CN107254083A - A kind of special sidewall rubber composition in white sidewall - Google Patents

A kind of special sidewall rubber composition in white sidewall Download PDF

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Publication number
CN107254083A
CN107254083A CN201710621618.3A CN201710621618A CN107254083A CN 107254083 A CN107254083 A CN 107254083A CN 201710621618 A CN201710621618 A CN 201710621618A CN 107254083 A CN107254083 A CN 107254083A
Authority
CN
China
Prior art keywords
sidewall
parts
white
rubber composition
special
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710621618.3A
Other languages
Chinese (zh)
Inventor
王中江
杜云峰
罗吉良
刘加强
张哲峰
郑涛
姜杰
龙飞飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Feng Yuan Tire Is Manufactured Ltd Co
Original Assignee
Shandong Feng Yuan Tire Is Manufactured Ltd Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Feng Yuan Tire Is Manufactured Ltd Co filed Critical Shandong Feng Yuan Tire Is Manufactured Ltd Co
Priority to CN201710621618.3A priority Critical patent/CN107254083A/en
Publication of CN107254083A publication Critical patent/CN107254083A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0025Compositions of the sidewalls
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Tires In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of white special sidewall rubber composition in sidewall, it is prepared from by the raw material of following parts by weight:100 parts of rubber;10 80 parts of reinforcing filler;38 parts of age resistor;2 20 parts of plasticizer, 16 parts of activating agent;2 ~ 5 parts of accelerator;1 ~ 6 part of vulcanizing agent.The present invention maintains sidewall formula physical and mechanical properties constant, improves itself and white sidewall or colored sidewall compound rear fastness, anti-pollution, anti-aging ability.

Description

A kind of special sidewall rubber composition in white sidewall
Technical field
The present invention relates to tire manufacturing techniques field, more particularly to a kind of special sidewall rubber composition in white sidewall.
Background technology
With the improvement of living standards and personalized life style pursuit, people match somebody with somebody the requirement generation of tire to vehicle Change, no longer only pursue tire quality, the different white sidewall tire of a variety of colors, color tyre more and more appear in people In the visual field of the people.
Color tyre is the product that coloured glue or white glue are combined with each other with the normal sidewall of tradition, but traditional white sidewall or The problem of colored sidewall changes colour in use is increasingly protruded, and the outward appearance of tire is directly affected after changing colour, and influences client Use feeling.
This project is studied primarily directed to white sidewall and colored sidewall tire discoloration problem, in view of the above-mentioned problems, right Traditional sidewall formula is redesigned, and develops new age resistor and formula, develops anti-tarnishing ability by force, antipollution newly to match somebody with somebody Square component, so that user is satisfied with, increases Products competitiveness.
The content of the invention
It is an object of the invention to provide a kind of white special sidewall rubber composition in sidewall, to solve above-mentioned technical problem.
The technical solution adopted by the present invention is to achieve the above object:A kind of special sidewall rubber composition in white sidewall, by The raw material of following parts by weight is prepared from:100 parts of rubber;10-80 parts of reinforcing filler;3-8 parts of age resistor;Plasticizer 2-20 Part, 1-6 parts of activating agent;2 ~ 5 parts of accelerator;1 ~ 6 part of vulcanizing agent.
Further scheme is invented as this case, the reinforcing filler is the carbon black N375 or general charcoals of high abrasion oven process Black N660.
Further scheme is invented as this case, the activating agent includes indirect process zinc oxide, stearic acid.
Further scheme is invented as this case, the age resistor is antioxidant 4020, RD, AFS, OK15032 mixing Agent.
Further scheme is invented as this case, the accelerator is TBBS.
Further scheme is invented as this case, the vulcanizing agent is HDOT 20.
Further scheme is invented as this case, plasticizer is that rubber operation oil includes TDAE, white naphthenic oil.
The beneficial effects of the invention are as follows:The present invention maintains sidewall formula physical and mechanical properties constant, improves itself and white tire Fastness, anti-pollution, anti-aging ability after side or colored sidewall are compound.
Embodiment
With reference to specific embodiment, the present invention is further elaborated.
A kind of special sidewall rubber composition in white sidewall, is prepared from by the raw material of following parts by weight:100 parts of rubber; 10-80 parts of reinforcing filler;3-8 parts of age resistor;2-20 parts of plasticizer, 1-6 parts of activating agent;2 ~ 5 parts of accelerator;Vulcanizing agent 1 ~ 6 Part;Wherein described reinforcing filler is the carbon black N375 or Universal carbon black N660 of high abrasion oven process;The activating agent includes indirect Method zinc oxide, stearic acid;The age resistor is antioxidant 4020, RD, AFS, OK15032 intermixture;The accelerator is TBBS;The vulcanizing agent is HDOT 20, and plasticizer is that rubber operation oil includes TDAE, white naphthenic oil.
New sidewall prepared by the present composition and traditional sidewall rubber material physical property contrast are as follows:
The physical property before and after the aging on new sidewall is suitable with traditional sidewall as can be seen from the above table, and tearing strength is not bad.
While traditional sidewall and new sidewall are being placed into anti-migration, color changeable effect contrast in 60 days naturally, draw using biography The white glue on system sidewall and colourless change colour contrast glue discoloration are fairly obvious, and transparent change colour contrast glue is because traditional sidewall is matched somebody with somebody Fang Zufen migration is changed into black substantially, and the white glue on the new sidewall contrasted then maintains original white, discoloration pair well Also only have light discolouration than glue, illustrate that new sidewall fastness anti-migration works well, by four kinds of age resistor in this case(4020、 RD、AFS、OK15032)Mix and be used in combination, play a key effect;It is effectively improved white sidewall or colored sidewall tire in use The problem of changing colour caused by the reasons such as the migration and thermo-oxidative ageing, ozone aging of sizing material material itself.
Above content is to combine specific preferred embodiment further description made for the present invention, it is impossible to assert The specific implementation of the present invention is confined to these explanations.For those skilled in the art, the present invention can have it is various more Change and change.Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., should be included in Within protection scope of the present invention.

Claims (7)

1. a kind of special sidewall rubber composition in white sidewall, it is characterised in that be prepared from by the raw material of following parts by weight:Rubber 100 parts of glue;10-80 parts of reinforcing filler;3-8 parts of age resistor;2-20 parts of plasticizer, 1-6 parts of activating agent;2 ~ 5 parts of accelerator;Sulphur 1 ~ 6 part of agent.
2. a kind of white special sidewall rubber composition in sidewall according to claim 1, it is characterised in that the reinforcement and filler Agent is the carbon black N375 or Universal carbon black N660 of high abrasion oven process.
3. a kind of white special sidewall rubber composition in sidewall according to claim 1, it is characterised in that the activating agent bag Include indirect process zinc oxide, stearic acid.
4. a kind of white special sidewall rubber composition in sidewall according to claim 1, it is characterised in that the age resistor is The intermixture of antioxidant 4020, RD, AFS, OK15032.
5. a kind of white special sidewall rubber composition in sidewall according to claim 1, it is characterised in that:The accelerator is TBBS。
6. a kind of white special sidewall rubber composition in sidewall according to claim 1, it is characterised in that:The vulcanizing agent is HDOT 20。
7. a kind of white special sidewall rubber composition in sidewall according to claim 1, it is characterised in that:Plasticizer is rubber Include TDAE, white naphthenic oil with operation oil.
CN201710621618.3A 2017-07-27 2017-07-27 A kind of special sidewall rubber composition in white sidewall Pending CN107254083A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710621618.3A CN107254083A (en) 2017-07-27 2017-07-27 A kind of special sidewall rubber composition in white sidewall

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710621618.3A CN107254083A (en) 2017-07-27 2017-07-27 A kind of special sidewall rubber composition in white sidewall

Publications (1)

Publication Number Publication Date
CN107254083A true CN107254083A (en) 2017-10-17

Family

ID=60026191

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710621618.3A Pending CN107254083A (en) 2017-07-27 2017-07-27 A kind of special sidewall rubber composition in white sidewall

Country Status (1)

Country Link
CN (1) CN107254083A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104292511A (en) * 2014-08-26 2015-01-21 赛轮集团股份有限公司 Preparation method for aging resistance protection glue at tire side-wall and seam allowance part and application method thereof
CN105482173A (en) * 2015-12-07 2016-04-13 江苏通用科技股份有限公司 Formula of rubber for reducing porosity of tire component and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104292511A (en) * 2014-08-26 2015-01-21 赛轮集团股份有限公司 Preparation method for aging resistance protection glue at tire side-wall and seam allowance part and application method thereof
CN105482173A (en) * 2015-12-07 2016-04-13 江苏通用科技股份有限公司 Formula of rubber for reducing porosity of tire component and preparation method thereof

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SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20171017

RJ01 Rejection of invention patent application after publication