CN107214292A - A kind of moulding sand for casting and preparation method thereof - Google Patents

A kind of moulding sand for casting and preparation method thereof Download PDF

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Publication number
CN107214292A
CN107214292A CN201710510154.9A CN201710510154A CN107214292A CN 107214292 A CN107214292 A CN 107214292A CN 201710510154 A CN201710510154 A CN 201710510154A CN 107214292 A CN107214292 A CN 107214292A
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CN
China
Prior art keywords
parts
casting
molding sand
starch
coupling agent
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CN201710510154.9A
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Chinese (zh)
Inventor
杨胜
谢枫
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ANHUI HUAFEI MACHINERY CASTING AND FORGING Co Ltd
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ANHUI HUAFEI MACHINERY CASTING AND FORGING Co Ltd
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Priority to CN201710510154.9A priority Critical patent/CN107214292A/en
Publication of CN107214292A publication Critical patent/CN107214292A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C1/00Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/02Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C1/00Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/16Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
    • B22C1/167Mixtures of inorganic and organic binding agents

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

The invention discloses a kind of moulding sand for casting, belong to molding sand technical field, include the raw material of following parts by weight:80 90 parts of silica flour, 20 26 parts of bentonite, 15 17 parts of glass-cermic powder, 12 14 parts of flyash, 79 parts of steel fibre, 14 18 parts of glass fibre, 10 15 parts of furane resins, 47 parts of inositol hexaphosphate, 12 parts of silicone oil, 46 parts of starch, 12 parts of coupling agent, 24 parts of curing agent, 15 18 parts of water;The invention also discloses a kind of preparation method of moulding sand for casting;Good mechanical property of the present invention, with preferably heat-resisting ability, heat endurance is good.

Description

Molding sand for casting and preparation method thereof
Technical Field
The invention relates to the technical field of molding sand, and particularly relates to molding sand for casting and a preparation method thereof.
Background
Molding sand is used as a molding material in casting. The molding sand is generally prepared by mixing molding materials such as raw sand for casting, a molding sand binder, auxiliary additives and the like according to a certain proportion. The molding sand can be classified into clay sand, water glass sand, cement sand, resin sand, etc. according to the binder used. Clay sand, sodium silicate sand and resin sand are used most.
The function of the molding sand in the casting production is very important, and casting waste products caused by poor quality of the molding sand account for about 30-50% of total casting waste products. The general requirements for molding sand are: the material has high strength and heat stability to bear various external forces and high temperature. Good fluidity, namely the capability of sand grains to move mutually under the action of external force or gravity. And thirdly, certain plasticity, namely the ability of the molding sand to deform under the action of external force and maintain the given shape after the external force is removed. And fourthly, better air permeability, namely the capability of the molding sand pores to permeate gas. High collapsibility, also called sand-out property, i.e. whether the molding sand is easy to be destroyed and removed from the casting after the casting is solidified.
But the prior molding sand has limited high temperature resistance, which causes insufficient thermal stability and poor quality; and the current casting field develops rapidly, and the requirements on the performances of steel castings and iron castings are higher, so that the performances of the molding sand are required to be further improved.
In patent document CN104057018A, a molding sand for casting is disclosed, which is made from the following raw materials by weight: 250-270 parts of silica sand powder, 40-50 parts of fly ash, 9-12 parts of aluminum hydroxide, 40-45 parts of rice bran, 20-30 parts of iron slag, 20-30 parts of calcium carbonate powder, 1-2 parts of polycarboxylic acid water reducing agent, 1-2 parts of polyacrylamide, 1-2 parts of tung oil, 45-50 parts of aluminum silicate, 30-40 parts of corn straw powder, 22-30 parts of bamboo charcoal, 30-40 parts of clay, 14-18 parts of corn flour, 3-4 parts of silane coupling agent KH-550, and a proper amount of water. The fly ash is used, so that the fineness of the molding sand is increased, the molding is easy, and the energy is saved; the straw powder, the corn flour and the like are used, so that the air permeability and the high-temperature collapsibility are improved; the stone powder is calcined and is combined with the addition of the organic adhesive, so that the plasticity, the dispersibility and the air permeability are enhanced. The invention is easy to shape and make core, solves the problems of shrinkage cavity and shrinkage porosity of the casting to reach more than 91 percent, and improves the finished product rate of the casting, but the invention has insufficient high temperature resistance and is difficult to ensure the thermal stability of the molding sand.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides molding sand for casting and a preparation method thereof, which have the advantages of good mechanical property, better high-temperature resistance and good thermal stability.
The invention provides molding sand for casting, which comprises the following raw materials in parts by weight:
80-90 parts of silica sand powder, 20-26 parts of bentonite, 15-17 parts of cast stone powder, 12-14 parts of fly ash, 7-9 parts of steel fiber, 14-18 parts of glass fiber, 10-15 parts of furan resin, 4-7 parts of inositol hexaphosphate, 1-2 parts of silicone oil, 4-6 parts of starch, 1-2 parts of coupling agent, 2-4 parts of hardening agent and 15-18 parts of water.
Preferably, the mesh number of the silica sand powder is 100-200 meshes, and the mesh number of the cast stone powder is 300-400 meshes; the bentonite is organic bentonite.
Preferably, the steel fibers have a length of 1 to 2mm and a diameter of 0.5 to 1 mm; the glass fiber has a length of 0.5-1mm and a diameter of 0.1-0.5 mm.
Preferably, the starch is one or a mixture of more than two of mung bean starch, cassava starch, sweet potato starch, potato starch and wheat starch.
Preferably, the coupling agent is a mixture of a silane coupling agent and a zirconium-based coupling agent in a weight ratio of 4: 1.
Preferably, the hardener is a mixture of an aliphatic hardener and an aromatic hardener, the weight ratio between the two being 1: 2.
The invention also provides a preparation method of the molding sand for casting, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding silica sand powder, bentonite, cast stone powder, fly ash, steel fiber and glass fiber into a stirrer, mixing for 10-15min, then adding furan resin, phytic acid ester, silicone oil, starch, a coupling agent, a hardening agent and water, and mixing for 20-30min to obtain a mixture;
(3) calcining the mixture in the step (2) for 2h, and controlling the temperature at 1300-1400 ℃;
(4) and cooling, crushing and screening to obtain the molding sand.
Wherein,
the stirring speed of the stirrer in the step (2) is 400-600 r/min.
In the step (2), the temperature is controlled to be 40-50 ℃.
The molding sand for casting and the preparation method thereof have the advantages of good mechanical property, better high-temperature resistance, good thermal stability and simple preparation process, and the specific beneficial effects are as follows:
(1) the cast stone powder can enhance the wear resistance, acid and alkali resistance of the molding sand; the steel fiber can greatly improve the physical strength of the molding sand; the glass fiber can improve the impact strength and toughness of the molding sand and also improve the heat resistance;
(2) the furan resin can improve the corrosion resistance and the heat resistance of the molding sand, and the inositol hexaphosphate, the starch and the bentonite can only bond the raw materials; the coupling agent can promote the adhesion between different substances and can improve the rheological property;
(3) the preparation method is simple, the molding sand can be stably prepared, and the silica sand powder and the cast stone powder have different meshes and can be effectively mixed into a whole.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Example 1
The molding sand for casting of the embodiment comprises the following raw materials in parts by weight:
80 parts of silica sand powder, 20 parts of bentonite, 15 parts of cast stone powder, 12 parts of fly ash, 7 parts of steel fiber, 14 parts of glass fiber, 10 parts of furan resin, 4 parts of inositol hexaphosphate, 1 part of silicone oil, 4 parts of starch, 1 part of coupling agent, 2 parts of hardening agent and 15 parts of water.
In this embodiment, the mesh number of the silica sand powder is 100 meshes, and the mesh number of the cast stone powder is 300 meshes; the bentonite is organic bentonite.
In this example, the steel fibers had a length of 1mm and a diameter of 0.5 mm; the glass fibers had a length of 0.5mm and a diameter of 0.1 mm.
In this example, the starch is a mixture of mung bean starch, tapioca starch, sweet potato starch, and wheat starch.
In this example, the coupling agent is a mixture of a silane coupling agent and a zirconium coupling agent, and the weight ratio of the silane coupling agent to the zirconium coupling agent is 4: 1.
In this example, the hardener is a mixture of an aliphatic hardener and an aromatic hardener, and the weight ratio of the aliphatic hardener to the aromatic hardener is 1: 2.
The embodiment also provides a preparation method of the molding sand for casting, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding silica sand powder, bentonite, cast stone powder, fly ash, steel fiber and glass fiber into a stirrer, mixing for 10min, then adding furan resin, phytic acid ester, silicone oil, starch, a coupling agent, a hardening agent and water, and mixing for 20min to obtain a mixture;
(3) calcining the mixture obtained in the step (2) for 2 hours, and controlling the temperature at 1300 ℃;
(4) and cooling, crushing and screening to obtain the molding sand.
Wherein,
the stirring speed of the stirrer in the step (2) is 400 r/min.
In the step (2), the temperature is controlled at 40 ℃.
Example 2
The molding sand for casting of the embodiment comprises the following raw materials in parts by weight:
85 parts of silica sand powder, 24 parts of bentonite, 16 parts of cast stone powder, 13 parts of fly ash, 8 parts of steel fiber, 16 parts of glass fiber, 13 parts of furan resin, 5 parts of inositol hexaphosphate, 1.5 parts of silicone oil, 5 parts of starch, 1.5 parts of coupling agent, 3 parts of hardening agent and 17 parts of water.
In this example, the mesh number of the silica sand powder is 200 meshes, and the mesh number of the cast stone powder is 300 meshes; the bentonite is organic bentonite.
In this example, the steel fibers had a length of 1.5mm and a diameter of 0.8 mm; the glass fibers had a length of 0.8mm and a diameter of 0.3 mm.
In this example, the starch is a mixture of mung bean starch, tapioca starch, sweet potato starch, and wheat starch.
In this example, the coupling agent is a mixture of a silane coupling agent and a zirconium coupling agent, and the weight ratio of the silane coupling agent to the zirconium coupling agent is 4: 1.
In this example, the hardener is a mixture of an aliphatic hardener and an aromatic hardener, and the weight ratio of the aliphatic hardener to the aromatic hardener is 1: 2.
The embodiment also provides a preparation method of the molding sand for casting, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding silica sand powder, bentonite, cast stone powder, fly ash, steel fiber and glass fiber into a stirrer, mixing for 13min, then adding furan resin, phytic acid ester, silicone oil, starch, a coupling agent, a hardening agent and water, and mixing for 25min to obtain a mixture;
(3) calcining the mixture obtained in the step (2) for 2 hours, and controlling the temperature to 1350 ℃;
(4) and cooling, crushing and screening to obtain the molding sand.
Wherein,
the stirring speed of the stirrer in the step (2) is 500 r/min.
In the step (2), the temperature is controlled at 45 ℃.
Example 3
The molding sand for casting of the embodiment comprises the following raw materials in parts by weight:
90 parts of silica sand powder, 26 parts of bentonite, 17 parts of cast stone powder, 14 parts of fly ash, 9 parts of steel fiber, 18 parts of glass fiber, 15 parts of furan resin, 7 parts of inositol hexaphosphate, 2 parts of silicone oil, 6 parts of starch, 2 parts of coupling agent, 4 parts of hardening agent and 18 parts of water.
In this example, the mesh number of the silica sand powder is 200 meshes, and the mesh number of the cast stone powder is 400 meshes; the bentonite is organic bentonite.
In this example, the length of the steel fiber is 2mm, and the diameter is 1 mm; the glass fibers had a length of 1mm and a diameter of 0.5 mm.
In this example, the starch is a mixture of mung bean starch, tapioca starch, sweet potato starch, and wheat starch.
In this example, the coupling agent is a mixture of a silane coupling agent and a zirconium coupling agent, and the weight ratio of the silane coupling agent to the zirconium coupling agent is 4: 1.
In this example, the hardener is a mixture of an aliphatic hardener and an aromatic hardener, and the weight ratio of the aliphatic hardener to the aromatic hardener is 1: 2.
The embodiment also provides a preparation method of the molding sand for casting, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding silica sand powder, bentonite, cast stone powder, fly ash, steel fiber and glass fiber into a stirrer, mixing for 15min, then adding furan resin, phytic acid ester, silicone oil, starch, a coupling agent, a hardening agent and water, and mixing for 30min to obtain a mixture;
(3) calcining the mixture in the step (2) for 2 hours, and controlling the temperature at 1400 ℃;
(4) and cooling, crushing and screening to obtain the molding sand.
Wherein,
the stirring speed of the stirrer in the step (2) is 600 r/min.
In the step (2), the temperature is controlled at 50 ℃.
The test results for examples 1-3 are as follows:
the high-temperature compressive strength is more than 1Mpa, the gas evolution is less than 13ml/g, the heat-resisting time is more than 6min, the room-temperature tensile strength is more than 0.1Mpa, and the hot tensile strength is more than 0.02 Mpa; the compactability was 37% and the air permeability was 117.
The above description is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.

Claims (9)

1. A molding sand for casting, characterized in that: the feed comprises the following raw materials in parts by weight:
80-90 parts of silica sand powder, 20-26 parts of bentonite, 15-17 parts of cast stone powder, 12-14 parts of fly ash, 7-9 parts of steel fiber, 14-18 parts of glass fiber, 10-15 parts of furan resin, 4-7 parts of inositol hexaphosphate, 1-2 parts of silicone oil, 4-6 parts of starch, 1-2 parts of coupling agent, 2-4 parts of hardening agent and 15-18 parts of water.
2. The molding sand for casting as set forth in claim 1, wherein: the mesh number of the silica sand powder is 100-200 meshes, and the mesh number of the cast stone powder is 300-400 meshes; the bentonite is organic bentonite.
3. The molding sand for casting as set forth in claim 1, wherein: the length of the steel fiber is 1-2mm, and the diameter is 0.5-1 mm; the glass fiber has a length of 0.5-1mm and a diameter of 0.1-0.5 mm.
4. The molding sand for casting as set forth in claim 1, wherein: one or more of starch mung bean starch, cassava starch, sweet potato starch, potato starch and wheat starch.
5. The molding sand for casting as set forth in claim 1, wherein: the coupling agent is a mixture of a silane coupling agent and a zirconium coupling agent, and the weight ratio of the silane coupling agent to the zirconium coupling agent is 4: 1.
6. The molding sand for casting as set forth in claim 1, wherein: the hardener is a mixture of an aliphatic hardener and an aromatic hardener, and the weight ratio of the aliphatic hardener to the aromatic hardener is 1: 2.
7. The method of producing molding sand for casting according to any one of claims 1 to 6, wherein: the method comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding silica sand powder, bentonite, cast stone powder, fly ash, steel fiber and glass fiber into a stirrer, mixing for 10-15min, then adding furan resin, phytic acid ester, silicone oil, starch, a coupling agent, a hardening agent and water, and mixing for 20-30min to obtain a mixture;
(3) calcining the mixture in the step (2) for 2h, and controlling the temperature at 1300-1400 ℃;
(4) and cooling, crushing and screening to obtain the molding sand.
8. The method of producing molding sand for casting according to claim 7, characterized in that: the stirring speed of the stirrer in the step (2) is 400-600 r/min.
9. The method of producing molding sand for casting according to claim 7, characterized in that: in the step (2), the temperature is controlled to be 40-50 ℃.
CN201710510154.9A 2017-06-28 2017-06-28 A kind of moulding sand for casting and preparation method thereof Pending CN107214292A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108568492A (en) * 2018-05-11 2018-09-25 佛山市高明利钢精密铸造有限公司 A kind of preparation method of the special molding sand of hot investment casting
CN108568493A (en) * 2018-05-11 2018-09-25 佛山市高明利钢精密铸造有限公司 A kind of preparation method of moulding sand for casting
CN109175214A (en) * 2018-10-19 2019-01-11 含山县兴达球墨铸铁厂 A kind of casting rapid-curing cutback sand formulation

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Publication number Priority date Publication date Assignee Title
CN102728776A (en) * 2012-06-08 2012-10-17 繁昌县琦祥铸造厂 Low-cost environment-friendly molding sand and preparation method thereof
CN102814460A (en) * 2012-08-20 2012-12-12 合肥江淮铸造有限责任公司 Casting molding sand and preparation method thereof
CN103521683A (en) * 2013-10-16 2014-01-22 合肥市田源精铸有限公司 Anti-sticky calcium carbonate molding sand and preparation method thereof
CN104057018A (en) * 2014-05-28 2014-09-24 安徽鑫润新型材料有限公司 Casting molding sand and preparation method thereof
CN104084520A (en) * 2014-06-25 2014-10-08 芜湖国鼎机械制造有限公司 Casting sand, mold core and preparation method thereof
CN104226888A (en) * 2014-08-29 2014-12-24 吴江市液铸液压件铸造有限公司 Easily-scattered precoated sand and preparation method thereof
CN104690212A (en) * 2015-02-04 2015-06-10 繁昌县金科机电科技有限公司 Pre-coated sand with uniform shell layer and unshelled performance and preparation method of pre-coated sand
CN106734854A (en) * 2016-12-30 2017-05-31 丁玉琴 A kind of method that compound resin prepares high temperature resistant cracking resistance precoated sand

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102728776A (en) * 2012-06-08 2012-10-17 繁昌县琦祥铸造厂 Low-cost environment-friendly molding sand and preparation method thereof
CN102814460A (en) * 2012-08-20 2012-12-12 合肥江淮铸造有限责任公司 Casting molding sand and preparation method thereof
CN103521683A (en) * 2013-10-16 2014-01-22 合肥市田源精铸有限公司 Anti-sticky calcium carbonate molding sand and preparation method thereof
CN104057018A (en) * 2014-05-28 2014-09-24 安徽鑫润新型材料有限公司 Casting molding sand and preparation method thereof
CN104084520A (en) * 2014-06-25 2014-10-08 芜湖国鼎机械制造有限公司 Casting sand, mold core and preparation method thereof
CN104226888A (en) * 2014-08-29 2014-12-24 吴江市液铸液压件铸造有限公司 Easily-scattered precoated sand and preparation method thereof
CN104690212A (en) * 2015-02-04 2015-06-10 繁昌县金科机电科技有限公司 Pre-coated sand with uniform shell layer and unshelled performance and preparation method of pre-coated sand
CN106734854A (en) * 2016-12-30 2017-05-31 丁玉琴 A kind of method that compound resin prepares high temperature resistant cracking resistance precoated sand

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108568492A (en) * 2018-05-11 2018-09-25 佛山市高明利钢精密铸造有限公司 A kind of preparation method of the special molding sand of hot investment casting
CN108568493A (en) * 2018-05-11 2018-09-25 佛山市高明利钢精密铸造有限公司 A kind of preparation method of moulding sand for casting
CN109175214A (en) * 2018-10-19 2019-01-11 含山县兴达球墨铸铁厂 A kind of casting rapid-curing cutback sand formulation

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Application publication date: 20170929