CN107201207A - A kind of clothes high viscous waterproof heat resistant glue and preparation method thereof - Google Patents
A kind of clothes high viscous waterproof heat resistant glue and preparation method thereof Download PDFInfo
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- CN107201207A CN107201207A CN201710622427.9A CN201710622427A CN107201207A CN 107201207 A CN107201207 A CN 107201207A CN 201710622427 A CN201710622427 A CN 201710622427A CN 107201207 A CN107201207 A CN 107201207A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of clothes with high viscous waterproof heat resistant glue, include the raw material of following parts by weight：12 16 parts of aliphatic dicarboxylic acid, 0.8 1.4 parts of stabilizer, 35 parts of coupling agent, 46 parts of tackifier, 12 parts of antioxidant, 6 10 parts of low-modulus polyurethane resin, 57 parts of PEPA, 59 parts of ethylene glycol, 12 18 parts of adhesive aid, 24 parts of stearic acid, 57 parts of thickener, 79 parts of ethanol, 12 parts of organosilicon levelling agent, 46 parts of antimycotic antiseptic additive.The present invention have good cohesive, water-fastness resistance to dry-cleaning, heat aging property, its pliability, cohesive, heat endurance are all more superior；While the preparation method of the present invention, its material cost is relatively low, raw material is easy to get and technique concise, it is easy to industrialized production is operated and realize, with higher practical value and good application prospect.
Description
Technical field
The present invention relates to clothes binder material technical field, and in particular to a kind of clothes with high viscous waterproof heat resistant glue and its
Preparation method.
Background technology
One side polyurethane leather designs and varieties are various, have well-regulated area, and the defect without natural leather is being cut out
More meet mechanization, efficient modernization large-scale production in terms of disconnected, sewing.Polyurethane leather largely apply to footwear,
The every profession and trades such as clothes, case and bag, furniture, the occupation rate in clothes is 8%~12%.Traditional leather-making technology is in order that polyurethane
The characteristics of clothing leather has abundant, soft and high resilience is, it is necessary to which first prepare one layer of wet method foaming layer, then applicator surface in base fabric
Layer resin, this technique is complex, power consumption is big.It is difficult and current polyurethane adhesive layer resin is applied to when preparing clothing leather
To reach the feel required by clothing leather.
Another aspect PUR is a kind of adhesive of plasticity, and its physical state changes with temperature in certain temperature range
Become and change, and chemical characteristic is constant, its is nonpoisonous and tasteless, belongs to environmental-protecting chemical product.Present polyamide hot has melting
The outstanding advantages such as narrow range, curing rate are fast, adhesion strength is high.In actual application, PUR heating melting is applied
After cloth, slightly cooling can solidify rapidly, and good adhesion strength is still being kept close near softening point, and due to the PUR
It is interior containing amide groups, amino, carboxyl isopolarity group, it is had good caking property to many polar materials.Therefore polyamides
Amine PUR is widely used in many industries such as chemical industry, automobile, light industry, food, weaving.But its high temperature resistant water washing poor-performing,
As the PUR of clothes, its water-fastness, dry cleaning resistance can need further raising.
The content of the invention
For the defect of prior art, waterproof heat resistant glue is glued with high it is an object of the invention to provide a kind of clothes, this has
Good cohesive, water-fastness resistance to dry-cleaning, heat aging property, its pliability, cohesive, heat endurance are all more superior；Together
When the present invention preparation method, its material cost is relatively low, raw material is easy to get and technique is concise, it is easy to operation and realize industrial metaplasia
Production, with higher practical value and good application prospect.
The present invention solves technical problem and adopted the following technical scheme that：
The invention provides a kind of clothes with high viscous waterproof heat resistant glue, include the raw material of following parts by weight：
12-16 parts of aliphatic dicarboxylic acid, 0.8-1.4 parts of stabilizer, 3-5 parts of coupling agent, 4-6 parts of tackifier, 1-2 parts of antioxidant,
6-10 parts of low-modulus polyurethane resin, 5-7 parts of PEPA, 5-9 parts of ethylene glycol, 12-18 parts of adhesive aid, stearic acid 2-4
Part, 5-7 parts of thickener, 7-9 parts of ethanol, 1-2 parts of organosilicon levelling agent, 4-6 parts of antimycotic antiseptic additive.
Preferably, the clothes include the raw material of following parts by weight with high viscous waterproof heat resistant glue：
14 parts of aliphatic dicarboxylic acid, 1.1 parts of stabilizer, 4 parts of coupling agent, 5 parts of tackifier, 1.5 parts of antioxidant, low-modulus polyurethane
It is 8 parts of resin, 6 parts of PEPA, 7 parts of ethylene glycol, 15 parts of adhesive aid, 3 parts of stearic acid, 6 parts of thickener, 8 parts of ethanol, organic
1.5 parts of silicon levelling agent, 5 parts of antimycotic antiseptic additive.
Preferably, the aliphatic dicarboxylic acid is adipic acid, 2- methyl adipic acid, 1,2- dimethyl adipic acid according to weight
Amount compares 2:1:The mixture of 1 composition.
Preferably, the stabilizer is 1- phenyl -3- pyrazolidones；The coupling agent is silane coupler, titanate esters idol
Join one kind in agent.
Preferably, the tackifier are newtrex and terpene resin according to weight ratio 3:The mixture of 2 compositions；It is described anti-
Oxygen agent is antioxidant 1098.
Preferably, the adhesive aid is flaxseed gum, oleic acid potash soap and polyvinyl alcohol according to weight ratio 2:1:3 compositions
Mixture.
Preferably, the thickener is ethoxyl methyl cellulose ether, sodium alginate, marine alga propylene glycol ester, according to weight
Than 2:1:The mixture of 1 composition.
Preferably, the antimildew disinfectant is nano zine oxide, potassium sorbate and nano titanium oxide, compares 1 according to weight:
1:The mixture of 2 compositions.
The present invention also provides a kind of preparation method of the viscous waterproof heat resistant glue of clothes height, comprises the following steps：
Step one, each component raw material is weighed on request；
Step 2, coupling agent, antimycotic antiseptic additive, antioxidant, ethanol, ethylene glycol are mixed and add mixer, 15-25 is stirred
Minute, speed of agitator is 250-350r/min, obtains mixture A；
Step 3, aliphatic dicarboxylic acid, low-modulus polyurethane resin, PEPA are mixed and added in reactor, in temperature
For 30-40 DEG C, 5-7 minutes are incubated, organosilicon levelling agent, stabilizer, adhesive aid, tackifier, thickener, stearic acid is added
70-80 DEG C is warming up to, with speed of agitator 400-500r/min, stirring reaction 10-20 minutes adds the mixing of step 2 preparation
Thing A, continues to stir 15-25 minutes, is prepared into mixture B；
Step 4, mixture B prepared by step 3 sends into kneading machine, is heated to 90-100 DEG C, kneads 15-25min；Will
Product after mixing is uniform is added to double screw extruder after vacuum defoamation, and extrusion product produces invention through cooling, granulation
Clothes with high viscous waterproof heat resistant glue.
Preferably, the clothes are with the preparation process of high viscous waterproof heat resistant glue：
Step one, each component raw material is weighed on request；
Step 2, coupling agent, antimycotic antiseptic additive, antioxidant, ethanol, ethylene glycol are mixed and add mixer, 20 points are stirred
Clock, speed of agitator is 300r/min, obtains mixture A；
Step 3, aliphatic dicarboxylic acid, low-modulus polyurethane resin, PEPA are mixed and added in reactor, in temperature
For 35 DEG C, 6 minutes are incubated, organosilicon levelling agent, stabilizer, adhesive aid, tackifier, thickener, stearic acid heating is added
To 75 DEG C, with speed of agitator 450r/min, stirring reaction 15 minutes adds the mixture A of step 2 preparation, continues to stir 20
Minute, it is prepared into mixture B；
Step 4, mixture B prepared by step 3 sends into kneading machine, is heated to 95 DEG C, kneads 20min；It will knead equal
Product after even is added to double screw extruder after vacuum defoamation, and extrusion product produces the clothes of invention through cooling, granulation
With the viscous waterproof heat resistant glue of height.
Compared with prior art, the present invention has following beneficial effect：
（1）A kind of clothes of the present invention are with high viscous waterproof heat resistant glue, with aliphatic dicarboxylic acid, low-modulus polyurethane resin, polyester
Polyalcohol is material of main part, pass through aid in addition each analog assistant so that the heat-resistant adhesive good film-forming property of preparation, be firmly bonded, it is soft
Soft rich and flexible, scratch resistance is good, water-fastness.
（2）A kind of clothes of the present invention glue waterproof heat resistant glue with high, and the tackifier of addition are mainly newtrex and terpenes
Resin, the adhesive aid of addition is flaxseed gum, oleic acid potash soap and polyvinyl alcohol, and its heat-resistant adhesive for prepare has good
Water resistance, mechanical property, excellent heat resistance, shape-retaining ability be good and the features such as resistance to organic corrosion.
（3）A kind of clothes of the present invention with the addition of by nano zine oxide, potassium sorbate and nanometer with high viscous waterproof heat resistant glue
The antimildew disinfectant of titanium dioxide composition, the compound action of several persons can make heat-resistant adhesive that there is preferable fungus and mildew resistance to act on, effectively
Reduce the bacteria growth problems in clothes crack.
（4）A kind of viscous waterproof heat resistant glue of clothes height of the present invention has a good cohesive, it is water-fastness it is resistance to dry-clean, it is heat-resisting
Ageing properties, its pliability, cohesive, heat endurance are all more superior；Simultaneously the present invention preparation method, its material cost compared with
Low, raw material is easy to get and technique is concise, it is easy to operate and realize industrialized production, should with good with higher practical value
Use prospect.
Embodiment
With reference to specific embodiment, the technical scheme in the embodiment of the present invention is clearly and completely described, shown
So, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the reality in the present invention
Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of clothes of the present embodiment include the raw material of following parts by weight with high viscous waterproof heat resistant glue：
12 parts of aliphatic dicarboxylic acid, 0.8 part of stabilizer, 3 parts of coupling agent, 4 parts of tackifier, 1 part of antioxidant, low-modulus polyurethane tree
6 parts of fat, 5 parts of PEPA, 5 parts of ethylene glycol, 12 parts of adhesive aid, 2 parts of stearic acid, 5 parts of thickener, 7 parts of ethanol, organosilicon
1 part of levelling agent, 4 parts of antimycotic antiseptic additive.
Aliphatic dicarboxylic acid in the present embodiment is adipic acid, 2- methyl adipic acid, 1,2- dimethyl adipic acid are according to weight
Amount compares 2:1:The mixture of 1 composition.
Stabilizer in the present embodiment is 1- phenyl -3- pyrazolidones；The coupling agent is silane coupler.
Tackifier in the present embodiment are newtrex and terpene resin according to weight ratio 3:The mixture of 2 compositions；It is described
Antioxidant is antioxidant 1098.
Adhesive aid in the present embodiment is flaxseed gum, oleic acid potash soap and polyvinyl alcohol according to weight ratio 2:1:3 compositions
Mixture.
Thickener in the present embodiment is ethoxyl methyl cellulose ether, sodium alginate, marine alga propylene glycol ester, according to weight
Than 2:1:The mixture of 1 composition.
Antimildew disinfectant in the present embodiment is nano zine oxide, potassium sorbate and nano titanium oxide, according to weight ratio
1:1:The mixture of 2 compositions.
A kind of clothes of the present embodiment preparation method of high viscous waterproof heat resistant glue, comprises the following steps：
Step one, each component raw material is weighed on request；
Step 2, coupling agent, antimycotic antiseptic additive, antioxidant, ethanol, ethylene glycol are mixed and add mixer, 15 points are stirred
Clock, speed of agitator is 250r/min, obtains mixture A；
Step 3, aliphatic dicarboxylic acid, low-modulus polyurethane resin, PEPA are mixed and added in reactor, in temperature
For 30 DEG C, 5 minutes are incubated, organosilicon levelling agent, stabilizer, adhesive aid, tackifier, thickener, stearic acid heating is added
To 70 DEG C, with speed of agitator 400r/min, stirring reaction 10 minutes adds the mixture A of step 2 preparation, continues to stir 15
Minute, it is prepared into mixture B；
Step 4, mixture B prepared by step 3 sends into kneading machine, is heated to 90 DEG C, kneads 15min；It will knead equal
Product after even is added to double screw extruder after vacuum defoamation, and extrusion product produces the clothes of invention through cooling, granulation
With the viscous waterproof heat resistant glue of height.
Embodiment 2.
A kind of clothes of the present embodiment include the raw material of following parts by weight with high viscous waterproof heat resistant glue：
16 parts of aliphatic dicarboxylic acid, 1.4 parts of stabilizer, 5 parts of coupling agent, 6 parts of tackifier, 2 parts of antioxidant, low-modulus polyurethane tree
It is 10 parts of fat, 7 parts of PEPA, 9 parts of ethylene glycol, 18 parts of adhesive aid, 4 parts of stearic acid, 7 parts of thickener, 9 parts of ethanol, organic
2 parts of silicon levelling agent, 6 parts of antimycotic antiseptic additive.
Aliphatic dicarboxylic acid in the present embodiment is adipic acid, 2- methyl adipic acid, 1,2- dimethyl adipic acid are according to weight
Amount compares 2:1:The mixture of 1 composition.
Stabilizer in the present embodiment is 1- phenyl -3- pyrazolidones；The coupling agent is titanate coupling agent.
Tackifier in the present embodiment are newtrex and terpene resin according to weight ratio 3:The mixture of 2 compositions；It is described
Antioxidant is antioxidant 1098.
Adhesive aid in the present embodiment is flaxseed gum, oleic acid potash soap and polyvinyl alcohol according to weight ratio 2:1:3 compositions
Mixture.
Thickener in the present embodiment is ethoxyl methyl cellulose ether, sodium alginate, marine alga propylene glycol ester, according to weight
Than 2:1:The mixture of 1 composition.
Antimildew disinfectant in the present embodiment is nano zine oxide, potassium sorbate and nano titanium oxide, according to weight ratio
1:1:The mixture of 2 compositions.
A kind of clothes of the present embodiment preparation method of high viscous waterproof heat resistant glue, comprises the following steps：
Step one, each component raw material is weighed on request；
Step 2, coupling agent, antimycotic antiseptic additive, antioxidant, ethanol, ethylene glycol are mixed and add mixer, 25 points are stirred
Clock, speed of agitator is 350r/min, obtains mixture A；
Step 3, aliphatic dicarboxylic acid, low-modulus polyurethane resin, PEPA are mixed and added in reactor, in temperature
For 40 DEG C, 7 minutes are incubated, organosilicon levelling agent, stabilizer, adhesive aid, tackifier, thickener, stearic acid heating is added
To 80 DEG C, with speed of agitator 500r/min, stirring reaction 20 minutes adds the mixture A of step 2 preparation, continues to stir 25
Minute, it is prepared into mixture B；
Step 4, mixture B prepared by step 3 sends into kneading machine, is heated to 100 DEG C, kneads 25min；It will knead equal
Product after even is added to double screw extruder after vacuum defoamation, and extrusion product produces the clothes of invention through cooling, granulation
With the viscous waterproof heat resistant glue of height.
Embodiment 3.
A kind of clothes of the present embodiment include the raw material of following parts by weight with high viscous waterproof heat resistant glue：
14 parts of aliphatic dicarboxylic acid, 1.1 parts of stabilizer, 4 parts of coupling agent, 5 parts of tackifier, 1.5 parts of antioxidant, low-modulus polyurethane
It is 8 parts of resin, 6 parts of PEPA, 7 parts of ethylene glycol, 15 parts of adhesive aid, 3 parts of stearic acid, 6 parts of thickener, 8 parts of ethanol, organic
1.5 parts of silicon levelling agent, 5 parts of antimycotic antiseptic additive.
Aliphatic dicarboxylic acid in the present embodiment is adipic acid, 2- methyl adipic acid, 1,2- dimethyl adipic acid are according to weight
Amount compares 2:1:The mixture of 1 composition.
Stabilizer in the present embodiment is 1- phenyl -3- pyrazolidones；The coupling agent is silane coupler.
Tackifier in the present embodiment are newtrex and terpene resin according to weight ratio 3:The mixture of 2 compositions；It is described
Antioxidant is antioxidant 1098.
Adhesive aid in the present embodiment is flaxseed gum, oleic acid potash soap and polyvinyl alcohol according to weight ratio 2:1:3 compositions
Mixture.
Thickener in the present embodiment is ethoxyl methyl cellulose ether, sodium alginate, marine alga propylene glycol ester, according to weight
Than 2:1:The mixture of 1 composition.
Antimildew disinfectant in the present embodiment is nano zine oxide, potassium sorbate and nano titanium oxide, according to weight ratio
1:1:The mixture of 2 compositions.
A kind of clothes of the present embodiment preparation method of high viscous waterproof heat resistant glue, comprises the following steps：
Step one, each component raw material is weighed on request；
Step 2, coupling agent, antimycotic antiseptic additive, antioxidant, ethanol, ethylene glycol are mixed and add mixer, 20 points are stirred
Clock, speed of agitator is 300r/min, obtains mixture A；
Step 3, aliphatic dicarboxylic acid, low-modulus polyurethane resin, PEPA are mixed and added in reactor, in temperature
For 35 DEG C, 6 minutes are incubated, organosilicon levelling agent, stabilizer, adhesive aid, tackifier, thickener, stearic acid heating is added
To 75 DEG C, with speed of agitator 450r/min, stirring reaction 15 minutes adds the mixture A of step 2 preparation, continues to stir 20
Minute, it is prepared into mixture B；
Step 4, mixture B prepared by step 3 sends into kneading machine, is heated to 95 DEG C, kneads 20min；It will knead equal
Product after even is added to double screw extruder after vacuum defoamation, and extrusion product produces the clothes of invention through cooling, granulation
With the viscous waterproof heat resistant glue of height.
Clothes prepared by various embodiments above are as follows with the performance test results of high viscous waterproof heat resistant glue：
| Tensile bond strength MPa | After-drawing adhesion strength of soaking MPa | Heat ageing after-drawing adhesion strength MPa | |
| Embodiment 1 | 2.1 | 1.9 | 1.7 |
| Embodiment 2 | 2.4 | 1.9 | 1.9 |
| Embodiment 3 | 2.2 | 2.0 | 1.8 |
| Comparative example | 1.5 | 1.1 | 0.5 |
A kind of viscous waterproof heat resistant glue of clothes height of the present invention has good cohesive, water-fastness resistance to dry-cleaning, heat-resistant aging
Can, its pliability, cohesive, heat endurance are all more superior；While the preparation method of the present invention, its material cost is relatively low, original
Material is easy to get and technique is concise, it is easy to industrialized production is operated and realize, before higher practical value and good application
Scape.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It may be appreciated other embodiment.
Claims (10)
1. a kind of clothes glue waterproof heat resistant glue with high, it is characterised in that include the raw material of following parts by weight：
12-16 parts of aliphatic dicarboxylic acid, 0.8-1.4 parts of stabilizer, 3-5 parts of coupling agent, 4-6 parts of tackifier, 1-2 parts of antioxidant,
6-10 parts of low-modulus polyurethane resin, 5-7 parts of PEPA, 5-9 parts of ethylene glycol, 12-18 parts of adhesive aid, stearic acid 2-4
Part, 5-7 parts of thickener, 7-9 parts of ethanol, 1-2 parts of organosilicon levelling agent, 4-6 parts of antimycotic antiseptic additive.
2. a kind of clothes according to claim 1 glue waterproof heat resistant glue with high, it is characterised in that the clothes are viscous anti-with height
Water heat-resistant adhesive includes the raw material of following parts by weight：
14 parts of aliphatic dicarboxylic acid, 1.1 parts of stabilizer, 4 parts of coupling agent, 5 parts of tackifier, 1.5 parts of antioxidant, low-modulus polyurethane
It is 8 parts of resin, 6 parts of PEPA, 7 parts of ethylene glycol, 15 parts of adhesive aid, 3 parts of stearic acid, 6 parts of thickener, 8 parts of ethanol, organic
1.5 parts of silicon levelling agent, 5 parts of antimycotic antiseptic additive.
3. a kind of clothes according to claim 1 or 2 glue waterproof heat resistant glue with high, it is characterised in that the aliphatic binary
Carboxylic acid is adipic acid, 2- methyl adipic acid, 1,2- dimethyl adipic acid compare 2 according to weight:1:The mixture of 1 composition.
4. a kind of clothes according to claim 1 or 2 are with high viscous waterproof heat resistant glue, it is characterised in that the stabilizer is
1- phenyl -3- pyrazolidones；The coupling agent is one kind in silane coupler, titanate coupling agent.
5. a kind of clothes according to claim 1 or 2 are with high viscous waterproof heat resistant glue, it is characterised in that the tackifier are
Newtrex and terpene resin are according to weight ratio 3:The mixture of 2 compositions；The antioxidant is antioxidant 1098.
6. a kind of clothes according to claim 1 or 2 glue waterproof heat resistant glue with high, it is characterised in that the adhesive aid
It is flaxseed gum, oleic acid potash soap and polyvinyl alcohol according to weight ratio 2:1:The mixture of 3 compositions.
7. a kind of clothes according to claim 1 or 2 are with high viscous waterproof heat resistant glue, it is characterised in that the thickener is
Ethoxyl methyl cellulose ether, sodium alginate, marine alga propylene glycol ester, compare 2 according to weight:1:The mixture of 1 composition.
8. a kind of clothes according to claim 1 or 2 glue waterproof heat resistant glue with high, it is characterised in that the antimycotic antiseptic
Agent is nano zine oxide, potassium sorbate and nano titanium oxide, compares 1 according to weight:1:The mixture of 2 compositions.
9. a kind of method for preparing the viscous waterproof heat resistant glue of clothes height as claimed in claim 1 or 2, it is characterised in that including
Following steps：
Step one, each component raw material is weighed on request；
Step 2, coupling agent, antimycotic antiseptic additive, antioxidant, ethanol, ethylene glycol are mixed and add mixer, 15-25 is stirred
Minute, speed of agitator is 250-350r/min, obtains mixture A；
Step 3, aliphatic dicarboxylic acid, low-modulus polyurethane resin, PEPA are mixed and added in reactor, in temperature
For 30-40 DEG C, 5-7 minutes are incubated, organosilicon levelling agent, stabilizer, adhesive aid, tackifier, thickener, stearic acid is added
70-80 DEG C is warming up to, with speed of agitator 400-500r/min, stirring reaction 10-20 minutes adds the mixing of step 2 preparation
Thing A, continues to stir 15-25 minutes, is prepared into mixture B；
Step 4, mixture B prepared by step 3 sends into kneading machine, is heated to 90-100 DEG C, kneads 15-25min；Will
Product after mixing is uniform is added to double screw extruder after vacuum defoamation, and extrusion product produces invention through cooling, granulation
Clothes with high viscous waterproof heat resistant glue.
10. a kind of clothes according to claim 9 preparation method of high viscous waterproof heat resistant glue, it is characterised in that described
Preparation process is：
Step one, each component raw material is weighed on request；
Step 2, coupling agent, antimycotic antiseptic additive, antioxidant, ethanol, ethylene glycol are mixed and add mixer, 20 points are stirred
Clock, speed of agitator is 300r/min, obtains mixture A；
Step 3, aliphatic dicarboxylic acid, low-modulus polyurethane resin, PEPA are mixed and added in reactor, in temperature
For 35 DEG C, 6 minutes are incubated, organosilicon levelling agent, stabilizer, adhesive aid, tackifier, thickener, stearic acid heating is added
To 75 DEG C, with speed of agitator 450r/min, stirring reaction 15 minutes adds the mixture A of step 2 preparation, continues to stir 20
Minute, it is prepared into mixture B；
Step 4, mixture B prepared by step 3 sends into kneading machine, is heated to 95 DEG C, kneads 20min；It will knead equal
Product after even is added to double screw extruder after vacuum defoamation, and extrusion product produces the clothes of invention through cooling, granulation
With the viscous waterproof heat resistant glue of height.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108285759A (en) * | 2018-02-05 | 2018-07-17 | 合肥梵腾环保科技有限公司 | Antibacterial high viscous waterproof white glue with vinyl of a kind of environment friendly mildew resistant and preparation method thereof |
| CN108456500A (en) * | 2018-03-14 | 2018-08-28 | 合肥远科服装设计有限公司 | A kind of high temperature resistant waterproof flame-retardant glues by force clothing hot melt adhesive and preparation method thereof |
| CN115093822A (en) * | 2022-07-18 | 2022-09-23 | 广州市嘉雁粘合剂有限公司 | Hot melt adhesive for laminating household appliance panels and preparation method thereof |
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| CN101724369A (en) * | 2009-11-13 | 2010-06-09 | 上海天洋热熔胶有限公司 | Preparation method of high-performance polyester hot melt adhesive |
| CN104228210A (en) * | 2013-06-17 | 2014-12-24 | 昭和电工包装株式会社 | Molding packaging material |
| CN104263259A (en) * | 2014-09-18 | 2015-01-07 | 东莞市雄林新材料科技股份有限公司 | Low-melting-point and high-bonding-strength TPU (thermoplastic polyurethane) hot melt adhesive membrane and preparation method thereof |
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| CN101724369A (en) * | 2009-11-13 | 2010-06-09 | 上海天洋热熔胶有限公司 | Preparation method of high-performance polyester hot melt adhesive |
| CN104228210A (en) * | 2013-06-17 | 2014-12-24 | 昭和电工包装株式会社 | Molding packaging material |
| CN104263259A (en) * | 2014-09-18 | 2015-01-07 | 东莞市雄林新材料科技股份有限公司 | Low-melting-point and high-bonding-strength TPU (thermoplastic polyurethane) hot melt adhesive membrane and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108285759A (en) * | 2018-02-05 | 2018-07-17 | 合肥梵腾环保科技有限公司 | Antibacterial high viscous waterproof white glue with vinyl of a kind of environment friendly mildew resistant and preparation method thereof |
| CN108456500A (en) * | 2018-03-14 | 2018-08-28 | 合肥远科服装设计有限公司 | A kind of high temperature resistant waterproof flame-retardant glues by force clothing hot melt adhesive and preparation method thereof |
| CN115093822A (en) * | 2022-07-18 | 2022-09-23 | 广州市嘉雁粘合剂有限公司 | Hot melt adhesive for laminating household appliance panels and preparation method thereof |
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Application publication date: 20170926 |
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