CN107217535A - A kind of antibacterial environmentally friendly paper and preparation method thereof - Google Patents
A kind of antibacterial environmentally friendly paper and preparation method thereof Download PDFInfo
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- CN107217535A CN107217535A CN201710526770.3A CN201710526770A CN107217535A CN 107217535 A CN107217535 A CN 107217535A CN 201710526770 A CN201710526770 A CN 201710526770A CN 107217535 A CN107217535 A CN 107217535A
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- paper
- environmentally friendly
- wood pulp
- leaf
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/30—Alginic acid or alginates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/47—Condensation polymers of aldehydes or ketones
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paper (AREA)
Abstract
The present invention relates to antibacterial environmentally friendly paper of one kind and preparation method thereof, the paper includes following raw materials：25 45 parts of wood composite slurry, 12 15 parts of alkyl ketene dimer, 15 20 parts of industrial filter paper, 6 10 parts of sodium alginate, 9 12 parts of methanol, 8 14 parts of palm oil, 10 15 parts of Lauxite, 6 11 parts of crystal whisker of gypsum, 37 parts of sorbierite：Manufacture craft of the present invention is simple, manufacturing process is environment friendly and pollution-free, obtained paper is environment-protecting and non-poisonous, and wood composite slurry is added with paper, so that the paper has less tear index and degree of holding, added with the antipathogenic composition such as palm oil and sorbierite so that the paper has fungistatic effect, it is harmless, and the crystal whisker of gypsum of addition can allow the paper to have preferable air permeability.
Description
Technical field
The present invention relates to environmentally friendly paper domains, more particularly to a kind of antibacterial environmentally friendly paper and preparation method thereof.
Background technology
Paper industry holds an important position in national economy, at present, area of woods only about 1.75 hundred million hectares, forest
Coverage rate only about 18.2%.In a short time, China can not possibly provide enough forest resourcess to paper industry and be made for slurrying
Paper.Therefore, in recent decades, straw pulp once turns into the primary raw material of papermaking.But the grass class system of papermaking empirical evidence for many years
There are many problems in slurry papermaking, its product variety, product quality and production capacity are much restricted.Meanwhile, with China
Rapid development of economy and the enhancing of environmental protection and energy saving consciousness, generally replace lumber fibre using secondary stock, papermaking filler etc.
Papermaking is carried out, and wherein papermaking filler is even more to be widely used.Over nearly 30 years, using papermaking filler this technology rapidly into
It is ripe, and as an indispensable part in paper-making process.
The opacity, whiteness and printability etc. of paper are not only improved to a certain extent into paper because paper is filled with
Performance, and the price of fiber is universal higher, and the price of filler is relatively inexpensive, promotes what high-filling amount papermaking was used by paper-making industry
Trend.However, the consumption of increase filler is implicitly present in many challenges, the fortune of paper machine can be influenceed by such as adding higher filling adding amount
Row performance, will also result in deposition of the filler in slurry and plain boiled water with keeping, and the clarification of plain boiled water is difficult, and wet end chemistry phase
Control problem is closed, while the strength character for also resulting in into paper significantly declines.
The content of the invention
In order to solve deficiency of the prior art, it is an object of the invention to provide the antibacterial environmentally friendly paper of one kind and its preparation
Method.
The technical solution adopted in the present invention is：A kind of antibacterial environmentally friendly paper, the paper is matched somebody with somebody by weight including following
The raw material of ratio：25-45 parts of wood composite slurry, 12-15 parts of alkyl ketene dimer, 15-20 parts of industrial filter paper, sodium alginate 6-10
Part, 9-12 parts of methanol, 8-14 parts of palm oil, 10-15 parts of Lauxite, 6-11 parts of crystal whisker of gypsum, 3-7 parts of sorbierite.
The wood composite slurry is pressed by ginkgo leaf wood pulp material, leaf of bamboo wood pulp material, Leaf of Magnolia officinalis wood pulp material and rhizome of chuanxiong leaf wood pulp material
According to 2-3：1-2：3-4：1-3 proportion mixing composition.
Further, the paper includes following raw materials：32 parts of wood composite slurry, alkyl ketene two
14 parts of aggressiveness, 18 parts of industrial filter paper, 8 parts of sodium alginate, 10 parts of methanol, 12 parts of palm oil, 12 parts of Lauxite, crystal whisker of gypsum 9
Part, 5 parts of sorbierite.
Further, the wood composite slurry is by ginkgo leaf wood pulp material, leaf of bamboo wood pulp material, Leaf of Magnolia officinalis wood pulp material and rhizome of chuanxiong leaf
Wood pulp material is according to 2.25：1.35：3.26：1.52 proportion mixing composition.
The preparation method of described antibacterial environmentally friendly paper comprises the steps：
1) it is wood composite slurry, alkyl ketene dimer, sodium alginate and Lauxite is scattered in methyl alcohol, it is made into
10%-25% suspension, sonic oscillation 15-45 minutes in ultrasonic oscillation device；
2) industrial filter paper is cut into the sequin that diameter is about 5-8cm, is then placed in 10%-25% filler methanol
It is repeatedly vertical to lift 3-7 times in suspension, the evengranular surface for being distributed in industrial filter paper of solid packing is increased paper
Surface roughness, natural air drying is standby；
3) palm oil, crystal whisker of gypsum and sorbierite are mixed, adds the 1-2 times of aqueous solution measured, add at 60-75 DEG C
After hot 20-30 minutes, room temperature is cooled to, mixed liquor is obtained, it is standby；
4) the industrial filter paper piece after air-drying is put into vertically lifting 3-6 times after standing 10-30 minutes in mixed liquor, made
Mixed liquor sprawls film forming, natural air drying in paper surface.
Further, the concentration of methanol is 2%-5% in the step 1.
Further, 20% suspension is made into the step 1.
Further, it is stirred 10-15 minutes while heating in the step 3.
The beneficial effect of the antibacterial environmentally friendly paper that the present invention is provided and preparation method thereof is：Manufacture craft of the present invention is simple,
Manufacturing process is environment friendly and pollution-free, and obtained paper is environment-protecting and non-poisonous, and added with wood composite slurry in paper so that the paper has
There are less tear index and degree of holding, added with the antipathogenic composition such as palm oil and sorbierite so that the paper has antibacterial effect
Really, it is harmless, and the crystal whisker of gypsum of addition can allow the paper to have preferable air permeability.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1
A kind of antibacterial environmentally friendly paper, the paper includes following raw materials：32 parts of wood composite slurry, alkane
14 parts of base ketene dimer, 18 parts of industrial filter paper, 8 parts of sodium alginate, 10 parts of methanol, 12 parts of palm oil, 12 parts of Lauxite, stone
9 parts of cream whisker, 5 parts of sorbierite.
The wood composite slurry is pressed by ginkgo leaf wood pulp material, leaf of bamboo wood pulp material, Leaf of Magnolia officinalis wood pulp material and rhizome of chuanxiong leaf wood pulp material
According to 2.25：1.35：3.26：1.52 proportion mixing composition.
The preparation method of described antibacterial environmentally friendly paper is：First by wood composite slurry, alkyl ketene dimer, alginic acid
Sodium and Lauxite are dispersed in 3% methanol, are made into 20% suspension, sonic oscillation 25 minutes in ultrasonic oscillation device；
Then industrial filter paper is cut into the sequin that diameter is about 6cm, be then placed in into 20% filler methanol suspension, repeatedly
It is vertical to lift 5 times, make the evengranular surface for being distributed in industrial filter paper of solid packing to increase the surface roughness of paper, from
So air-dry, it is standby；Then palm oil, crystal whisker of gypsum and sorbierite are mixed, the aqueous solution of 2 times of amounts is added, at 65 DEG C
Heating 25 minutes, while after stirring 12 minutes, be cooled to room temperature, obtain mixed liquor, it is standby；Finally by the industrial filter paper piece after air-drying
Vertically lifting 5 times are put into after standing 20 minutes in mixed liquor, mixed liquor is sprawled film forming in paper surface, natural air drying is
Can.
Manufacture craft of the present invention is simple, and manufacturing process is environment friendly and pollution-free, and obtained paper is environment-protecting and non-poisonous, and adds in paper
Added with wood composite slurry so that the paper has less tear index and degree of holding, added with the suppression such as palm oil and sorbierite
Bacterium composition so that the paper has fungistatic effect, harmless, and the crystal whisker of gypsum of addition can allow the paper to have preferably
Air permeability.
Embodiment 2
A kind of antibacterial environmentally friendly paper, the paper includes following raw materials：25 parts of wood composite slurry, alkane
12 parts of base ketene dimer, 15 parts of industrial filter paper, 6 parts of sodium alginate, 9 parts of methanol, 8 parts of palm oil, 10 parts of Lauxite, gypsum
6 parts of whisker, 3 parts of sorbierite.
The wood composite slurry is pressed by ginkgo leaf wood pulp material, leaf of bamboo wood pulp material, Leaf of Magnolia officinalis wood pulp material and rhizome of chuanxiong leaf wood pulp material
According to 2：1：3：1 proportion mixing composition.
The preparation method of described antibacterial environmentally friendly paper is：First by wood composite slurry, alkyl ketene dimer, alginic acid
Sodium and Lauxite are dispersed in 2% methanol, are made into 10% suspension, sonic oscillation 15 minutes in ultrasonic oscillation device；
Then industrial filter paper is cut into the sequin that diameter is about 5cm, be then placed in into 10% filler methanol suspension, repeatedly
It is vertical to lift 3 times, make the evengranular surface for being distributed in industrial filter paper of solid packing to increase the surface roughness of paper, from
So air-dry, it is standby；Then palm oil, crystal whisker of gypsum and sorbierite are mixed, the aqueous solution of 1 times of amount is added, at 60 DEG C
Heating 20 minutes, while after stirring 10 minutes, be cooled to room temperature, obtain mixed liquor, it is standby；Finally by the industrial filter paper piece after air-drying
Vertically lifting 3 times are put into after standing 10 minutes in mixed liquor, mixed liquor is sprawled film forming in paper surface, natural air drying is
Can.
Manufacture craft of the present invention is simple, and manufacturing process is environment friendly and pollution-free, and obtained paper is environment-protecting and non-poisonous, and adds in paper
Added with wood composite slurry so that the paper has less tear index and degree of holding, added with the suppression such as palm oil and sorbierite
Bacterium composition so that the paper has fungistatic effect, harmless, and the crystal whisker of gypsum of addition can allow the paper to have preferably
Air permeability.
Embodiment 3
A kind of antibacterial environmentally friendly paper, the paper includes following raw materials：45 parts of wood composite slurry, alkane
15 parts of base ketene dimer, 20 parts of industrial filter paper, 10 parts of sodium alginate, 12 parts of methanol, 14 parts of palm oil, 15 parts of Lauxite,
11 parts of crystal whisker of gypsum, 7 parts of sorbierite.
The wood composite slurry is pressed by ginkgo leaf wood pulp material, leaf of bamboo wood pulp material, Leaf of Magnolia officinalis wood pulp material and rhizome of chuanxiong leaf wood pulp material
According to 3：2：4：3 proportion mixing composition.
The preparation method of described antibacterial environmentally friendly paper is：First by wood composite slurry, alkyl ketene dimer, alginic acid
Sodium and Lauxite are dispersed in 5% methanol, are made into 25% suspension, sonic oscillation 45 minutes in ultrasonic oscillation device；
Then industrial filter paper is cut into the sequin that diameter is about 8cm, be then placed in into 25% filler methanol suspension, repeatedly
It is vertical to lift 7 times, make the evengranular surface for being distributed in industrial filter paper of solid packing to increase the surface roughness of paper, from
So air-dry, it is standby；Then palm oil, crystal whisker of gypsum and sorbierite are mixed, the aqueous solution of 2 times of amounts is added, at 75 DEG C
Heating 30 minutes, while after stirring 15 minutes, be cooled to room temperature, obtain mixed liquor, it is standby；Finally by the industrial filter paper piece after air-drying
Vertically lifting 6 times are put into after standing 30 minutes in mixed liquor, mixed liquor is sprawled film forming in paper surface, natural air drying is
Can.
Manufacture craft of the present invention is simple, and manufacturing process is environment friendly and pollution-free, and obtained paper is environment-protecting and non-poisonous, and adds in paper
Added with wood composite slurry so that the paper has less tear index and degree of holding, added with the suppression such as palm oil and sorbierite
Bacterium composition so that the paper has fungistatic effect, harmless, and the crystal whisker of gypsum of addition can allow the paper to have preferably
Air permeability.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modifications, equivalent substitutions and improvements made within refreshing and principle etc., should be included in protection scope of the present invention.
Claims (7)
1. a kind of antibacterial environmentally friendly paper, it is characterised in that the paper includes following raw materials：Compound wood pulp
25-45 parts of material, 12-15 parts of alkyl ketene dimer, 15-20 parts of industrial filter paper, 6-10 parts of sodium alginate, 9-12 parts of methanol, palm fibre
8-14 parts of palmitic acid oil, 10-15 parts of Lauxite, 6-11 parts of crystal whisker of gypsum, 3-7 parts of sorbierite；
The wood composite slurry is by ginkgo leaf wood pulp material, leaf of bamboo wood pulp material, Leaf of Magnolia officinalis wood pulp material and rhizome of chuanxiong leaf wood pulp material according to 2-
3：1-2：3-4：1-3 proportion mixing composition.
2. antibacterial environmentally friendly paper according to claim 1, it is characterised in that the paper include it is following by weight ratio
Raw material：32 parts of wood composite slurry, 14 parts of alkyl ketene dimer, 18 parts of industrial filter paper, 8 parts of sodium alginate, 10 parts of methanol, palm fibre
12 parts of palmitic acid oil, 12 parts of Lauxite, 9 parts of crystal whisker of gypsum, 5 parts of sorbierite.
3. antibacterial environmentally friendly paper according to claim 1, it is characterised in that the wood composite slurry is by ginkgo leaf wood pulp
Material, leaf of bamboo wood pulp material, Leaf of Magnolia officinalis wood pulp material and rhizome of chuanxiong leaf wood pulp material are according to 2.25：1.35：3.26：1.52 proportion mixing group
Into.
4. the preparation method based on any described antibacterial environmentally friendly paper of claim 1-3, it is characterised in that methods described includes
Following step：
1) it is wood composite slurry, alkyl ketene dimer, sodium alginate and Lauxite is scattered in methyl alcohol, it is made into 10%-
25% suspension, sonic oscillation 15-45 minutes in ultrasonic oscillation device；
2) industrial filter paper is cut into the sequin that diameter is about 5-8cm, is then placed in 10%-25% filler methanol suspension
It is repeatedly vertical to lift 3-7 times in liquid, the evengranular surface for being distributed in industrial filter paper of solid packing is increased the table of paper
Surface roughness, natural air drying is standby；
3) palm oil, crystal whisker of gypsum and sorbierite are mixed, adds the 1-2 times of aqueous solution measured, heated at 60-75 DEG C
After 20-30 minutes, room temperature is cooled to, mixed liquor is obtained, it is standby；
4) the industrial filter paper piece after air-drying is put into vertically lifting 3-6 times after standing 10-30 minutes in mixed liquor, makes mixing
Liquid sprawls film forming, natural air drying in paper surface.
5. the preparation method of antibacterial environmentally friendly paper according to claim 4, it is characterised in that methanol in the step 1
Concentration is 2%-5%.
6. the preparation method of antibacterial environmentally friendly paper according to claim 4, it is characterised in that be made into the step 1
20% suspension.
7. the preparation method of antibacterial environmentally friendly paper according to claim 4, it is characterised in that heated in the step 3
It is stirred 10-15 minutes simultaneously.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710526770.3A CN107217535A (en) | 2017-06-30 | 2017-06-30 | A kind of antibacterial environmentally friendly paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710526770.3A CN107217535A (en) | 2017-06-30 | 2017-06-30 | A kind of antibacterial environmentally friendly paper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107217535A true CN107217535A (en) | 2017-09-29 |
Family
ID=59951604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710526770.3A Pending CN107217535A (en) | 2017-06-30 | 2017-06-30 | A kind of antibacterial environmentally friendly paper and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108867181A (en) * | 2018-05-29 | 2018-11-23 | 平阳县恒信印业有限公司 | A kind of novel environment friendly paper and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104532656A (en) * | 2014-11-22 | 2015-04-22 | 安徽索亚装饰材料有限公司 | PVC wallpaper base paper with toughness and moisture absorption performance, and preparation method thereof |
| WO2015166452A1 (en) * | 2014-05-02 | 2015-11-05 | Munksjö Oyj | Twisting paper |
| CN105155336A (en) * | 2015-09-11 | 2015-12-16 | 姚志宏 | Composite body paper resisting corrosion of acid and alkali and manufacturing method thereof |
| CN105421140A (en) * | 2015-11-25 | 2016-03-23 | 赖清甜 | Environment-friendly paper and preparation method thereof |
| CN105442390A (en) * | 2015-11-25 | 2016-03-30 | 赖清甜 | High-filler paper and preparation method thereof |
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2017
- 2017-06-30 CN CN201710526770.3A patent/CN107217535A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015166452A1 (en) * | 2014-05-02 | 2015-11-05 | Munksjö Oyj | Twisting paper |
| CN104532656A (en) * | 2014-11-22 | 2015-04-22 | 安徽索亚装饰材料有限公司 | PVC wallpaper base paper with toughness and moisture absorption performance, and preparation method thereof |
| CN105155336A (en) * | 2015-09-11 | 2015-12-16 | 姚志宏 | Composite body paper resisting corrosion of acid and alkali and manufacturing method thereof |
| CN105421140A (en) * | 2015-11-25 | 2016-03-23 | 赖清甜 | Environment-friendly paper and preparation method thereof |
| CN105442390A (en) * | 2015-11-25 | 2016-03-30 | 赖清甜 | High-filler paper and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108867181A (en) * | 2018-05-29 | 2018-11-23 | 平阳县恒信印业有限公司 | A kind of novel environment friendly paper and preparation method thereof |
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Application publication date: 20170929 |