CN107240448A - A kind of aluminium alloy flexible cable for power equipment - Google Patents

A kind of aluminium alloy flexible cable for power equipment Download PDF

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Publication number
CN107240448A
CN107240448A CN201710614872.0A CN201710614872A CN107240448A CN 107240448 A CN107240448 A CN 107240448A CN 201710614872 A CN201710614872 A CN 201710614872A CN 107240448 A CN107240448 A CN 107240448A
Authority
CN
China
Prior art keywords
aluminium alloy
alloy flexible
flexible cable
layer
cable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710614872.0A
Other languages
Chinese (zh)
Inventor
邵晓东
管莉
刘继婷
刘冬
孙涵
张永超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linyi Beyond Power Construction Co Ltd
State Grid Corp of China SGCC
Linyi Power Supply Co of State Grid Shandong Electric Power Co Ltd
Original Assignee
Linyi Beyond Power Construction Co Ltd
State Grid Corp of China SGCC
Linyi Power Supply Co of State Grid Shandong Electric Power Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linyi Beyond Power Construction Co Ltd, State Grid Corp of China SGCC, Linyi Power Supply Co of State Grid Shandong Electric Power Co Ltd filed Critical Linyi Beyond Power Construction Co Ltd
Priority to CN201710614872.0A priority Critical patent/CN107240448A/en
Publication of CN107240448A publication Critical patent/CN107240448A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/04Flexible cables, conductors, or cords, e.g. trailing cables
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/2806Protection against damage caused by corrosion
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/42Insulated conductors or cables characterised by their form with arrangements for heat dissipation or conduction
    • H01B7/428Heat conduction
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00Power cables
    • H01B9/02Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
    • H01B9/024Power cables with screens or conductive layers, e.g. for avoiding large potential gradients composed of braided metal wire

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  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention belongs to field of cable technology, a kind of aluminium alloy flexible cable for power equipment is disclosed, from inside to outside including conductor, fireprotection layer, screen layer, heat transfer filler layer, and cable insulation;The conductor uses aluminium alloy flexible conductor;The fireprotection layer is mica belt;The screen layer is tinned copper wire woven shield.Aluminium alloy flexible cable flexility of the present invention is good, acid-alkali-corrosive-resisting, and anti-aging high-temperature resistance is strong, has a extensive future.

Description

A kind of aluminium alloy flexible cable for power equipment
Technical field
The invention belongs to field of electrical equipment, and in particular to a kind of aluminium alloy flexible cable for power equipment.
Background technology
Cable is the important component in distribution system, recently as production and living electric wire utilization day increasingly Exhibition and popularize, quickly, and with expanding economy, the requirement to its material is also increasingly for amount increase the need for electric wire Height, it requires the performances such as soft, wear-resisting, corrosion-resistant and high-low temperature resistant.Aluminium alloy conductor is the conductor material commonly used in cable.
The power outputs such as modern heavy construction equipment, high-tension electricity equipment increase increasingly, the electric wire fed for the kind equipment Cable voltage class and the cross-section of cable also increase therewith, and the equipment fed by midium voltage cable distribution increases increasingly.Particularly case Formula transformer, switch cubicle, high voltage converter etc., because device interior wiring space is with respect to relatively narrower, laying, installs, use Middle cable is in smaller case of bending, and the rigid screen resilience that the bending of cable is produced causes laying installation extremely difficult, and mistake Insulating barrier internal mechanical stresses caused by degree bending easily cause cable breakdown.Solve wiring space inside power equipment narrow Small, it is difficult to laying installation, the problem for the failure risk that cable bend state is produced need to be reduced by improving cable bend performance The rigid screen resilience produced during bending, and improve the electrical performance of cable insulation bend tension state, therefore it is contemplated that Overcome the deficiencies in the prior art, develop a kind of aluminium alloy flexible cable for power equipment, solve above technical barrier.
The content of the invention
The purpose of the present invention is to overcome the defect of above-mentioned prior art there is provided a kind of aluminium alloy for power equipment is soft Cable.
The present invention is achieved by the following technical solution:
A kind of aluminium alloy flexible cable for power equipment, from inside to outside including conductor 1, fireprotection layer 2, screen layer 3, heat transfer is filled out Fill nitride layer 4, and cable insulation 5;
Further, the conductor 1 uses aluminium alloy flexible conductor;
Further, the fireprotection layer 2 is mica belt;
Further, the screen layer 3 is tinned copper wire woven shield;
Further, the heat transfer filler layer 4 by silicone grease and aluminium nitride according to 3:1 mass ratio, which is mixed, to be made;
Further, the cable insulation 5 is prepared according to following technique:
Nanometer silicon carbide is put into the polyvinylpyrrolidone of equal quality, 300rpm stirring 5min are subsequently placed in damp and hot 6 hours in environment, modified Nano carborundum is obtained;
By acrylic resin, bisphenol f type epoxy resin, phenolic resin, white carbon, phthalic anhydride, polytetrafluoroethylene (PTFE), poly- carbon Acid esters and modified Nano carborundum are according to 200-300:70-120:30-50:10-15:3-5:5-7:15-20:7-12 quality Than well mixed, banbury is added, mixing time is 5min, and mixing temperature is 90 DEG C, obtains major ingredient;
By major ingredient, magnesium stearate, cerous hypophosphate and molybdenum disulfide according to 200-300:2-3:3-5:2-3 mass ratio is thrown successively Enter into centrifuge, after being well mixed, molten condition, Ran Houjing are squeezed into double screw extruder by 500rpm stirring 10min After forming machine pulls out product, by cutting machine fixed length cutting, pipe-expanding machine is sent into, is produced after the completion of enlarging.
In the present invention, research foothold and beneficial effect mainly include the following aspects:
Conductive filler nitride layer of the present invention is made using silicone grease and aluminium nitride blend, good heat conductivity;Silicone grease is synthesized by refining Oily thick inorganic thickening agent based on oil, and refine and form added with structural stabilizing agent, anticorrosive additive, with good waterproof Sealing, waterproof, solvent resistance and creep resistance energy, do not corrode metal;Have the disadvantage that material is softer, make under long term high temperature state With having dissociant precipitation in heat-conducting cream, processability is poor.Aluminium nitride powder thermal conductivity is good, and thermal coefficient of expansion is small, is good Heat shock resistance material, said two devices are used cooperatively, and possess preferable heat conductivility;
Cable insulation outer layer needs intensity high, high pressure resistant, fire-retardant fireproof and flexible, phenolic resin and gather that the present invention is selected Allyl resin, resistance to elevated temperatures is preferable, especially phenolic resin, even if the globality that can also keep its structure at high temperature and surely It is qualitative;
Cerous hypophosphate maintains the stability of material, enhances the fire resistance property of material, fire-retardant using halogen-free expansion fire retardant Performance is higher.Polytetrafluoroethylene (PTFE) has self-extinguishment, once ignition of cable, can prevent flame spread.Anti-wear agent is molybdenum disulfide, Considerably increase the abrasion resistance of overcoat;Above-mentioned material not only greatly strengthen fireproof flame-retardant effect, and Stability Analysis of Structures, be difficult Aoxidize and wear-resisting, service life is long;
Nanometer silicon carbide is the inorganic non-metallic material of excellent performance, and it has specific surface area big, and superficial attractive forces are strong, and chemistry is pure The special performance such as degree is high, dispersive property is good, with its superior stability, reinforcing, thickening property and thixotropy, the present invention is led to Cross and processing is modified to nanometer silicon carbide, it is evenly spread in organic material skeleton, tissue same performance is good, is distributed in In the skeleton of material, mechanical strength is improved, and do not interfere with flexility;Magnesium stearate can strengthen heat endurance, prevent Decompose oxidation.
The thermoplastic polyester that the present invention is readily able to deformation is changed into the thermosetting height with high resiliency, higher toughness Molecularly Imprinted Polymer;Compared with Halogen crosslinking polyolefin insulated cable, cable insulation is more soft, and flexible, disclosure satisfy that High pressure resistant and fire resistance is provided simultaneously with use, bear the requirement of overbending in narrow and small environment in cable.
Brief description of the drawings
Fig. 1 is the structural representation of cable of the present invention;
In Fig. 1:1- conductors, 2- fireprotection layers, 3- screen layers, 4- heat transfer filler layers, 5- cable insulations.
Embodiment
In order that those skilled in the art more fully understand the technical scheme in the application, have below in conjunction with the application Body embodiment, is more clearly and completely described, it is clear that described embodiment is only the application one to the present invention Divide embodiment, rather than whole embodiments.Based on the embodiment in the application, those of ordinary skill in the art are not making The every other embodiment obtained under the premise of creative work, should all belong to the scope of protection of the invention.
Embodiment 1
As shown in figure 1, a kind of aluminium alloy flexible cable for power equipment, from inside to outside including conductor 1, fireprotection layer 2, screen layer 3, heat transfer filler layer 4, and cable insulation 5;
The conductor 1 uses aluminium alloy flexible conductor;
The fireprotection layer 2 is mica belt;
The screen layer 3 is tinned copper wire woven shield;
The heat transfer filler layer 4 is by silicone grease and aluminium nitride according to 3:1 mass ratio, which is mixed, to be made;
The cable insulation 5 is prepared according to following technique:
Nanometer silicon carbide is put into the polyvinylpyrrolidone of equal quality, 300rpm stirring 5min are subsequently placed in damp and hot 6 hours in environment, modified Nano carborundum is obtained;
By acrylic resin, bisphenol f type epoxy resin, phenolic resin, white carbon, phthalic anhydride, polytetrafluoroethylene (PTFE), poly- carbon Acid esters and modified Nano carborundum are according to 200:70:30:10:3:5:15:7 mass ratio is well mixed, and adds banbury, close The refining time is 5min, and mixing temperature is 90 DEG C, obtains major ingredient;
By major ingredient, magnesium stearate, cerous hypophosphate and molybdenum disulfide according to 200:2:3:2 mass ratio puts into centrifuge successively In, after being well mixed, molten condition is squeezed into double screw extruder, then will be produced through forming machine by 500rpm stirring 10min After product are pulled out, by cutting machine fixed length cutting, pipe-expanding machine is sent into, is produced after the completion of enlarging.
Embodiment 2
As shown in figure 1, a kind of aluminium alloy flexible cable for power equipment, from inside to outside including conductor 1, fireprotection layer 2, screen layer 3, heat transfer filler layer 4, and cable insulation 5;
The conductor 1 uses aluminium alloy flexible conductor;
The fireprotection layer 2 is mica belt;
The screen layer 3 is tinned copper wire woven shield;
The heat transfer filler layer 4 is by silicone grease and aluminium nitride according to 3:1 mass ratio, which is mixed, to be made;
The cable insulation 5 is prepared according to following technique:
Nanometer silicon carbide is put into the polyvinylpyrrolidone of equal quality, 300rpm stirring 5min are subsequently placed in damp and hot 6 hours in environment, modified Nano carborundum is obtained;
By acrylic resin, bisphenol f type epoxy resin, phenolic resin, white carbon, phthalic anhydride, polytetrafluoroethylene (PTFE), poly- carbon Acid esters and modified Nano carborundum are according to 300:120:50:15:5:7:20:12 mass ratio is well mixed, and adds banbury, Mixing time is 5min, and mixing temperature is 90 DEG C, obtains major ingredient;
By major ingredient, magnesium stearate, cerous hypophosphate and molybdenum disulfide according to 300:3:5:3 mass ratio puts into centrifuge successively In, after being well mixed, molten condition is squeezed into double screw extruder, then will be produced through forming machine by 500rpm stirring 10min After product are pulled out, by cutting machine fixed length cutting, pipe-expanding machine is sent into, is produced after the completion of enlarging.
Embodiment 3
The performance test of cable insulation layer material of the present invention, by taking embodiment 1 as an example, with conventional Halogen cross-linked polyolefin insulated electro As a control group, specific test result is shown in Table 1 to cable:
Table 1
Project Unit Control group Embodiment 1
Shore hardness HA 70 57
Modulus of elasticity(Surely 100% is stretched) MPa 0.7 1.9
Tensile strength MPa 12.3 11.7
Elongation at break % 205 601
Tensile strength change after 135 DEG C/168h heat ageings % +7.3 +2.1
Elongation at break rate of change after 135 DEG C/168h heat ageings % -10.4 -5.2
Specific insulation ×10-15(Ω•cm) 1.08 3.07
Insulation puncture test(4D case of bendings) KV 45 84
Pressure test(23KV/5min) It can not puncture It can not puncture
Conclusion:Cable insulation layer material flexility of the present invention is good, and anti-aging high-temperature resistance is strong, and possesses preferable resistance to height Performance is pressed, better than conventional Halogen cross-linked polyolefin insulating outer layer material.
Embodiment 4
Acid-alkali-corrosive-resisting performance test:
1st, test material is dipped into 10wt% sulfuric acid solution 30 days, by taking embodiment 2 as an example, gathered with conventional Halogen crosslinking As a control group, each Specifeca tion speeification is determined alkene insulated cable, is shown in Table 2:
Table 2
Group Specific insulation conservation rate(%) Modulus of elasticity conservation rate(%) Tensile strength retention(%) Hardness conservation rate(%)
Embodiment 2 98.1 96.6 95.4 105.7
Control group 91.3 89.4 90.2 104.1
2nd, test material is dipped into 6wt% sodium hydroxide solution 30 days, by taking embodiment 2 as an example, be crosslinked with conventional Halogen As a control group, each Specifeca tion speeification is determined polyolefine insulated cable, is shown in Table 3:
Table 3
Group Specific insulation conservation rate(%) Modulus of elasticity conservation rate(%) Tensile strength retention(%) Hardness conservation rate(%)
Embodiment 2 95.8 97.1 95.3 104.7
Control group 91.5 84.7 92.6 103.2
Conclusion:Cable of the present invention being capable of effectively acid-alkali-corrosive-resisting, and can keep preferable mechanical performance and insulating properties Can etc., better than general cable product.
Above in association with specific embodiment, invention has been described, it will be appreciated by those skilled in the art that these are retouched It is all exemplary to state, and is not limiting the scope of the invention.Those skilled in the art can be according to essence of the invention God and principle make various variants and modifications to the present invention, and these variants and modifications are also within the scope of the invention.

Claims (6)

1. a kind of aluminium alloy flexible cable for power equipment, from inside to outside including conductor 1, fireprotection layer 2, screen layer 3, heat transfer Filler layer 4, and cable insulation 5.
2. aluminium alloy flexible cable according to claim 1, it is characterised in that the conductor 1 uses aluminium alloy flexible conductor.
3. aluminium alloy flexible cable according to claim 1, it is characterised in that the fireprotection layer 2 is mica belt.
4. aluminium alloy flexible cable according to claim 1, it is characterised in that the screen layer 3 is that tinned copper wire weaves screen Cover layer.
5. aluminium alloy flexible cable according to claim 1, it is characterised in that the heat transfer filler layer 4 by silicone grease and Aluminium nitride is according to 3:1 mass ratio, which is mixed, to be made.
6. aluminium alloy flexible cable according to claim 1, it is characterised in that the cable insulation 5 is according to following technique It is prepared:
1)Nanometer silicon carbide is put into the polyvinylpyrrolidone of equal quality, 300rpm stirring 5min are subsequently placed in wet 6 hours in thermal environment, modified Nano carborundum is obtained;
2)By acrylic resin, bisphenol f type epoxy resin, phenolic resin, white carbon, phthalic anhydride, polytetrafluoroethylene (PTFE), poly- Carbonic ester and modified Nano carborundum are according to 200-300:70-120:30-50:10-15:3-5:5-7:15-20:7-12 matter Amount adds banbury, mixing time is 5min than well mixed, and mixing temperature is 90 DEG C, obtains major ingredient;
3)By major ingredient, magnesium stearate, cerous hypophosphate and molybdenum disulfide according to 200-300:2-3:3-5:2-3 mass ratio is successively Put into centrifuge, 500rpm stirring 10min after being well mixed, are squeezed into molten condition, then into double screw extruder After product is pulled out through forming machine, by cutting machine fixed length cutting, pipe-expanding machine is sent into, is produced after the completion of enlarging.
CN201710614872.0A 2017-07-26 2017-07-26 A kind of aluminium alloy flexible cable for power equipment Pending CN107240448A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710614872.0A CN107240448A (en) 2017-07-26 2017-07-26 A kind of aluminium alloy flexible cable for power equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710614872.0A CN107240448A (en) 2017-07-26 2017-07-26 A kind of aluminium alloy flexible cable for power equipment

Publications (1)

Publication Number Publication Date
CN107240448A true CN107240448A (en) 2017-10-10

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CN201710614872.0A Pending CN107240448A (en) 2017-07-26 2017-07-26 A kind of aluminium alloy flexible cable for power equipment

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1534690A (en) * 2003-04-02 2004-10-06 珠海粤科清华电子陶瓷有限公司 High heat conducting insulating silicon grease and its manufacturing method
CN105778300A (en) * 2016-03-16 2016-07-20 国网山东省电力公司费县供电公司 Underground power cable sheath tube
US20160260524A1 (en) * 2015-03-03 2016-09-08 General Cable Technologies Corporation Cables formed from halogen-free compositions having fire retardant properties
CN105957631A (en) * 2016-06-30 2016-09-21 安徽埃克森科技集团有限公司 Flexible cable and preparation method therefor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1534690A (en) * 2003-04-02 2004-10-06 珠海粤科清华电子陶瓷有限公司 High heat conducting insulating silicon grease and its manufacturing method
US20160260524A1 (en) * 2015-03-03 2016-09-08 General Cable Technologies Corporation Cables formed from halogen-free compositions having fire retardant properties
CN105778300A (en) * 2016-03-16 2016-07-20 国网山东省电力公司费县供电公司 Underground power cable sheath tube
CN105957631A (en) * 2016-06-30 2016-09-21 安徽埃克森科技集团有限公司 Flexible cable and preparation method therefor

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Application publication date: 20171010