CN1072390A - Safe oxygen producing agent (solid oxygen) - Google Patents

Safe oxygen producing agent (solid oxygen) Download PDF

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Publication number
CN1072390A
CN1072390A CN 92114505 CN92114505A CN1072390A CN 1072390 A CN1072390 A CN 1072390A CN 92114505 CN92114505 CN 92114505 CN 92114505 A CN92114505 A CN 92114505A CN 1072390 A CN1072390 A CN 1072390A
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CN
China
Prior art keywords
oxygen
manganse dioxide
loaded
kaolin
active carbon
Prior art date
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Granted
Application number
CN 92114505
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Chinese (zh)
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CN1032128C (en
Inventor
龚承元
苏建勇
朱孟府
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Institute of Medical Equipment Chinese Academy of Military Medical Sciences
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Institute of Medical Equipment Chinese Academy of Military Medical Sciences
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Application filed by Institute of Medical Equipment Chinese Academy of Military Medical Sciences filed Critical Institute of Medical Equipment Chinese Academy of Military Medical Sciences
Priority to CN 92114505 priority Critical patent/CN1032128C/en
Publication of CN1072390A publication Critical patent/CN1072390A/en
Application granted granted Critical
Publication of CN1032128C publication Critical patent/CN1032128C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

Safety oxygen producing agent of the present invention (solid oxygen) belongs to the medical oxygen technical field, particularly adopts SPC-D to make reagent, and under the effect of catalyzer, the oxygenous prescription of decomposition reaction takes place Yu Shuizhong.The present invention development by Manganse Dioxide, kaolin and be loaded with composite catalyst that the granulated active carbon of Manganse Dioxide forms and produce in the oxygen process at chemistry and controlled speed of response preferably, and it is steady to produce oxygen speed, oxygen and oxygen purity meet the state-promulgated pharmacopoeia regulation.Prove that through clinical use three kinds of compositions of this composite catalyst mix use, produce oxygen evenly, add conveniently, the user grasps easily.

Description

Safe oxygen producing agent (solid oxygen)
The invention belongs to the medical oxygen technical field, particularly adopt SPC-D to make reagent, the oxygenous prescription of decomposition reaction takes place in water under the effect of catalyzer.
Before the present invention, the method for existing several chemical oxygen generations.The key problem in technology of chemical oxygen generation is to adopt the appropriate means controls reaction speed, produces oxygen speed more uniformly in the hope of obtaining, and when satisfying the use needs, improves the utilization ratio of oxygen.USP4,548,730 provide a kind of method that adds the salt hydrate (as subsulphate, thiosulphate and hydrophosphate etc.) with heat absorption capacity in reactant to come the conditioned reaction liquid temp, to reach the purpose of controls reaction speed.Its shortcoming is that drug dosage is big, and the cost height if the oxygen producing agent SPC-D is packed with heat-sink material, also may influence the stability of oxygen producing agent.The decomposition reaction that WO86/02063 provides a kind of method that adds Sodium peroxoborate in SPC-D to slow down oxygen producing agent, controls reaction speed prevents to react strong.Because the decomposition temperature of Sodium peroxoborate is higher, when therefore using at a lower temperature, the speed of response in later stage is slow excessively, so that not thorough at the oxygen time that the puts internal reaction of expection.EP0093938 provides a kind of and catalyzer (as Manganse Dioxide etc.) is made the water-soluble slow-releasing particle with different release rate has regulated the speed of producing oxygen and putting oxygen, makes needed catalyzer after the particle of different release rate is mixed by a certain percentage.This granules of catalyst is with after water mixes, though can progressively discharge catalyzer by its original speed, the decomposition reaction that prevents oxygen producing agent is too fast, but along with discharging progressively increasing and the continuous rising of reacting liquid temperature of catalytic amount in the reaction solution, the speed of response in its later stage is still wayward.The manufacture craft more complicated of the granules of catalyst of this different release rate, the also corresponding raising of cost.In addition, CN86104506A adopts Sodium peroxoborate to make oxygen producing agent, and Manganse Dioxide is catalyzer, and potassium permanganate is accelerator, and water glass is a moderator.This method provides the medicine of three kinds of controls reaction speed, is decided according to different situations by the user to add which kind and add how many amounts, operate cumbersome, and, if grasp badly, cause a deviation easily.Invented a kind of new safe oxygen producing agent (solid oxygen) prescription for overcoming in the prior art with defective and deficiency.
The objective of the invention is: a kind of safe oxygen producing agent (solid oxygen) is provided, and by the composite catalyst formulating of recipe, the control chemistry produces the speed of response in the oxygen process, in the hope of reaching even product oxygen, when satisfying the use needs, improves the utilization ratio of oxygen.
Main points of the present invention are: a kind of safe oxygen producing agent (solid oxygen); it adopts SPC-D to make reagent; under the effect of catalyzer; decomposition reaction takes place and produces oxygen in Yu Shuizhong; oxygen level and oxygen purity meet the state-promulgated pharmacopoeia regulation; it is characterized in that used catalyzer is by Manganse Dioxide, kaolin and be loaded with the composite catalyst that the granulated active carbon of Manganse Dioxide is formed.
The safe oxygen producing agent (solid oxygen) that the present invention proposes is made up of A agent and B agent two portions, and the A agent is a SPC-D, and the B agent is by Manganse Dioxide, kaolin and is loaded with the composite catalyst that the granulated active carbon of Manganse Dioxide is formed.Controls reaction speed discharges oxygen with relative constant speed effectively.
Manganse Dioxide is made Powdered, increases surface in contact, strengthens katalysis, can improve initial product oxygen speed significantly, satisfies the needs of first aid, the also corresponding consumption that reduces Manganse Dioxide.Powdered Manganse Dioxide is suspended in reaction process in the reaction solution, helps the speed of response in mild later stage.The granularity of Manganse Dioxide is below 60 orders.
Pulverous kaolin has good dispersiveness in water, be evenly distributed in reaction in the middle of the mixture of SPC-D and Manganse Dioxide composition, also can play the effect of mild speed of response.Kaolinic granularity is below 60 orders.
Granulated active carbon makes the micropore surface of gac carry the superfine Manganse Dioxide of last layer, thereby has catalyst action by suitable chemical treatment (as handling till the absorption of granulated active carbon reaches capacity with potassium permanganate solution).Because activated carbon granule proportion is less; progressively rise to liquid level in the reaction process or be suspended in the reaction solution; thereby weakened its katalysis; help controls reaction speed; especially produce the oxygen later stage,, cause product oxygen too fast easily along with reacting liquid temperature raises; be loaded with the granulated active carbon rising liquid level of Manganse Dioxide, help mild speed of response.
In the composite catalyst, Manganse Dioxide, kaolin and be loaded with the uniform mixing such as granulated active carbon of Manganse Dioxide, three's ratio is 1: 0.5-2: 1-3
Specific embodiments of the invention are as follows:
Embodiment 1
1. A agent (reagent)
SPC-D (2Na 2CO 33H 2O 2) 60 kilograms
Be distributed into 1000 parts
2. B agent (composite catalyst)
Manganse Dioxide 400 grams
Kaolin 800 grams
Be loaded with granulated active carbon 400 grams of Manganse Dioxide
Be distributed into 1000 parts after the mixing
Inject about 15 ℃ clear water in existing oxygen generator, successively add 2 parts of B agent and 4 parts of A agent successively, build lid, the oxygen of generation will be emitted slowly, supplies to smoke behind the humidifying gas washing.The about 1.5/min of oxygen flow is about type discharge oxygen time 16min.
Embodiment 2
1. A agent (reagent)
SPC-D (2Na 2CO 33H 2O 2) 200 kilograms
Be distributed into 1000 parts
2. B agent (composite catalyst)
Manganse Dioxide 600 grams
Kaolin 800 grams
Be loaded with granulated active carbon 600 grams of Manganse Dioxide
Be distributed into 1000 parts after the mixing
Mix for adding 2 parts of A agent and 2 parts of B agent in the oxygen-generating bag existing, inject clear water then, sealing, the oxygen of birth supplies to smoke behind the humidifying gas washing.The about 3L/min of oxygen flow is about type discharge oxygen 15min.
Safe oxygen producing agent of the present invention (solid oxygen) catalyst system therefor is the composite catalyst that Manganse Dioxide, kaolin and the granulated active carbon that is loaded with Manganse Dioxide are formed.Controlled product oxygen speed of response preferably, produced oxygen speed steadily (seeing figure), produced oxygen level and oxygen purity and meet the state-promulgated pharmacopoeia regulation.Prove that through clinical use three kinds of composition parts of composite catalyst mix uses oxygen even, adds conveniently, the user grasps easily.

Claims (4)

1, a kind of safe oxygen producing agent (solid oxygen); it adopts SPC-D to make reagent; under the effect of catalyzer; decomposition reaction takes place and produces oxygen in Yu Shuizhong; oxygen level and oxygen purity meet the state-promulgated pharmacopoeia regulation; it is characterized in that used catalyzer is by Manganse Dioxide, kaolin and be loaded with the composite catalyst that the granulated active carbon of Manganse Dioxide is formed.
According to the described safe oxygen producing agent of claim 1, it is characterized in that 2, used Manganse Dioxide and kaolin are powdered, its granularity is below 60 orders.
According to claim 1,2 described safe oxygen producing agents, it is characterized in that 3, the used granulated active carbon that is loaded with Manganse Dioxide adopts chemical process, prepares as handling with potassium permanganate solution, the activated carbon capillary surface is loaded with superfine Manganse Dioxide particulate.
According to claim 1,2,3 described safe oxygen producing agents, it is characterized in that 4, used Manganse Dioxide, kaolin and the granulated active carbon that is loaded with Manganse Dioxide are uniform mixing, three's ratio is 1: 0.5-2: 1-3
CN 92114505 1992-12-18 1992-12-18 Safety oxygen producing agent (solid oxygen) Expired - Fee Related CN1032128C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 92114505 CN1032128C (en) 1992-12-18 1992-12-18 Safety oxygen producing agent (solid oxygen)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 92114505 CN1032128C (en) 1992-12-18 1992-12-18 Safety oxygen producing agent (solid oxygen)

Publications (2)

Publication Number Publication Date
CN1072390A true CN1072390A (en) 1993-05-26
CN1032128C CN1032128C (en) 1996-06-26

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Application Number Title Priority Date Filing Date
CN 92114505 Expired - Fee Related CN1032128C (en) 1992-12-18 1992-12-18 Safety oxygen producing agent (solid oxygen)

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CN (1) CN1032128C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100340628C (en) * 2002-11-08 2007-10-03 权东淳 Solid matter A, liquid matter B produced by using the A, liquid heating matter produced by using the B and method for producing the heating matter
CN103288055A (en) * 2013-06-24 2013-09-11 濮阳宏业汇龙化工有限公司 Rapid oxygen preparation agent combination and oxygen preparation method
CN111252738A (en) * 2020-01-21 2020-06-09 陕西斯达防爆安全科技股份有限公司 Oxygen candle medicine

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100340628C (en) * 2002-11-08 2007-10-03 权东淳 Solid matter A, liquid matter B produced by using the A, liquid heating matter produced by using the B and method for producing the heating matter
CN103288055A (en) * 2013-06-24 2013-09-11 濮阳宏业汇龙化工有限公司 Rapid oxygen preparation agent combination and oxygen preparation method
CN111252738A (en) * 2020-01-21 2020-06-09 陕西斯达防爆安全科技股份有限公司 Oxygen candle medicine

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