * 2015-01-20 2015-05-06 广西中粮生物质能源有限公司 Method for treating wastewater generated after preparing alcohol from cassavas as raw material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101269904A (en) * 2008-04-29 2008-09-24 安徽瑞福祥食品有限公司 Method for wastewater treatment of fermentation groove liquid and uses thereof
CN104591440A (en) * 2015-01-20 2015-05-06 广西中粮生物质能源有限公司 Method for treating wastewater generated after preparing alcohol from cassavas as raw material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王龙等: "混凝法强化城市污水一级处理试验", 《水处理技术》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107572643A (en) * 2017-11-02 2018-01-12 重庆大学 A kind of preparation technology of compound coagulant and its application

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Application publication date: 20171020

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