CN107214061A - One kind utilizes nano-TiO2Processing method of the film to blade - Google Patents

One kind utilizes nano-TiO2Processing method of the film to blade Download PDF

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Publication number
CN107214061A
CN107214061A CN201710477095.XA CN201710477095A CN107214061A CN 107214061 A CN107214061 A CN 107214061A CN 201710477095 A CN201710477095 A CN 201710477095A CN 107214061 A CN107214061 A CN 107214061A
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China
Prior art keywords
blade
tio
film
processing method
nano
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Granted
Application number
CN201710477095.XA
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Chinese (zh)
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CN107214061B (en
Inventor
刘子源
李其胜
王丽佳
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China University of Geosciences
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China University of Geosciences
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Priority to CN201710477095.XA priority Critical patent/CN107214061B/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/002—Pretreatement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218—Pretreatment, e.g. heating the substrate

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)

Abstract

Nano-TiO is utilized the invention discloses one kind2Film is to the processing method of blade, including leaf vegetables plantation, collection, leaf is carried out anti-dry, concora crush moisturizing, flatiron setting, cut study for a second time courses one has flunked shape, dispute over trifles lacing wire and coating problems.Processing method of the present invention is simple, and the various pigment of blade after processing easily in leaf mixing on chip and disperse, and is effectively ensured and scribbles uniformly, degree of staining and transparency are high, preserved suitable for long-time, the base-material drawn a picture is inhibited from yellowing and loss of gloss, can effectively keep whiteness, anti-grinded hardness index is good, tone and glossiness can be effectively kept, is bitten moreover, being difficult to be gnawed by worm mosquito, air can be purified, is put suitable for house.

Description

One kind utilizes nano-TiO2Processing method of the film to blade
Technical field
Nano-TiO is utilized the present invention relates to material processing field, more particularly to one kind2Processing method of the film to blade.
Background technology
It is, using leaf as carrier, to be painted in the above that leaf, which is drawn, but due to leaf not easy coloring, and transparency is not high, Therefore, existing leaf is drawn generally to exist and is difficult to draw a picture, and various pigment are difficult in leaf mixing on chip and scattered, scribbles uneven, Colourity and transparency be not high, and the leaf preserved for a long time is drawn, and the base-material for drawing a picture easily turns yellow and loss of gloss, it is impossible to keep white Degree, anti-grinded hardness index is poor, it is impossible to keep tone and glossiness.
The content of the invention
In view of this, scribbled uniformly The embodiment provides one kind, degree of staining and transparency are high, leaf can be kept to draw The utilization nano-TiO of whiteness, tone and glossiness2Processing method of the film to blade.
Embodiments of the invention provide one kind and utilize nano-TiO2Film comprises the following steps to the processing method of blade：
S1, the leaf vegetables drawn a picture will be ready to use in it is planted near the mountain and by the river, few sun, and the place of wind sheltering；
S2, gather frivolous, roomy, color it is refined, flesh is rich, natural, complete blade；
Blade is wrapped up stand-by by S3, the method educated with anti-dry paper, by the moisture control of blade in 60-80%；
S4, continuous flat is carried out to blade to leveling blade, be 20- by smooth blade aeration-drying to moisture content 30%, and the moisture content of blade is maintained at 20-30% using NMF sodium carboxymethylcellulose or glycerine；
S5, blade shaped by ironing technology, the moisture content of setting rear blade is 15-20%, ironing temperature 150-170 DEG C, ironing-time 2s, ironing press 39.2N/cm2；
S6, the shape of blade according to needed for being drawn leaf cut studying for a second time courses one has flunked shape；
S7, lacing wire of being disputed over trifles to vein progress prominent on blade；
S8, the coated with nano level TiO on blade2Film, that is, be made the blade for drawing a picture.
Further, in the step S8, nanoscale TiO2Film is obtained by the following method：
S8.1, to TiO2Ground and be classified, by TiO2Corase particles is processed as the TiO with pigment performance2Fine particle；
S8.2, the TiO for obtaining step S8.12Fine particle is surface-treated；
S8.3, by the TiO after surface treatment2Airslide disintegrating mill ultramicro grinding is used, that is, is obtained for being coated on blade Nanoscale TiO2Film.
Further, in the step S8.2, surface treatment is concretely comprised the following steps TiO2Fine particle is processed as TiO2Aqueous suspension Body, and add inorganic compound cladding TiO2；Again to the TiO coated by inorganic compound2Middle addition inorganic agent.
Further, the inorganic compound is aluminium, silicon, Ti-inorganic compound.
Further, the blade selects leaf of Japanese banana.
Compared with prior art, the invention has the advantages that：Processing method of the present invention is simple, the blade after processing Various pigment easily in leaf mixing on chip and disperse, and are effectively ensured and scribble uniform, degree of staining and transparency height, it is adaptable to protect for a long time Deposit, the base-material drawn a picture is inhibited from yellowing and loss of gloss, can effectively keep whiteness, anti-grinded hardness index is good, can effectively keep tone and gloss Degree, bites moreover, being difficult to be gnawed by worm mosquito, can purify air, is put suitable for house.
Brief description of the drawings
Fig. 1 is that one kind of the present invention utilizes nano-TiO2A flow chart of the film to the processing method of blade.
Fig. 2 is a flow chart of step S8 in Fig. 1.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with accompanying drawing to embodiment party of the present invention Formula is further described.
Fig. 1 and Fig. 2 are refer to, nano-TiO is utilized The embodiment provides one kind2Processing side of the film to blade Method, comprises the following steps：
S1, the leaf vegetables drawn a picture will be ready to use in it is planted near the mountain and by the river, few sun, and the place of wind sheltering；
S2, gather frivolous, roomy, color it is refined, flesh is rich, natural, complete blade；Blade preferentially selects leaf of Japanese banana；
Blade is wrapped up stand-by by S3, the method educated with anti-dry paper, by the moisture control of blade in 60-80%；
S4, continuous flat is carried out to blade to leveling blade, be 20- by smooth blade aeration-drying to moisture content 30%, and the moisture content of blade is maintained at 20-30% using NMF sodium carboxymethylcellulose or glycerine；
S5, blade shaped by ironing technology, the moisture content of setting rear blade is 15-20%, ironing temperature 150-170 DEG C, ironing-time 2s, ironing press 39.2N/cm2；
S6, the shape of blade according to needed for being drawn leaf cut studying for a second time courses one has flunked shape；
S7, lacing wire of being disputed over trifles to vein progress prominent on blade；
S8, the coated with nano level TiO on blade2Film；TiO2It is a kind of n-type semiconductor in broadband, it is high with nontoxicity The chemically physics excellent with heat endurance and light sensitivity etc. and chemical property, it is considered to be most attractive inorganic material One of.Nano-TiO2Film toxicity is low, and heat endurance is good, cheap, and cell membrane, cell membrane are directly destroyed in the presence of light Or intracellular members, with very strong sterilizing ability, it is a kind of excellent anti-biotic material, the time of mould proof phase can be lengthened, and subtract Few VOC generation.Effect of anticorrosive mildewproof can be reached.
Meanwhile, nano-TiO2Film also has the function of purification air, using quartzy photo catalysis reactor to TiO2In ultraviolet light Lower photocatalysis SO2Studied, research finds O2Presence to nano-TiO2Film ultraviolet photochemical catalytic oxidation SO2Play very Important effect, while demonstrating SO2A product through photochemical catalytic oxidation generates H with water2SO2The reaction mechanism mechanism of reaction.Simultaneously in reality Issue after examination and approval the TiO of existing 750 DEG C of preparations2Adsorption efficiency highest, and TiO2Adsorption efficiency increase with the increase of light application time, It has been also demonstrated that TiO2The absorption of PARA FORMALDEHYDE PRILLS(91,95) is chemisorbed, the TiO of formaldehyde adsorption2It can not be reused after heating.Therefore explanation Nano-TiO2Film has air cleaning, anti-ultraviolet function.
Nanoscale TiO2Film is obtained by the following method：
S8.1, to TiO2Ground and be classified, by TiO2Corase particles is processed as the TiO with pigment performance2Fine particle；
S8.2, the TiO for obtaining step S8.12Fine particle is surface-treated；What is be surface-treated concretely comprises the following steps TiO2 Fine particle is processed as TiO2Water suspension, and add inorganic compound cladding TiO2, improve TiO2Weatherability, inorganic compound Preferably aluminium, silicon, Ti-inorganic compound；Again to the TiO coated by inorganic compound2Middle addition inorganic agent, improves TiO2Profit Wet dispersiveness；
S8.3, by the TiO after surface treatment2Airslide disintegrating mill ultramicro grinding is used, that is, is obtained for being coated on blade Nanoscale TiO2Film；
Coated on blade, that is, the blade for drawing a picture is made.
Processing method of the present invention is simple, and the various pigment of blade after processing easily in leaf mixing on chip and disperse, and are effectively ensured Scribble uniform, degree of staining and transparency are high, it is adaptable to preserve for a long time, the base-material drawn a picture is inhibited from yellowing and loss of gloss, can effectively protect Whiteness is held, anti-grinded hardness index is good, can effectively keep tone and glossiness, is bitten moreover, being difficult to be gnawed by worm mosquito, air can be purified, Put suitable for house.
In the case where not conflicting, the feature in embodiment and embodiment herein-above set forth can be combined with each other.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.

Claims (5)

1. one kind utilizes nano-TiO2Processing method of the film to blade, it is characterised in that comprise the following steps：
S1, the leaf vegetables drawn a picture will be ready to use in it is planted near the mountain and by the river, few sun, and the place of wind sheltering；
S2, gather frivolous, roomy, color it is refined, flesh is rich, natural, complete blade；
Blade is wrapped up stand-by by S3, the method educated with anti-dry paper, by the moisture control of blade in 60-80%；
S4, continuous flat is carried out to blade to leveling blade, be 20-30% by smooth blade aeration-drying to moisture content, and The moisture content of blade is maintained at 20-30% using NMF sodium carboxymethylcellulose or glycerine；
S5, blade shaped by ironing technology, the moisture content of setting rear blade is 15-20%, 150-170 DEG C of ironing temperature, Ironing-time 2s, ironing press 39.2N/cm2；
S6, the shape of blade according to needed for being drawn leaf cut studying for a second time courses one has flunked shape；
S7, lacing wire of being disputed over trifles to vein progress prominent on blade；
S8, the coated with nano level TiO on blade2Film, that is, be made the blade for drawing a picture.
2. utilization nano-TiO according to claim 12Processing method of the film to blade, it is characterised in that the step In S8, nanoscale TiO2Film is obtained by the following method：
S8.1, to TiO2Ground and be classified, by TiO2Corase particles is processed as the TiO with pigment performance2Fine particle；
S8.2, the TiO for obtaining step S8.12Fine particle is surface-treated；
S8.3, by the TiO after surface treatment2Airslide disintegrating mill ultramicro grinding is used, that is, obtains the nanoscale for being coated on blade TiO2Film.
3. utilization nano-TiO according to claim 22Processing method of the film to blade, it is characterised in that the step In S8.2, surface treatment is concretely comprised the following steps TiO2Fine particle is processed as TiO2Water suspension, and add inorganic compound cladding TiO2；Again to the TiO coated by inorganic compound2Middle addition inorganic agent.
4. utilization nano-TiO according to claim 32Processing method of the film to blade, it is characterised in that described inorganic Compound is aluminium, silicon, Ti-inorganic compound.
5. utilization nano-TiO according to claim 12Processing method of the film to blade, it is characterised in that the blade From leaf of Japanese banana.
CN201710477095.XA 2017-06-21 2017-06-21 It is a kind of to utilize nano-TiO2Processing method of the film to blade Expired - Fee Related CN107214061B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5480874A (en) * 1977-12-02 1979-06-27 Miyomatsu Tanaka Sprayer for tree and flowering plant
CN1651269A (en) * 2004-02-05 2005-08-10 上海温兴生物工程有限公司 Photo catalyst artistic plant
CN1743187A (en) * 2005-09-22 2006-03-08 李永健 Method for making transparent leaf painting
JP3151580U (en) * 2009-01-20 2009-07-02 株式会社マルニ商会 Harmless catalyst processed lump / grain product
US20090226686A1 (en) * 2004-06-03 2009-09-10 Neely Richard A Glass Paneling With a Sublimated Image and Process For Making the Same
CN101797863A (en) * 2009-02-06 2010-08-11 武汉市硚口区忆贝轩叶画工作室 Manufacturing method of glue film leaf painting
CN101932245A (en) * 2007-12-12 2010-12-29 纳米创新基金会 Protective layer for plants and trees, the production thereof and use thereof
CN202357779U (en) * 2011-11-03 2012-08-01 杨淑慧 Environment-friendly artistic simulative bonsai

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5480874A (en) * 1977-12-02 1979-06-27 Miyomatsu Tanaka Sprayer for tree and flowering plant
CN1651269A (en) * 2004-02-05 2005-08-10 上海温兴生物工程有限公司 Photo catalyst artistic plant
US20090226686A1 (en) * 2004-06-03 2009-09-10 Neely Richard A Glass Paneling With a Sublimated Image and Process For Making the Same
CN1743187A (en) * 2005-09-22 2006-03-08 李永健 Method for making transparent leaf painting
CN101932245A (en) * 2007-12-12 2010-12-29 纳米创新基金会 Protective layer for plants and trees, the production thereof and use thereof
JP3151580U (en) * 2009-01-20 2009-07-02 株式会社マルニ商会 Harmless catalyst processed lump / grain product
CN101797863A (en) * 2009-02-06 2010-08-11 武汉市硚口区忆贝轩叶画工作室 Manufacturing method of glue film leaf painting
CN202357779U (en) * 2011-11-03 2012-08-01 杨淑慧 Environment-friendly artistic simulative bonsai

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王琦等: "《植物病理学研究进展》", 31 October 2007, 中国农业科学技术出版社 *

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