CN107252669A - Automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production - Google Patents

Automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production Download PDF

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Publication number
CN107252669A
CN107252669A CN201710633576.5A CN201710633576A CN107252669A CN 107252669 A CN107252669 A CN 107252669A CN 201710633576 A CN201710633576 A CN 201710633576A CN 107252669 A CN107252669 A CN 107252669A
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CN
China
Prior art keywords
middle level
top layer
agitating shaft
charging aperture
blade
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Pending
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CN201710633576.5A
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Chinese (zh)
Inventor
施海若
施玄烨
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Deqing Donglai Chemical Co Ltd
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Deqing Donglai Chemical Co Ltd
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Priority to CN201710633576.5A priority Critical patent/CN107252669A/en
Publication of CN107252669A publication Critical patent/CN107252669A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • B01J19/0066Stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/001Feed or outlet devices as such, e.g. feeding tubes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)

Abstract

The invention discloses a kind of liquid barium zinc heat stabilizer production automatic charging reactor, including housing and agitating device, agitating device includes agitating shaft and blade, blade is fixed on agitating shaft, agitating shaft is extend into housing, housing is divided into four layers, respectively top layer, upper middle level, lower middle level and bottom, agitating shaft passes through top layer, upper middle level, lower middle level and bottom, every layer is mounted on charging aperture, conveyance conduit is respectively connected with each charging aperture, the conveyance conduit being connected with the charging aperture of top layer is connected with suction pump, the conveyance conduit being connected with the charging aperture in upper middle level one of them be connected with suction pump, another is connected with air blower, the conveyance conduit being connected with the charging aperture in lower middle level is connected with air blower, the conveyance conduit being connected with the charging aperture of bottom is connected with air blower.Automatic charging reactor use in a kind of liquid barium zinc heat stabilizer production of the present invention, can automatic charging, feeding is simple, time saving and energy saving, raising production efficiency.

Description

Automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production
Technical field
The present invention relates to the equipment that a kind of production of liquid barium zinc heat stabilizer is used, more particularly to the reactor used.
Background technology
Liquid barium zinc heat stabilizer can increase the stability of solution, colloid, solid, mixture, and it can slow down reaction, Chemical balance is kept, surface tension is reduced, prevents light, thermal decomposition or oxidation Decomposition etc. from acting on.Liquid barium zinc heat stabilizer due to Composition is different, and property is also different.But usually light yellow to yellow clear liquid, proportion 0.95-1.02 under normal temperature, viscosity is less than 100 centipoises, freezing point is at -15 DEG C or so.It is similar to liquid barium zinc, there are excellent heat, photostability, initial coloring is small, good The good transparency and color stability.Liquid barium zinc heat stabilizer importance then increasingly increases, and liquid ba/ is supplied in the market Zn stabilizer types are various, may be used with nearly all spectra from semi-rigid product to plasticized PVC, including roll, extrude, being molded and squeeze Go out blowing, injection blowing and the processing of plastisol.
Application publication number is CN106397831A, and date of publication disclosed for the Chinese invention patent application of on 2 5th, 2017 A kind of liquid barium zinc heat stabilizer and preparation method and application.The liquid barium zinc heat stabilizer is by including solvent, organic acid, oxygen Change zinc, water, barium salt, antioxidant, the raw material of auxiliary stabilizer to be made of " one-step method " substep single preparation technology, it prepares step Suddenly it is:
1) solvent, organic acid are added in reactor (bottle), 70-80 DEG C, held for some time (general 10- is heated to 30min) to material clear (organic acid all dissolves);
2) zinc oxide and catalyst water are added, in 70-80 DEG C of insulation reaction certain time (general 30-60min), to reaction System clear;
3) add barium salt, in 115-125 DEG C of insulation reaction 1-3 hour, then pressure -0.09MPa extremely -0.098MPa, Reacted 0.5-2 hours under the conditions of 115-125 DEG C of temperature, obtain thick liquid (dark-brown no suspended substance);
4) antioxidant, auxiliary stabilizer are added, (general 30-60min is left in 80-120 DEG C of insulation reaction certain time It is right), brownish red oily liquids (this step typically need not be heated additionally, be incubated by original material self heat) is obtained, Filter clear liquid produces the liquid barium zinc heat stabilizer.
Above-mentioned preparation method prepares liquid barium zinc heat stabilizer by reactor and there is following defect:
1st, in above-mentioned preparation process, needing to be incubated in a kettle. in 10-30min, step 2 in step 1 needs in reaction It is incubated in 30-60min, step 3 to need to be incubated in a kettle. after 60-180min in kettle and is incubated again in 30-120min, step 4 30-60min is incubated in a kettle., and to complete the preparation of liquid barium zinc heat stabilizer needs to be incubated 160min- in a kettle. 450min, it is relatively low using existing reactor production efficiency.
2nd, artificial loading is needed, artificial loading is wasted time and energy, and reduces production efficiency.
The content of the invention
In order to overcome existing reactor in the relatively low defect of the production efficiency that production liquid barium zinc heat stabilizer is present, this hair It is bright to use automatic charging reactor there is provided a kind of production of liquid barium zinc heat stabilizer, liquid barium zinc heat is prepared by the reactor steady When determining agent, can automatic charging, feeding is simple, time saving and energy saving.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is:
Automatic charging reactor, including housing and agitating device, agitating device are used in a kind of liquid barium zinc heat stabilizer production Including agitating shaft and blade, blade is fixed on agitating shaft, and agitating shaft is extend into housing, it is characterised in that:Housing is divided into four Layer, respectively top layer, upper middle level, lower middle level and bottom, agitating shaft passes through top layer, upper middle level, lower middle level and bottom, top layer, on Middle level, lower middle level and bottom are separated by dividing plate, and discharging opening is provided with every layer of dividing plate and bottom layer bottom, and discharge outlet is provided with Magnetic valve, top layer, upper middle level, is provided with two charging apertures, the housing in lower middle level on the housing of bottom and is provided with a charging Mouthful, charging aperture connects with enclosure interior, magnetic valve is mounted at charging aperture, the junction of dividing plate and agitating shaft is provided with axle Set, axle sleeve is socketed on agitating shaft, is provided with polylith blade, top layer, upper middle level, lower middle level and bottom and at least sets on agitating shaft It is equipped with one piece of blade, each charging aperture and is respectively connected with conveyance conduit, the conveyance conduit being connected with the charging aperture of top layer connects Suction pump is connected to, one of them is connected with suction pump to the conveyance conduit being connected with the charging aperture in upper middle level, and another is connected with drum Blower fan, the conveyance conduit being connected with the charging aperture in lower middle level is connected with air blower, the conveyance conduit being connected with the charging aperture of bottom It is connected with air blower.
It is preferred that, longitudinal chute is provided with the agitating shaft, blade is stuck in longitudinal chute by sliding axle, on agitating shaft It is provided with four cylinders, top layer, upper middle level, lower middle level and bottom and a cylinder is respectively installed, the other end of cylinder is connected to leaf On the sliding axle of piece.
It is preferred that, it is also associated with the agitating shaft in many stainless steel wires, top layer, upper middle level, lower middle level and bottom at least Respectively there are four steel wires.
It is preferred that, supersonic oscillations instrument is installed in the top layer, upper middle level, lower middle level and bottom, top layer, upper middle level, under The supersonic oscillations instrument in middle level is arranged on dividing plate, and the supersonic oscillations instrument of bottom is arranged on the bottom of enclosure interior.
It is preferred that, the blade is formed by connecting by polylith rectangular sheet, and each piece of rectangular sheet is linked together by rotary shaft, every piece Rectangular sheet is all connected with one piece of pulling-on piece, and the other end of pulling-on piece is both connected on sliding axle.
Compared with prior art, the present invention has advantages below:
1st, the present invention includes housing and agitating device, and agitating device includes agitating shaft and blade, and blade is fixed on agitating shaft On, agitating shaft is extend into housing, it is characterised in that:Housing is divided into four layers, respectively top layer, upper middle level, lower middle level and bottom, Agitating shaft passes through top layer, upper middle level, lower middle level and bottom, and top layer, upper middle level, lower middle level and bottom are separated by dividing plate, every layer It is provided with discharging opening on dividing plate and bottom layer bottom, discharge outlet is provided with magnetic valve, top layer, upper middle level, sets on the housing of bottom It is equipped with two charging apertures, the housing in lower middle level and is provided with a charging aperture, charging aperture is connected with enclosure interior, equal at charging aperture Magnetic valve is installed, the junction of dividing plate and agitating shaft is provided with axle sleeve, axle sleeve is socketed on agitating shaft, is installed on agitating shaft There is a polylith blade, at least provided with one piece of blade in top layer, upper middle level, lower middle level and bottom, connect at each charging aperture Conveyance conduit is connected to, the conveyance conduit being connected with the charging aperture of top layer is connected with suction pump, be connected with the charging aperture in upper middle level One of them is connected with suction pump to conveyance conduit, and another is connected with air blower, the delivery pipe being connected with the charging aperture in lower middle level Road is connected with air blower, and the conveyance conduit being connected with the charging aperture of bottom is connected with air blower.The present invention divide into reactor Four layers, it is used for solvent in top layer and organic acid adds mixing insulation, the addition that zinc oxide and catalyst water are used in upper middle level is protected Temperature, is used for the addition and insulation of barium salt in lower middle level, adds and is incubated in bottom antioxidant, auxiliary stabilizer, specific work Process is:First by two charging apertures of top layer, solvent and organic acid are separately added into, after insulation reaches requirement, electricity is opened Solution is put into upper middle level by magnet valve, adds zinc oxide and catalyst water by two charging apertures in upper middle level, insulation reaches It is required that after, control magnetic valve is opened, and is put into lower middle level, then adds barium salt by the charging aperture in lower middle level, insulation reaches It is required that after, regulation air pressure is to after requiring in insulation, and insulation is reached after requirement, opens magnetic valve and enters in bottom, passes through bottom Two charging apertures add antioxidant, auxiliary stabilizer, insulation reach after requirement, open discharging opening magnetic valve, you can obtain Barium zinc stabilizer.Because reactor divide into top layer, upper middle level, lower middle level and bottom by the present invention, enter in the material of top layer To after upper middle level, top layer is fed intake, and such advantage is, the insulation of the material of four layers has been entered within the same time, this Sample has been considerably improved production efficiency.The present invention by the effect of conveyance conduit and air blower and suction pump, can automatically on Material, substitutes artificial loading, improves loading efficiency, improve production efficiency, liquid is passed through by suction pump feeding, object material Air blower air blast feeding.
2nd, longitudinal chute is provided with agitating shaft of the present invention, blade is stuck in longitudinal chute by sliding axle, stirred It is provided with axle in four cylinders, top layer, upper middle level, lower middle level and bottom and a cylinder is respectively installed, the other end connection of cylinder On the sliding axle of blade.Blade can be controlled to move up and down by cylinder, guiding and spacing blade can be played by chute Effect.By the up and down motion of blade, stirring can be promoted more uniform, be all so uniformly heated in stirring up and down, Reaction is more thorough.
3rd, it is also associated with agitating shaft of the present invention at least each in many stainless steel wires, top layer, upper middle level, lower middle level and bottom There are four steel wires.Agitating shaft is when stirring, and stainless steel wire can carry out centrifugal motion under the influence of centrifugal force, thus can Play a part of a stirring to liquid, stirring action face is bigger, stirring is more uniform thorough.
The 4th, supersonic oscillations instrument be installed in top layer of the present invention, upper middle level, lower middle level and bottom, top layer, upper middle level, it is lower in The supersonic oscillations instrument of layer is arranged on dividing plate, and the supersonic oscillations instrument of bottom is arranged on the bottom of enclosure interior.Pass through ultrasound The effect of ripple shaker is exactly to play a part of a vibration, and the mixing of strength imparting material accelerates reaction, improves production efficiency.
5th, blade of the present invention is formed by connecting by polylith rectangular sheet, and each piece of rectangular sheet is linked together by rotary shaft, every piece Rectangular sheet is all connected with one piece of pulling-on piece, and the other end of pulling-on piece is both connected on sliding axle.Sliding axle, will when moving up and down Drive pulling-on piece to move left and right, so as to pull rectangular sheet to rotate upwardly and downwardly, realize that the length of blade is shunk and swung up and down, stirring is just Can be more thorough, accelerate the reaction of material, improve production efficiency.
Brief description of the drawings
Fig. 1 is overall structure diagram of the present invention
Fig. 2 is the structural representation of blade of the present invention.
Reference 1, housing, 2, agitating shaft, 3, blade, 4, conveyance conduit, 5, top layer, 6, upper middle level, 7, lower middle level, 8, Bottom, 9, dividing plate, 10, magnetic valve, 11, charging aperture, 12, longitudinal chute, 13, sliding axle, 14, cylinder, 15, stainless steel wire, 16, Supersonic oscillations instrument, 17, rectangular sheet, 18, rotary shaft, 19, pulling-on piece, 20, discharging opening.
Embodiment
Invention shape is further described with reference to embodiment, described embodiment is only a part of the invention Embodiment, is not whole embodiments.Based on embodiments of the invention, one of ordinary skill in the art is not making wound Other embodiments used obtained under the premise of the property made work, belong to protection scope of the present invention.
The present invention includes housing 1 and agitating device, and agitating device includes agitating shaft 2 and blade 3, and blade 3 is fixed on stirring On axle 2, agitating shaft 2 is extend into housing 1, and resistive heater is arranged in the inside circumference (not shown) of housing 1, its feature It is:1 point of housing is four layers, respectively top layer 5, upper middle level 6, lower middle level 7 and bottom 8, agitating shaft through top layer, upper middle level, Lower middle level and bottom, top layer, upper middle level, lower middle level and bottom are separated by dividing plate 9, are set on every layer of dividing plate 9 and the bottom of bottom 8 There is a discharging opening, discharge outlet is provided with magnetic valve 10, top layer, upper middle level, be provided with two charging apertures 11 on the housing of bottom, under A charging aperture and an air pressure adjustment mouthful (not shown) are provided with the housing in middle level, charging aperture connects with enclosure interior It is logical, magnetic valve 10 is mounted at charging aperture, the junction of dividing plate 9 and agitating shaft 2 axle sleeve is provided with, axle sleeve is socketed in stirring It is provided with axle, on agitating shaft in polylith blade 3, top layer, upper middle level, lower middle level and bottom at least provided with one piece of blade.Institute State and be respectively connected with conveyance conduit 4 at each charging aperture 11, the conveyance conduit being connected with the charging aperture 11 of top layer is connected with suction pump (not shown), one of them is connected with suction pump (not shown) to the conveyance conduit 4 being connected with the charging aperture in upper middle level, Another is connected with air blower (not shown), and the conveyance conduit 4 being connected with the charging aperture in lower middle level is connected with air blower (figure Not shown in), the conveyance conduit being connected with the charging aperture of bottom is connected with air blower (not shown).The present invention is by reactor Four layers are divide into, being used for solvent and organic acid in top layer adds mixing insulation, zinc oxide and catalyst water are used in upper middle level Insulation is added, is used for the addition and insulation of barium salt in lower middle level, adds and is incubated in bottom antioxidant, auxiliary stabilizer, specifically The course of work be:First by two charging apertures of top layer, solvent and organic acid are separately added into, after insulation reaches requirement, Open magnetic valve solution is put into upper middle level, add zinc oxide and catalyst water by two charging apertures in upper middle level, protect Temperature reaches after requirement that control magnetic valve is opened, and is put into lower middle level, then adds barium salt by the charging aperture in lower middle level, protects Temperature reaches after requirement that regulation air pressure is to after requiring in insulation, and insulation is reached after requirement, opens magnetic valve and enters in bottom, leads to Two charging apertures for crossing bottom add antioxidant, auxiliary stabilizer, and insulation is reached after requirement, opens the magnetic valve of discharging opening, i.e., It can obtain barium zinc stabilizer.Because reactor divide into top layer, upper middle level, lower middle level and bottom by the present invention, in the thing of top layer Material is entered behind middle level, and top layer is fed intake, and such advantage is, the guarantor of the material of four layers has been entered within the same time Temperature, thus substantially increases production efficiency.
Longitudinal chute 12 is provided with agitating shaft 2 of the present invention, blade 3 is stuck in longitudinal chute 12 by sliding axle 13 It is interior, it is provided with agitating shaft 2 in four cylinders 14, top layer, upper middle level, lower middle level and bottom and a cylinder 14, cylinder is respectively installed 14 other end is connected on the sliding axle 13 of blade.Blade can be controlled to move up and down by cylinder, can be risen by chute To the effect being oriented to spacing blade.By the up and down motion of blade, stirring can be promoted more uniform, up and down all in stirring, So it is uniformly heated, reacts more thorough.
It is also associated with agitating shaft 2 of the present invention in many stainless steel wires 15, top layer, upper middle level, lower middle level and bottom at least Respectively there are four steel wires.Agitating shaft is when stirring, and stainless steel wire can carry out centrifugal motion under the influence of centrifugal force, thus A stirring can be played a part of to liquid, stirring action face is bigger, stirring is more uniform thorough.
Supersonic oscillations instrument 16 is installed in top layer of the present invention, upper middle level, lower middle level and bottom, top layer, upper middle level, it is lower in The supersonic oscillations instrument of layer is arranged on dividing plate, and the supersonic oscillations instrument of bottom is arranged on the bottom of enclosure interior.Pass through ultrasound The effect of ripple shaker is exactly to play a part of a vibration, and the mixing of strength imparting material accelerates reaction, improves production efficiency.
Blade of the present invention is formed by connecting by polylith rectangular sheet 17, and each piece of rectangular sheet 17 is linked together by rotary shaft 18, Every piece of rectangular sheet 17 is all connected with one piece of pulling-on piece 19, and the other end of pulling-on piece 19 is both connected on sliding axle 13.Sliding axle is being transported up and down When dynamic, pulling-on piece will be driven to move left and right, so as to pull rectangular sheet to rotate upwardly and downwardly, realize blade length shrink and on Lower swing, stirring more thoroughly, will accelerate the reaction of material, improve production efficiency.

Claims (5)

1. automatic charging reactor, including housing and agitating device, agitating device bag are used in a kind of liquid barium zinc heat stabilizer production Agitating shaft and blade are included, blade is fixed on agitating shaft, and agitating shaft is extend into housing, it is characterised in that:Housing is divided into four layers, Respectively top layer, upper middle level, lower middle level and bottom, agitating shaft pass through top layer, upper middle level, lower middle level and bottom, top layer, it is upper in Layer, lower middle level and bottom are separated by dividing plate, discharging opening are provided with every layer of dividing plate and bottom layer bottom, discharge outlet is provided with electricity Magnet valve, top layer, upper middle level, is provided with two charging apertures, the housing in lower middle level on the housing of bottom and is provided with a charging aperture, Charging aperture is connected with enclosure interior, and magnetic valve is mounted at charging aperture, and the junction of dividing plate and agitating shaft is provided with axle sleeve, Axle sleeve is socketed on agitating shaft, is provided with polylith blade on agitating shaft, in top layer, upper middle level, lower middle level and bottom at least provided with Have and be respectively connected with conveyance conduit at one piece of blade, each charging aperture, the conveyance conduit connected with the charging aperture of top layer is connected There is suction pump, one of them is connected with suction pump to the conveyance conduit being connected with the charging aperture in upper middle level, and another is connected with air blast Machine, the conveyance conduit being connected with the charging aperture in lower middle level is connected with air blower, and the conveyance conduit being connected with the charging aperture of bottom connects It is connected to air blower.
2. automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production according to claim 1, it is characterised in that: Longitudinal chute is provided with the agitating shaft, blade is stuck in longitudinal chute by sliding axle, four gas are installed on agitating shaft One cylinder is respectively installed, the other end of cylinder is connected on the sliding axle of blade in cylinder, top layer, upper middle level, lower middle level and bottom.
3. automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production according to claim 1, it is characterised in that: It is also associated with least respectively there are four steel wires in many stainless steel wires, top layer, upper middle level, lower middle level and bottom on the agitating shaft.
4. automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production according to claim 1, it is characterised in that: Supersonic oscillations instrument is installed, top layer, upper middle level, the ultrasonic wave in lower middle level shake in the top layer, upper middle level, lower middle level and bottom Instrument is swung on dividing plate, and the supersonic oscillations instrument of bottom is arranged on the bottom of enclosure interior.
5. automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production according to claim 1, it is characterised in that: The blade is formed by connecting by polylith rectangular sheet, and each piece of rectangular sheet is linked together by rotary shaft, and every piece of rectangular sheet is all connected with One piece of pulling-on piece, the other end of pulling-on piece is both connected on sliding axle.
CN201710633576.5A 2017-07-28 2017-07-28 Automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production Pending CN107252669A (en)

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CN201710633576.5A CN107252669A (en) 2017-07-28 2017-07-28 Automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production

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CN201710633576.5A CN107252669A (en) 2017-07-28 2017-07-28 Automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107694506A (en) * 2017-11-22 2018-02-16 刘涔 One kind graduation Chemical Manufacture reactor
CN111375366A (en) * 2018-12-31 2020-07-07 中国石油化工股份有限公司 Rotating bed reactor and two-stage absorption process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106512892A (en) * 2016-11-04 2017-03-22 中国建筑材料科学研究总院 Continuous reaction device
CN206276378U (en) * 2016-11-02 2017-06-27 潍坊盛瑜药业股份有限公司 A kind of reactor stirring vane for synthesizing hexanicit
CN206996599U (en) * 2017-07-28 2018-02-13 德清县东来化学有限公司 Automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN206276378U (en) * 2016-11-02 2017-06-27 潍坊盛瑜药业股份有限公司 A kind of reactor stirring vane for synthesizing hexanicit
CN106512892A (en) * 2016-11-04 2017-03-22 中国建筑材料科学研究总院 Continuous reaction device
CN206996599U (en) * 2017-07-28 2018-02-13 德清县东来化学有限公司 Automatic charging reactor is used in a kind of liquid barium zinc heat stabilizer production

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107694506A (en) * 2017-11-22 2018-02-16 刘涔 One kind graduation Chemical Manufacture reactor
CN111375366A (en) * 2018-12-31 2020-07-07 中国石油化工股份有限公司 Rotating bed reactor and two-stage absorption process

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Application publication date: 20171017