CN107244053A - The production method and obtained film of a kind of Environment-friendlygold gold green onion film - Google Patents

The production method and obtained film of a kind of Environment-friendlygold gold green onion film Download PDF

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Publication number
CN107244053A
CN107244053A CN201710482829.3A CN201710482829A CN107244053A CN 107244053 A CN107244053 A CN 107244053A CN 201710482829 A CN201710482829 A CN 201710482829A CN 107244053 A CN107244053 A CN 107244053A
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CN
China
Prior art keywords
green onion
friendlygold
environment
eva
production method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710482829.3A
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Chinese (zh)
Inventor
王家金
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DONGGUAN KAIYUAN PLASTICATION TECHNOLOGY Co Ltd
Original Assignee
DONGGUAN KAIYUAN PLASTICATION TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DONGGUAN KAIYUAN PLASTICATION TECHNOLOGY Co Ltd filed Critical DONGGUAN KAIYUAN PLASTICATION TECHNOLOGY Co Ltd
Priority to CN201710482829.3A priority Critical patent/CN107244053A/en
Publication of CN107244053A publication Critical patent/CN107244053A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/002Combinations of extrusion moulding with other shaping operations combined with surface shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853Vinylacetate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2491/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The invention discloses a kind of production method of Environment-friendlygold gold green onion film and obtained film, production process comprises the following steps:EVA is added into a mixing bowl, White Mineral Oil is added while stirring, White Mineral Oil stirs after adding, and adds glitter powder and stirs, mixed material is made;Mixed material is put into extruder, is extruded after heating melting by T-shaped advection mould, adjusts die gap and linear velocity to produce required thickness, packaging is produced after certified products are wound after cutting edge.The present invention makees raw material using EVA, more environmentally friendly, using adsorbent of the environmentally friendly White Mineral Oil as glitter powder, glitter powder is well mixed it with material with simple a mixing bowl, no solvent residue;Using the production technology one-shot forming of extrusion curtain coating, without laminating, production efficiency is higher.The present invention can replace conventional EVA, PEVA, PE film, for packing the fields such as toy, stationery, household articles.

Description

The production method and obtained film of a kind of Environment-friendlygold gold green onion film
Technical field
The present invention relates to thin-film material technical field, the production method of specifically a kind of Environment-friendlygold gold green onion film and obtained thin Film.
Background technology
With the fast development of China's printing packaging industry, market for adapt to people make rapid progress it is spiritual cultural and green The demand that colour circle is protected is more strong and urgent, and due to current printed apcksging material in the market, quality of materials difference is big, price is unstable Fixed, especially innovative material cycle length, input be big, price is high-leveled and difficult in being acceptable to the market, therefore, a kind of economic, attractive in appearance, ring of exploitation The packaging product of guarantor has just put on agenda, and glitter film is exactly to be developed under such market environment.Glitter film is Extraordinary plate-making imprint process technique, which is combined, using the reflection and refraction of light forms lens array imaging and cone on the plastic film Different faces light reflects, changed over by painting, aluminizing as a kind of packaging film of raising decorative effect, and its material can be divided into PP Two kinds of material and PVC material, glitter film are rolled in material surface formation frosted texture, according to film version not by special film version Together, different pattern effect can be produced.Difference with common glitter powder is:Surface is produced by spreading glitter powder or plating aluminium powder Come into force fruit, but using optical principle the surface imprint definite shape of film film line to reach irreflexive effect, its is reflective Effect easily will not reduce reflecting effect as glitter powder because coming off.Glitter film is applied to offset printing, gravure, silk-screen, special type Printing, the processing mode such as gold stamping, at present in tobacco and wine, toothpaste box, CD boxes, cosmetics, stationery, gift wrap, lamp decoration, building materials, wide The package decoration in the market for accusing all trades and professions such as decoration, window patch, adhesive sticker, footwear industry, hairdressing place's lamp is widely applied.Market Glitter powder is clipped in two membranes by upper traditional glitter film based on PP materials or PVC materials using gluing, powder, the technique fitted Centre, exist processing technology it is complicated, not environmentally, the low deficiency of production efficiency.
The content of the invention
It is above-mentioned to solve it is an object of the invention to provide a kind of production method of Environment-friendlygold gold green onion film and obtained film The problem of being proposed in background technology.
To achieve the above object, the present invention provides following technical scheme:
A kind of production method of Environment-friendlygold gold green onion film, comprises the following steps:
1)By EVA(Ethylene-vinyl acetate copolymer)A mixing bowl is poured into, White Mineral Oil is added while stirring, and stir to White Mineral Oil Uniformly it is attached on EVA particles, adds green onion powder and continue to stir, until green onion powder is uniformly attached on EVA particle surfaces.
2)Mixed material is put into extruder, extruded after heating melting by T-shaped advection mould, adjustment die gap and line Speed produces required thickness, and packaging produces Environment-friendlygold gold green onion film after certified products are wound after cutting edge.
It is used as further scheme of the invention:VA weight/mass percentage composition is 10-28% in the EVA.
It is used as further scheme of the invention:Step 1)In, the addition of White Mineral Oil is the 0.1-2% of EVA mass.
It is used as further scheme of the invention:Step 1)In, the addition of White Mineral Oil is the 0.2-1% of EVA mass.
It is used as further scheme of the invention:Step 1)In, the addition of glitter powder is the 0.1-10% of EVA mass.
It is used as further scheme of the invention:Step 2)In, the temperature of heating melting is 120-190 DEG C.
It is used as further scheme of the invention:Step 2)In, also using minute surface knurling rolls and minute surface rubber roll to pressure after extrusion.
It is used as further scheme of the invention:Step 2)In, the linear velocity of extrusion is 5-30m/min.
It is used as further scheme of the invention:The color of glitter powder is radium-shine silver-colored, radium-shine golden, radium-shine color, silver color or gold.
Another object of the present invention is to provide golden green onion film made from methods described.
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention makees raw material using EVA, more environmentally friendly.The production technology one-shot forming that the present invention is cast using extrusion, without laminating, Production efficiency is higher.The present invention allows glitter powder with simple stirring using adsorbent of the environmentally friendly White Mineral Oil as glitter powder It is well mixed by cylinder with material, no solvent residue.In addition, the present invention also by minute surface knurling rolls and minute surface rubber roll to pressure, make Glitter film surface more smooth, glitter powder reflecting effect is more preferable.In summary, production process of the present invention have technique it is simple, Fast, it is easy to operate, be integrally formed, practical, production cost is low, production efficiency is high, the low feature of easy to use, energy consumption; Obtained golden green onion film safety and environmental protection, it is applied widely, conventional EVA, PEVA, PE film can be replaced, for membrane material, packaging, The fields such as ornaments, stationery, household articles, advertisement, building, with good market prospects.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of production method of Environment-friendlygold gold green onion film comprises the following steps:
1)EVA is poured into a mixing bowl, the White Mineral Oil of EVA mass 0.1% is then added while stirring, stirring is uniformly sticked to White Mineral Oil It is attached on EVA particles, the glitter powder stirring of EVA mass 2% is added, until green onion powder is uniformly attached on EVA particle surfaces.Institute The weight/mass percentage composition for stating VA in EVA is 10%.
2)Mixed material is put into extruder, extruded after 150 DEG C of heating meltings by T-shaped advection mould, the linear velocity of extrusion For 10m/min.Adjust die gap and linear velocity to produce required thickness, packaging produces ring after certified products are wound after cutting edge Insurance money green onion film.
Embodiment 2
In the embodiment of the present invention, a kind of production method of Environment-friendlygold gold green onion film comprises the following steps:
1)EVA is added into a mixing bowl, the White Mineral Oil of EVA mass 0.2% is then added while stirring, White Mineral Oil is stirred after adding More than 2min, the glitter powder for adding EVA mass 10% stirs, and mixed material is made;VA quality percentage in the EVA Content is 28%.
2)Mixed material is put into extruder, extruded after 160 DEG C of heating meltings by T-shaped advection mould, the linear velocity of extrusion For 15m/min.Adjust die gap and linear velocity to produce required thickness, packaging produces ring after certified products are wound after cutting edge Insurance money green onion film.
Embodiment 3
In the embodiment of the present invention, a kind of production method of Environment-friendlygold gold green onion film comprises the following steps:
1)EVA is poured into a mixing bowl, the White Mineral Oil of EVA mass 0.3% is then added while stirring, stirring is uniformly sticked to White Mineral Oil It is attached on EVA particles, the glitter powder stirring of EVA mass 2% is added, until green onion powder is uniformly attached on EVA particle surfaces.Institute The weight/mass percentage composition for stating VA in EVA is 16%.
2)Mixed material is put into extruder, extruded after 170 DEG C of heating meltings by T-shaped advection mould, the linear velocity of extrusion For 20m/min.Adjustment die gap and linear velocity use minute surface knurling rolls and minute surface rubber roll to produce after required thickness, extrusion To pressure, packaging produces Environment-friendlygold gold green onion film after certified products are wound after cutting edge.
Embodiment 4
In the embodiment of the present invention, a kind of production method of Environment-friendlygold gold green onion film comprises the following steps:
1)EVA is added into a mixing bowl, the White Mineral Oil of EVA mass 0.5% is then added while stirring, stirring is uniformly sticked to White Mineral Oil It is attached on EVA particles, the glitter powder for adding EVA mass 8% stirs, until green onion powder is uniformly attached on EVA particle tables Face.VA weight/mass percentage composition is 18% in the EVA.
2)Mixed material is put into extruder, extruded after 175 DEG C of heating meltings by T-shaped advection mould, the linear velocity of extrusion For 15m/min.Adjustment die gap and linear velocity use minute surface knurling rolls and minute surface rubber roll to produce after required thickness, extrusion To pressure, packaging produces Environment-friendlygold gold green onion film after certified products are wound after cutting edge.
Embodiment 5
In the embodiment of the present invention, a kind of production method of Environment-friendlygold gold green onion film comprises the following steps:
1)EVA is added into a mixing bowl, the White Mineral Oil of EVA mass 1% is then added while stirring, stirring is uniformly sticked to White Mineral Oil On EVA particles, the glitter powder for adding EVA mass 4% stirs, until green onion powder is uniformly attached on EVA particle surfaces. VA weight/mass percentage composition is 22% in the EVA.
2)Mixed material is put into extruder, extruded after 180 DEG C of heating meltings by T-shaped advection mould, the linear velocity of extrusion For 12m/min.Adjustment die gap and linear velocity use minute surface knurling rolls and minute surface rubber roll to produce after required thickness, extrusion To pressure, packaging produces Environment-friendlygold gold green onion film after certified products are wound after cutting edge.
Embodiment 6
In the embodiment of the present invention, a kind of production method of Environment-friendlygold gold green onion film comprises the following steps:
1)EVA is added into a mixing bowl, the White Mineral Oil of EVA mass 2% is then added while stirring, stirring is uniformly sticked to White Mineral Oil On EVA particles, the glitter powder for adding EVA mass 6% stirs, until green onion powder is uniformly attached on EVA particle surfaces. VA weight/mass percentage composition is 28% in the EVA.
2)Mixed material is put into extruder, extruded after 170 DEG C of heating meltings by T-shaped advection mould, the linear velocity of extrusion For 14m/min.Adjustment die gap and linear velocity use minute surface knurling rolls and minute surface rubber roll to produce after required thickness, extrusion To pressure, packaging produces Environment-friendlygold gold green onion film after certified products are wound after cutting edge.
Embodiment 7
In the embodiment of the present invention, a kind of production method of Environment-friendlygold gold green onion film comprises the following steps:
1)EVA is added into a mixing bowl, the White Mineral Oil of EVA mass 0.5% is then added while stirring, stirring is uniformly sticked to White Mineral Oil It is attached on EVA particles, the glitter powder for adding EVA mass 5% stirs, until green onion powder is uniformly attached on EVA particle tables Face.VA weight/mass percentage composition is 28% in the EVA.
2)Mixed material is put into extruder, extruded after 150 DEG C of heating meltings by T-shaped advection mould, the linear velocity of extrusion For 13m/min.Adjustment die gap and linear velocity use minute surface knurling rolls and minute surface rubber roll to produce after required thickness, extrusion To pressure, packaging produces Environment-friendlygold gold green onion film after certified products are wound after cutting edge.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It may be appreciated other embodiment.

Claims (10)

1. a kind of production method of Environment-friendlygold gold green onion film, it is characterised in that comprise the following steps:
1)EVA is added into a mixing bowl, White Mineral Oil is then added while stirring, White Mineral Oil stirs after adding, and adds golden green onion Powder stirs, and mixed material is made;
2)Mixed material is put into extruder, extruded after heating melting by T-shaped advection mould, adjustment die gap and linear velocity To produce required thickness, packaging produces Environment-friendlygold gold green onion film after certified products are wound after cutting edge.
2. the production method of Environment-friendlygold gold green onion film according to claim 1, it is characterised in that VA quality in the EVA Percentage composition is 10-28%.
3. the production method of Environment-friendlygold gold green onion film according to claim 1, it is characterised in that step 1)In, White Mineral Oil Addition is the 0.1-2% of EVA mass.
4. the production method of Environment-friendlygold gold green onion film according to claim 1, it is characterised in that step 1)In, White Mineral Oil Addition is the 0.2-1% of EVA mass.
5. the production method of Environment-friendlygold gold green onion film according to claim 1, it is characterised in that step 1)In, glitter powder Addition is the 0.1-10% of EVA mass.
6. the production method of Environment-friendlygold gold green onion film according to claim 1, it is characterised in that step 2)In, heating melting Temperature be 140-190 DEG C.
7. the production method of Environment-friendlygold gold green onion film according to claim 1, it is characterised in that step 2)In, after extrusion also Using minute surface knurling rolls and minute surface rubber roll to pressure.
8. the production method of Environment-friendlygold gold green onion film according to claim 1, it is characterised in that step 2)In, the line of extrusion Speed is 5-30m/min.
9. the production method of Environment-friendlygold gold green onion film according to claim 1, it is characterised in that the color of glitter powder is radium-shine Silver-colored, radium-shine golden, radium-shine color, silver color or gold.
10. the golden green onion film according to made from any described methods of claim 1-9.
CN201710482829.3A 2017-06-22 2017-06-22 The production method and obtained film of a kind of Environment-friendlygold gold green onion film Pending CN107244053A (en)

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CN201710482829.3A CN107244053A (en) 2017-06-22 2017-06-22 The production method and obtained film of a kind of Environment-friendlygold gold green onion film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710482829.3A CN107244053A (en) 2017-06-22 2017-06-22 The production method and obtained film of a kind of Environment-friendlygold gold green onion film

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116080215A (en) * 2022-12-09 2023-05-09 佛山市联塑万嘉科技有限公司 Preparation method and application of co-extrusion type glitter film

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101125933A (en) * 2007-09-18 2008-02-20 佛山塑料集团股份有限公司 Plastic film and preparation method thereof
US20100215902A1 (en) * 2009-02-20 2010-08-26 Thorsten Kiehne White coated polyester film, process for production thereof and use thereof as a backside cover in solar modules
CN103057137A (en) * 2012-12-20 2013-04-24 温州市华艺激光材料公司 Manufacturing method for glitter film
CN103182780A (en) * 2011-12-28 2013-07-03 比亚迪股份有限公司 Device and method for producing ethylene-vinyl acetate copolymer packaging film
CN104448523A (en) * 2014-11-24 2015-03-25 苏州市贝克生物科技有限公司 Medical EVA film and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101125933A (en) * 2007-09-18 2008-02-20 佛山塑料集团股份有限公司 Plastic film and preparation method thereof
US20100215902A1 (en) * 2009-02-20 2010-08-26 Thorsten Kiehne White coated polyester film, process for production thereof and use thereof as a backside cover in solar modules
CN103182780A (en) * 2011-12-28 2013-07-03 比亚迪股份有限公司 Device and method for producing ethylene-vinyl acetate copolymer packaging film
CN103057137A (en) * 2012-12-20 2013-04-24 温州市华艺激光材料公司 Manufacturing method for glitter film
CN104448523A (en) * 2014-11-24 2015-03-25 苏州市贝克生物科技有限公司 Medical EVA film and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116080215A (en) * 2022-12-09 2023-05-09 佛山市联塑万嘉科技有限公司 Preparation method and application of co-extrusion type glitter film
CN116080215B (en) * 2022-12-09 2023-10-20 广东班特斯膜材科技有限公司 Preparation method and application of co-extrusion type glitter film

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Application publication date: 20171013