CN107236309B - A kind of hot investment casting wax-pattern material and preparation method thereof based on Fischer-Tropsch wax - Google Patents

A kind of hot investment casting wax-pattern material and preparation method thereof based on Fischer-Tropsch wax Download PDF

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CN107236309B
CN107236309B CN201610181463.1A CN201610181463A CN107236309B CN 107236309 B CN107236309 B CN 107236309B CN 201610181463 A CN201610181463 A CN 201610181463A CN 107236309 B CN107236309 B CN 107236309B
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wax
fischer
hot investment
investment casting
tropsch wax
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CN107236309A (en
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徐勇军
李柏鸿
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Dongguan University of Technology
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Dongguan University of Technology
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)

Abstract

The invention discloses a kind of hot investment casting wax-pattern material and preparation method thereof based on Fischer-Tropsch wax comprising basic component, the basic component are made of the raw material of following mass percent: paraffin: 10%~50%;Fischer-Tropsch wax: 5%~20%;Stearic acid: 10%~50%;Petropols: 5%~30%;Lignite wax: 0~10%.Preparation method are as follows: in a heated condition, various raw materials are mixed evenly into transparent liquid, formed after filtering.Hot investment casting wax softening point of the invention is moderate, and needle penetration is minimum, and linear shrinkage ratio is small, and bending strength is larger, and ash content is small, can be widely used for the wax pattern of preparation high precision aviation cast structure part and the wax pattern of other hot investment castings.

Description

A kind of hot investment casting wax-pattern material and preparation method thereof based on Fischer-Tropsch wax
Technical field
The present invention relates to a kind of hot investment casting wax-pattern material and preparation method thereof based on Fischer-Tropsch wax.
Background technique
Hot investment casting is otherwise known as precision-investment casting, it is a kind of metal forming process, by obtained by model casting Each casting be the result to cooperate jointly through working procedures, a variety of materials, many technologies.The general technology of model casting can It is divided into: the die mould that design is met the size requirements with manufacture;Meet the wax of various physicochemical properties by the manufacture of suitable die mould Mould;The several layers of refractory material in wax pattern surface repetitive coatings;Make wax material all from fire resisting by high-temperature steam and hot water dewaxing It is removed in material, forms ghost;Liquid metal is poured in ghost;It is finally cooling, shelling and casting cleaning.Wherein, high temperature The wax of removal can also be reused in the manufacture of wax-pattern.Due to the accurate size of casting obtained by this way, corner angle Clearly, surface is smooth, final form close to zero pendant, therefore also known as hot investment casting.
In certain special dimensions, such as many of aerospace industry field ultra-large type integral structure component, have in structure Many local thickness is larger, it is desirable that mould material shrinking percentage is small, good stability of the dimension, good fluidity, flexural strength are high, hardness Height, surface is smooth and there is wetability refractory material to be made to be easily adhered to model surface.Most of mould material is being made on the market It is often had the following problems when standby above-mentioned thick big monolithic devices fine structure part: 1) since the shrinking percentage at wax-pattern thick and solid position larger, It cannot obtain the model of exact scale;2) surface smoothness of wax-pattern is not high, wetability is bad, leads to refractory material mould obtained The inside of tool easily forms concave-convex, hollow surface.
Summary of the invention
The purpose of the present invention is to provide a kind of hot investment casting wax-pattern material and preparation method thereof based on Fischer-Tropsch wax.
The technical solution used in the present invention is:
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax comprising basic component, the basic component is by following matter Measure the raw material composition of percentage: paraffin: 10%~50%;Fischer-Tropsch wax: 5%~20%;Stearic acid: 10%~50%;Petropols: 5%~ 30%;Lignite wax: 0~10%.
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax comprising basic component, the basic component is by following matter Measure the raw material composition of percentage: paraffin: 28%~43%;Fischer-Tropsch wax: 7%~15%;Stearic acid: 25%~35%;Petropols: 15% ~28%;Lignite wax: 0~2%.
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, it is characterised in that: it includes basic component, and described basic group Divide and be made of the raw material of following mass percent: paraffin: 40%;Fischer-Tropsch wax: 12%;Stearic acid: 33%;Petropols: 15%.
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, it is characterised in that: it includes basic component, and described basic group Divide and be made of the raw material of following mass percent: paraffin: 43%;Fischer-Tropsch wax: 15%;Stearic acid: 27%;Petropols: 15%.
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, it is characterised in that: it includes basic component, and described basic group Divide and be made of the raw material of following mass percent: paraffin: 43%;Fischer-Tropsch wax: 10%;Stearic acid: 25%;Petropols: 20%;Lignite Wax: 2%.
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, it is characterised in that: it includes basic component, and described basic group Divide and be made of the raw material of following mass percent: paraffin: 28%;Fischer-Tropsch wax: 7%;Stearic acid: 35%;Petropols: 28%;Lignite Wax: 2%.
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, further includes the pigment for accounting for 0.3%~0.5wt% of basic component.
The melting point of paraffin wax is 55~60 DEG C.
The fusing point of the Fischer-Tropsch wax is 100~110 DEG C.
The stearic fusing point is 60~65 DEG C.
The fusing point of the lignite wax is 80~90 DEG C.
The softening point of the Petropols is 90~100 DEG C.
The preparation method of the above-mentioned hot investment casting wax-pattern material based on Fischer-Tropsch wax, step are as follows: in a heated condition, by various originals Transparent liquid is mixed evenly into material, forms after filtering.
The beneficial effects of the present invention are: hot investment casting wax softening point of the invention is moderate, needle penetration is minimum, linear shrinkage ratio Small, bending strength is larger, and ash content is small, can be widely used for the wax pattern for preparing high precision aviation cast structure part and other precisions The wax pattern of casting.
Specific embodiment
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax comprising basic component, the basic component is by following matter Measure the raw material composition of percentage: paraffin: 10%~50%;Fischer-Tropsch wax: 5%~20%;Stearic acid: 10%~50%;Petropols: 5%~ 30%;Lignite wax: 0~10%.
Preferably, a kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax comprising basic component, the basic component by The raw material of following mass percent forms: paraffin: 28%~43%;Fischer-Tropsch wax: 7%~15%;Stearic acid: 25%~35%;Petroleum tree Rouge: 15%~28%;Lignite wax: 0~2%.
Preferably, a kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, it is characterised in that: it includes basic component, described Basic component be made of the raw material of following mass percent: paraffin: 40%;Fischer-Tropsch wax: 12%;Stearic acid: 33%;Petropols: 15%。
Preferably, a kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, it is characterised in that: it includes basic component, described Basic component be made of the raw material of following mass percent: paraffin: 43%;Fischer-Tropsch wax: 15%;Stearic acid: 27%;Petropols: 15%。
Preferably, a kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, it is characterised in that: it includes basic component, described Basic component be made of the raw material of following mass percent: paraffin: 43%;Fischer-Tropsch wax: 10%;Stearic acid: 25%;Petropols: 20%;Lignite wax: 2%.
Preferably, a kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, it is characterised in that: it includes basic component, described Basic component be made of the raw material of following mass percent: paraffin: 28%;Fischer-Tropsch wax: 7%;Stearic acid: 35%;Petropols: 28%;Lignite wax: 2%.
Preferably, a kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, further includes accounting for 0.3%~0.5wt% of basic component Pigment.
Preferably, the melting point of paraffin wax is 55~60 DEG C.
Preferably, the fusing point of the Fischer-Tropsch wax is 100~110 DEG C.
Preferably, the stearic fusing point is 60~65 DEG C.
Preferably, the fusing point of the lignite wax is 80~90 DEG C.
Preferably, the softening point of the Petropols is 90~100 DEG C.
Preferably, the Petropols are the C5/C9 copolymerized petroleum resin of Puyang Kai Ruide Petropols Co., Ltd.
The preparation method of the above-mentioned hot investment casting wax-pattern material based on Fischer-Tropsch wax, step are as follows: in a heated condition, by various originals Transparent liquid is mixed evenly into material, forms after filtering.
The present invention will be further explained combined with specific embodiments below and explanation.
Embodiment 1:
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, is made of the raw material of following mass percent: paraffin: 40%;Fischer-Tropsch wax: 12%;Stearic acid: 33%;Petropols: 15%.
Embodiment 2:
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, is made of the raw material of following mass percent: paraffin: 43%;Fischer-Tropsch wax: 15%;Stearic acid: 27%;Petropols: 15%.
Embodiment 3:
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, is made of the raw material of following mass percent: paraffin: 43%;Fischer-Tropsch wax: 10%;Stearic acid: 25%;Petropols: 20%;Lignite wax: 2%.
Embodiment 4:
A kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, is made of the raw material of following mass percent: paraffin: 28%;Fischer-Tropsch wax: 7%;Stearic acid: 35%;Petropols: 28%;Lignite wax: 2%.
The hot investment casting wax-pattern material of Examples 1 to 4 the preparation method is as follows: each component is existed according to certain feeding sequence Transparent wax liquor is mixed evenly under the conditions of 130~150 DEG C of temperature, forms after filtering.
The performance test data of the hot investment casting wax-pattern material of 1 Examples 1 to 4 of table
Note: " preceding " represents the first time test data of mould material in table, and " rear " represents mould material and use the test data after 5 times.
Test method:
Softening point: GB/T4507-1984;
Needle penetration: GB/T14235.5-1993;
Linear shrinkage ratio: GB/T14235.4-1993;
Ash content: GB/T14235.3-1993.
As shown in Table 1: hot investment casting wax softening point of the invention is moderate, and needle penetration is minimum, and linear shrinkage ratio is small, bending strength Larger, ash content is small, can be widely used for the wax pattern of preparation high precision aviation cast structure part and the wax of other hot investment castings Model.Hot investment casting wax all data of the invention is good, can meet the needs of actual production well.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention, It should be equivalent substitute mode, be included within the scope of the present invention.

Claims (7)

1. a kind of hot investment casting wax-pattern material based on Fischer-Tropsch wax, it is characterised in that: it includes basic component, the basic component It is made of the raw material of following mass percent: paraffin: 28%~43%;Fischer-Tropsch wax: 7%~15%;Stearic acid: 25%~ 35%;Petropols: 15%~28%;Lignite wax: 0~2%;The melting point of paraffin wax is 55~60 DEG C;The Fischer-Tropsch wax Fusing point is 100~110 DEG C;The stearic fusing point is 60~65 DEG C;The fusing point of the lignite wax is 80~90 DEG C;The stone The softening point of oleoresin is 90~100 DEG C.
2. the hot investment casting wax-pattern material according to claim 1 based on Fischer-Tropsch wax, it is characterised in that: it includes basic group Point, the basic component is made of the raw material of following mass percent: paraffin: 40%;Fischer-Tropsch wax: 12%;Stearic acid: 33%;Petropols: 15%.
3. the hot investment casting wax-pattern material according to claim 1 based on Fischer-Tropsch wax, it is characterised in that: it includes basic group Point, the basic component is made of the raw material of following mass percent: paraffin: 43%;Fischer-Tropsch wax: 15%;Stearic acid: 27%;Petropols: 15%.
4. the hot investment casting wax-pattern material according to claim 1 based on Fischer-Tropsch wax, it is characterised in that: it includes basic group Point, the basic component is made of the raw material of following mass percent: paraffin: 43%;Fischer-Tropsch wax: 10%;Stearic acid: 25%;Petropols: 20%;Lignite wax: 2%.
5. the hot investment casting wax-pattern material according to claim 1 based on Fischer-Tropsch wax, it is characterised in that: it includes basic group Point, the basic component is made of the raw material of following mass percent: paraffin: 28%;Fischer-Tropsch wax: 7%;Stearic acid: 35%; Petropols: 28%;Lignite wax: 2%.
6. the hot investment casting wax-pattern material described according to claim 1~any one of 5 based on Fischer-Tropsch wax, it is characterised in that: It further include the pigment for accounting for 0.3%~0.5wt% of basic component.
7. the preparation method of the hot investment casting wax-pattern material described in any one of Claims 1 to 5 based on Fischer-Tropsch wax, feature It is: step are as follows: in a heated condition, various raw materials are mixed evenly into transparent liquid, formed after filtering.
CN201610181463.1A 2016-03-28 2016-03-28 A kind of hot investment casting wax-pattern material and preparation method thereof based on Fischer-Tropsch wax Active CN107236309B (en)

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CN107936582B (en) * 2017-10-19 2019-08-06 惠州市优恒科三维材料有限公司 A kind of 3D printing molding wax of high rigidity-toughness balanced and preparation method thereof
CN109438999B (en) * 2018-11-30 2021-05-07 广州市德馨蜡制品有限公司 Dental 3D printing wax material based on MJP technology and preparation method thereof
CN110358311A (en) * 2019-07-10 2019-10-22 南通亚泰蜡业工艺品有限公司 A kind of electric candle modified paraffin and preparation method thereof
CN111607238A (en) * 2020-07-03 2020-09-01 江苏法迩蜡业有限公司 Composite wax for PVC (polyvinyl chloride) stone-plastic floor and preparation method thereof

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