CN107243331B - Environment-friendly type water purification bag for water process and preparation method thereof - Google Patents
Environment-friendly type water purification bag for water process and preparation method thereof Download PDFInfo
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- CN107243331B CN107243331B CN201710694062.0A CN201710694062A CN107243331B CN 107243331 B CN107243331 B CN 107243331B CN 201710694062 A CN201710694062 A CN 201710694062A CN 107243331 B CN107243331 B CN 107243331B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2805—Sorbents inside a permeable or porous casing, e.g. inside a container, bag or membrane
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/286—Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/46—Materials comprising a mixture of inorganic and organic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
- B01J2220/485—Plants or land vegetals, e.g. cereals, wheat, corn, rice, sphagnum, peat moss
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Abstract
Provided by the present invention for the environment-friendly type water purification bag of water process, including water-purifying material packaging bag and the water-purifying material that is arranged in water-purifying material packaging bag；The water-purifying material packaging bag is made of bamboo charcoal fiber；The raw material of the water-purifying material includes following component by weight：25~30 parts of palygorskite, 20~25 parts of diatomite, 10~15 parts of bentonite, 10~20 parts of vermiculite, modified 15~20 parts of luffa fibers, 5~8 parts of bamboo scraps, 8~10 parts of charcoal powder.The raw material components for the water-purifying material that the present invention uses can be compounded well, it can mutually cooperate with and play a role between each component in obtained water-purifying material, achieve the purpose that synergy, the processing needs of different type water are adapted to, the pollutant in water removal can be efficiently removed, reach good purifying water effect, at the same time, water-purifying material packaging bag, which is made, using bamboo charcoal fiber also has superpower adsorption capacity, can cooperate with the water-purifying material collective effect in bag, removes the pollutant in water removal.
Description
Technical field
The present invention relates to water-treatment technology field, and in particular to a kind of for the environment-friendly type water purification bag of water process and its preparation
Method.
Background technology
Essential natural resources during water is human being's production and lives, and the environmental resource that biology is depended on for existence, with
The aggravation and water resource quality for water resources crisis constantly deteriorate, and shortage of water resources has evolved into what the whole world was paid close attention to jointly
Problem, and greatly developing method for treating water will play a crucial role for solving shortage of water resources this technical problem.
The method of water process has very much, and it is a kind of common method for treating water that water purification agent is added into water, this water process
Method mainly adsorbs water pollutant by water purification agent or is reacted with water pollutant, to reach water process
Purpose.In existing water purification agent, although some are nontoxic, treatment effect is very poor, although some treatment effects are excellent, is added with
Many chemical reagent, these chemical reagent easily remain in water in water treatment procedure, and remain chemical substance in water
It is likely to cause damage to human body, and the environmental problem that the residue after water purification is also be easy to cause.
Therefore, a kind of high treating effect is searched out, cost is low, and to all safe and non-toxic water purification agent of the mankind and environment, shows
Obtain very urgent and necessary.
The content of the invention
In view of this, the environment-friendly type for water process that the present invention provides a kind of environmental protection, cost is low and clean-up effect is good
Water purification bag, while additionally provide the preparation method of the environment-friendly type water purification bag.
Provided by the present invention for the environment-friendly type water purification bag of water process, including water-purifying material packaging bag and it is arranged at water purification material
Expect the water-purifying material in packaging bag；
The water-purifying material packaging bag is made of bamboo charcoal fiber；
The raw material of the water-purifying material includes following component by weight：
Further, the raw material of the water-purifying material includes following component by weight：
Further, the preparation method of the modified luffa fibers includes the following steps：
(1) after luffa being cut into segment, it is torn into single sponge gourd silk；
(2) the sponge gourd silk of gained in step (1) is placed in the ammonium hydroxide that concentration is 5~12%, is boiled at a temperature of 100 DEG C
2~4h, is then filtered, and is collected sponge gourd silk and is washed repeatedly with distilled water, untill to the last a cleaning solution is shown as neutrality；
(3) sponge gourd silk cleaned in step (2) is dried into 4~5h at 100~150 DEG C, is then cut into 1~1.5cm,
Modified luffa fibers are made；
Further, in the step (2), the concentration of ammonium hydroxide is 10%, and the time boiled is 3h；, will in the step (3)
Sponge gourd silk dry 4.5h at 120 DEG C, is then cut into 1.2cm, that is, modified luffa fibers are made；
Invention additionally discloses a kind of preparation method of the environment-friendly type water purification bag for water process, include the following steps：
A, it is 400~500 purposes palygorskite, diatomite, bentonite, vermiculite, bamboo scraps and charcoal powder to be all ground into granularity
After powder, mixed powder is mixed to prepare；
B, modified luffa fibers are added in obtained mixed powder into step a, and stirring is mixing modified luffa fibers
Be uniformly dispersed in powder, then add the suitable quantity of water for being enough to soak mixed powder and modified luffa fibers thereto, continue stirring 1.5~
2.5h, makes modified luffa fibers further disperse in mixed powder, refilters collection solid mixture；
C, the solid mixture of gained in step b is subjected to extruder grain, the nearly spherical shape that a diameter of 5~8mm is made is real
Bulbus cordis, is then dried, and the mixture medicine ball that moisture is not higher than 10% is made, and is water-purifying material；
D, the mixture medicine ball obtained by step c is placed in the water-purifying material packaging bag of bamboo charcoal fiber material, after envelope
The finished product of the environment-friendly type water purification bag for water process is made；
Further, in the step b, continue to stir 2h, modified luffa fibers is further disperseed in mixed powder；It is described
In step c, manufactured nearly spherical shape diameter of solid sphere is 6mm.
Beneficial effects of the present invention：Present invention employs palygorskite, diatomite, bentonite, vermiculite, modified luffa fibers,
Bamboo scraps and charcoal powder carry out compounding and have been made water-purifying material, and performance can be mutually cooperateed between each component in obtained water-purifying material
Effect, so as to efficiently remove the pollutant in water removal, reaches good purifying water effect, including removes the heavy metal and organic in water removal
Material etc..Wherein：Palygorskite has larger specific surface area, and strong adsorption, has heavy metal extremely strong adsorptivity；Vermiculite is layer
The silicate of shape structure, has the characteristics that porosity is high, specific surface area is big, and adsorption capacity is big, can remove ammonia nitrogen in water, again
Metallic element, phosphate, rare earth ion, organic pollution etc.；Diatomite is also loose structure, has larger specific surface area,
With extremely strong water imbibition and permeability, substantial amounts of water and oil can be adsorbed；Bentonitic structures shape it there is natural suction
Attached property, can remove a variety of inorganic and organic pollution in water removal；Contain substantial amounts of cellulose, hemicellulose in bamboo scraps, by means of
Porous, surface area is big, has the advantages that affine adsorptivity, can help the dissolubility pollutant matter in removing water, and can be right
Handling heavy metal in water；Charcoal powder is porous material, can adsorb the harmful substance in water, and is removed at the same time different
Taste；Luffa fibers are modified with processing by the means of alkali process modified luffa fibers are made so that fiber fibrillation, i.e., it is fine
Shu Bianchang, draw ratio increase are tieed up, and can effectively remove the lignin around cellulose, increases hole and surface is compared in absorption
Product, can be effectively improved the hydrophobicity and adsorptivity of luffa fibers, so as to greatly enhance the adsorptivity of luffa fibers, make obtained
Modified luffa fibers have stronger adsorptivity and desorption property, can not only remove heavy metal in water removal, incrustation scale, greasy dirt and organic
Material, and the random of modified luffa fibers plays the role of connection to irregular distribution, is conducive to be had Multiple components
Machine it is soft, so as to preferably play synergistic effect, can effectively prevent and water-purifying material finished product made from suppressing occur from
Analysis.
Each raw material components derive from a wealth of sources, are cheap in the water-purifying material of the present invention, property is stablized, and is nontoxic
Environmentally friendly material, can ensure the security of water quality, and reduce processing cost at the same time；Definite proportion relation can make
Palygorskite, diatomite, bentonite, vermiculite, modified luffa fibers, bamboo scraps and charcoal powder are preferably compounded, and are played respective
Advantage, achieve the purpose that synergy, adapt to the processing needs of different type water；In addition, bamboo scraps and luffa fibers are light, can
To increase the floatability of water-purifying material product, suspension and sink-float controllability, be conducive to the purification for reaching water body 3 D stereo
Effect.Meanwhile water-purifying material packaging bag is made using environmentally protective bamboo charcoal fiber in the present invention, not only with excellent permeable
Property and gas permeability, and because bamboo charcoal fiber specific surface area is big and is loose structure, therefore bamboo charcoal fiber also has superpower absorption
Power, can cooperate with the water-purifying material collective effect in bag, the pollutant in Adsorption water, in addition, bamboo charcoal fiber also has suppression
The features such as bacterium antibacterial.The environment-friendly type water purification bag clean-up effect of the present embodiment is good, and cost is low and to all safe nothing of the mankind and environment
Poison.
Meanwhile the present invention also provides a kind of preparation method of environment-friendly type water purification bag easy to operate, can be by each raw material group
Divide and uniformly mixed, each component is preferably carried out synergy, modified luffa fibers are dispersed in mixed powder, energy
Reach water-purifying material (i.e. mixture medicine ball) finished product made from effectively preventing and suppressing to isolate, while modified silk can also be made
Melon fiber is cooperateed with other components, preferably plays its suction-operated；The mixture diameter of solid sphere prepared is smaller, makes
Water-purifying material can occur more to contact with water in obtained water purification bag, so as to reach more preferable purifying water effect, by this reality
Excellent performance may finally be prepared by applying the preparation method of example, and stability is good, the good environment-friendly type water purification bag of purifying water effect.
Embodiment
Environment-friendly type water purification bag provided in this embodiment for water process, including water-purifying material packaging bag and it is arranged at water purification
Water-purifying material in material packaging bag；
The water-purifying material packaging bag is made of bamboo charcoal fiber；
The raw material of the water-purifying material includes following component by weight：
Preferably, the raw material of the water-purifying material includes following component by weight：
In the present embodiment, palygorskite, diatomite, bentonite, vermiculite, modified luffa fibers, bamboo scraps and charcoal powder are employed
Carry out compounding and be made water-purifying material, can mutually cooperate with and play a role between each component in obtained water-purifying material, so that high
The pollutant gone in water removal of effect, including remove heavy metal and organic substance etc. in water removal.Wherein：Palygorskite has larger ratio
Surface area, strong adsorption, has heavy metal extremely strong adsorptivity；Vermiculite is the silicate of layer structure, has porosity height, ratio
The characteristics of surface area is big, adsorption capacity is big, can remove ammonia nitrogen in water, heavy metal element, phosphate, rare earth ion, organic
Pollutant etc.；Diatomite is also loose structure, has larger specific surface area, has extremely strong water imbibition and permeability, can inhale
Attached substantial amounts of water and oil；It has natural adsorptivity to bentonitic structures shape, can go a variety of inorganic in water removal and have
Organic pollutants；Containing substantial amounts of cellulose, hemicellulose in bamboo scraps, by means of porous, surface area it is big, there is affine adsorptivity etc.
Advantage, can help the dissolubility pollutant matter in water removal, and can be to being handled in water heavy metal；Charcoal powder is
Porous material, can adsorb the harmful substance in water, and go to eliminate the unusual smell at the same time；Cellular knot is presented inside modified luffa fibers
Structure, has stronger adsorptivity and desorption property, can not only remove heavy metal, incrustation scale, greasy dirt and organic substance in water removal, and
Modified luffa fibers disorderly play the role of connection to irregular distribution, be conducive to carry out Multiple components it is organic soft,
So as to preferably play synergistic effect, it can effectively prevent and water-purifying material finished product isolates made from suppressing.This implementation
Each raw material components derive from a wealth of sources, are cheap in the water-purifying material of example, property is stablized, and are nontoxic environmentally friendly
Material, can ensure the security of water quality, and reduce processing cost at the same time；Definite proportion relation can make palygorskite, diatom
Soil, bentonite, vermiculite, modified luffa fibers, bamboo scraps and charcoal powder are preferably compounded, and play respective advantage, are reached
Synergistic purpose, adapts to the processing needs of different type water；In addition, bamboo scraps and luffa fibers are light, water purification can be increased
Floatability, suspension and the sink-float controllability of material product, are conducive to the clean-up effect for reaching water body 3 D stereo.Meanwhile
Water-purifying material packaging bag is made using environmentally protective bamboo charcoal fiber in the present embodiment, not only with excellent water penetration and ventilative
Property, and because bamboo charcoal fiber specific surface area is big and is loose structure, therefore bamboo charcoal fiber also has superpower adsorption capacity, can assist
With the water-purifying material collective effect in bag, the pollutant in Adsorption water, in addition, bamboo charcoal fiber also has the spies such as bacteriostasis antibiosis
Point.The environment-friendly type water purification bag clean-up effect of the present embodiment is good, and cost is low and all safe and non-toxic to the mankind and environment.
In the present embodiment, the preparation method of the modified luffa fibers includes the following steps：
(1) after luffa being cut into segment, it is torn into single sponge gourd silk；
(2) the sponge gourd silk of gained in step (1) is placed in the ammonium hydroxide that concentration is 5~12%, is boiled at a temperature of 100 DEG C
2~4h, is then filtered, and is collected sponge gourd silk and is washed repeatedly with distilled water, untill to the last a cleaning solution is shown as neutrality；
(3) sponge gourd silk cleaned in step (2) is dried into 4~5h at 100~150 DEG C, is then cut into 1~1.5cm,
Modified luffa fibers are made；
Wherein, in the step (2), the concentration of ammonium hydroxide is preferably 10%, and the time boiled is preferably 3h；The step
(3) in, sponge gourd silk is dried to 4.5h preferably at 120 DEG C, is then preferably cut into 1.2cm, that is, modified luffa fibers are made；
Luffa fibers are modified with processing by the means of alkali process in the present embodiment so that fiber fibrillation, i.e., it is fine
Shu Bianchang, draw ratio increase are tieed up, and can effectively remove the lignin around cellulose, increases hole and surface is compared in absorption
Product, can be effectively improved the hydrophobicity and adsorptivity of luffa fibers, so as to greatly enhance the adsorptivity of luffa fibers.
A kind of preparation method of the environment-friendly type water purification bag for water process is also disclosed in the present embodiment, includes the following steps：
A, it is 400~500 purposes palygorskite, diatomite, bentonite, vermiculite, bamboo scraps and charcoal powder to be all ground into granularity
After powder, mixed powder is mixed to prepare；
B, modified luffa fibers are added in obtained mixed powder into step a, and stirring is mixing modified luffa fibers
Be uniformly dispersed in powder, then add the suitable quantity of water for being enough to soak mixed powder and modified luffa fibers thereto, continue stirring 1.5~
2.5h, makes modified luffa fibers further disperse in mixed powder, refilters collection solid mixture；
C, the solid mixture of gained in step b is subjected to extruder grain, the nearly spherical shape that a diameter of 5~8mm is made is real
Bulbus cordis, is then dried, and the mixture medicine ball that moisture is not higher than 10% is made, and is water-purifying material；
D, the mixture medicine ball obtained by step c is placed in the water-purifying material packaging bag of bamboo charcoal fiber material, after envelope
The finished product of the environment-friendly type water purification bag for water process is made；
Wherein, in the step b, continue to stir 2h, modified luffa fibers is further disperseed in mixed powder；The step
In rapid c, manufactured nearly spherical shape diameter of solid sphere is 6mm；
The preparation method of environment-friendly type water purification bag provided in this embodiment is easy to operate, can carry out each raw material components uniform
Mixing, makes each component preferably carry out synergy, and modified luffa fibers are dispersed in mixed powder, can effectively be prevented
Only isolated with water-purifying material (i.e. mixture medicine ball) finished product made from suppression, while modified luffa fibers and its can also be made
He is cooperateed with component, preferably plays its suction-operated；The mixture diameter of solid sphere prepared is smaller, makes obtained water purification
Water-purifying material can occur more to contact with water in bag, so that reach more preferable purifying water effect, preparation through this embodiment
Method may finally prepare excellent performance, and stability is good, the good environment-friendly type water purification bag of purifying water effect.
In the present embodiment, it can be achieved to prepare water-purifying material packaging bag using bamboo charcoal fiber by the prior art, therefore herein
Repeat no more.
In the present embodiment, the raw material components used in water-purifying material can commercially be bought.
In the present embodiment, the equipment of use is conventional equipment, and as extruder grain can use screw extruder, drying can adopt
With drying box etc., therefore also repeat no more herein.
Environment-friendly type water purification bag made from the present embodiment when in use, the amount of the water that can be handled as needed and water quality it is specific
Situation, determines the usage amount of environment-friendly type water purification bag, so as to the treatment effect being optimal.
With reference to specific embodiment, the present invention is described further：
Embodiment one
Environment-friendly type water purification bag provided in this embodiment for water process, including water-purifying material packaging bag and it is arranged at water purification
Water-purifying material in material packaging bag；The water-purifying material packaging bag is made of bamboo charcoal fiber；The raw material of the water-purifying material is pressed
Parts by weight include following component：25 parts of palygorskite, 25 parts of diatomite, 15 parts of bentonite, 20 parts of vermiculite, modified luffa fibers 18
Part, 5 parts of bamboo scraps, 8 parts of charcoal powder；
Wherein, the preparation method of the modified luffa fibers includes the following steps：
(1) after luffa being cut into segment, it is torn into single sponge gourd silk；
(2) the sponge gourd silk of gained in step (1) is placed in the ammonium hydroxide that concentration is 5%, boils 3h at a temperature of 100 DEG C,
Then filter, collect sponge gourd silk and washed repeatedly with distilled water, untill to the last a cleaning solution is shown as neutrality；
(3) sponge gourd silk cleaned in step (2) is dried into 5h at 100 DEG C, is then cut into 1cm, that is, modified silk is made
Melon fiber.
In the present embodiment, for the preparation method of the environment-friendly type water purification bag of water process, include the following steps：
A, it is 400~500 purposes palygorskite, diatomite, bentonite, vermiculite, bamboo scraps and charcoal powder to be all ground into granularity
After powder, mixed powder is mixed to prepare；
B, modified luffa fibers are added in obtained mixed powder into step a, and stirring is mixing modified luffa fibers
It is uniformly dispersed in powder, then adds the suitable quantity of water for being enough to soak mixed powder and modified luffa fibers thereto, continue to stir 2h, make
Modified luffa fibers further disperse in mixed powder, refilter collection solid mixture；
C, the solid mixture of gained in step b is subjected to extruder grain, the nearly spherical shape that a diameter of 6mm is made is solid
Ball, is then dried, and the mixture medicine ball that moisture is not higher than 10% is made, and is water-purifying material；
D, the mixture medicine ball obtained by step c is placed in the water-purifying material packaging bag of bamboo charcoal fiber material, after envelope
The finished product of the environment-friendly type water purification bag for water process is made.
Embodiment two
Environment-friendly type water purification bag provided in this embodiment for water process, including water-purifying material packaging bag and it is arranged at water purification
Water-purifying material in material packaging bag；The water-purifying material packaging bag is made of bamboo charcoal fiber；The raw material of the water-purifying material is pressed
Parts by weight include following component：30 parts of palygorskite, 20 parts of diatomite, 10 parts of bentonite, 10 parts of vermiculite, modified luffa fibers 20
Part, 8 parts of bamboo scraps, 8 parts of charcoal powder；
Wherein, the preparation method of the modified luffa fibers includes the following steps：
(1) after luffa being cut into segment, it is torn into single sponge gourd silk；
(2) the sponge gourd silk of gained in step (1) is placed in the ammonium hydroxide that concentration is 12%, boils 2h at a temperature of 100 DEG C,
Then filter, collect sponge gourd silk and washed repeatedly with distilled water, untill to the last a cleaning solution is shown as neutrality；
(3) sponge gourd silk cleaned in step (2) is dried into 4h at 150 DEG C, is then cut into 1.5cm, that is, be made and be modified
Luffa fibers.
In the present embodiment, for the preparation method of the environment-friendly type water purification bag of water process, include the following steps：
A, it is 400~500 purposes palygorskite, diatomite, bentonite, vermiculite, bamboo scraps and charcoal powder to be all ground into granularity
After powder, mixed powder is mixed to prepare；
B, modified luffa fibers are added in obtained mixed powder into step a, and stirring is mixing modified luffa fibers
It is uniformly dispersed in powder, then adds the suitable quantity of water for being enough to soak mixed powder and modified luffa fibers thereto, continue to stir 2.5h,
Modified luffa fibers is further disperseed in mixed powder, refilter collection solid mixture；
C, the solid mixture of gained in step b is subjected to extruder grain, the nearly spherical shape that a diameter of 8mm is made is solid
Ball, is then dried, and the mixture medicine ball that moisture is not higher than 10% is made, and is water-purifying material；
D, the mixture medicine ball obtained by step c is placed in the water-purifying material packaging bag of bamboo charcoal fiber material, after envelope
The finished product of the environment-friendly type water purification bag for water process is made.
Embodiment three
Environment-friendly type water purification bag provided in this embodiment for water process, including water-purifying material packaging bag and it is arranged at water purification
Water-purifying material in material packaging bag；The water-purifying material packaging bag is made of bamboo charcoal fiber；The raw material of the water-purifying material is pressed
Parts by weight include following component：25 parts of palygorskite, 20 parts of diatomite, 10 parts of bentonite, 10 parts of vermiculite, modified luffa fibers 15
Part, 5 parts of bamboo scraps, 8 parts of charcoal powder；
Wherein, the preparation method of the modified luffa fibers includes the following steps：
(1) after luffa being cut into segment, it is torn into single sponge gourd silk；
(2) the sponge gourd silk of gained in step (1) is placed in the ammonium hydroxide that concentration is 10%, boils 3h at a temperature of 100 DEG C,
Then filter, collect sponge gourd silk and washed repeatedly with distilled water, untill to the last a cleaning solution is shown as neutrality；
(3) sponge gourd silk cleaned in step (2) is dried into 4.5h at 120 DEG C, is then cut into 1.2cm, that is, be made and change
Property luffa fibers.
In the present embodiment, for the preparation method of the environment-friendly type water purification bag of water process, include the following steps：
A, it is 400~500 purposes palygorskite, diatomite, bentonite, vermiculite, bamboo scraps and charcoal powder to be all ground into granularity
After powder, mixed powder is mixed to prepare；
B, modified luffa fibers are added in obtained mixed powder into step a, and stirring is mixing modified luffa fibers
It is uniformly dispersed in powder, then adds the suitable quantity of water for being enough to soak mixed powder and modified luffa fibers thereto, continue to stir 1.5h,
Modified luffa fibers is further disperseed in mixed powder, refilter collection solid mixture；
C, the solid mixture of gained in step b is subjected to extruder grain, the nearly spherical shape that a diameter of 5mm is made is solid
Ball, is then dried, and the mixture medicine ball that moisture is not higher than 10% is made, and is water-purifying material；
D, the mixture medicine ball obtained by step c is placed in the water-purifying material packaging bag of bamboo charcoal fiber material, after envelope
The finished product of the environment-friendly type water purification bag for water process is made.
Example IV
Environment-friendly type water purification bag provided in this embodiment for water process, including water-purifying material packaging bag and it is arranged at water purification
Water-purifying material in material packaging bag；The water-purifying material packaging bag is made of bamboo charcoal fiber；The raw material of the water-purifying material is pressed
Parts by weight include following component：30 parts of palygorskite, 25 parts of diatomite, 15 parts of bentonite, 20 parts of vermiculite, modified luffa fibers 20
Part, 8 parts of bamboo scraps, 10 parts of charcoal powder；
Wherein, the preparation method of the modified luffa fibers includes the following steps：
(1) after luffa being cut into segment, it is torn into single sponge gourd silk；
(2) the sponge gourd silk of gained in step (1) is placed in the ammonium hydroxide that concentration is 12%, boils 4h at a temperature of 100 DEG C,
Then filter, collect sponge gourd silk and washed repeatedly with distilled water, untill to the last a cleaning solution is shown as neutrality；
(3) sponge gourd silk cleaned in step (2) is dried into 5h at 100 DEG C, is then cut into 1cm, that is, modified silk is made
Melon fiber.
In the present embodiment, for the preparation method of the environment-friendly type water purification bag of water process, include the following steps：
A, it is 400~500 purposes palygorskite, diatomite, bentonite, vermiculite, bamboo scraps and charcoal powder to be all ground into granularity
After powder, mixed powder is mixed to prepare；
B, modified luffa fibers are added in obtained mixed powder into step a, and stirring is mixing modified luffa fibers
It is uniformly dispersed in powder, then adds the suitable quantity of water for being enough to soak mixed powder and modified luffa fibers thereto, continue to stir 2.5h,
Modified luffa fibers is further disperseed in mixed powder, refilter collection solid mixture；
C, the solid mixture of gained in step b is subjected to extruder grain, the nearly spherical shape that a diameter of 6mm is made is solid
Ball, is then dried, and the mixture medicine ball that moisture is not higher than 10% is made, and is water-purifying material；
D, the mixture medicine ball obtained by step c is placed in the water-purifying material packaging bag of bamboo charcoal fiber material, after envelope
The finished product of the environment-friendly type water purification bag for water process is made.
Embodiment five
Environment-friendly type water purification bag provided in this embodiment for water process, including water-purifying material packaging bag and it is arranged at water purification
Water-purifying material in material packaging bag；The water-purifying material packaging bag is made of bamboo charcoal fiber；The raw material of the water-purifying material is pressed
Parts by weight include following component：27 parts of palygorskite, 23 parts of diatomite, 12 parts of bentonite, 15 parts of vermiculite, modified luffa fibers 18
Part, 6 parts of bamboo scraps, 9 parts of charcoal powder；
Wherein, the preparation method of the modified luffa fibers includes the following steps：
(1) after luffa being cut into segment, it is torn into single sponge gourd silk；
(2) the sponge gourd silk of gained in step (1) is placed in the ammonium hydroxide that concentration is 5%, boils 4h at a temperature of 100 DEG C,
Then filter, collect sponge gourd silk and washed repeatedly with distilled water, untill to the last a cleaning solution is shown as neutrality；
(3) sponge gourd silk cleaned in step (2) is dried into 4h at 150 DEG C, is then cut into 1cm, that is, modified silk is made
Melon fiber.
In the present embodiment, for the preparation method of the environment-friendly type water purification bag of water process, include the following steps：
A, it is 400~500 purposes palygorskite, diatomite, bentonite, vermiculite, bamboo scraps and charcoal powder to be all ground into granularity
After powder, mixed powder is mixed to prepare；
B, modified luffa fibers are added in obtained mixed powder into step a, and stirring is mixing modified luffa fibers
It is uniformly dispersed in powder, then adds the suitable quantity of water for being enough to soak mixed powder and modified luffa fibers thereto, continue to stir 1.5h,
Modified luffa fibers is further disperseed in mixed powder, refilter collection solid mixture；
C, the solid mixture of gained in step b is subjected to extruder grain, the nearly spherical shape that a diameter of 5mm is made is solid
Ball, is then dried, and the mixture medicine ball that moisture is not higher than 10% is made, and is water-purifying material；
D, the mixture medicine ball obtained by step c is placed in the water-purifying material packaging bag of bamboo charcoal fiber material, after envelope
The finished product of the environment-friendly type water purification bag for water process is made.
Embodiment six
Environment-friendly type water purification bag provided in this embodiment for water process, including water-purifying material packaging bag and it is arranged at water purification
Water-purifying material in material packaging bag；The water-purifying material packaging bag is made of bamboo charcoal fiber；The raw material of the water-purifying material is pressed
Parts by weight include following component：30 parts of palygorskite, 25 parts of diatomite, 10 parts of bentonite, 10 parts of vermiculite, modified luffa fibers 20
Part, 7 parts of bamboo scraps, 8 parts of charcoal powder；
Wherein, the preparation method of the modified luffa fibers includes the following steps：
(1) after luffa being cut into segment, it is torn into single sponge gourd silk；
(2) the sponge gourd silk of gained in step (1) is placed in the ammonium hydroxide that concentration is 10%, boils 3h at a temperature of 100 DEG C,
Then filter, collect sponge gourd silk and washed repeatedly with distilled water, untill to the last a cleaning solution is shown as neutrality；
(3) sponge gourd silk cleaned in step (2) is dried into 4h at 120 DEG C, is then cut into 1.2cm, that is, be made and be modified
Luffa fibers.
In the present embodiment, for the preparation method of the environment-friendly type water purification bag of water process, include the following steps：
A, it is 400~500 purposes palygorskite, diatomite, bentonite, vermiculite, bamboo scraps and charcoal powder to be all ground into granularity
After powder, mixed powder is mixed to prepare；
B, modified luffa fibers are added in obtained mixed powder into step a, and stirring is mixing modified luffa fibers
It is uniformly dispersed in powder, then adds the suitable quantity of water for being enough to soak mixed powder and modified luffa fibers thereto, continue to stir 2.5h,
Modified luffa fibers is further disperseed in mixed powder, refilter collection solid mixture；
C, the solid mixture of gained in step b is subjected to extruder grain, the nearly spherical shape that a diameter of 5mm is made is solid
Ball, is then dried, and the mixture medicine ball that moisture is not higher than 10% is made, and is water-purifying material；
D, the mixture medicine ball obtained by step c is placed in the water-purifying material packaging bag of bamboo charcoal fiber material, after envelope
The finished product of the environment-friendly type water purification bag for water process is made.
Water purification bag made from embodiment one to embodiment six is used to carry out Industrial Waste Water Treatments, using each weight as 0.5g
Water purification bag is made, 4 water purification bags, stir process 12h are placed in every cubic meter of water；
The water quality situation of contrast before and after the processing, draws following form：
Table 1
As seen from the above table, the water purification bag prepared using above-described embodiment being capable of most of organic matter in Adsorption water, again
Metallic element and pigment, have good purifying water effect, can reduce COD, can adsorb or make suspended substance sedimentation,
Improve water quality.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail in good embodiment, it will be understood by those of ordinary skill in the art that, can be to the skill of the present invention
Art scheme technical scheme is modified or replaced equivalently, without departing from the objective and scope of technical solution of the present invention, it should all cover at this
Among the right of invention.
Claims (5)
- A kind of 1. environment-friendly type water purification bag for water process, it is characterised in that：By water-purifying material packaging bag and it is arranged at water purification material Expect the water-purifying material composition in packaging bag；The water-purifying material packaging bag is made of bamboo charcoal fiber；The raw material of the water-purifying material is made of following component by weight：The preparation method of the modified luffa fibers includes the following steps：(1) after luffa being cut into segment, it is torn into single sponge gourd silk；(2) the sponge gourd silk of gained in step (1) is placed in the ammonium hydroxide that concentration is 5~12%, boil 2 at a temperature of 100 DEG C~ 4h, is then filtered, and is collected sponge gourd silk and is washed repeatedly with distilled water, untill to the last a cleaning solution is shown as neutrality；(3) sponge gourd silk cleaned in step (2) is dried into 4~5h at 100~150 DEG C, is then cut into 1~1.5cm, that is, makes Luffa fibers must be modified.
- 2. the environment-friendly type water purification bag according to claim 1 for water process, it is characterised in that：The original of the water-purifying material Material is made of following component by weight：
- 3. according to the environment-friendly type water purification bag for water process described in claim 1, it is characterised in that：In the step (2), The concentration of ammonium hydroxide is 10%, and the time boiled is 3h；In the step (3), sponge gourd silk is dried into 4.5h at 120 DEG C, is then cut into 1.2cm, that is, modified luffa fibers are made.
- A kind of 4. preparation method of the environment-friendly type water purification bag for water process described in claim 1, it is characterised in that：Including such as Lower step：A, it is 400~500 mesh powders palygorskite, diatomite, bentonite, vermiculite, bamboo scraps and charcoal powder to be all ground into granularity Afterwards, it is mixed to prepare mixed powder；B, modified luffa fibers are added in obtained mixed powder into step a, and stirring makes modified luffa fibers in mixed powder Be uniformly dispersed, then add the suitable quantity of water for being enough to soak mixed powder and modified luffa fibers thereto, continue stirring 1.5~ 2.5h, makes modified luffa fibers further disperse in mixed powder, refilters collection solid mixture；C, the solid mixture of gained in step b is subjected to extruder grain, the nearly spherical shape medicine ball of a diameter of 5~8mm is made, Then dried, the mixture medicine ball that moisture is not higher than 10% is made, be water-purifying material；D, the mixture medicine ball obtained by step c is placed in the water-purifying material packaging bag of bamboo charcoal fiber material, after envelope, that is, made It must be used for the finished product of the environment-friendly type water purification bag of water process.
- 5. the preparation method of the environment-friendly type water purification bag according to claim 4 for water process, it is characterised in that：The step In rapid b, continue to stir 2h, modified luffa fibers is further disperseed in mixed powder；In the step c, manufactured nearly ball Shape diameter of solid sphere is 6mm.
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| CN108083376B (en) * | 2017-12-25 | 2020-10-20 | 芜湖皖江知识产权运营中心有限公司 | Sewage treatment agent and preparation method thereof |
| CN108545798A (en) * | 2018-04-27 | 2018-09-18 | 苏州科技大学 | Water treatment agent of high-efficiency environment friendly and preparation method thereof |
| CN108675364A (en) * | 2018-05-23 | 2018-10-19 | 重庆工程职业技术学院 | Industrial Waste Water Treatments water purification packet and preparation method thereof |
| CN113244894B (en) * | 2021-05-13 | 2023-03-17 | 重庆南科环工环保科技有限公司 | Preparation method and application of composite water treatment agent |
| CN113321527A (en) * | 2021-06-30 | 2021-08-31 | 陈宁 | Novel composite ceramic and manufacturing method thereof |
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