CN107216834A - A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol and preparation method thereof - Google Patents

A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol and preparation method thereof Download PDF

Info

Publication number
CN107216834A
CN107216834A CN201710457423.XA CN201710457423A CN107216834A CN 107216834 A CN107216834 A CN 107216834A CN 201710457423 A CN201710457423 A CN 201710457423A CN 107216834 A CN107216834 A CN 107216834A
Authority
CN
China
Prior art keywords
byk
alcohol
parts
sensitive adhesive
pressure sensitive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710457423.XA
Other languages
Chinese (zh)
Inventor
张英强
娄静洁
李美佳
李烨
李婧怡
徐乐平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Institute of Technology
Original Assignee
Shanghai Institute of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Institute of Technology filed Critical Shanghai Institute of Technology
Priority to CN201710457423.XA priority Critical patent/CN107216834A/en
Publication of CN107216834A publication Critical patent/CN107216834A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol, calculate, be made up of 50 80 parts of water-white Abietyl modified alcohol-soluble resin, 50 80 parts of alcohol-soluble organic silicon sol, 0.05 0.1 parts of levelling agents, 1 10 parts of wetting agent, 0.2 1 parts of defoamer and 10 60 parts of alcoholic solvents by weight.Present invention also offers the preparation method of above-mentioned quick-drying pressure sensitive adhesive.The characteristics of quick-drying pressure sensitive adhesive of the present invention has fast rate of drying, tack, holds viscosity and high 180 peel strengths;It can be applied to can be used for the fields such as diaper, woman article, two-sided tape, label, packaging, health care, bookbinding, surface protection film, timber processing, wallpaper and shoemaking.

Description

A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol and preparation method thereof
Technical field
The invention belongs to technical field of polymer materials, it is related to a kind of pressure sensitive adhesive, specifically one kind contains alkaline alcohol Quick-drying pressure sensitive adhesive of dissolubility organic silicon sol and preparation method thereof.
Background technology
Pressure sensitive adhesive is that a class is slightly exerted pressure and can just be bonded at the binder on other surfaces.Pressure sensitive adhesive physical characteristic is gluing Band is pasted on adherend, and when peeling off, pressure sensitive adhesive must completely disengage from adherend and noresidue, must meet following condition:Quickstick Power<Bonding force<Base adhesion force<Cohesive force.It is commonly divided into solvent pressure-sensitive adhesive and solvent-free property pressure sensitive adhesive.No-solvent type pressure Quick glue is in production without using solvent, predominantly hot-fusible pressure-sensitive adhesive and UV solidified pressure-sensitives.Hot-fusible pressure-sensitive adhesive, which need to be heated, to be applied Cloth.UV solidified pressure-sensitives then need, by the method such as ultraviolet (UV) or electron beam (EB) irradiation, to be crosslinked oligomer Pressure-sensitive adhesive product is made.Solvent pressure-sensitive adhesive can be divided into again according to its type of solvent emulsion based pressure sensitive using water as solvent and with Organic solvent is the solvent pressure-sensitive adhesive of solvent.Solvent pressure-sensitive adhesive, it has excellent pressure-sensitive and cementability, and due to resistance to Aging, light resistance, water resistance, oil resistivity are excellent, so almost no rheological parameters' change with time causes the problem of pressure-sensitive declines, and And removability is excellent, but it is increasingly strict with environmental law, and being unsatisfactory for the solvent pressure-sensitive adhesive of environmental requirement has by other The trend of pressure sensitive adhesive substitution.Emulsion-type pressure-sensitive have cost it is low, using it is safe and pollution-free the features such as, but because it contains emulsification Agent, its water resistance is low, heat resistance is poor, due to making solvent with water, so drying time is long, is unsatisfactory for some industry and quickly applies The need for work.Be badly in need of exploitation it is a kind of have fast dry characteristic, meet environmental requirement, it is easy construction, with low cost, excellent performance Pressure sensitive adhesive.
The content of the invention
For above-mentioned technical problem of the prior art, contain alkaline alcohol-soluble organic silicon sol the invention provides one kind Quick-drying pressure sensitive adhesive and preparation method thereof, the described this quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol and its system Preparation Method will solve that emulsion-type pressure-sensitive water resistance of the prior art is low, heat resistance is poor, the technical problem of drying time length.
The invention provides a kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol, calculate by weight, Its raw material is constituted and content is as follows:
Water-white 50-80 parts Abietyl modified of alcohol-soluble resin;
Alkaline 50-80 parts of alcohol-soluble organic silicon sol;
0.05-0.1 parts of levelling agent;
1-10 parts of wetting agent;
0.2-1 parts of defoamer;
10-60 parts of alcoholic solvent;
Wherein, described water-white Abietyl modified alcohol-soluble resin is water-white Abietyl modified alcohol-soluble self-crosslinking acrylic ester tree Fat;
Described wetting agent is any one in the NP-100 or Germany's levelling agents of BYK 333 of LG-DOW company or two kinds Mixture;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described alcoholic solvent is any one in ethanol, propyl alcohol, butanol, propane diols, glycerine or two or more mixtures;
Described levelling agent be selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, One or more in BYK-345, BYK-346, BYK-347 or BYK-348;Described defoamer is selected from Germany BYK Bi Ke Any one or two kinds in BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038 with On mixture;.
Present invention also offers a kind of preparation side of above-mentioned quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol Method, comprises the following steps:According to formula, wetting agent, levelling agent, defoamer are added in high speed dispersor, is turned through 600r/min Rotating speed is down to 300r/min after the lower scattered 15-20min of speed, water-white Abietyl modified alcohol-soluble resin, alkaline alcohol-soluble is added Organic silicon sol and alcoholic solvent, continue scattered 5-10min, are well mixed, that is, obtain containing alkaline alcohol-soluble organic silicon sol Quick-drying pressure sensitive adhesive.
A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol of the present invention, because the water-white rosin of addition changes Property alcohol-soluble self-crosslinking acrylic ester resin be by the relatively low soft monomer of glass transition temperature, glass transition temperature and have hardness hard list Body, monomer's copolymerization through it is water-white it is Abietyl modified form, make pressure sensitive adhesive rise adhesive attraction, possess pressure-sensitive, cohesive performance is big Big to improve, monomer makes pressure sensitive adhesive strand produce crosslinking, the raising of cohesive strength and adhesive property is served not small. Alkaline alcohol-soluble organic silicon sol adds the rate of drying of pressure sensitive adhesive, improves the cohesive strength of pressure sensitive adhesive and holds viscosity.This Invention is 16- according to GB/T 1728-1979 " paint film, the putty membrane drying time determination method " drying times for determining pressure sensitive adhesive 59min;
The present invention is according to GB/T4852-2002 " pressure-sensitive tape tack test method (rolling ball method) ", i.e., on self-control inclined-plane On (30o), a series of not equal steel balls of diameter are rolled down from big to small, by being placed on the pressure-sensitive tape of skewback lower end, The maximum steel ball on inclined-plane can wherein be stopped at completely by finding out, and the initial cohesiveness of pressure sensitive adhesive is measured with the number N of steel ball.To made The initial adhesion force of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol is measured, and initial adhesion force is 19-21 steel balls.
180 ° of peel strengths newly think carefully the CMT5104 electronic tension testers of company at room temperature according to GB/ using Shenzhen T 2792-1998 standards " 180 ° of peeling strength test methods of pressure-sensitive tape " are determined.Pressure sensitive adhesive tape is attached to stainless steel substrate (50 mm×125 mm)On, rolled back and forth three times with the Manual pressure roller of 2 kg weights, peel test carried out after placing 20 min, Peeling rate is 300mm/min, and reading is simultaneously recorded.Parallel testing five times, averages.Alkaline alcohol-soluble is contained to preparation The quick-drying pressure sensitive adhesive of organic silicon sol carries out 180 ° of peel strength tests, and peel strength is 18.9-21.3N/25mm.
The present invention is surveyed according to GB/T 4851-1998 " pressure-sensitive tape holds viscosity test method " standard using holding power Instrument is tried to determine.By pressure sensitive adhesive tape patch on stainless steel, rolled back and forth three times with 2 kg Manual pressure roller, place 20 min Vertically hang afterwards on test stand, lower end hangs 1 kg counterweight, the time that record sample is completely disengaged from.Parallel testing three times, Average.Viscous force is held for 18-25h.
The present invention is compared with prior art, and its technological progress is significant.The present invention have rate of drying fast, tack, The characteristics of holding viscosity and high 180 peel strengths.Easy to control and preparation technology is simple, quick, environmental protection can be applied to can be used for Diaper, woman article, two-sided tape, label, packaging, health care, bookbinding, surface protection film, timber processing, wallpaper and The fields such as shoemaking.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available, Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows:
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol, is calculated by weight, its raw material composition and content It is as follows:
Water-white 50 parts Abietyl modified of alcohol-soluble resin
Alkaline 50 parts of alcohol-soluble organic silicon sol
0.05 part of levelling agent
1 part of wetting agent
0.2 part of defoamer
10 parts of alcoholic solvent
Wherein described water-white Abietyl modified alcohol-soluble resin is calculated by weight, and it is constituted and content is as follows:
10 parts of mix monomer
Water-white 3 parts of rosin
60 parts of solvent
0.2 part of thermal initiator
Described water-white Abietyl modified alcohol-soluble resin is prepared as follows:Equipped with stirring, four mouthfuls of burnings of condensing reflux All 60 parts of absolute ethyl alcohols are added in bottle and are used as solvent and 3 parts of mix monomers(Butyl acrylate, methyl methacrylate, methyl Acrylic acid, VTES in mass ratio 45:11:10:3), nitrogen protection is passed through, it is 300r/ to control mixing speed min.3 parts of water-white rosin and thermal initiator BPO, which are dissolved, with remaining mix monomer is configured to initiator solution.When temperature rises to 80 DEG C When, first add a quarter initiator solution.Supplement remaining initiator solution in 3 hours in batches, initiator completion of dropping with Afterwards, then react after one hour.Question response is cooled to room temperature afterwards completely, produces water-white Abietyl modified alcohol-soluble resin.
Calculate by weight, it is constituted and content is as follows:
9 parts of dimethyl diethyl oxosilane
23 parts of three ethoxy silane of methyl
3 parts of ethanol
2.7 parts of ammoniacal liquor
Described alkaline alcohol-soluble organic silicon sol is prepared as follows:By 9 parts of dimethyl diethyl oxosilanes and 23 parts of methyl Three ethoxy silane, 3 parts of ethanol, 2.7 parts of ammoniacal liquor are added in 500ml three-necked flask, and magnetic agitation is simultaneously heated to 90 DEG C of reactions 4h, treats that flask temperature drops to room temperature, produces alkaline alcohol-soluble organic silicon sol.
Described levelling agent is the high Tego Glide 410 of enlightening;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described alcoholic solvent is ethanol and propane diols in mass ratio 1:The mixture of 1 composition;
In the present embodiment, a kind of preparation method of the quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol, specifically include as Lower step:
According to formula, in GFJ-0.4 type high speed dispersors(The new promise experimental instruments and equipment limited in Shanghai)Middle 1 part of wetting agent of addition, 0.05 part of levelling agent, 0.2 part of defoamer, 300r/min is down to after disperseing 15min under 600r/min rotating speeds by rotating speed, adds 50 The water-white Abietyl modified alcohol-soluble resin of part, 50 parts of alcohol-soluble organic silicon sols, 10 parts of alcoholic solvents, continue scattered 10min, mixing Uniformly, that is, the quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol is obtained.
Further, drying time GB/T 1728-1979 " paint film, putty membrane drying time determination method " determine pressure sensitive adhesive Drying time be 16min;
According to by according to GB/T4852-2002 " pressure-sensitive tape tack test method (rolling ball method) ", i.e., on self-control inclined-plane On (30o), a series of not equal steel balls of diameter are rolled down from big to small, by being placed on the pressure-sensitive tape of skewback lower end, The maximum steel ball on inclined-plane can wherein be stopped at completely by finding out, and the initial cohesiveness of pressure sensitive adhesive is measured with the number N of steel ball.To made The initial adhesion force of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol is measured, and the results are shown in Table 1.
Further, determined according to GB/T 2792-1998 standards " the peeling strength test method of pressure-sensitive tape 180 ". Pressure sensitive adhesive tape is attached to stainless steel substrate(50 mm×125 mm)On, rolled three times, put back and forth with the Manual pressure roller of 2 kg weights Put and peel test is carried out after 20 min, peeling rate is 300mm/min, reading is simultaneously recorded.Parallel testing five times, is averaged Value.180 ° of peel strength tests are carried out to the quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol of preparation, be the results are shown in Table 1。
The quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol obtained by the present embodiment is according to GB/T 4851-1998 " pressure-sensitive tape holds viscosity test method " standard, is determined using holding power tester.By pressure sensitive adhesive tape patch on stainless steel, Rolled three times, vertically hung after placing 20 min on test stand back and forth with 2 kg Manual pressure roller, lower end hangs 1 kg Counterweight, record time for completely disengaging from of sample.Parallel testing three times, averages.Testing result is shown in Table 1.
The quick-drying pressure sensitive adhesive drying time containing alkaline alcohol-soluble organic silicon sol of the gained of above example 1 is short, just viscous Property, hold viscosity and 180 peel strengths it is higher.
The performance of pressure sensitive adhesive
Embodiment Drying time, min Tack/steel ball number Hold viscosity/h 180 peel strengths(N/25mm)
Embodiment 1 16 19 19 18.9
Embodiment 2 59 21 26 21.3
Embodiment 2
A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol, is calculated by weight, its raw material composition and content It is as follows:
Water-white 80 parts Abietyl modified of alcohol-soluble resin
Alkaline 80 parts of alcohol-soluble organic silicon sol
0.1 part of levelling agent
10 parts of wetting agent
1 part of defoamer
60 parts of alcoholic solvent
Wherein described water-white Abietyl modified alcohol-soluble resin is calculated by weight, and it is constituted and content is as follows:
10 parts of mix monomer
Water-white 5 parts of rosin
60 parts of solvent
0.2 part of thermal initiator
Described water-white Abietyl modified alcohol-soluble resin is prepared as follows:Equipped with stirring, four mouthfuls of burnings of condensing reflux All 60 parts of absolute ethyl alcohols are added in bottle and are used as solvent and 3 parts of mix monomers(Butyl acrylate, methyl methacrylate, methyl Acrylic acid, VTES in mass ratio 45:11:10:3), nitrogen protection is passed through, it is 300r/ to control mixing speed min.5 parts of water-white rosin and thermal initiator BPO, which are dissolved, with remaining mix monomer is configured to initiator solution.When temperature rises to 80 DEG C When, first add a quarter initiator solution.Supplement remaining initiator solution in 3 hours in batches, initiator completion of dropping with Afterwards, then react after one hour.Question response is cooled to room temperature afterwards completely, produces water-white Abietyl modified alcohol-soluble resin.
Calculate by weight, it is constituted and content is as follows:
9 parts of dimethyl diethyl oxosilane
23 parts of three ethoxy silane of methyl
1 part of ethanol
0.7 part of ammoniacal liquor
Described alkaline alcohol-soluble organic silicon sol is prepared as follows:By 9 parts of dimethyl diethyl oxosilanes and 23 parts of methyl Three ethoxy silane, 1 part of ethanol, 0.7 part of ammoniacal liquor are added in 500ml three-necked flask, and magnetic agitation is simultaneously heated to 90 DEG C of reactions 4h, treats that flask temperature drops to room temperature, produces alkaline alcohol-soluble organic silicon sol.
Described levelling agent is the high Tego Glide 410 of enlightening;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described alcoholic solvent is ethanol and propane diols in mass ratio 1:The mixture of 1 composition;
In the present embodiment, a kind of preparation method of the quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol, specifically include as Lower step:
According to formula, in GFJ-0.4 type high speed dispersors(The new promise experimental instruments and equipment limited in Shanghai)Middle 10 parts of wetting agents of addition, 0.1 part of levelling agent, 1 part of defoamer, 300r/min is down to after disperseing 15min under 600r/min rotating speeds by rotating speed, adds 80 parts Water-white Abietyl modified alcohol-soluble resin, 80 parts of alcohol-soluble organic silicon sols, 60 parts of alcoholic solvents, continue scattered 10min, and mixing is equal It is even, that is, obtain the quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol.
Further, drying time GB/T 1728-1979 " paint film, putty membrane drying time determination method " determine pressure sensitive adhesive Drying time be 59min;
According to by according to GB/T4852-2002 " pressure-sensitive tape tack test method (rolling ball method) ", i.e., on self-control inclined-plane On (30o), a series of not equal steel balls of diameter are rolled down from big to small, by being placed on the pressure-sensitive tape of skewback lower end, The maximum steel ball on inclined-plane can wherein be stopped at completely by finding out, and the initial cohesiveness of pressure sensitive adhesive is measured with the number N of steel ball.To made The initial adhesion force of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol is measured, and the results are shown in Table 1.
Further, determined according to GB/T 2792-1998 standards " the peeling strength test method of pressure-sensitive tape 180 ". Pressure sensitive adhesive tape is attached to stainless steel substrate(50 mm×125 mm)On, rolled three times, put back and forth with the Manual pressure roller of 2 kg weights Put and peel test is carried out after 20 min, peeling rate is 300mm/min, reading is simultaneously recorded.Parallel testing five times, is averaged Value.180 ° of peel strength tests are carried out to the quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol of preparation, be the results are shown in Table 1。
The quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol obtained by the present embodiment is according to GB/T 4851-1998 " pressure-sensitive tape holds viscosity test method " standard, is determined using holding power tester.By pressure sensitive adhesive tape patch on stainless steel, Rolled three times, vertically hung after placing 20 min on test stand back and forth with 2 kg Manual pressure roller, lower end hangs 1 kg Counterweight, record time for completely disengaging from of sample.Parallel testing three times, averages.Test result is shown in Table 1.
Quick-drying pressure sensitive adhesive drying time containing alkaline alcohol-soluble organic silicon sol of the gained of above example 2 is short, tack, hold Viscosity and 180 peel strengths are higher.
In summary, the quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol of the invention uses alcohol-soluble and matched somebody with somebody Side, the high speed volatilization of ethanol improves its curing rate, only a few minutes, effectively overcomes asking for pressure sensitive adhesive slow drying speed Topic.A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol of the present invention, is used as the water-white pine of main film forming substance The modified alcohol-soluble resin molecular structure of perfume is organosilicon structures, with very low surface energy, is reduced between film and base material Interaction, is allowed to embody preferably from fissility, is not required to add stripping auxiliary agent again,
Above said content is only the basic explanation under present inventive concept, and according to technical scheme made it is any etc. Effect conversion, all should belong to protection scope of the present invention.

Claims (2)

1. a kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol, it is characterised in that calculate by weight, it is former Material composition and content are as follows:
Water-white 50-80 parts Abietyl modified of alcohol-soluble resin;
Alkaline 50-80 parts of alcohol-soluble organic silicon sol;
0.05-0.1 parts of levelling agent;
1-10 parts of wetting agent;
0.2-1 parts of defoamer;
10-60 parts of alcoholic solvent;
Wherein, described water-white Abietyl modified alcohol-soluble resin is water-white Abietyl modified alcohol-soluble self-crosslinking acrylic ester tree Fat;
Described wetting agent is any one in the NP-100 or Germany's levelling agents of BYK 333 of LG-DOW company or two kinds Mixture;
Described defoamer is the Nopco NXZ of Henkel KGaA company;
Described alcoholic solvent is any one in ethanol, propyl alcohol, butanol, propane diols, glycerine or two or more mixtures;
Described levelling agent be selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, One or more in BYK-345, BYK-346, BYK-347 or BYK-348;Described defoamer is selected from Germany BYK Bi Ke Any one or two kinds in BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038 with On mixture.
2. a kind of preparation method of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol described in claim 1, it is special Levy and be to comprise the following steps:According to formula, wetting agent, levelling agent, defoamer are added in high speed dispersor, through 600r/min Rotating speed is down to 300r/min after scattered 15-20min under rotating speed, water-white Abietyl modified alcohol-soluble resin, alkaline alcohol is added molten Property organic silicon sol and alcoholic solvent, continue scattered 5-10min, be well mixed, that is, obtain containing alkalescence alcohol-soluble organic silicon sol Quick-drying pressure sensitive adhesive.
CN201710457423.XA 2017-06-16 2017-06-16 A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol and preparation method thereof Pending CN107216834A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710457423.XA CN107216834A (en) 2017-06-16 2017-06-16 A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710457423.XA CN107216834A (en) 2017-06-16 2017-06-16 A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107216834A true CN107216834A (en) 2017-09-29

Family

ID=59949679

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710457423.XA Pending CN107216834A (en) 2017-06-16 2017-06-16 A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107216834A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101613434A (en) * 2009-07-15 2009-12-30 华南理工大学 A kind of alcohol soluble polyacrylate resin and preparation method thereof and application
CN101818033A (en) * 2010-01-22 2010-09-01 北京高盟新材料股份有限公司 Alcohol-soluble composite film adhesive and preparation method thereof
CN102226067A (en) * 2011-05-16 2011-10-26 永一胶粘(中山)有限公司 Acrylate solvent-based pressure sensitive adhersive and product thereof
CN102516906A (en) * 2011-12-16 2012-06-27 北京石油化工学院 Method for preparing ethanol-soluble laminating adhesive
CN103254857A (en) * 2013-05-11 2013-08-21 北京化工大学 Alcohol-soluble self-crosslinking acrylic resin adhesive and preparation method thereof
CN106118285A (en) * 2016-06-20 2016-11-16 青岛乐化科技有限公司 A kind of skin recoating heat-reflecting insulating coating and preparation method thereof
CN106832809A (en) * 2017-01-06 2017-06-13 晋江市中辉印刷包装有限公司 High-resistance anti-ultraviolet environment friendly PET composite soft packaging material and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101613434A (en) * 2009-07-15 2009-12-30 华南理工大学 A kind of alcohol soluble polyacrylate resin and preparation method thereof and application
CN101818033A (en) * 2010-01-22 2010-09-01 北京高盟新材料股份有限公司 Alcohol-soluble composite film adhesive and preparation method thereof
CN102226067A (en) * 2011-05-16 2011-10-26 永一胶粘(中山)有限公司 Acrylate solvent-based pressure sensitive adhersive and product thereof
CN102516906A (en) * 2011-12-16 2012-06-27 北京石油化工学院 Method for preparing ethanol-soluble laminating adhesive
CN103254857A (en) * 2013-05-11 2013-08-21 北京化工大学 Alcohol-soluble self-crosslinking acrylic resin adhesive and preparation method thereof
CN106118285A (en) * 2016-06-20 2016-11-16 青岛乐化科技有限公司 A kind of skin recoating heat-reflecting insulating coating and preparation method thereof
CN106832809A (en) * 2017-01-06 2017-06-13 晋江市中辉印刷包装有限公司 High-resistance anti-ultraviolet environment friendly PET composite soft packaging material and preparation method thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
张玉龙: "《有机涂料改性技术》", 31 January 2007, 机械工业出版社 *
戴志成等: "《硅化合物的生产与应用》", 31 May 1994, 成都科技大学出版社 *
李广宇等: "《胶粘与密封新技术》", 31 January 2006, 国防工业出版社 *
李红强: "《胶粘原理、技术及应用》", 31 January 2014, 华南理工大学出版社 *

Similar Documents

Publication Publication Date Title
CN107001874B (en) Bonding sheet
CN109897574B (en) Pressure-sensitive adhesive and preparation method thereof, and adhesive label and preparation method thereof
CN105219316B (en) A kind of high adhesiveness energy medical polyacrylate pressure-sensitive adhesive sticks agent
CN105264036B (en) Response to temperature adhesive
CN104946171B (en) Response to temperature adhesive
EP3380535A1 (en) Thermally reversible polymer crosslinking for pressure sensitive adhesives
CN109593497B (en) UV-cured acrylate pressure-sensitive adhesive suitable for plastic material and preparation method and application thereof
ES2459305T3 (en) Pressure sensitive adhesive with initial and double crosslinked adhesion capacity
CN106883794B (en) Single-component peelable water-based adhesive and adhesive sheet thereof
CN111154429B (en) Polyacrylate pressure-sensitive adhesive
CN108795340B (en) Solvent type acrylate pressure-sensitive adhesive with high molecular weight and high conversion rate, and preparation method and application thereof
JPH06509827A (en) Removable glue stick
CN107815275A (en) The adhesive and its processing technology of a kind of adhesive tape for exterior wall protection
JP2018076390A (en) Repeelable aqueous adhesive composition and repeelable adhesive sheet
CN112391134A (en) Acrylate pressure-sensitive adhesive and preparation process and application thereof
CN103030914A (en) Acrylic ester composition, preparation method of acrylic ester composition, and adhesive tape applying composition
CN112680129A (en) Adhesive label and preparation method thereof
JP2012067315A (en) Pressure sensitive adhesive composition, double-sided pressure sensitive adhesive tape, and method for bonding
CN115605557A (en) Aqueous adhesive and adhesive sheet
CN107216833A (en) A kind of quick-drying pressure sensitive adhesive containing acid alcohol-soluble Ludox and preparation method thereof
CN107216834A (en) A kind of quick-drying pressure sensitive adhesive containing alkaline alcohol-soluble organic silicon sol and preparation method thereof
JP2007126546A (en) Tackifier resin emulsion and aqueous adhesive composition containing the same
CN107236495A (en) A kind of quick-drying pressure sensitive adhesive and preparation method thereof
CN107216835A (en) A kind of improved quick-drying pressure sensitive adhesive and preparation method thereof
CN111808562B (en) Hot melt adhesive for ultraviolet curing label and preparation method and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170929

WD01 Invention patent application deemed withdrawn after publication