CN107201570B - A kind of diamond of core shell structure/fiber flexibility rubbing down tool - Google Patents
A kind of diamond of core shell structure/fiber flexibility rubbing down tool Download PDFInfo
- Publication number
- CN107201570B CN107201570B CN201710451801.3A CN201710451801A CN107201570B CN 107201570 B CN107201570 B CN 107201570B CN 201710451801 A CN201710451801 A CN 201710451801A CN 107201570 B CN107201570 B CN 107201570B
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- China
- Prior art keywords
- diamond
- rubbing down
- shell structure
- high polymers
- solution
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D1/00—Treatment of filament-forming or like material
- D01D1/02—Preparation of spinning solutions
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/08—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Artificial Filaments (AREA)
- Inorganic Fibers (AREA)
Abstract
A kind of diamond of core shell structure/fiber flexibility rubbing down tool, it is a kind of using the fiber that conduction high polymer is constituted as internal cored structure, and the diamond of half embedment is as shell structure with rubbing down tool that is flexible, being bonded with complex-curved formation adaptivity;Mainly solvent dissolution is added in conducting high polymers object by the preparation method of above-mentioned rubbing down tool, is then divided into two parts;A copy of it is added diamond and carries out ultrasonic mixing, preferably using conducting high polymers object solution as cored structure solution, using the mixture of diamond and conducting high polymers object as shell structure solution, carry out electrostatic spinning, after spinning, obtained spinning is put into Muffle furnace, 180 DEG C of heat treatment in 2 hours is carried out.The method of the present invention is simple, can reduce polishing cost, and diamond/fiber flexible can form being bonded for adaptivity with complex-curved, can become the polishing and grinding head of automation rubbing down machine, applied widely.
Description
Technical field
The present invention relates to a kind of rubbing down tools and preparation method thereof.
Background technique
Rubbing down technique is thick using physical mechanical effect reduction element part, optical element, electronic component etc. surface
The technique of rugosity has important application in numerous areas such as aviation, optics manufacture, electronic industry, precision manufactureings.Sometimes rubbing down work
The superiority and inferiority of skill is directly related to the total quality and its availability of device, to throwing if the integral blade disk of high-performance aeroengine
Mill requires high.But traditional rubbing down tool can not form good fit with this three-dimension curved surface, can only often use inefficient
The artificial rubbing down of rate limits the development of automation rubbing down machinery.Development and the complex-curved flexible rubbing down with adaptivity
Tool is the key that open technical bottleneck.In addition, many optical elements, electronic component need the surface of ultra-smooth, engineering at present
On be often used the grinding tools such as polyurethane and add and be processed by shot blasting containing diamond polishing liquid.But this technique is to the demand of diamond
Greatly, higher cost.
Summary of the invention
A kind of diamond of the purpose of the present invention is to provide methods core shell structure that is simple, can reduce polishing cost/
Fiber flexibility rubbing down tool.
The diamond of core shell structure of the invention/fiber flexibility rubbing down tool is a kind of fiber constituted with conduction high polymer
As internal cored structure, the diamond of half embedment is flexible as having for shell structure, can be adaptive with complex-curved formation
The rubbing down tool of answering property fitting.
Above-mentioned rubbing down tool the preparation method is as follows:
(1) raw materials:
Diamond, solvent and conducting high polymers object, the mass percent of solvent and conducting high polymers object are as follows: 10
~11.5:1~1.5, the mass percent of diamond and conducting high polymers object are as follows: 1:9~19;
The partial size of the diamond is 1 μm~5nm;The solvent is N,N-dimethylformamide, deionized water or ethyl alcohol
One of;The conducting high polymers object is polyacrylonitrile, polyvinyl alcohol, chitosan, polymethyl methacrylate or poly-
One of vinylpyrrolidone;
(2) diamond of core shell structure/fiber flexibility rubbing down tool preparation:
1. conducting high polymers object is added in solvent, constantly stirred, is guaranteed conductive high with magnetic stirring apparatus
Molecularly Imprinted Polymer sufficiently dissolves;Then the solution of conducting high polymers object is uniformly divided into two parts;
2. the portion in the conducting high polymers object solution for taking step (1) to prepare, diamond is added thereto, is surpassed
Sound mixing, supersonic frequency 20KHz guarantee that diamond is dispersed in solution;
3. using coaxial electrostatic spinning equipment, the conducting high polymers object solution 1. prepared using step is molten as cored structure
Then liquid carries out electrostatic spinning using the mixture of the diamond of step 2. and conducting high polymers object as shell structure solution, if
Determining spinning voltage is 18~22kV, and spinning distance is 5~15cm, and after spinning, obtained spinning is put into Muffle furnace, into
Row 180 DEG C of heat treatment in 2 hours, and then obtain diamond/fiber flexibility rubbing down tool of core shell structure.
The fiber that conduction high polymer is constituted is internal cored structure, is the flexible substrate of rubbing down tool, is microcosmic presentation three
Tie up the supporter of reticular structure;The diamond of half embedment is shell structure, plays the role of rubbing down to device, has Buddha's warrior attendant flexible
Stone/fiber can form being bonded for adaptivity with complex-curved, can become the polishing and grinding head of automation rubbing down machine, can also use
In the polishing of optics, electronic component.
The invention has the following advantages over the prior art:
(1) coaxial electrostatic spinning technology is used, diamond need to only be added to shell solution, save diamond dosage, simultaneously
Internal cored structure supports three-dimensional structure, maintains the flexibility of material.
(2) diamond/fiber flexible can form being bonded for adaptivity with complex-curved, can become automation rubbing down
The polishing and grinding head of machine, it is applied widely.
(3) preparation method is simple, and diamond has been fixed in rubbing down tool, reduces loss, has saved polishing cost.
Detailed description of the invention
Fig. 1 is diamond/fiber scanning electron microscope (SEM) photograph in the embodiment of the present invention 2.
Specific embodiment
Embodiment 1
It takes 13.5g polyvinyl alcohol to pour into the deionized water of 90g, during which needs constantly to be stirred using magnetic stirring apparatus
It mixes, guarantees that polyvinyl alcohol sufficiently dissolves;Then polyvinyl alcohol water solution is divided into two parts, a copy of it does coaxial electrostatic spinning
The core solution of silk is added the diamond that 0.75g partial size is 1 μm, diamond uniform is dispersed in solution using ultrasound in another
In, using this solution as shell solution.Will core, in shell solution injection coaxial electrostatic spinning equipment, set spinning voltage as 18kV, spinning
Distance be 5cm, then carry out electrostatic spinning, after spinning, obtained sample be put into Muffle furnace, carry out 2 hours 180 DEG C
Heat treatment, and then obtain core shell structure diamond/fiber flexibility rubbing down tool.
Embodiment 2
It takes 7.8g polyacrylonitrile to pour into the n,N-Dimethylformamide of 90g, during which needs to carry out using magnetic stirring apparatus
Continuous stirring guarantees that polyacrylonitrile sufficiently dissolves.Then the polyacrylonitrile solution is divided into two parts, a copy of it is done together
The diamond that 0.205g partial size is 100nm is added, using ultrasound by diamond uniform in the core solution of axis electrostatic spinning in another
Disperse in the solution, using this solution as shell solution.By in core, shell solution injection coaxial electrostatic spinning equipment, spinning voltage is set
For 20kV, spinning distance is 10cm, then carries out electrostatic spinning, after spinning, obtained sample is put into Muffle furnace, into
Row 180 DEG C of heat treatment in 2 hours, and then obtain diamond/fiber flexibility rubbing down tool of core shell structure.Diamond/fiber
Shown in microscopic appearance figure such as Fig. 1 (electron microscope), diamond/fiber forms tridimensional network, and fiber diameter size is uniform, gold
Hard rock is embedded in fibre structure.
Embodiment 3
It takes 10g polyvinylpyrrolidone to pour into 90g ethyl alcohol, during which needs constantly to be stirred using magnetic stirring apparatus
It mixes, guarantees that polyvinylpyrrolidone sufficiently dissolves.Then the polyvinylpyrrolidonesolution solution is divided into two parts, a copy of it
The diamond that 0.5g partial size is 5nm is added, using ultrasound by diamond uniform in the core solution for doing coaxial electrostatic spinning in another
Disperse in the solution, using this solution as shell solution.By in core, shell solution injection coaxial electrostatic spinning equipment, spinning voltage is set
For 22kV, spinning distance is 15cm, then carries out electrostatic spinning, after spinning, obtained sample is put into Muffle furnace, into
Row 180 DEG C of heat treatment in 2 hours, and then obtain diamond/fiber flexibility rubbing down tool of core shell structure.
Claims (2)
1. a kind of diamond of core shell structure/fiber flexibility rubbing down tool preparation method, diamond/fibre of the core shell structure
Tieing up flexible rubbing down tool is a kind of using the fiber that conduction high polymer is constituted as internal cored structure, the diamond conduct of half embedment
The rubbing down tool that having for shell structure is flexible, can be bonded with complex-curved formation adaptivity, it is characterised in that:
(1) raw materials:
Diamond, solvent and conducting high polymers object, the mass percent of solvent and conducting high polymers object are as follows: 10~
11.5:1~1.5, the mass percent of diamond and conducting high polymers object are as follows: 1:9~19;
(2) diamond of core shell structure/fiber flexibility rubbing down tool preparation:
1. conducting high polymers object is added in solvent, constantly stirred with magnetic stirring apparatus, guarantees conducting polymer
Polymer sufficiently dissolves;Then the solution of conducting high polymers object is uniformly divided into two parts;
2. the portion in the conducting high polymers object solution for taking step (1) to prepare, diamond is added thereto, it is mixed to carry out ultrasound
It closes, supersonic frequency 20KHz guarantees that diamond is dispersed in solution;
3. use coaxial electrostatic spinning equipment, the conducting high polymers object solution 1. prepared using step as cored structure solution, with
The mixture of the diamond of step 2. and conducting high polymers object is shell structure solution, then carries out electrostatic spinning, and setting is spun
Filament voltage is 18~22kV, and spinning distance is 5~15cm, and after spinning, obtained spinning is put into Muffle furnace, carries out 2
The heat treatment of 180 DEG C of hour, and then obtain diamond/fiber flexibility rubbing down tool of core shell structure.
2. the diamond of core shell structure according to claim 1/fiber flexibility rubbing down tool preparation method, feature exist
In: the partial size of the diamond is 1 μm~5nm;The solvent is one in N,N-dimethylformamide, deionized water or ethyl alcohol
Kind;The conducting high polymers object is polyacrylonitrile, polyvinyl alcohol, chitosan, polymethyl methacrylate or polyethylene pyrrole
One of pyrrolidone.
Priority Applications (1)
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CN201710451801.3A CN107201570B (en) | 2017-06-15 | 2017-06-15 | A kind of diamond of core shell structure/fiber flexibility rubbing down tool |
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CN107201570A CN107201570A (en) | 2017-09-26 |
CN107201570B true CN107201570B (en) | 2019-07-26 |
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Families Citing this family (2)
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CN109605235A (en) * | 2018-11-27 | 2019-04-12 | 华侨大学 | A method of polishing pad is woven using consolidated diamond carbon nano-tube fibre |
CN114990724B (en) * | 2022-06-20 | 2024-04-02 | 苏州卡彭新材料科技有限公司 | Diamond doped PLGA nanofiber composite material |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101675839A (en) * | 2008-09-18 | 2010-03-24 | E.I.内穆尔杜邦公司 | Industrial brush bristles and brush comprising same |
CN101994167A (en) * | 2009-08-11 | 2011-03-30 | 慈溪市洁达纳米复合材料有限公司 | Method for preparing grinding silk |
CN106498565A (en) * | 2016-10-26 | 2017-03-15 | 中原工学院 | A kind of Nano diamond/carbon fiber carbon composite and preparation method thereof |
-
2017
- 2017-06-15 CN CN201710451801.3A patent/CN107201570B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101675839A (en) * | 2008-09-18 | 2010-03-24 | E.I.内穆尔杜邦公司 | Industrial brush bristles and brush comprising same |
CN101994167A (en) * | 2009-08-11 | 2011-03-30 | 慈溪市洁达纳米复合材料有限公司 | Method for preparing grinding silk |
CN106498565A (en) * | 2016-10-26 | 2017-03-15 | 中原工学院 | A kind of Nano diamond/carbon fiber carbon composite and preparation method thereof |
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