CN107216031A - A kind of dark-brown glass and its method for preparing dark-brown glass crisper - Google Patents
A kind of dark-brown glass and its method for preparing dark-brown glass crisper Download PDFInfo
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- CN107216031A CN107216031A CN201710528510.XA CN201710528510A CN107216031A CN 107216031 A CN107216031 A CN 107216031A CN 201710528510 A CN201710528510 A CN 201710528510A CN 107216031 A CN107216031 A CN 107216031A
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- Prior art keywords
- glass
- dark
- brown glass
- brown
- titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of dark-brown glass and its method for preparing dark-brown glass crisper, the primary raw material formula of the tea yellow glass includes ferrous sulfide 0.04 0.3%, manganese powder 0.2 0.7%, titanium dioxide 0.3 0.8%, above-mentioned raw materials are introduced in dark-brown glass formula material can be effectively increased dark-brown glass Fe3+ and S2 ion concentration, so as to increase the red degree of glass, improve the red ratio of dark-brown glass, ferrous sulfide, the titanium dioxide strong absorption ultraviolet of energy, make its absorptivity close to 100%, and titanium dioxide is favorably improved the chemical stability of glass, in addition, the appropriate manganese dioxide that adds can make glass become colorless, gradually increase manganese dioxide consumption can make glass have different colours, the optimal addition of above-mentioned raw materials and its be used for developer reach improve anti-ultraviolet function purpose.
Description
Technical field
The present invention relates to a kind of dark-brown glass and its method for preparing dark-brown glass crisper.
Background technology
The color that colouring agent is formed in high borosilicate glass, is distinguishing, master with the color in soda-lime-silica glass
If because coloring ion ligancy is different, so as to have impact on color and luster, tea yellow glass is a kind of with anti-ultraviolet function
Glass, for packaging for foodstuff, with good fresh-keeping effect.
The content of the invention
It is an object of the invention to provide a kind of dark-brown glass and its method for preparing dark-brown glass crisper, by formula
Ferrous sulfide is introduced in raw material, manganese powder, titanium dioxide reaches the purpose for improving anti-ultraviolet function.
In order to solve the above-mentioned technical problem, the invention provides a kind of dark-brown glass, the primary raw material of the dark-brown glass
Formula includes ferrous sulfide 0.04-0.3%, manganese powder 0.2-0.7%, titanium dioxide 0.3-0.8%.
As the improvement of such scheme, primary raw material formula of the dark-brown glass in terms of mass parts is as follows:
Quartz sand 300-380;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 50-60;Barium carbonate 5-15;Sulphur
Change ferrous iron 0.12-0.9;Manganese powder 0.6-1.4;Titanium dioxide 0.9-2.4.
It should be noted that the primary raw material formula of the dark-brown glass is the various originals for the glass metal that mass parts are 1000
Expect consumption.
As the improvement of such scheme, primary raw material formula of the dark-brown glass in terms of mass parts is as follows:
Quartz sand 240-290;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 65-75;Barium carbonate 20-25;It is pure
Alkali 20-30;Ferrous sulfide 1-1.2;Manganese powder 1.5-2;Titanium dioxide 2.5-3.
It should be noted that the primary raw material formula of the dark-brown glass is the various originals for the glass metal that mass parts are 1000
Expect consumption.
As the improvement of such scheme, the above-mentioned glass batch of different quality is weighed, wherein being converted into SiO respectively2、
AL2O3、Na2O、K2O、B2O2Molar content ratio with BaO is SiO2:AL2O3:Na2O:K2O:B2O2:BaO=1.0: 0.03:
0.05∶0.01∶0.16∶0.01。
Correspondingly, present invention also offers a kind of method for preparing dark-brown glass crisper, comprise the following steps successively:
It is as follows by primary raw material formula of the dark-brown glass in terms of mass parts:
Quartz sand 300-380;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 50-60;Barium carbonate 5-15;Sulphur
Change ferrous iron 0.12-0.9;Manganese powder 0.6-1.4;Titanium dioxide 0.9-2.4;
The dispensing is entered into melting furnaces, is founded under conditions of temperature is 900-1480 degree and obtains glass metal;
Temperature is placed on to the crisper punching press of the rotary table driven by motor in the glass metal of 950-1100 degree
Glass preservation box is formed after carrying out punch forming by flexible staking punch again in mould;
Glass preservation box Jing Guo forming processes is made annealing treatment in 600-650 degree, dark-brown glass crisper is obtained.
Present invention also offers another method for preparing dark-brown glass crisper, comprise the following steps successively:
It is as follows by primary raw material formula of the dark-brown glass in terms of mass parts:
Quartz sand 240-290;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 65-75;Barium carbonate 20-25;It is pure
Alkali 20-30;Ferrous sulfide 1-1.2;Manganese powder 1.5-2;Titanium dioxide 2.5-3;
The dispensing is entered into melting furnaces, is founded under conditions of temperature is 900-1480 degree and obtains glass metal;
Temperature is placed on to the crisper stamping die of the rotary table driven by motor in the glass metal of 750-900 degree
Glass preservation box is formed after carrying out punch forming by flexible staking punch again in tool;
Glass preservation box Jing Guo forming processes is made annealing treatment in 550-590 degree, dark-brown glass crisper is obtained.
Implement the embodiment of the present invention, have the advantages that:
The present invention relates to a kind of dark-brown glass and its method for preparing dark-brown glass crisper, vulcanization is introduced in formula material sub-
Iron, manganese powder, titanium dioxide finds optimal addition and its proportioning as developer, makes its display dark brown, and titanium dioxide is helped
In the chemical stability for improving glass, the purpose for the dark brown ratio for improving dark-brown glass is reached, it is specific as follows:
Ferrous sulfide, titanium dioxide are introduced in dark-brown glass formula material can be effectively increased dark-brown glass Fe3+ and S2- ion
Content, so as to increase the red degree of glass, improves the red ratio of dark-brown glass, the suction that ferrous sulfide, titanium dioxide can be strong
Ultraviolet is received, makes its absorptivity close to 100%, and titanium dioxide is favorably improved the chemical stability of glass.
The main component of manganese powder is manganese dioxide, and manganese dioxide has good with being good colouring agent in glass
Effect of painting fruit, because manganese dioxide has multiple crystal habits, chemical formula can be write as MnO2-x(H2O) n, wherein x be situated between 0 to
Between 0.5, and n can be more than 0.The manganese dioxide precipitate thing of coffee color is very dry and very active.Placing manganese dioxide in right amount can make
Glass becomes colorless, and gradually increase manganese dioxide consumption can make glass have different colours.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, present invention work is further retouched in detail below
State.
The embodiments of the invention provide a kind of dark-brown glass, its primary raw material formula includes ferrous sulfide 0.04-0.3%, manganese
Powder 0.2-0.7%, titanium dioxide 0.3-0.8%.
Preferably, primary raw material formula of the dark-brown glass in terms of mass parts is as follows:
Quartz sand 300-380;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 50-60;Barium carbonate 5-15;Sulphur
Change ferrous iron 0.12-0.9;Manganese powder 0.6-1.4;Titanium dioxide 0.9-2.4.
It should be noted that the primary raw material formula of the dark-brown glass is the various originals for the glass metal that mass parts are 1000
Expect consumption.
Preferably, primary raw material formula of the dark-brown glass in terms of mass parts is as follows:
Quartz sand 240-290;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 65-75;Barium carbonate 20-25;It is pure
Alkali 20-30;Ferrous sulfide 1-1.2;Manganese powder 1.5-2;Titanium dioxide 2.5-3.
It should be noted that the primary raw material formula of the dark-brown glass is the various originals for the glass metal that mass parts are 1000
Expect consumption.
Preferably, the quartz sand of different quality, aluminium hydroxide, borax, boric acid, potassium carbonate, barium carbonate glass batch are weighed
Material, wherein being converted into SiO respectively2、AL2O3、Na2O、K2O、B2O2Molar content ratio with BaO is SiO2:AL2O3:Na2O:
K2O:B2O2:BaO=1.0: 0.03: 0.05: 0.01: 0.16: 0.01.
Introduce ferrous sulfide in formula material the present invention relates to a kind of dark-brown glass, manganese powder, titanium dioxide as developer,
Optimal addition and its proportioning is found, makes its display dark brown, and titanium dioxide is favorably improved the chemical stability of glass, reaches
It is specific as follows to the purpose for the dark brown ratio for improving dark-brown glass:
Ferrous sulfide, titanium dioxide are introduced in dark-brown glass formula material can be effectively increased dark-brown glass Fe3+ and S2- ion
Content, so as to increase the red degree of glass, improves the red ratio of dark-brown glass, the suction that ferrous sulfide, titanium dioxide can be strong
Ultraviolet is received, makes its absorptivity close to 100%, and titanium dioxide is favorably improved the chemical stability of glass;Manganese powder it is main into
It is divided into manganese dioxide, manganese dioxide has good colouring effect fruit, because titanium dioxide with being good colouring agent in glass
Manganese has multiple crystal habits, and chemical formula can be write as MnO2-x(H2O) n, wherein x are situated between 0 to 0.5, and n can be more than 0.
The manganese dioxide precipitate thing of coffee color is very dry and very active.Placing manganese dioxide in right amount can make glass become colorless, and gradually increase
Manganese dioxide consumption can make glass have different colours;So as to which by introducing ferrous sulfide, manganese powder, titanium dioxide is used as colour developing
Agent reaches the purpose for improving anti-ultraviolet function.
The embodiment of the present invention additionally provides a kind of method for preparing dark-brown glass crisper, comprises the following steps successively:
It is as follows by primary raw material formula of the dark-brown glass in terms of mass parts:
Quartz sand 300-380;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 50-60;Barium carbonate 5-15;Sulphur
Change ferrous iron 0.12-0.9;Manganese powder 0.6-1.4;Titanium dioxide 0.9-2.4;
The dispensing is entered into melting furnaces, is founded under conditions of temperature is 900-1480 degree and obtains glass metal;
Temperature is placed on to the crisper punching press of the rotary table driven by motor in the glass metal of 950-1100 degree
Glass preservation box is formed after carrying out punch forming by flexible staking punch again in mould;
Glass preservation box Jing Guo forming processes is made annealing treatment in 600-650 degree, dark-brown glass crisper is obtained.
The embodiment of the present invention additionally provides another method for preparing dark-brown glass crisper, comprises the following steps successively:
It is as follows by primary raw material formula of the dark-brown glass in terms of mass parts:
Quartz sand 240-290;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 65-75;Barium carbonate 20-25;It is pure
Alkali 20-30;Ferrous sulfide 1-1.2;Manganese powder 1.5-2;Titanium dioxide 2.5-3;
The dispensing is entered into melting furnaces, is founded under conditions of temperature is 900-1480 degree and obtains glass metal;
Temperature is placed on to the crisper stamping die of the rotary table driven by motor in the glass metal of 750-900 degree
Glass preservation box is formed after carrying out punch forming by flexible staking punch again in tool;
Glass preservation box Jing Guo forming processes is made annealing treatment in 550-590 degree, dark-brown glass crisper is obtained.
Claims (6)
1. a kind of dark-brown glass, it is characterised in that:The primary raw material formula of the tea yellow glass includes ferrous sulfide 0.04-
0.3%, manganese powder 0.2-0.7%, titanium dioxide 0.3-0.8%.
2. dark-brown glass according to claim 1, it is characterised in that:Its in terms of mass parts primary raw material formula it is as follows:
Quartz sand 300-380;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 50-60;Barium carbonate 5-15;Sulphur
Change ferrous iron 0.12-0.9;Manganese powder 0.6-1.4;Titanium dioxide 0.9-2.4.
3. dark-brown glass according to claim 1, it is characterised in that:Its in terms of mass parts primary raw material formula it is as follows:
Quartz sand 240-290;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 65-75;Barium carbonate 20-25;It is pure
Alkali 20-30;Ferrous sulfide 1-1.2;Manganese powder 1.5-2;Titanium dioxide 2.5-3.
4. the dark-brown glass according to Claims 2 or 3, it is characterised in that:The above-mentioned glass batch of different quality is weighed,
SiO is wherein converted into respectively2、AL2O3、Na2O、K2O、B2O2Molar content ratio with BaO is SiO2:AL2O3:Na2O:K2O:
B2O2:BaO=1.0: 0.03: 0.05: 0.01: 0.16: 0.01.
5. a kind of method for preparing dark-brown glass crisper, it is characterised in that comprise the following steps successively:
It is as follows by primary raw material formula of the tea yellow glass in terms of mass parts:
Quartz sand 300-380;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 50-60;Barium carbonate 5-15;Sulphur
Change ferrous iron 0.12-0.9;Manganese powder 0.6-1.4;Titanium dioxide 0.9-2.4;
The dispensing is entered into melting furnaces, is founded under conditions of temperature is 900-1480 degree and obtains glass metal;
Temperature is placed on to the crisper punching press of the rotary table driven by motor in the glass metal of 950-1100 degree
Glass preservation box is formed after carrying out punch forming by flexible staking punch again in mould;
Glass preservation box Jing Guo forming processes is made annealing treatment in 600-650 degree, dark-brown glass crisper is obtained.
6. a kind of method for preparing dark-brown glass crisper, it is characterised in that comprise the following steps successively:
It is as follows by primary raw material formula of the dark-brown glass in terms of mass parts:
Quartz sand 240-290;Aluminium hydroxide 10-20;Borax 18-25;Boric acid 5-10;Potassium carbonate 65-75;Barium carbonate 20-25;It is pure
Alkali 20-30;Ferrous sulfide 1-1.2;Manganese powder 1.5-2;Titanium dioxide 2.5-3;
The dispensing is entered into melting furnaces, is founded under conditions of temperature is 900-1480 degree and obtains glass metal;
Temperature is placed on to the crisper stamping die of the rotary table driven by motor in the glass metal of 750-900 degree
Glass preservation box is formed after carrying out punch forming by flexible staking punch again in tool;
Glass preservation box Jing Guo forming processes is made annealing treatment in 550-590 degree, dark-brown glass crisper is obtained.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108558206A (en) * | 2018-05-23 | 2018-09-21 | 江苏宝恒新材料科技有限公司 | The preparation method of the one high borosilicate heat-proof glass of plant tea yellow |
CN109431321A (en) * | 2018-12-27 | 2019-03-08 | 山东乐和家日用品有限公司 | Heat-resisting soy bean milk making machine lid of antibacterial and preparation method thereof |
CN109748504A (en) * | 2018-12-27 | 2019-05-14 | 山东乐和家日用品有限公司 | Completely separate crisper and preparation method thereof |
CN111792840A (en) * | 2020-07-22 | 2020-10-20 | 山东乐和家日用品有限公司 | Dark brown glass and method for preparing dark brown glass preservation box by using dark brown glass |
CN113233761A (en) * | 2021-05-11 | 2021-08-10 | 山东乐和家日用品有限公司 | Glass capable of improving thermal shock resistance and preparation method thereof |
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US5639701A (en) * | 1996-01-09 | 1997-06-17 | Corning Incorporated | Permanent tint photochromic glasses |
CN103508671A (en) * | 2012-06-26 | 2014-01-15 | 广东华兴玻璃有限公司 | Brown glass and preparation method thereof |
CN105036553A (en) * | 2015-08-04 | 2015-11-11 | 沧州四星玻璃股份有限公司 | Medicinal neutral borosilicate glass tube and preparing method thereof |
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2017
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US5639701A (en) * | 1996-01-09 | 1997-06-17 | Corning Incorporated | Permanent tint photochromic glasses |
CN103508671A (en) * | 2012-06-26 | 2014-01-15 | 广东华兴玻璃有限公司 | Brown glass and preparation method thereof |
CN105036553A (en) * | 2015-08-04 | 2015-11-11 | 沧州四星玻璃股份有限公司 | Medicinal neutral borosilicate glass tube and preparing method thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108558206A (en) * | 2018-05-23 | 2018-09-21 | 江苏宝恒新材料科技有限公司 | The preparation method of the one high borosilicate heat-proof glass of plant tea yellow |
CN109431321A (en) * | 2018-12-27 | 2019-03-08 | 山东乐和家日用品有限公司 | Heat-resisting soy bean milk making machine lid of antibacterial and preparation method thereof |
CN109748504A (en) * | 2018-12-27 | 2019-05-14 | 山东乐和家日用品有限公司 | Completely separate crisper and preparation method thereof |
CN111792840A (en) * | 2020-07-22 | 2020-10-20 | 山东乐和家日用品有限公司 | Dark brown glass and method for preparing dark brown glass preservation box by using dark brown glass |
CN113233761A (en) * | 2021-05-11 | 2021-08-10 | 山东乐和家日用品有限公司 | Glass capable of improving thermal shock resistance and preparation method thereof |
CN113233761B (en) * | 2021-05-11 | 2023-07-21 | 山东乐和家日用品有限公司 | Glass capable of improving thermal shock resistance and preparation method thereof |
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