CN107200389A - A kind of dyeing waste water advanced treating integral process of oxidization time in seconds - Google Patents
A kind of dyeing waste water advanced treating integral process of oxidization time in seconds Download PDFInfo
- Publication number
- CN107200389A CN107200389A CN201710505995.0A CN201710505995A CN107200389A CN 107200389 A CN107200389 A CN 107200389A CN 201710505995 A CN201710505995 A CN 201710505995A CN 107200389 A CN107200389 A CN 107200389A
- Authority
- CN
- China
- Prior art keywords
- water
- fenton
- pipeline
- waste water
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002351 wastewater Substances 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000004043 dyeing Methods 0.000 title claims abstract description 16
- 238000007254 oxidation reaction Methods 0.000 title claims description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 230000000694 effects Effects 0.000 claims abstract description 13
- 238000004062 sedimentation Methods 0.000 claims abstract description 13
- 230000001112 coagulating effect Effects 0.000 claims abstract description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 36
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 7
- -1 iron ion Chemical class 0.000 claims description 6
- 239000011790 ferrous sulphate Substances 0.000 claims description 4
- 239000010865 sewage Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001882 dioxygen Inorganic materials 0.000 claims description 2
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 2
- 238000005984 hydrogenation reaction Methods 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims 1
- 238000002474 experimental method Methods 0.000 abstract description 6
- 238000012545 processing Methods 0.000 abstract description 5
- 239000003814 drug Substances 0.000 abstract description 4
- 238000012546 transfer Methods 0.000 abstract description 3
- 239000012028 Fenton's reagent Substances 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract description 2
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000446 fuel Substances 0.000 abstract 1
- 238000001228 spectrum Methods 0.000 abstract 1
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 10
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 10
- 229960000907 methylthioninium chloride Drugs 0.000 description 10
- 230000003647 oxidation Effects 0.000 description 6
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000009303 advanced oxidation process reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/30—Nature of the water, waste water, sewage or sludge to be treated from the textile industry
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
- C02F2201/007—Modular design
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/026—Fenton's reagent
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention provides integrated Fenton reactor designed based on a kind of experiment by quick Fenton's reaction.The present invention have studied degradation effect of the Fenton's reaction to part of fuel under the conditions of being sufficiently mixed, and propose the system that dyeing waste water bio-chemical effluent is handled to fast deep first by residence spectrum instrument.The system is added into Fenton reagent by pipe-line mixer in two stage treatment technique secondary clarifier effluent pipeline, using the strong mixed effect of pipe-line mixer, mass transfer enhancement effect, to just realize being sufficiently mixed and reacting complete for Fenton medicament in the duct.And alkali lye is added in pipe end, pH is adjusted, and PAM is added, coagulating sedimentation is carried out, then discharged.The advanced treatment system, substantially reduces the time needed for traditional Fenton processing waster water process, and also eliminate it is cumbersome add pond body, saved construction cost and operation cost.
Description
Technical field
The invention belongs to technical field of sewage, and in particular to a kind of dyeing waste water depth of oxidization time in seconds
Manage integral process.
Background technology
Fenton's reaction is a kind of advanced oxidation reaction being widely known by the people, and has also had all in the processing containing organic wastewater
Many applications.Fenton's reaction mainly make use of Fe2+Ion in acid condition with H2O2Solution is contacted, and can react generation substantial amounts of
Reactive hydroxyl radical HO, and then oxidation Decomposition organic substance.Hydroxyl radical free radical has very high oxidation-reduction potential
(2.80eV), therefore can also have good removal effect for the organic matter of some difficult degradations in water body.The principle of Fenton's reaction
Shown in following reaction equation：
Fe2++H2O2→HO·+Fe3++OH-
RH+HO·→H2O+R·
And Fe3+Ion can also regenerate ferrous ion by further reacting：
Fe3++H2O2→Fe-OOH2++H+
Fe-OOH2+→HO2·+Fe2+
By experimental studies have found that, Fenton's reaction in the case where being sufficiently mixed, can complete in a short period of time reaction.
In the quick Fenton's reaction by reaction substrate of methylene blue test result indicates that, in 30s or so Fenton's reactions to methylene blue
Removal effect be basically completed.Fenton advanced treating side of the experimental result to oxidization time proposed by the present invention in seconds
Method provides theoretical foundation.
Under the present situation that current dyeing standard of drainage is improved constantly, the draining of many sewage treatment plants can not be met
New standard, thus carry mark transformation seem particularly urgent.Fenton process is as advanced oxidation processes, to the high treating effect of organic matter,
Cost is cheap, and reagent does not have toxicity in use, and generation product does not have overt toxicity yet, therefore to waste water
Advanced treating technique in be popular.But traditional Fenton technology still need build pond body carry out multi-step dosing and
Sludge is removed, it is necessary to new space and construction period.
The content of the invention
It is an object of the invention to provide a kind of dyeing waste water advanced treating integral process of oxidization time in seconds, sheet
Invention devises that a kind of mass-transfer efficiency is high, and reaction speed is fast and the Fenton reactor of oxidization time of high treating effect in seconds,
Coordinate coagulating sedimentation, the advanced treating applied to dyeing waste water.
The dyeing waste water advanced treatment process of the quick Fenton process of the oxidization time of the present invention in seconds is anti-with quick Fenton
Based on should testing, and influence of the mass transfer to reaction effect of having analyzed and researched, using water sprayer as dosing method, quick mixing
Pharmacy response and processing water body, pH terminating reactions are adjusted in delivery port, neutralize water outlet, and add at flocculant progress coagulating sedimentation
Reason, improves effluent quality.
A kind of dyeing waste water advanced treating integral process of oxidization time proposed by the present invention in seconds, specific steps are such as
Under：
(1) pending waste water is pumped into pipeline with pump first, pending wastewater flow is 1000- in control pipeline
3000m3/ h, to meet daily at least 20000 tons sewage load；
(2) first water sprayer is accessed in pipeline front end, adds the Fe of the acidifying prepared in advance2SO4Solution, control
Fe2SO4The pH value of solution is 0.5~1.5；After being sufficiently mixed, the pH value in control waste water is less than 4；First water sprayer of control is thrown
HCl dropwise Fe2SO4The speed of solution is 1~5m3Ferrous sulfate concentration is 400-800mg/L in/h, waste water；
(3) in step (2), pipeline accesses second water sprayer again afterwards, and for adding hydrogen peroxide solution, control hydrogen peroxide is dense
Spend for 25%~50%, second water sprayer adds dioxygen water speed for 1~5m3/ h, it is ensured that hydrogen peroxide dosage be 100~
250mg/L, it is the 100%~200% of COD to add equivalent, to ensure that effluent quality is up to standard；The quality of ferrous sulfate and hydrogen peroxide
Add than for 4：1~8：1；
(4) enough duct lengths are provided afterwards in step (3), control pipeline length is 50~100m, it is allowed to which water body is in pipe
30~60s can be flowed in road, it is ensured that Fenton's reaction is abundant；
(5) in step (4), pipeline accesses the 3rd water sprayer afterwards, for adding sodium hydroxide solution, for terminating reaction,
And promote iron ion to play coagulating sedimentation effect；It is 20%~40% to control concentration of sodium hydroxide solution, and the 3rd water sprayer is thrown
It is 1~5m to be hydrogenated with sodium hydroxide solution speed3Water pH value is 7~9 after/h, hydrogenation sodium hydroxide solution；
(6) PAM solution is added by the 4th water sprayer before step (5) afterwards pipe drainage mouthful, PAM solution concentrations are
8%~10%, the 4th water sprayer dispensing speed is 1~5m3/h；PAM adds rear concentration for 3~7ppm.
In the present invention, the caliber DN of pipeline described in step (1) is 1000-2000mm.
In the present invention, described in step (2) control waste water in pH value be less than 4, specially the pH value of water body be 2.5~
3.5。
The present invention has following outstanding feature and beneficial effect：
(1) the new Fenton reactor substantially reduces the time that Fenton's reaction handles dyeing waste water, changes tradition right
With the application mode of Fenton's reaction.According to experimental result, in the case of pipeline mixing sufficiently, Fenton's reaction can be complete in 30s
Into.Under conditions of being sufficiently mixed of Fenton medicament and dyeing waste water, reaction can be just basically completed in one minute.Need not
Again as the reaction time in traditional handicraft using 20 to four ten minutes, hydraulic detention time is substantially reduced
(2) the new Fenton reactor greatly reduces occupation of land face of traditional Fenton reactor in actual application
Product.In traditional Fenton reactor, multiple regulating reservoirs and dosing pond are generally required；In this reactor, pass through pipeline dosing
Device, eliminates acidification pool, dosing pond need to only arrange that a coagulative precipitation tank can complete processing after water outlet, be conducive to simultaneously
Transformed for the mark that carries for being completed waste water treatment plant.
Brief description of the drawings
Fig. 1 is process chart of the invention.
The dyeing waste water advanced treating integral process of oxidization time of the present invention in seconds, including enter liquid zone, offer medicine area I,
Reaction zone, offer medicine area II, subsequent treatment area.
It is dispensing area I near water inlet goes out, for adding Fenton examination by staying water by being pumped into pipeline
Agent.Ferrous iron solution is added first, then adds hydrogen peroxide solution, it is both acidified, to reach while adjusting inlet flow-patterm
Effect.
Intermediate conduit is reaction zone.Duct length needs to ensure that water body can flow 1-2min wherein to ensure that reaction is filled
Point.
It is dispensing area II near delivery port, to adjust pH value and add flocculant.In the design of the present invention, first throw
Plus alkali lye, then add PAM.
Delivery port connects sedimentation basin as subsequent treatment, and reactor water outlet is the supernatant of sedimentation basin.
Fig. 2 is hydrogen peroxide and the ferrous graph of a relation for adding the clearance for comparing methylene blue.
Fig. 3 is the graph of a relation of the clearance of hydrogen peroxide dosage and methylene blue under identical ferrous dosage.
Fig. 4 is that holding is added than constant, the graph of a relation of the dosage of hydrogen peroxide and the clearance of methylene blue.
Embodiment
The present invention is further illustrated below by embodiment.
Embodiment 1
Zhejiang treatment of dyeing wastewater factory employs：Preliminary sedimentation tank+biochemistry+second pond+end Fenton (catalysis oxidation)/coagulation
Depositing technology, end-o f-pipe -control employs pipeline doser, and pipeline flow is 200m3/h；Acidifying has been firstly added in pipeline opening
Copperas solution, pH is 1, and concentration is that dispensing speed is 5m3/ h, then adds hydrogen peroxide, and concentration is 30%, and dispensing speed is
3m3/ h, reaction section length is about 50m, and the reaction time is about 30s.The sodium hydroxide that concentration is 30% is added after reaction end of extent
Solution, adds speed for 3m3/h.The PAM that concentration is 8% is added in exit, coagulating kinetics are carried out.Factory's second pond goes out
Water COD is 156 ± 3mg/L, and water outlet COD can reach 68 ± 3mg/L after present invention process end-o f-pipe -control, meet GB 4287-
2012 discharge standard.
Embodiment 2
Anhui Taihu Lake certain treatment of dyeing wastewater factory of bank employs：(the catalysis of preliminary sedimentation tank+oxidation ditch+second pond+end Fenton
Oxidation)/coagulation-settlement process, end-o f-pipe -control employs pipeline doser, and pipeline flow reaches 300m3/ h, in pipeline opening first
The copperas solution of acidifying is added, pH is 1.5, concentration is that dispensing speed is 5m3/ h, then adds hydrogen peroxide, and concentration is
30%, concentration is added for 150mg/L, and reaction section length is about 100m, and the reaction time is about 50s.Added after reaction end of extent dense
The sodium hydroxide solution for 30% is spent, speed is added for 3m3/h.The PAM that concentration is 8% is added in exit, coagulation is carried out and sinks
Shallow lake is handled.Factory secondary clarifier effluent COD is 182 ± 3mg/L, and water outlet COD can reach 75 after present invention process end-o f-pipe -control
± 3mg/L, meets GB 4287-2012 discharge standard.
Embodiment 3
Guangdong treatment of dyeing wastewater factory employs：Preliminary sedimentation tank+activated sludge process+second pond+end Fenton (catalysis oxygen
Change)/coagulation-settlement process, end-o f-pipe -control employs pipeline doser, and pipeline flow reaches 250m3/ h, adds first in pipeline opening
The copperas solution of acidifying is entered, pH is 1, concentration is that dispensing speed is 3m3/ h, then adds hydrogen peroxide, and concentration is 50%,
Concentration is added for 150mg/L, reaction section length is about 80m, and the reaction time is about 50s.Adding concentration after reaction end of extent is
40% sodium hydroxide solution, adds speed for 2.5m3/h.The PAM that concentration is 8% is added in exit, coagulating sedimentation is carried out
Processing.Factory secondary clarifier effluent COD is 167 ± 3mg/L, after present invention process end-o f-pipe -control water outlet COD can reach 72 ±
3mg/L, meets GB 4287-2012 discharge standard.
Fig. 2, Fig. 3 and Fig. 4 are the experimental result picture on quick Fenton's reaction, using methylene blue as object, progress
Fenton is tested, and experiment condition is as follows：
Determine the absorbance of methylene blue at 664nm respectively using UV-detector.For the Fenton oxidation of the dyestuff
Experiment, initial pH is 2.0, and primary pollutant concentration is 10mg/L, 20 DEG C of reaction temperature.Change 1) oxidant in experiment
H2O2Dosage；2) oxidant H2O2Compare with adding for catalyst Fe SO47H2O, 8 groups of experiments carried out to methylene blue,
As shown in table 1：
The quick Fenton oxidation experiment reaction condition of the dyestuff of table 1
| Sequence number | pH | H2O2Dosage (mg/L) | n(H2O2):n(Fe2+) |
| 1 | 2.0 | 36 | 2：1 |
| 2 | 2.0 | 36 | 1：1 |
| 3 | 2.0 | 36 | 1：2 |
| 4 | 2.0 | 36 | 1：4 |
| 5 | 2.0 | 72 | 2：1 |
| 6 | 2.0 | 144 | 4：1 |
| 7 | 2.0 | 72 | 1：1 |
| 8 | 2.0 | 144 | 1：1 |
According to the 1st, 2,3,4 group of experimental result, conclusion 1 can be obtained) it is obvious that as hydrogen peroxide and ferrous iron add ratio
Increase, the reaction rate of methylene blue is progressively speeded, and can reach reaction end faster.When adding than for 2：1(A)
When, reaction is about completed in 20s or so, when adding than reaching 1：When more than 1 (B, C, D), reaction is about completed in 10s or so.
Conclusion 2 can be obtained according to the 2nd, 5,6 group of experimental result) when keeping ferrous dosage constant, as hydrogen peroxide is added
The increase of amount, reaction rate is also speeded therewith.
According to the 2nd, 7,8 group of experimental result, conclusion 3 can be obtained) when keep add than it is constant when, with the dosage of hydrogen peroxide
Increase, reaction rate also speeds therewith, and when can improve reaction end methylene blue clearance.
Iron ion (III) itself has coagulating sedimentation effect in the basic conditions in Fenton reagent, coordinates the flocculants such as PAM
Good coagulating sedimentation effect can be played, the SS and COD in water can be effectively reduced, water quality is improved out.
Claims (3)
1. the dyeing waste water advanced treating integral process of a kind of oxidization time in seconds, it is characterised in that comprise the following steps that：
（1）Pending waste water is pumped into pipeline with pump first, pending wastewater flow is 1000-3000m in control pipeline3/ h,
To meet daily at least 20000 tons sewage load；
（2）First water sprayer is accessed in pipeline front end, the Fe of the acidifying prepared in advance is added2SO4Solution, controls the pH of waste water
It is worth for 0.5 ~ 1.5；After being sufficiently mixed, the pH value in control waste water is less than 4；First water sprayer of control adds the Fe of acidifying2SO4
The speed of solution is 1 ~ 5m3Ferrous sulfate concentration is 400-800mg/L in/h, waste water；
（3）In step（2）Pipeline accesses second water sprayer again afterwards, for adding hydrogen peroxide solution, controls the hydrogen peroxide concentration to be
25% ~ 50%, second water sprayer adds dioxygen water speed for 1 ~ 5m3/ h, it is ensured that hydrogen peroxide dosage is 100 ~ 250mg/L, is thrown
Sovolin amount is the 100% ~ 200% of COD, to ensure that effluent quality is up to standard；The quality of ferrous sulfate and hydrogen peroxide is added than for 4：1~
8：1；
（4）In step（3）Enough duct lengths are provided afterwards, and control pipeline length is 50 ~ 100m, it is allowed to which water body can in pipeline
To flow 30 ~ 60s, it is ensured that Fenton's reaction is abundant；
（5）In step（4）Pipeline accesses the 3rd water sprayer afterwards, for adding sodium hydroxide solution, for terminating reaction, and promotees
Enter iron ion and play coagulating sedimentation effect；It is 20% ~ 40% to control concentration of sodium hydroxide solution, and the 3rd water sprayer adds hydroxide
Sodium solution speed is 1 ~ 5m3Water pH value is 7 ~ 9 after/h, hydrogenation sodium hydroxide solution；
（6）In step（5）PAM solution is added by the 4th water sprayer before pipe drainage mouthful afterwards, PAM solution concentrations are 8% ~
10%, the 4th water sprayer dispensing speed is 1 ~ 5m3/h；PAM adds rear concentration for 3 ~ 7ppm.
2. technique according to claim 1, it is characterised in that step（1）Described in pipeline caliber DN be 1000-
2000mm。
3. technique according to claim 1, it is characterised in that step（2）Described in control waste water in pH value be less than 4, tool
Body is that the pH value of water body is 2.5 ~ 3.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710505995.0A CN107200389B (en) | 2017-06-28 | 2017-06-28 | A kind of dyeing waste water advanced treating integral process of oxidization time in seconds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710505995.0A CN107200389B (en) | 2017-06-28 | 2017-06-28 | A kind of dyeing waste water advanced treating integral process of oxidization time in seconds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107200389A true CN107200389A (en) | 2017-09-26 |
| CN107200389B CN107200389B (en) | 2019-10-15 |
Family
ID=59907946
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710505995.0A Expired - Fee Related CN107200389B (en) | 2017-06-28 | 2017-06-28 | A kind of dyeing waste water advanced treating integral process of oxidization time in seconds |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107200389B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473453A (en) * | 2017-09-30 | 2017-12-15 | 北京中晟清源环保科技有限公司 | A kind of novel pure hydrostatic pipeline reactor |
| CN107640854A (en) * | 2017-09-25 | 2018-01-30 | 复旦大学 | A kind of dyeing waste water advanced treating integral method of oxidization time in seconds |
| CN109592813A (en) * | 2017-09-30 | 2019-04-09 | 北京中晟清源环保科技有限公司 | One type Fenton adds the integrated artistic method of air-float technology |
| CN112939279A (en) * | 2021-02-06 | 2021-06-11 | 湖州光正水质净化有限公司 | Method for automatically adjusting Fenton process parameters based on PH and ORP linkage |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011136296A (en) * | 2009-12-28 | 2011-07-14 | Shimizu Corp | Method and apparatus for decoloring colored discharge water |
| CN202717623U (en) * | 2012-08-15 | 2013-02-06 | 天津市联合环保工程设计有限公司 | Integrated Fenton reaction unit |
| CN105236625A (en) * | 2015-11-11 | 2016-01-13 | 苏州市环境保护有限公司 | Fenton printing-dyeing-wastewater deep treatment method |
| CN206014551U (en) * | 2016-08-15 | 2017-03-15 | 浙江省环境工程有限公司 | Convergent improvement type Fenton catalytic oxidation treatment system |
-
2017
- 2017-06-28 CN CN201710505995.0A patent/CN107200389B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011136296A (en) * | 2009-12-28 | 2011-07-14 | Shimizu Corp | Method and apparatus for decoloring colored discharge water |
| CN202717623U (en) * | 2012-08-15 | 2013-02-06 | 天津市联合环保工程设计有限公司 | Integrated Fenton reaction unit |
| CN105236625A (en) * | 2015-11-11 | 2016-01-13 | 苏州市环境保护有限公司 | Fenton printing-dyeing-wastewater deep treatment method |
| CN206014551U (en) * | 2016-08-15 | 2017-03-15 | 浙江省环境工程有限公司 | Convergent improvement type Fenton catalytic oxidation treatment system |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107640854A (en) * | 2017-09-25 | 2018-01-30 | 复旦大学 | A kind of dyeing waste water advanced treating integral method of oxidization time in seconds |
| CN107473453A (en) * | 2017-09-30 | 2017-12-15 | 北京中晟清源环保科技有限公司 | A kind of novel pure hydrostatic pipeline reactor |
| CN109592813A (en) * | 2017-09-30 | 2019-04-09 | 北京中晟清源环保科技有限公司 | One type Fenton adds the integrated artistic method of air-float technology |
| CN112939279A (en) * | 2021-02-06 | 2021-06-11 | 湖州光正水质净化有限公司 | Method for automatically adjusting Fenton process parameters based on PH and ORP linkage |
| CN112939279B (en) * | 2021-02-06 | 2022-10-21 | 湖州光正水质净化有限公司 | Method for automatically adjusting Fenton process parameters based on PH and ORP linkage |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107200389B (en) | 2019-10-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107200389B (en) | A kind of dyeing waste water advanced treating integral process of oxidization time in seconds | |
| CN106007221A (en) | Pharmaceutical wastewater treatment process | |
| CN204874213U (en) | Petrochemical industry waste water is with synthesizing water treatment facilities | |
| CN101698550A (en) | Advanced treating method of landfill leachate | |
| CN102452770A (en) | Biochemical treatment/advanced oxidation treatment coupled sewage treatment technique | |
| CN104355478A (en) | Printing and dyeing sewage treatment system | |
| CN104192964B (en) | A kind of sewage water treatment method based on the backflow of flocculation sedimentation tank supernatant liquor | |
| CN104860475B (en) | District drainage formula short distance nitration connects denitrification anaerobic ammoxidation and carries out the apparatus and method of sewage deep denitrogenation | |
| CN210103631U (en) | Treatment device for non-phosphate-containing total phosphorus wastewater | |
| CN106630314A (en) | Treatment system for organic matters in petrochemical sewage reverse osmosis concentrated water and treatment method thereof | |
| CN106116050A (en) | The sewage disposal system of a kind of efficient dephosphorization and processing method thereof | |
| CN204211601U (en) | Sewerage integrated processing system | |
| CN112624280A (en) | Sewage treatment device for removing SS and TP by reinforced coagulation and application | |
| CN206345748U (en) | The processing system of the reverse osmosis concentrated Organic substance in water of petrifaction sewage | |
| CN104402164A (en) | Integrated processing system and method thereof for sewage | |
| CN106587531A (en) | Treatment system and method for synthesizing type industrial park sewage | |
| CN207451707U (en) | A kind of dyeing waste water advanced treating integrated apparatus of oxidization time in seconds | |
| CN112551744A (en) | Method for treating wastewater by utilizing acidic coagulated Fenton oxidation | |
| CN208843873U (en) | A kind of oxidation equipment | |
| CN206915881U (en) | A kind of Fenton processing unit of batch (-type) waste water | |
| CN216191773U (en) | Sewage biochemical treatment system for strengthening phosphorus removal | |
| CN107640854A (en) | A kind of dyeing waste water advanced treating integral method of oxidization time in seconds | |
| CN116813082A (en) | Integrated sedimentation built-in double-mixed liquid reflux dephosphorization and denitrification device and treatment method | |
| CN112299655B (en) | Novel treatment process for aged landfill leachate | |
| CN213771494U (en) | Upflow type sewage enhanced biological phosphorus removal coupled anaerobic ammonia oxidation denitrification integrated system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20191015 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |