CN107216790A - A kind of roof water-proof anti-aging ground finish paint and preparation method - Google Patents
A kind of roof water-proof anti-aging ground finish paint and preparation method Download PDFInfo
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- CN107216790A CN107216790A CN201710459857.3A CN201710459857A CN107216790A CN 107216790 A CN107216790 A CN 107216790A CN 201710459857 A CN201710459857 A CN 201710459857A CN 107216790 A CN107216790 A CN 107216790A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of roof water-proof anti-aging ground finish paint and preparation method, the coating includes the following raw material:Organic silicon modified polyurethane, styrene-acrylic emulsion, Phenolic resin powder, epoxy resin, nano silicon, nano titanium oxide, alumina silicate, graphene, barium sulfate, attapulgite, defoamer, stabilizer, pigment.Preparation method includes:Organic silicon modified polyurethane, epoxy resin and graphene are mixed into 1 ~ 2h of reaction, styrene-acrylic emulsion, nano silicon, 30 ~ 60min of stirring reaction is then added;Add Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate, 10 ~ 20min of mixing shearing;Attapulgite, defoamer are added, 10 ~ 20min of ultrasound adds pigment and stabilizer, be well mixed, produce described ground finish paint.Described ground finish paint not only has preferable waterproof effect, also with preferable anti-aging, cracking resistance performance, with preferable application value.
Description
Technical field
The present invention relates to ground finish paint technical field, and in particular to a kind of roof water-proof anti-aging ground finish paint and preparation side
Method.
Background technology
With the development and constantly progress of society, particularly skyscraper and various functions is built(Structure)The appearance of thing is built, it is right
Build(Structure)Build the requirement also more and more higher of the water-proof function on the roof of thing.Existing movable roof has shock conditions with some other
The roof of generation, because existing waterproof layer structure is unreasonable, is easily caused roof membrane and is cracked, so as to destroy roof
Waterproof effect.Further, since roof membrane typically employs coiled material or malthoid, because vibrations easily make waterproof layer and bottom
It is subjected to displacement, so as to form cracking or hollowing.
Roof receives to expose to the sun and rain, particularly rainwater weather is, it is necessary to which roof can throughout the year because being arranged on the top in house
Quick drainage, if can not draining in time, rainwater overstock on roof, easily causes the making moist of roof, mouldy or even cracking so that
The service life on roof is affected, so as to influence using for whole building thing safe.
Therefore, a kind of roof land used finish paint tool that there is preferable waterproof effect, there is preferable stability again is researched and developed
It is significant, the demand of existing market is also complied with, with preferable application prospect.
The content of the invention
For defect of the prior art, it is an object of the invention to provide a kind of roof water-proof anti-aging ground finish paint and system
Preparation Method, described ground finish paint not only has preferable waterproof effect, effectively prevent roof leak, the phenomenon of infiltration occurs, also
With preferable anti-aging, cracking resistance performance so that ground finish paint has a preferable stability in use, the ground finish paint of extension makes
With the life-span, it is to avoid the cost that lacquer painting weight brush is come caused by ground finish paint aging or cracking is improved, with preferable application value.
The present invention solves technical problem and adopted the following technical scheme that:
The present invention relates to a kind of roof water-proof anti-aging ground finish paint, include each component of following parts by weight:It is organic-silicon-modified poly-
45 ~ 65 parts of urethane, 15 ~ 22 parts of styrene-acrylic emulsion, 10 ~ 20 parts of Phenolic resin powder, 12 ~ 25 parts of epoxy resin, nano silicon 8
~ 15 parts, 6 ~ 12 parts of nano titanium oxide, 5 ~ 9 parts of alumina silicate, 1 ~ 3 part of graphene, 7 ~ 15 parts of barium sulfate, 3 ~ 8 parts of attapulgite,
2 ~ 6 parts of defoamer, 3 ~ 5 parts of stabilizer, 1 ~ 4 part of pigment.
Preferably, 50 parts of the organic silicon modified polyurethane, 20 parts of styrene-acrylic emulsion, 15 parts of Phenolic resin powder, asphalt mixtures modified by epoxy resin
20 parts of fat, 11 parts of nano silicon, 8 parts of nano titanium oxide, 6 parts of alumina silicate, 2 parts of graphene, 10 parts of barium sulfate, concave convex rod
5 parts of soil, 4 parts of defoamer, 4 parts of stabilizer, 3 parts of pigment.
Preferably, the defoamer is dimethyl silicone polymer or polyoxyethylene polyoxypropylene pentaerythrite ether.
Preferably, the stabilizer is rare-earth stabilizer.
The invention further relates to a kind of method of with preparing roof water-proof anti-aging finish paint, comprise the following steps:
(1)Organic silicon modified polyurethane, epoxy resin and graphene are weighed respectively according to proportioning to be added in reactor, are added suitable
Water is measured, under the conditions of 60 ~ 80 DEG C, then 1 ~ 2h of stirring reaction adds styrene-acrylic emulsion, nano silicon into mixture, stir
30 ~ 60min of reaction is mixed, mixture a1 is obtained;
(2)Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate are added into mixture a1, is well mixed, then
It is placed in the cutter that rotating speed is 2000 ~ 3000 turns/min and shears 10 ~ 20min, obtains mixture a2;
(3)Attapulgite, defoamer are added into mixture a2,5 ~ 10min is stirred, is placed in after being well mixed ultrasonic in ultrasonic wave
10 ~ 20min, then pigment and stabilizer are added to mixture, it is well mixed, produces described ground finish paint.
Preferably, the step(1)The graphene of middle addition is the concentration of graphene aqueous solution, wherein graphene aqueous solution
For 0.3 ~ 0.5g/L.
Preferably, the step(1)The quality of middle addition water is 10 ~ 20 times of polymer quality.
Preferably, the step(2)Before middle addition Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate first
Particle diameter is crushed to less than 300 mesh.
Compared with prior art, the present invention has following beneficial effect:
(1)Roof water-proof anti-aging of the present invention ground finish paint, applied to roof ground, is not only imitated with preferable waterproof
Really, it effectively prevent roof leak, the phenomenon of infiltration occurs, also with preferable anti-aging, cracking resistance performance so that ground
Service life of the paint with preferable stability in use, with extending roof finish paint, it is to avoid ground finish paint is due to aging or cracking
The raising for the cost that caused lacquer painting weight brush is come, so as to greatly reduce use cost, meets the demand of existing market, has
Preferable application value.
(2)Roof water-proof anti-aging of the present invention finish paint be added with graphene, because graphene has lamella
Conjugated structure, is layering to form the anticorrosive coat of densification, can effectively suppress infiltration and infiltration of the water to material, so that stone
The modified polymer of black alkene is applied to considerably increase the water-fast decay resistance of paint film in ground finish paint;Further, since graphite
Alkene excellent mechanical property and chemical stability so that ground finish paint has preferable wear-resisting, scratch-resistant mechanical property and chemistry
Stability, improves the service life of ground finish paint, reduces use cost.
(3)Roof of the present invention with water-proof anti-aging finish paint addition epoxy resin enhance bonding between each raw material
Fastness so that ground finish paint has a preferable antistrip performance, the presence of phenolic resin cause ground finish paint have it is preferably acidproof,
The mechanical properties such as heat-resisting and preferable scratch-resistant.
(4)Roof water-proof anti-aging of the present invention finish paint be added with attapulgite, with it is preferable viscosity and
Plasticity, emulsification rate is higher, saves emulsification production process, reduces production cost, is conducive to the emulsification between raw material and glues
Knot so that the ground finish paint prepared has higher adhesive property, antistrip performance and preferable waterproof effect, in addition, recessed
Convex rod soil itself has preferable suspension, levelability and a thickening property, the addition of attapulgite can replace original suspending agent,
Thickener and stabilizer, greatly reduce consumption of raw materials, and Concave-convex clay rod is pure natural substance, and chemical inertness is pollution-free,
Suppress growth of microorganism, absorb poisonous volatile ingredient, environmental protection.
(5)Roof water-proof anti-aging of the present invention finish paint preparation technology is simple, mild condition, preparation process without
Pollutant is produced, safety and environmental protection, is adapted to industrialization promotion production.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.The experimental method of unreceipted actual conditions in the following example, generally according to normal condition, for example
Sambrook equimoleculars are cloned:Laboratory manual(New York:Cold Spring Harbor Laboratory Press,
1989)Described in condition, or according to the condition proposed by manufacturer.
Embodiment 1:
A kind of roof water-proof anti-aging of the preferred embodiment of the present invention ground finish paint and preparation method;
Roof water-proof anti-aging ground finish paint, is prepared from by each component of following parts by weight:
50 parts of organic silicon modified polyurethane, 20 parts of styrene-acrylic emulsion, 15 parts of Phenolic resin powder, 20 parts of epoxy resin, nano-silica
11 parts of SiClx, 8 parts of nano titanium oxide, 6 parts of alumina silicate, 2 parts of graphene, 10 parts of barium sulfate, 5 parts of attapulgite, defoamer 4
Part, 4 parts of stabilizer, 3 parts of pigment.
The defoamer is dimethyl silicone polymer.
The stabilizer is rare-earth stabilizer.
The method of with preparing roof water-proof anti-aging finish paint of the present invention, comprises the following steps:
(1)Organic silicon modified polyurethane, epoxy resin and graphene are weighed respectively according to proportioning to be added in reactor, are added suitable
Water is measured, under the conditions of 75 ~ 78 DEG C, then stirring reaction 2h adds styrene-acrylic emulsion, nano silicon, stirring into mixture
50min is reacted, mixture a1 is obtained;
(2)Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate are added into mixture a1, is well mixed, then
It is placed in the cutter that rotating speed is 3000 turns/min and shears 20min, obtains mixture a2;
(3)Attapulgite, defoamer are added into mixture a2,10min is stirred, is placed in after being well mixed ultrasonic in ultrasonic wave
15min, then pigment and stabilizer are added to mixture, it is well mixed, produces described ground finish paint.
Step(1)The graphene of middle addition is graphene aqueous solution, and wherein the concentration of graphene aqueous solution is 0.4g/L.
Step(1)The quality of middle addition water is 16 times of polymer quality.
Step(2)Grain is first crushed to before middle addition Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate
Footpath is less than 300 mesh.
Embodiment 2:
A kind of roof water-proof anti-aging of the preferred embodiment of the present invention ground finish paint and preparation method;
Roof water-proof anti-aging ground finish paint, is prepared from by each component of following parts by weight:
45 parts of organic silicon modified polyurethane, 15 parts of styrene-acrylic emulsion, 10 parts of Phenolic resin powder, 12 parts of epoxy resin, nano-silica
8 parts of SiClx, 6 parts of nano titanium oxide, 5 parts of alumina silicate, 1 part of graphene, 7 parts of barium sulfate, 3 parts of attapulgite, 2 parts of defoamer,
3 parts of stabilizer, 1 part of pigment.
The defoamer is dimethyl silicone polymer.
The stabilizer is rare-earth stabilizer.
The method of with preparing roof water-proof anti-aging finish paint of the present invention, comprises the following steps:
(1)Organic silicon modified polyurethane, epoxy resin and graphene are weighed respectively according to proportioning to be added in reactor, are added suitable
Water is measured, under the conditions of 60 ~ 75 DEG C, then stirring reaction 2h adds styrene-acrylic emulsion, nano silicon, stirring into mixture
30min is reacted, mixture a1 is obtained;
(2)Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate are added into mixture a1, is well mixed, then
It is placed in the cutter that rotating speed is 2000 turns/min and shears 20min, obtains mixture a2;
(3)Attapulgite, defoamer are added into mixture a2,5min is stirred, is placed in after being well mixed ultrasonic in ultrasonic wave
10min, then pigment and stabilizer are added to mixture, it is well mixed, produces described ground finish paint.
Step(1)The graphene of middle addition is graphene aqueous solution, and wherein the concentration of graphene aqueous solution is 0.3g/L.
Step(1)The quality of middle addition water is 10 times of polymer quality.
Step(2)Grain is first crushed to before middle addition Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate
Footpath is less than 300 mesh.
Embodiment 3:
A kind of roof water-proof anti-aging of the preferred embodiment of the present invention ground finish paint and preparation method;
Roof water-proof anti-aging ground finish paint, is prepared from by each component of following parts by weight:
65 parts of organic silicon modified polyurethane, 22 parts of styrene-acrylic emulsion, 20 parts of Phenolic resin powder, 25 parts of epoxy resin, nano-silica
15 parts of SiClx, 12 parts of nano titanium oxide, 9 parts of alumina silicate, 3 parts of graphene, 15 parts of barium sulfate, 8 parts of attapulgite, defoamer 6
Part, 5 parts of stabilizer, 4 parts of pigment.
The defoamer is polyoxyethylene polyoxypropylene pentaerythrite ether.
The stabilizer is rare-earth stabilizer.
The method of with preparing roof water-proof anti-aging finish paint of the present invention, comprises the following steps:
(1)Organic silicon modified polyurethane, epoxy resin and graphene are weighed respectively according to proportioning to be added in reactor, are added suitable
Water is measured, under the conditions of 78 ~ 80 DEG C, then stirring reaction 1h adds styrene-acrylic emulsion, nano silicon, stirring into mixture
60min is reacted, mixture a1 is obtained;
(2)Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate are added into mixture a1, is well mixed, then
It is placed in the cutter that rotating speed is 3000 turns/min and shears 10min, obtains mixture a2;
(3)Attapulgite, defoamer are added into mixture a2,10min is stirred, is placed in after being well mixed ultrasonic in ultrasonic wave
20min, then pigment and stabilizer are added to mixture, it is well mixed, produces described ground finish paint.
Step(1)The graphene of middle addition is graphene aqueous solution, and wherein the concentration of graphene aqueous solution is 0.5g/L.
Step(1)The quality of middle addition water is 20 times of polymer quality.
Step(2)Grain is first crushed to before middle addition Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate
Footpath is less than 300 mesh.
The roof water-proof anti-aging that embodiment 1 ~ 3 is prepared finish paint respectively according to GB/T 19250-2013《It is poly-
Urethane water-repellent paint》Performance detection is carried out, concrete outcome is as shown in the table:
As seen from the above table, the roof water-proof anti-aging for preparing of the present invention finish paint there is preferable waterproof, ageing resistance
Energy and preferably scratch resistance, with preferable application value.
In summary, roof water-proof anti-aging of the present invention ground finish paint, applied to roof ground, not only with compared with
Good waterproof effect, effectively prevent roof leak, the phenomenon of infiltration occurs, also with preferable anti-aging, cracking resistance property
Can so that ground finish paint has preferable stability in use, with extending roof the service life of finish paint, it is to avoid ground finish paint is due to old
The raising for the cost that lacquer painting weight brush is come, so as to greatly reduce use cost, meets existing market caused by changing or ftractureing
Demand, with preferable application value.The preparation technology is simple, mild condition, and preparation process contamination-free is produced, safety
Environmental protection, is adapted to industrialization promotion production.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of roof water-proof anti-aging ground finish paint, it is characterised in that:Include each component of following parts by weight:It is organic-silicon-modified
45 ~ 65 parts of polyurethane, 15 ~ 22 parts of styrene-acrylic emulsion, 10 ~ 20 parts of Phenolic resin powder, 12 ~ 25 parts of epoxy resin, nanometer titanium dioxide
8 ~ 15 parts of silicon, 6 ~ 12 parts of nano titanium oxide, 5 ~ 9 parts of alumina silicate, 1 ~ 3 part of graphene, 7 ~ 15 parts of barium sulfate, attapulgite 3 ~ 8
Part, 2 ~ 6 parts of defoamer, 3 ~ 5 parts of stabilizer, 1 ~ 4 part of pigment.
2. roof water-proof anti-aging according to claim 1 ground finish paint, it is characterised in that:The organic-silicon-modified poly- ammonia
50 parts of ester, 20 parts of styrene-acrylic emulsion, 15 parts of Phenolic resin powder, 20 parts of epoxy resin, 11 parts of nano silicon, nanometer titanium dioxide
8 parts of titanium, 6 parts of alumina silicate, 2 parts of graphene, 10 parts of barium sulfate, 5 parts of attapulgite, 4 parts of defoamer, 4 parts of stabilizer, 3 parts of pigment.
3. roof water-proof anti-aging according to claim 1 ground finish paint, it is characterised in that:The defoamer is poly- diformazan
Radical siloxane or polyoxyethylene polyoxypropylene pentaerythrite ether.
4. roof water-proof anti-aging according to claim 1 ground finish paint, it is characterised in that:The stabilizer is that rare earth is steady
Determine agent.
5. the method for one kind with preparing the roof water-proof anti-aging as described in any one of claim 1 ~ 4 finish paint, its feature exists
In:Comprise the following steps:
(1)Organic silicon modified polyurethane, epoxy resin and graphene are weighed respectively according to proportioning to be added in reactor, are added suitable
Water is measured, under the conditions of 60 ~ 80 DEG C, then 1 ~ 2h of stirring reaction adds styrene-acrylic emulsion, nano silicon into mixture, stir
30 ~ 60min of reaction is mixed, mixture a1 is obtained;
(2)Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate are added into mixture a1, is well mixed, then
It is placed in the cutter that rotating speed is 2000 ~ 3000 turns/min and shears 10 ~ 20min, obtains mixture a2;
(3)Attapulgite, defoamer are added into mixture a2,5 ~ 10min is stirred, is placed in after being well mixed ultrasonic in ultrasonic wave
10 ~ 20min, then pigment and stabilizer are added to mixture, it is well mixed, produces described ground finish paint.
6. roof water-proof anti-aging according to claim 5 finish paint preparation method, it is characterised in that:The step
(1)The graphene of middle addition is graphene aqueous solution, and wherein the concentration of graphene aqueous solution is 0.3 ~ 0.5g/L.
7. roof water-proof anti-aging according to claim 5 finish paint preparation method, it is characterised in that:The step
(1)The quality of middle addition water is 10 ~ 20 times of polymer quality.
8. roof water-proof anti-aging according to claim 5 finish paint preparation method, it is characterised in that:The step
(2)Particle diameter is first crushed to less than 300 mesh before middle addition Phenolic resin powder, nano titanium oxide, alumina silicate and barium sulfate.
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CN108373305A (en) * | 2018-01-17 | 2018-08-07 | 百氏高涂料(苏州)有限公司 | A kind of graphene is modified clear-water concrete/protective coating and technology of preparing |
CN108384387A (en) * | 2018-03-12 | 2018-08-10 | 合肥同佑电子科技有限公司 | A kind of high-temperature resistant coating and preparation method thereof for solar energy equipment |
CN108384388A (en) * | 2018-03-14 | 2018-08-10 | 合肥尚涵装饰工程有限公司 | A kind of environmental protection modelled after an antique is high to glue weather-resistant coating and preparation method thereof |
CN108641556A (en) * | 2018-05-07 | 2018-10-12 | 合肥羿振电力设备有限公司 | A kind of power equipment protective paint of heat-resisting crack resistence |
CN110944416A (en) * | 2019-10-29 | 2020-03-31 | 珠海烯蟀科技有限公司 | Graphene composite slurry, heating coating and preparation method thereof |
CN112282082A (en) * | 2020-10-23 | 2021-01-29 | 安徽四建控股集团有限公司 | Waterproof construction method for building |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN108373305A (en) * | 2018-01-17 | 2018-08-07 | 百氏高涂料(苏州)有限公司 | A kind of graphene is modified clear-water concrete/protective coating and technology of preparing |
CN108384387A (en) * | 2018-03-12 | 2018-08-10 | 合肥同佑电子科技有限公司 | A kind of high-temperature resistant coating and preparation method thereof for solar energy equipment |
CN108384388A (en) * | 2018-03-14 | 2018-08-10 | 合肥尚涵装饰工程有限公司 | A kind of environmental protection modelled after an antique is high to glue weather-resistant coating and preparation method thereof |
CN108641556A (en) * | 2018-05-07 | 2018-10-12 | 合肥羿振电力设备有限公司 | A kind of power equipment protective paint of heat-resisting crack resistence |
CN110944416A (en) * | 2019-10-29 | 2020-03-31 | 珠海烯蟀科技有限公司 | Graphene composite slurry, heating coating and preparation method thereof |
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