CN107201029A - A kind of fishing net of high intensity - Google Patents
A kind of fishing net of high intensity Download PDFInfo
- Publication number
- CN107201029A CN107201029A CN201710390580.3A CN201710390580A CN107201029A CN 107201029 A CN107201029 A CN 107201029A CN 201710390580 A CN201710390580 A CN 201710390580A CN 107201029 A CN107201029 A CN 107201029A
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- CN
- China
- Prior art keywords
- parts
- fishing net
- high intensity
- mentioned
- pmt
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
Abstract
The present invention discloses a kind of fishing net of high intensity, is made up of the component of following parts by weight：60 75 parts of nylon 6 slice, 30 40 parts of polypropylene chip, 57 parts of tetrabutyl ammonium fluoride, 13 parts of zinc undecylenate, 69 parts of nano zine oxide, 24 parts of 4 hydroxyl PMT, 11 16 parts of hollow glass micropearl, 821 69 parts of aluminate coupling agent.Fishing net produced by the present invention, netting twine fineness is low, and intensity is high, light weight, and flexible preferable, receives folded convenient, greatly improves the quality of fishing net.
Description
Technical field
The invention belongs to fishing net preparation field, and in particular to a kind of high intensity fishing net.
Background technology
With the fast development of culture fishery and fishery, the development of fishing net industry has been promoted.But it is presently commercially available general
Logical fishing net, although some intensity are higher, netting twine is thicker, and the phenomenon of stripped thread occurs in fishing net during braiding,
And its pliability is not enough, although some netting twines are relatively thin, its insufficient strength, therefore it is badly in need of a kind of more excellent high-strength of quality
The fishing net preparation method of degree.
The content of the invention
In order to solve the above problems, the present invention provides a kind of high intensity fishing net.
The present invention is achieved by the following technical solutions.
A kind of fishing net of high intensity, it is characterised in that be made up of the component of following parts by weight：60-75 parts of nylon 6 slice,
30-40 parts of polypropylene chip, 5-7 parts of tetrabutyl ammonium fluoride, 1-3 parts of zinc undecylenate, 6-9 parts of nano zine oxide, 4- hydroxyls-
2-4 parts of PMT, 11-16 parts of hollow glass micropearl, 6-9 parts of aluminate coupling agent 821.
Specifically, above-mentioned tetrabutyl ammonium fluoride is the lotion state of white, the Average Particle Diameters of above-mentioned zinc undecylenate
For 2-4 μm, the average grain diameter of above-mentioned nano zine oxide is 50nm, and above-mentioned 4- hydroxyls-PMT average grain diameter is 1-3 μm.
Specifically, the average grain diameter of above-mentioned hollow glass micropearl is 55 μm, and it is mainly constituted as soda lime-borosilicate glass
Glass, is shaped as white rigid spheroid.
Specifically, the preparation method of the fishing net of the high intensity includes following operating procedure：（1）By nylon 6 slice, poly- third
After alkene section, tetrabutyl ammonium fluoride mixing, drying and processing 2 hours in 50 DEG C of baking oven are put into；（2）By the material after drying and ten
Monoenoic acid zinc, nano zine oxide, 4- hydroxyls-PMT, hollow glass micropearl, aluminate coupling agent 821 are mixed, and pass through plastic extrusion
Machine melting extrusion, then through supercooling, drawing-off, winding, line processed, knitmesh, finished product.
Technical scheme more than, the beneficial effects of the invention are as follows：
Fishing net produced by the present invention, netting twine fineness is low, and intensity is high, light weight, and flexible preferable, receives folded convenient, greatly
Improve the quality of fishing net.Wherein, when nylon 6 slice, polypropylene chip are dried, tetrabutyl ammonium fluoride is added, can be with
Effectively remove moisture contained therein, and also have and prevent nylon 6 slice, the effect of polypropylene chip temperature distortion,
During extrusion melting step, its crystallization water that may be such that in raw material is farthest removed, and reduction moisture content is made to the quality of fishing net
Into influence；Zinc undecylenate, nano zine oxide can effectively reduce the fineness of obtained netting twine, can prevent in drafting step
When, fracture occurs in netting twine, and it can also effectively lift the pliability of obtained fishing net, greatly improve fishing net
Quality；The addition of hollow glass micropearl, greatly improves the abrasion resistance properties and every mechanical property of fishing net, and 4- hydroxyls-
After PMT, aluminate coupling agent 821 act synergistically, the active ingredient in fishing net can be made to be difficult to disperse to come off during use,
Hollow glass micropearl presence stable in fishing net is may be such that, the service life of fishing net is extended.
Embodiment
Following examples are used to illustrate the present invention, but can not be used for limiting the scope of the present invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of fishing net of high intensity, it is characterised in that be made up of the component of following parts by weight：60 parts of nylon 6 slice, polypropylene are cut
30 parts of piece, 5 parts of tetrabutyl ammonium fluoride, 1 part of zinc undecylenate, 6 parts of nano zine oxide, 2 parts of 4- hydroxyls-PMT, hollow glass are micro-
11 parts of pearl, 821 6 parts of aluminate coupling agent.
Specifically, above-mentioned tetrabutyl ammonium fluoride is the lotion state of white, the Average Particle Diameters of above-mentioned zinc undecylenate
For 2 μm, the average grain diameter of above-mentioned nano zine oxide is 50nm, and above-mentioned 4- hydroxyls-PMT average grain diameter is 1 μm.
Specifically, the average grain diameter of above-mentioned hollow glass micropearl is 55 μm, and it is mainly constituted as soda lime-borosilicate glass
Glass, is shaped as white rigid spheroid.
Specifically, the preparation method of the fishing net of the high intensity includes following operating procedure：（1）By nylon 6 slice, poly- third
After alkene section, tetrabutyl ammonium fluoride mixing, drying and processing 2 hours in 50 DEG C of baking oven are put into；（2）By the material after drying and ten
Monoenoic acid zinc, nano zine oxide, 4- hydroxyls-PMT, hollow glass micropearl, aluminate coupling agent 821 are mixed, and pass through plastic extrusion
Machine melting extrusion, then through supercooling, drawing-off, winding, line processed, knitmesh, finished product.
Embodiment 2
A kind of fishing net of high intensity, it is characterised in that be made up of the component of following parts by weight：70 parts of nylon 6 slice, polypropylene are cut
35 parts of piece, 6 parts of tetrabutyl ammonium fluoride, 2 parts of zinc undecylenate, 7 parts of nano zine oxide, 3 parts of 4- hydroxyls-PMT, hollow glass are micro-
13 parts of pearl, 821 8 parts of aluminate coupling agent.
Specifically, above-mentioned tetrabutyl ammonium fluoride is the lotion state of white, the Average Particle Diameters of above-mentioned zinc undecylenate
For 3 μm, the average grain diameter of above-mentioned nano zine oxide is 50nm, and above-mentioned 4- hydroxyls-PMT average grain diameter is 2 μm.
Specifically, the average grain diameter of above-mentioned hollow glass micropearl is 55 μm, and it is mainly constituted as soda lime-borosilicate glass
Glass, is shaped as white rigid spheroid.
Specifically, the preparation method of the fishing net of the high intensity includes following operating procedure：（1）By nylon 6 slice, poly- third
After alkene section, tetrabutyl ammonium fluoride mixing, drying and processing 2 hours in 50 DEG C of baking oven are put into；（2）By the material after drying and ten
Monoenoic acid zinc, nano zine oxide, 4- hydroxyls-PMT, hollow glass micropearl, aluminate coupling agent 821 are mixed, and pass through plastic extrusion
Machine melting extrusion, then through supercooling, drawing-off, winding, line processed, knitmesh, finished product.
Embodiment 3
A kind of fishing net of high intensity, it is characterised in that be made up of the component of following parts by weight：75 parts of nylon 6 slice, polypropylene are cut
40 parts of piece, 7 parts of tetrabutyl ammonium fluoride, 3 parts of zinc undecylenate, 9 parts of nano zine oxide, 4 parts of 4- hydroxyls-PMT, hollow glass are micro-
16 parts of pearl, 821 9 parts of aluminate coupling agent.
Specifically, above-mentioned tetrabutyl ammonium fluoride is the lotion state of white, the Average Particle Diameters of above-mentioned zinc undecylenate
For 4 μm, the average grain diameter of above-mentioned nano zine oxide is 50nm, and above-mentioned 4- hydroxyls-PMT average grain diameter is 3 μm.
Specifically, the average grain diameter of above-mentioned hollow glass micropearl is 55 μm, and it is mainly constituted as soda lime-borosilicate glass
Glass, is shaped as white rigid spheroid.
Specifically, the preparation method of the fishing net of the high intensity includes following operating procedure：（1）By nylon 6 slice, poly- third
After alkene section, tetrabutyl ammonium fluoride mixing, drying and processing 2 hours in 50 DEG C of baking oven are put into；（2）By the material after drying and ten
Monoenoic acid zinc, nano zine oxide, 4- hydroxyls-PMT, hollow glass micropearl, aluminate coupling agent 821 are mixed, and pass through plastic extrusion
Machine melting extrusion, then through supercooling, drawing-off, winding, line processed, knitmesh, finished product.
Comparative example 1
Without zinc undecylenate, nano zine oxide, remaining composition is identical with embodiment 1.
Comparative example 2
Without hollow glass micropearl, remaining composition is identical with embodiment 2.
Experiment：
Fishing net is made with the method provided in each embodiment and comparative example respectively, then by obtained fishing net and commercially available common
It is that fishing lines made from raw material is stretched on strength of filament instrument with nylon 6, tests fracture strength, elongation at break, test result
As shown in table 1：
The fishing net strength test results of table 1
| Project | Fracture strength（cn/dtex） | Elongation at break（%） | Flexibility |
| Embodiment 1 | 7.8 | 40.2 | Flexibility is good |
| Comparative example 1 | 7.6 | 39.4 | Flexibility is poor |
| Embodiment 2 | 8.1 | 42.4 | Flexibility is good |
| Comparative example 2 | 6.2 | 28.5 | Flexibility is good |
| Embodiment 3 | 8.2 | 42.9 | Flexibility is good |
| Control group | 6.0 | 28.9 | Flexibility is poor |
As shown in Table 1, the every excellent in mechanical performance of fishing net produced by the present invention, and pliability is preferably, the excellent quality of fishing net.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (4)
1. a kind of fishing net of high intensity, it is characterised in that be made up of the component of following parts by weight：It is 60-75 parts of nylon 6 slice, poly-
30-40 parts of propylene section, 5-7 parts of tetrabutyl ammonium fluoride, 1-3 parts of zinc undecylenate, 6-9 parts of nano zine oxide, 4- hydroxyls-PMT
2-4 parts, 11-16 parts of hollow glass micropearl, 6-9 parts of aluminate coupling agent 821.
2. the fishing net of a kind of high intensity according to claim 1, it is characterised in that above-mentioned tetrabutyl ammonium fluoride is white
Lotion state, the Average Particle Diameters of above-mentioned zinc undecylenate are 2-4 μm, and the average grain diameter of above-mentioned nano zine oxide is
50nm, above-mentioned 4- hydroxyls-PMT average grain diameter are 1-3 μm.
3. a kind of fishing net of high intensity according to claim 1, it is characterised in that above-mentioned hollow glass micropearl is averaged
Particle diameter is 55 μm, and it is mainly constituted as soda lime-borosilicate glass, is shaped as white rigid spheroid.
4. a kind of fishing net of high intensity according to claim 1, it is characterised in that the preparation of the fishing net of the high intensity
Method includes following operating procedure：（1）After nylon 6 slice, polypropylene chip, tetrabutyl ammonium fluoride are mixed, 50 DEG C are put into
Drying and processing 2 hours in baking oven；（2）By the material after drying and zinc undecylenate, nano zine oxide, 4- hydroxyls-PMT, hollow
Glass microballoon, aluminate coupling agent 821 are mixed, by plastic extruder melting extrusion, then through supercooling, drawing-off, winding, system
Line, knitmesh, finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710390580.3A CN107201029A (en) | 2017-05-27 | 2017-05-27 | A kind of fishing net of high intensity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710390580.3A CN107201029A (en) | 2017-05-27 | 2017-05-27 | A kind of fishing net of high intensity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107201029A true CN107201029A (en) | 2017-09-26 |
Family
ID=59905461
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710390580.3A Pending CN107201029A (en) | 2017-05-27 | 2017-05-27 | A kind of fishing net of high intensity |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107201029A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868991A (en) * | 2017-12-08 | 2018-04-03 | 巢湖市翔宇渔具有限公司 | A kind of fishing net with excellent toughness |
| CN109082729A (en) * | 2018-05-19 | 2018-12-25 | 巢湖市翔宇渔具有限公司 | A kind of preparation method and cleaning method of easy cleaning deodorization fishing net |
| CN110295412A (en) * | 2019-06-18 | 2019-10-01 | 安徽省六安市兴渔绳网科技有限公司 | A kind of fishing net drawing process |
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|---|---|---|---|---|
| CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
| CN102978741A (en) * | 2012-10-12 | 2013-03-20 | 杭州千岛湖茂源网业有限公司 | Manufacturing method for high-strength netting twine |
| CN103146189A (en) * | 2013-02-26 | 2013-06-12 | 上海凯赛生物技术研发中心有限公司 | Nylon modified plastic |
| CN103214842A (en) * | 2013-04-17 | 2013-07-24 | 常熟市康宝医疗器械厂 | Polypropylene-modified polyamide composite |
| CN103214841A (en) * | 2013-04-17 | 2013-07-24 | 常熟市康宝医疗器械厂 | Preparation method of polypropylene-modified polyamide composite |
| CN104788807A (en) * | 2015-03-31 | 2015-07-22 | 苏州市鼎立包装有限公司 | High-strength polypropylene packaging bag and preparation method thereof |
-
2017
- 2017-05-27 CN CN201710390580.3A patent/CN107201029A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
| CN102978741A (en) * | 2012-10-12 | 2013-03-20 | 杭州千岛湖茂源网业有限公司 | Manufacturing method for high-strength netting twine |
| CN103146189A (en) * | 2013-02-26 | 2013-06-12 | 上海凯赛生物技术研发中心有限公司 | Nylon modified plastic |
| CN103214842A (en) * | 2013-04-17 | 2013-07-24 | 常熟市康宝医疗器械厂 | Polypropylene-modified polyamide composite |
| CN103214841A (en) * | 2013-04-17 | 2013-07-24 | 常熟市康宝医疗器械厂 | Preparation method of polypropylene-modified polyamide composite |
| CN104788807A (en) * | 2015-03-31 | 2015-07-22 | 苏州市鼎立包装有限公司 | High-strength polypropylene packaging bag and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868991A (en) * | 2017-12-08 | 2018-04-03 | 巢湖市翔宇渔具有限公司 | A kind of fishing net with excellent toughness |
| CN109082729A (en) * | 2018-05-19 | 2018-12-25 | 巢湖市翔宇渔具有限公司 | A kind of preparation method and cleaning method of easy cleaning deodorization fishing net |
| CN110295412A (en) * | 2019-06-18 | 2019-10-01 | 安徽省六安市兴渔绳网科技有限公司 | A kind of fishing net drawing process |
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Application publication date: 20170926 |